Citation: | Xiang Jie, Wang Xinyu. Study on Heavy Metal Migration and Optimal Allocation of Water Resources in Tailing Pond[J]. Multipurpose Utilization of Mineral Resources, 2022, 43(5): 51-57. doi: 10.3969/j.issn.1000-6532.2022.05.010 |
Based on the potential threat of heavy metal pollution from a metal tailings pond in Tongling, Anhui Province to the mining area and the surrounding underground aquifer, the leaching test analysis of soil samples, the modeling of water quality and the prediction of groundwater level were carried out. The optimal allocation scheme of water resources was proposed finally. The results showed that the leaching concentration of major heavy metal elements in the soil tended to increase with the decrease of pH value or the increase of Ca2+ concentration, while Pb elements could not be leached out. By comparing with the local background value, the leaching toxicity of heavy metal elements in the mining area was relatively low. By simulating the underground flow through the MODFLOW module, it can be concluded that it takes about 63.5 years for the dynamic balance of 80 m level to be reached after the mine is stopped discharging. The transport of shallow groundwater to the west and deep groundwater to the south and east can be obtained by simulating solute transport through MT3DMS module. Based on the above research, the optimal allocation of mine water and artificial lake water was carried out, which provided scientific basis for the utilization of water resources in Tongling Mining area and reference value for other similar mining areas.
[1] | 汤波. 陕南金属尾矿库区土壤重金属迁移规律及其环境效应研究[D]. 西安: 西安科技大学, 2017. TANG B. Study on the migration of heavy metals in soil and its environmental effects in the area of metal tailings reservoir in southern Shaanxi Province [D]. Xi 'an: Xi 'an University of Science and Technology, 2017. |
[2] | 秦玉芳, 马莹, 李娜. 白云鄂博尾矿库及其资源利用研究概况[J]. 矿产综合利用, 2020(6):100-109. doi: 10.3969/j.issn.1000-6532.2020.06.018 QIN Y F, MA Y, LI N. Study on Bayan Obo tailings reservoir and its utilization[J]. Multipurpose Utilization of Mineral Resources, 2020(6):100-109. doi: 10.3969/j.issn.1000-6532.2020.06.018 |
[3] | 田恩源, 惠博, 陈晓青. 拉拉铜矿尾矿工艺矿物学研究[J]. 矿产综合利用, 2020(3): 148-152. TIAN E Y, HUI B, CHEN X Q. Study on process mineralogy of tailings from Lala copper mine [J]. Multipurpose Utilization of Mineral Resources, 2020(3): 148-152. |
[4] | 张毅. 基于GMS的地下水溶质运移规律研究[J]. 陕西水利, 2020(7):222-224+227. doi: 10.16747/j.cnki.cn61-1109/tv.2020.07.090 ZHANG Y. Study on the law of solute transport in groundwater based on GMS[J]. Shaanxi Water Resources, 2020(7):222-224+227. doi: 10.16747/j.cnki.cn61-1109/tv.2020.07.090 |
[5] | 单士锋. 安徽铜陵某废弃金属矿山矿化围岩酸性水污染分析[J]. 资源信息与工程, 2020, 35(3):10-13. doi: 10.3969/j.issn.2095-5391.2020.03.004 SHAN S F. Analysis of acid water pollution in mineralized surrounding rock of a waste metal mine in Tongling, Anhui Province[J]. Resources Information and Engineering, 2020, 35(3):10-13. doi: 10.3969/j.issn.2095-5391.2020.03.004 |
[6] | 杨扬. 铜陵铜尾矿废弃地中参与金属硫化物氧化的微生物主要类群与分布[D]. 合肥: 安徽大学, 2014. YANG Y. The main groups and distribution of microorganisms involved in metal sulfide oxidation in the wasteland of copper tailings in Tongling [D]. Hefei: Anhui University, 2014. |
[7] | 陈艳平, 毛益林, 陈晓青, 等. 四川某铜矿选矿实验研究[J]. 矿产综合利用, 2020(2):87-90+101. doi: 10.3969/j.issn.1000-6532.2020.02.015 CHEN Y P, MAO Y L, CHEN X Q, et al. Experimental study on beneficiation of a copper mine in Sichuan Province[J]. Multipurpose Utilization of Mineral Resources, 2020(2):87-90+101. doi: 10.3969/j.issn.1000-6532.2020.02.015 |
[8] | 郭争争, 管俊芳, 陈菲, 等. 重金属对膨润土膨胀性的影响[J]. 矿产综合利用, 2020(1):203-208. doi: 10.3969/j.issn.1000-6532.2020.01.041 GUO Z Z, GUAN J F, CHEN F, et al. Effect of heavy metals on the swelling property of bentonite[J]. Multipurpose Utilization of Mineral Resources, 2020(1):203-208. doi: 10.3969/j.issn.1000-6532.2020.01.041 |
[9] | 陈铁爻, 李虹丽, 苏庆平. 低品位铁矿中铜离子的淋溶规律及环境影响[J]. 矿产综合利用, 2013(2):67-70. doi: 10.3969/j.issn.1000-6532.2013.02.018 CHEN T Y, LI H L, SU Q P. Leaching law of copper ions in low grade iron ore and its environmental impact[J]. Multipurpose Utilization of Mineral Resources, 2013(2):67-70. doi: 10.3969/j.issn.1000-6532.2013.02.018 |
[10] | 毛香菊, 刘璐, 肖芳, 等. 锍镍试金-微波消解-高分辨率连续光源石墨炉原子吸收光谱法测定岩石矿物中超痕量铂钯钌铑铱[J]. 冶金分析, 2020, 40(3):1-8. doi: 10.13228/j.boyuan.issn1000-7571.010915 MAO X J, LIU L, XIAO F, et al. Determination of ultra-trace platinum, palladium, ruthenium, rhodium and iridium in rock minerals by nickel matte assay with microwave digestion and high resolution continuous source graphite furnace atomic absorption spectrometry[J]. Metallurgical Analysis, 2020, 40(3):1-8. doi: 10.13228/j.boyuan.issn1000-7571.010915 |
[11] | HJ/T 299-2007, 固体废物. 浸出毒性浸出方法. 硫酸硝酸法[S]. HJ/T 299-2007, Solid waste. Extraction toxic leaching method. Nitric Acid Method with Sulfuric Acid [S]. |
[12] | 王春淼. 安徽铜陵典型尾矿库重金属迁移规律研究[D]. 北京: 中国地质大学(北京), 2020. WANG C M. Study on Heavy metal migration of typical tailings in Tongling, Anhui Province [D]. Beijing: China University of Geosciences (Beijing), 2020. |
[13] | 刘超. 基于改进的GM(1, 1)模型的辽宁锦州地区地下水时空预测研究[J]. 地下水, 2020, 42(2): 46-48. LIU C. Spatiotemporal prediction of groundwater in Jinzhou area of Liaoning Province based on improved GM(1, 1) model [J]. Groundwater, 2020 (2) : 46 to 48. |
[14] | 杨进忠, 毛益林, 陈晓青, 等. 某尾矿资源化处置与综合利用研究[J]. 矿产综合利用, 2019(6):117-122+156. doi: 10.3969/j.issn.1000-6532.2019.06.025 YANG J Z, MAO Y L, CHEN X Q, et al. Research on resource treatment and comprehensive utilization of tailings[J]. Multipurpose Utilization of Mineral Resources, 2019(6):117-122+156. doi: 10.3969/j.issn.1000-6532.2019.06.025 |
[15] | GB 15618-1995, 土壤环境质量标准[S]. GB 15618-1995, Soil environmental quality standard [S]. |
[16] | 张雅楠. 基于HYDRUS-MODFLOW地表水与地下水耦合模型研究[D]. 郑州: 郑州大学, 2019. ZHANG Y N. Study on coupling model of surface water and groundwater based on HYDRUS-MODFLOW [D]. Zhengzhou: Zhengzhou University, 2019. |
[17] | 王保申. 水资源的节约保护与优化配置研究[J]. 资源节约与环保, 2020(7):159. doi: 10.16317/j.cnki.12-1377/x.2020.07.123 WANG B S. Study on conservation, protection and optimal allocation of water resources[J]. Resources Conservation and Environmental Protection, 2020(7):159. doi: 10.16317/j.cnki.12-1377/x.2020.07.123 |
[18] | 万丽, 周少珍, 曾克文, 等. 安徽某铜硫矿选矿工艺优化试验研究[J]. 矿产综合利用, 2019(6):41-44. doi: 10.3969/j.issn.1000-6532.2019.06.009 WAN L, ZHOU S Z, ZENG K W, et al. Experimental study on beneficiation process optimization of a copper and sulfur ore in Anhui[J]. Multipurpose Utilization of Mineral Resources, 2019(6):41-44. doi: 10.3969/j.issn.1000-6532.2019.06.009 |
Leaching curve of pH value to heavy metal elements in soil
Leaching curve of heavy metal elements in soil under different Ca2+ conditions
Groundwater model of the Tongling basin