Determination of Manganese Content in Soils and Sediments by X-ray Fluorescence Spectrometry

Chun-fei CHEN; Xin HONG; Xiao-fei WANG; Rong SU; Xiao-xi LIANG; Yu HE; Qiu LU; Yan TIAN

doi:10.15898/j.cnki.11-2131/td.201905300077

2020 Vol. 39, No. 5

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Chun-fei CHEN, Xin HONG, Xiao-fei WANG, Rong SU, Xiao-xi LIANG, Yu HE, Qiu LU, Yan TIAN. Determination of Manganese Content in Soils and Sediments by X-ray Fluorescence Spectrometry[J]. Rock and Mineral Analysis, 2020, 39(5): 777-784. doi: 10.15898/j.cnki.11-2131/td.201905300077

Citation:

Chun-fei CHEN, Xin HONG, Xiao-fei WANG, Rong SU, Xiao-xi LIANG, Yu HE, Qiu LU, Yan TIAN. Determination of Manganese Content in Soils and Sediments by X-ray Fluorescence Spectrometry[J]. Rock and Mineral Analysis, 2020, 39(5): 777-784. doi: 10.15898/j.cnki.11-2131/td.201905300077

Determination of Manganese Content in Soils and Sediments by X-ray Fluorescence Spectrometry

1.
Guangxi Zhuang Autonomous Region Ecological and Environmental Monitoring Centre, Nanning 530028, China
2.
School of Environmental Science and Engineering, Hubei Polytechnic University, Huangshi 435003, China

Received Date: 30 May 2019

Revised Date: 30 September 2019

Accepted Date: 04 June 2020

Abstract

Abstract

OBJECTIVES Due to the advantages of simple sample preparation, non-destructive determination, and rapid detection, the X-ray fluorescence spectrometry technique has become a robust method for determination of manganese in soil or sediment. Manganese in soil and sediment standard material has the maximum content of 2490mg/kg, thus the traditional X-ray fluorescence spectrometry (XRF) can easily suffer from the drawbacks of standard curve measurement range due to the limited manganese content in standard soil or sediment samples. OBJECTIVES To develop a good method for the determination of manganese in polluted soil or sediment. METHODS To address this major concern, manganese solutions were added to the commercially available soil standards in a quantitative manner to give a series of new soil standards with higher manganese content. The content of manganese can be determined by X-ray fluorescence spectrometry. RESULTS The establishment of a novel standard curve by taking advantage of these new soil standards could significantly promote the upper limit of manganese measurement from 2490mg/kg to 3780mg/kg. The analytical results of manganese were consistent with the reference value and a recovery of 97.8%-108.3%. The results of high-manganese samples were consistent with the values acquired by inductively coupled plasma-optical emission spectrometry, with the relative deviation less than 5.7% and the relative standard deviation lower than 0.4% (n=7). Conclusion Results show good accuracy and precision in the determination of high-manganese soils and sediments.
- X-ray fluorescence spectrometry /
- spiked recovery test /
- manganese /
- soil /
- sediment

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References

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