An Infrared Standard Curve Method for Calculating the Total Amount of Petroleum in Environmental Samples

AN Caixiu; LIU Shuhong; SHI Huiqing; YANG Lijuan; HE Yantao; CHEN Yang

doi:10.15898/j.cnki.11-2131/td.202111040162

2022 Vol. 41, No. 5

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AN Caixiu, LIU Shuhong, SHI Huiqing, YANG Lijuan, HE Yantao, CHEN Yang. An Infrared Standard Curve Method for Calculating the Total Amount of Petroleum in Environmental Samples[J]. Rock and Mineral Analysis, 2022, 41(5): 849-856. doi: 10.15898/j.cnki.11-2131/td.202111040162

Citation:

AN Caixiu, LIU Shuhong, SHI Huiqing, YANG Lijuan, HE Yantao, CHEN Yang. An Infrared Standard Curve Method for Calculating the Total Amount of Petroleum in Environmental Samples[J]. Rock and Mineral Analysis, 2022, 41(5): 849-856. doi: 10.15898/j.cnki.11-2131/td.202111040162

An Infrared Standard Curve Method for Calculating the Total Amount of Petroleum in Environmental Samples

1.
Hebei Research Center for Geoanalysis, Baoding 071051, China
2.
Hebei Key Laboratory of Mineral Resources and Ecological Environment Monitoring, Baoding 071051, China

More Information

Corresponding author: LIU Shuhong, 332964676@qq.com

Received Date: 04 November 2021

Revised Date: 18 March 2022

Accepted Date: 30 April 2022

Publish Date: 28 September 2022

Abstract

Abstract

BACKGROUND
Petroleum oil is one of the necessary indicators for environmental monitoring, which mainly exists in the form of hydrocarbons. Therefore, infrared spectrophotometry is one of the most reliable methods to determine the total amount of petroleum oil. At present, there are two methods for the determination of petroleum by infrared spectrophotometry, which are the three-wave number correction coefficient method and the non-dispersive single wave number standard curve method. The correction coefficient method has many calculation steps and a heavy workload; the single wave number standard curve method does not specify which wave number to use for calculation or is abandoned due to the limited scope of application.
OBJECTIVES
To establish a simple standard curve method for calculating the total amount of petroleum.
METHODS
Five kinds of oils were scanned by Fourier transform infrared (FTIR) spectroscopy. The absorbance of the three scanning wavenumbers was arranged and combined to obtain five standard curve methods. After comparing the calculated concentration with the prepared concentration, the standard curve method of the sum of three-wave number absorbance was established.
RESULTS
When the proportion of aromatic hydrocarbons was less than 50%, the calculation results of this method were consistent with those of the correction coefficient method. The precision of this method was 5.9%-8.0%, and the recovery rate of standard addition was 76.4%-98.2%, which meets the requirements of China's petroleum pollution determination and environmental standards.
CONCLUSIONS
This method expands the application scope of the standard curve method. It is simple and easy to understand and has strong operability. It is a useful supplement to the correction coefficient method.
- environmental samples /
- total amount of petroleum /
- infrared spectrophotometry /
- standard curve method of the sum of three wavenumbers

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References

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