Zhengzhou Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological SciencesHost
2025 Vol. 45, No. 1
Article Contents

NING Guodong, LIU Hong, LIU Yingzhi, LI Wenming. Hydrogen−based Mineral Phase Transformation−low Intensity Magnetic Separation−reverse Flotation of an Iron Ore Abroad[J]. Conservation and Utilization of Mineral Resources, 2025, 45(1): 53-59. doi: 10.13779/j.cnki.issn1001-0076.2024.08.025
Citation: NING Guodong, LIU Hong, LIU Yingzhi, LI Wenming. Hydrogen−based Mineral Phase Transformation−low Intensity Magnetic Separation−reverse Flotation of an Iron Ore Abroad[J]. Conservation and Utilization of Mineral Resources, 2025, 45(1): 53-59. doi: 10.13779/j.cnki.issn1001-0076.2024.08.025

Hydrogen−based Mineral Phase Transformation−low Intensity Magnetic Separation−reverse Flotation of an Iron Ore Abroad

More Information
  • China's iron ore is heavily dependent on imports. In order to solve the problem of import dependence, enterprises are actively searching for available iron ore resources and developing independent innovation technologies. The hydrogen−based mineral phase conversion technology uses hydrogen or hydrogen−rich gas as a reducing agent to chemically react the ore in a suspended state and at a certain temperature, so that the weakly magnetic iron minerals in the ore are converted into strong magnetic magnetite or maghemite, and then magnetic separation is performed using magnetic differences between minerals. The iron grade of an iron ore is 52. 11%. Iron mainly exists in the form of hematite/limonite, accounting for 85. 54% of total iron. The main gangue mineral is quartz, with a content of 20. 87%. In order to determine the reasonable utilization process of the ore, the experimental study of hydrogen−based mineral phase transformation−low intensity magnetic separation−reverse flotation was carried out. The results show that when the reduction temperature is 540 ℃, the reduction time is 20 min, the reduction gas volume concentration is 25%, the reduction atmosphere V(CO)∶V(H2)=1∶3, the grinding fineness −0. 074 mm content accounts for 72%, and the magnetic field strength is1600 Gs, the magnetic concentrate iron grade is 65. 55%, and the iron recovery rate is 98. 14%. The iron in the magnetic separation concentrate mainly exists in the magnetic iron. Compared with the iron content in the magnetic iron of the raw ore, the iron content in the magnetic iron increases by about 58%, and the content of hematite/limonite decreases to 0. 20%, indicating that the weak magnetic hematite/limonite minerals are reduced to strong magnetic magnetite after the conversion of the raw ore by the hydrogen−based mineral phase, and the iron minerals are effectively recovered during the weak magnetic separation process. The magnetic separation concentrate was ground to −0. 074 mm content of 88%. After one roughing, one cleaning and one scavenging reverse flotation test, the final concentrate with iron grade of 68. 47% and recovery rate of 97. 48% was obtained. The SiO2 content was 3. 06%, which was about 18 percentage points lower than that of the raw ore. In this paper, through the process of ' hydrogen−based mineral phase transformation−low intensity magnetic separation−reverse flotation ', the experimental research on iron extraction and impurity reduction is completed. It is a suitable process for treating the ore. The process has great economic, social and environmental benefits, and improves the high−quality utilization of mineral resources. Ability, resource sustainability and market risk prevention capabilities.

  • 加载中
  • [1] 赵立群, 王春女, 张敏, 等. 中国铁矿资源勘查开发现状及供需形势分析[J]. 地质与勘探, 2020, 56(3): 635−642.

    Google Scholar

    ZHAO L Q, WANG C N, ZHANG M, et al. Current exploration status and supply−demand situation of iron ore resources in China mainland[J]. Geology and Exploration, 2022, 42(2): 67−73.

    Google Scholar

    [2] 张玉成. 中国铁矿石进口布局多元化研究—基于分散依赖性风险视角[D]. 昆明: 云南财经大学, 2023: 11−16.

    Google Scholar

    ZHANG Y C. The diversification of China's iron ore import layout study−based on the perspective of dispersed dependence risk[D]. Kun Ming: Yunnan University of Finance and Economics, 2023: 11−16.

    Google Scholar

    [3] 温子龙. 2019年中国铁矿供需现状及未来发展建议[J]. 矿产资源研究, 2020(1): 28−30.

    Google Scholar

    WEN Z L. China's iron ore supply and demand status and future development suggestions in 2019[J]. Research on Mineral Resources, 2020(1): 28−30.

    Google Scholar

    [4] 周廷波, 魏晓彤, 孙永升, 等. 菱铁矿微波磁化焙烧磁选工艺及机理研究[J]. 金属矿山, 2023(6): 107−111.

    Google Scholar

    ZHOU T B, WEI X T, SUN Y S, et al. Research on process and mechanism of microwave magnetization roasting and magnetic separation for siderite[J]. Metal Mine, 2023(6): 107−111.

    Google Scholar

    [5] 韩跃新, 张强, 孙永升, 等. 难选铁矿石矿相转化清洁高效利用技术新进展[J]. 钢铁研究学报, 2022, 34(12): 1303−1313.

    Google Scholar

    HAN Y X, ZHANG Q, SUN Y S, et al. Progress in phase transformation technology for clean and efficient utilization of refractory iron ore[J]. Journal of Iron and Steel Research, 2022, 34(12): 1303−1313.

    Google Scholar

    [6] 郭磊, 陈宏超, 高鹏, 等. 白云鄂博中贫氧化矿预富集—氢基矿相转化试验研究[J]. 金属矿山, 2023(6): 96−100.

    Google Scholar

    GUO L, CHEN H C, GAO P, et al. Study on pre−concentration and hydrogen−based phase transformation technology for medium−low grade oxidized ore of Baya Obo[J]. Metal Mine, 2023(6): 96−100.

    Google Scholar

    [7] 曾永杰, 王星. 白云鄂博中贫氧化矿氢基矿相转化—磁选试验研究[J]. 包钢科技, 2023, 49(1): 12−16.

    Google Scholar

    ZENG Y J, WANG X. Experimental Study on hydrogen−based mineral phase transformation−magnetic separation of medium−lean oxidized ore in Bayan Obo[J]. Science and Technology of Baotou Steel, 2023, 49(1): 12−16.

    Google Scholar

    [8] 韩文杰, 朱一民, 李文博, 等. 海南石碌铁矿氢基矿相转化过程中的氢还原动力学和微观结构演变[J]. 钢铁研究学报, 2022, 34(12): 1352−1360.

    Google Scholar

    HAN W J, ZHU Y M, LI W B, et al. Hydrogen reduction kinetics and microstructure evolution of Hainan Shilu iron ore during hydrogen−based ore phase transformation[J]. Journal of Iron and Steel Research, 2022, 34(12): 1352−1360.

    Google Scholar

    [9] 张淑敏, 董再蒸, 袁帅, 等. 高铁低锰矿石氢基矿相转化分选试验研究[J]. 工程科学学报, 2023, 45(12): 1997−2004.

    Google Scholar

    ZHANG S M, DONG Z Z, YUAN S, et al. Hydrogen−based phase transformation and separation of high iron and low manganese ores[J]. Chinese Journal of Engineering, 2023, 45(12): 1997−2004.

    Google Scholar

    [10] 韩跃新, 张琦, 李艳军, 等. 海南石碌铁矿石氢基矿相转化新技术研究及应用[J]. 中国矿业大学学报, 2022, 51(3): 538−548.

    Google Scholar

    HAN Y X, ZHANG Q, LI Y J, et al. Research and application of a new hydrogen−based phase transformation technology for Hainan−Shilu iron ore[J]. Journal of China University of Mining & Technology, 2022, 51(3): 538−548.

    Google Scholar

  • 加载中
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Figures(8)

Tables(8)

Article Metrics

Article views(118) PDF downloads(19) Cited by(0)

Access History

Other Articles By Authors

Catalog

    /

    DownLoad:  Full-Size Img  PowerPoint