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Abiodun B Ogbesejana, Oluwasesan M Bello, Tijjani Ali, 2020. Origin and depositional environments of source rocks and crude oils from Niger Delta Basin: Carbon isotopic evidence, China Geology, 3, 602-610. doi: 10.31035/cg2020057
Citation: Abiodun B Ogbesejana, Oluwasesan M Bello, Tijjani Ali, 2020. Origin and depositional environments of source rocks and crude oils from Niger Delta Basin: Carbon isotopic evidence, China Geology, 3, 602-610. doi: 10.31035/cg2020057
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Origin and depositional environments of source rocks and crude oils from Niger Delta Basin: Carbon isotopic evidence

  • Department of Applied Chemistry, Federal University Dutsin-Ma, P.M.B. 5001, Dutsin-Ma, Katsina State, Nigeria

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Received Date:  22 November 2019
Revised Date:  21 July 2020
Accepted Date:  25 August 2020
Available Online:  27 October 2020
Publish Date:  25 December 2020
    Abstract

  • Thirty-nine crude oils and twenty-one rock samples from Niger Delta Basin, Nigeria have been characterized based on their isotope compositions by elemental analysis-isotope ratio mass spectrometry and gas chromatography-isotope ratio mass spectrometry. The bulk carbon isotopic values of the whole rock extracts, saturate and aromatic fractions range from –28.7‰ to –26.8‰, –29.2‰ to –27.2 ‰ and –28.5‰ to –26.7‰, respectively while the bulk carbon isotopic values of the whole oils, saturate and aromatic fractions range from –25.4‰ to –27.8‰, –25.9‰ to –28.4‰ and –23.5‰ to –26.9‰, respectively. The average carbon isotopic compositions of individual alkanes (nC12-nC33) in the rock samples range from –34.9‰ to –28.2‰ whereas the average isotopic values of individual n-alkanes in the oils range from –31.1‰ to –23.8‰. The δ13C isotope ratios of pristane and phytane in the rock samples range from –29.2‰ to –28.2‰ and –30.2‰ to –27.4‰ respectively while the pristane and phytane isotopic values range from –32.1‰ to –21.9‰ and –30.5‰ to –26.9‰, respectively. The isotopic values recorded for the samples indicated that the crude oils were formed from the mixed input of terrigenous and marine organic matter and deposited under oxic to sub-oxic condition in lacustrine-fluvial/deltaic environments. The stable carbon isotopic compositions were found to be effective in assessing the origin and depositional environments of crude oils in the Niger Delta Basin.

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  • [1] Andrusevich VE, Engel MH, Zumberge JE, Brothers LA. 1998. Secular episodic changes in stable carbon isotopic composition of crude oils. Chemical Geology, 152, 59–72. doi: 10.1016/S0009-2541(98)00096-5

    CrossRef Google Scholar

    [2] Audino M, Grice K, Alexander R, Kagi RI. 2002. Macrocyclic alkanes in crude oils from the algaenan of Botryococcus braunii. Organic Geochemistry, 33, 979–984. doi: 10.1016/S0146-6380(02)00061-X

    CrossRef Google Scholar

    [3] Cai CF, Zhang CM, Worden RH, Wang TK, Li HG, Jiang L, Huang S, Zhang B. 2015. Application of sulfur and carbon isotopes to oil–source rock correlation: A case study from the Tazhong area, Tarim Basin, China. Organic Geochemistry, 83–84, 140–152.

    Google Scholar

    [4] Chung HM, Rooney MA, Toon MB, Claypool GE. 1992. Carbon isotope composition of marine crude oils. AAPG Bulletin, 76, 1000–1007.

    Google Scholar

    [5] Clayton CJ. 1991. Effect of maturity on carbon isotope ratios of oils and condensates. Organic Geochemistry, 17, 887–899. doi: 10.1016/0146-6380(91)90030-N

    CrossRef Google Scholar

    [6] Dawson D, Grice K, Alexander R. 2005. Effect of maturation on the indigenous delta D signatures of individual hydrocarbons in sediments and crude oils from the Perth Basin (Western Australia). Organic Geochemistry, 36, 95–104. doi: 10.1016/j.orggeochem.2004.06.020

    CrossRef Google Scholar

    [7] Doust H, Omatsola E. 1990. Niger Delta divergent/passive margin basins. AAPG Memoir, 45, 201–238.

    Google Scholar

    [8] Ekweozor CM, Daukoru CM. 1994. Northern delta depobelt portion of the Akata-Agbada petroleum system, Niger Delta, Nigeria, in the petroleum system from source to trap. AAPG Memoir, 60, 599–613.

    Google Scholar

    [9] Eneogwe C, Ekundayo O. 2003. Geochemical correlation of crude oils in the NW Niger Delta. Nigeria. Journal of Petroleum Geology, 26, 95–103. doi: 10.1111/j.1747-5457.2003.tb00019.x

    CrossRef Google Scholar

    [10] Evamy BD, Haremboure J, Kamerling P, Knaap WA, Molloy FA, Rowlands PH. 1978. Hydrocarbon habitat of Tertiary Niger Delta. AAPG Bulletin, 62, 277–298.

    Google Scholar

    [11] Fuex AN. 1977. The use of stable carbon isotopes in hydrocarbon exploration. Journal of Geochemical Exploration, 7, 155–188. doi: 10.1016/0375-6742(77)90080-2

    CrossRef Google Scholar

    [12] Grice K, Audino M, Alexander R, Boreham CJ, Kagi RI. 2001. Distribution stable carbon isotopic compositions of biomarkers in torbanites from different palaeogeographical locations. Organic Geochemistry, 32, 1195–1210. doi: 10.1016/S0146-6380(01)00087-0

    CrossRef Google Scholar

    [13] Grice K, de Mesmay R, Glucina A, Wang S. 2008a. An improved and rapid 5A molecular sieve method for gas chromatography isotope ratio mass spectrometry of n-alkanes (C8-C30+). Organic Geochemistry, 39, 284–288. doi: 10.1016/j.orggeochem.2007.12.009

    CrossRef Google Scholar

    [14] Hayes TM, Freeman KH, Popp B, Hoham CH. 1990. Compound-specific isotope analyses: A novel tool for reconstruction of biogeochemical processes. Organic Geochemistry, 16, 1115–1128. doi: 10.1016/0146-6380(90)90147-R

    CrossRef Google Scholar

    [15] Hoefs J. 1987. Stable isotope geochemistry. Berlin, Springer-Verlag.

    Google Scholar

    [16] Hunt JM. 1996. Petroleum Geochemistry and Geology, 2nd End, Freeman, 1–743.

    Google Scholar

    [17] Killops SD, Killops VJ. 2005. Introduction to organic geochemistry. Second edition. U.K, Blackwell Publishing Limited.

    Google Scholar

    [18] Kulke H. 1995. Nigeria. In: Kulke H (Eds.), Regional Petroleum Geology of the World. Part II: Africa, America, Australia, and Antarctica. Berlin, Gebrüder Borntraeger, 143–172.

    Google Scholar

    [19] Lu H, Peng P, Sun Y. 2003. Molecular and stable carbon isotopic composition of monomethylalkanes from one oil sand sample: Source implications. Organic Geochemistry, 34, 745–754. doi: 10.1016/S0146-6380(03)00039-1

    CrossRef Google Scholar

    [20] Matthews DE, Hayes JM. 1978. Isotope-ratio monitoring gas Chromatography-mass spectrometry. Analytical Chemistry, 50, 1465–1473. doi: 10.1021/ac50033a022

    CrossRef Google Scholar

    [21] Murray AP, Summons RE, Boreham CJ, Dowling LM. 1994. Biomarker and normal alkane isotope profiles of Tertiary oils: Relationship to source rock depositional setting. Organic Geochemistry, 22, 521–542. doi: 10.1016/0146-6380(94)90124-4

    CrossRef Google Scholar

    [22] Ogbesejana AB, Bello OM, Tijjani, A. 2017. Occurrence and distributions of biphenyls and alkylbiphenyls as indicators of maturity in crude oils from the Tertiary Niger Delta Basin, Nigeria. FUPRE Journal of Scientific and Industrial Research, 1(2), 49–62.

    Google Scholar

    [23] Ogbesejana AB. 2018. The distributions and geochemical significance of triaromatic steroids and aromatic dinosteroids in crude oils from Niger Delta Basin. Nigeria. FUPRE Journal of Scientific and Industrial Research, 2(1), 55–70.

    Google Scholar

    [24] Ogbesejana AB, Bello OM, Uduma AU. 2018a. Characterization of source rocks from Off-shore Niger Delta Basin, Nigeria. Journal of Applied Science and Environmental Management, 22(3), 356–361.

    Google Scholar

    [25] Ogbesejana AB, Bello OM, Uduma AU. 2018b. Occurrence of biphenyl and alkylbiphenyls in source rocks from Tertiary Niger Delta Basin, Nigeria. Chem Search Journal, 9(1), 29–37.

    Google Scholar

    [26] Ogbesejana AB, Zhong NN, Sonibare OO. 2019a. The distribution and significance of dimethyldibenzothiophenes, trimethyldibenzothiophenes and benzo[b] naphthothiophenes in source rock extracts from offshore Niger Delta basin, Nigeria. Petroleum Science and Technology, 37(18), 1978-1986. doi: 10.1080/10916466.2018.1496103.

    Google Scholar

    [27] Ogbesejana AB, Sonibare OO, Ningning Z. 2019b. Occurrence and distribution of Pyrene and its derivatives in crude oils and source rock extracts from Niger Delta, Nigeria. Journal of Petroleum Science and Technology, 9(1), 3–17.

    Google Scholar

    [28] Ogbesejana AB, Sonibare OO, Ningning Z. 2019c. Occurrence and distribution of chrysene and its derivatives in crude oils and source rock extracts from Niger Delta, Nigeria. Iranian Journal of Oil and Gas Science and Technology, 8(2), 34–52.

    Google Scholar

    [29] Peters KE, Moldowan JM. 1993. The Biomarker Guide, Interpreting Molecular Fossils in Petroleum and Ancient Sediments. New Jersey, Prentice-Hall, Englewood Cliffs.

    Google Scholar

    [30] Rooney MA, Vuletich AK, Griffith CE. 1998. Compound-specific isotope analysis as a tool for characterizing mixed oils: An example from West of Shetlands area. Organic Geochemistry, 29, 241–254. doi: 10.1016/S0146-6380(98)00136-3

    CrossRef Google Scholar

    [31] Samuel OJ, Cornford C, Jones M, Adekeye OA, Akande SO. 2009. Improved understanding of the petroleum systems of Niger Delta Basin, Nigeria. Organic Geochemistry, 40, 461–483. doi: 10.1016/j.orggeochem.2009.01.009

    CrossRef Google Scholar

    [32] Schouten S, Hoefs MJL, Sinninghe Damste JS. 2000. A molecular and stable carbon isotopic study of lipids in late Quartenary sediments from the Arabian Sea. Organic Geochemistry, 31, 509–521. doi: 10.1016/S0146-6380(00)00031-0

    CrossRef Google Scholar

    [33] Schwas VF, Spangenberg JE. 2007. Molecular and isotopic characterization of biomarkers in the Frick Swiss Jura sediments: A palaeoenvironmental reconstruction on the northern Tethys margin. Organic Geochemistry, 38, 419–439. doi: 10.1016/j.orggeochem.2006.06.013

    CrossRef Google Scholar

    [34] Short KC, Stauble AJ. 1967. Outline of geology of Niger Delta. AAPG Bulletin, 51, 761–779.

    Google Scholar

    [35] Sofer Z. 1984. Stable carbon isotope compositions of crude oils: Applications to source depositional environments and petroleum alteration. AAPG Bulletin, 68, 31–49.

    Google Scholar

    [36] Sonibare OO, Alimi H, Jarvie D, Ehinola OA. 2008. Origin and occurrence of crude oil in the Niger Delta, Nigeria. Journal Petroleum Science and Engineering, 61, 99–107. doi: 10.1016/j.petrol.2008.05.002

    CrossRef Google Scholar

    [37] Stacher P. 1995. Present understanding of the Niger Delta hydrocarbon habitat. In: Oti MN, Postma G (Eds.), Geology of Deltas: Rotterdam, A.A. Balkema, 257-267.

    Google Scholar

    [38] Zhu YM, Weng HX, Su AG, Liang DG, Peng DH. 2005. Geochemical characteristics of Tertiary saline lacustrine oils in the Western Qaidam Basin, northwest China. Applied Geochemistry, 33, 1225–1240.

    Google Scholar

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