Citation: | NING Guodong, LIU Hong, LIU Yingzhi, LI Wenming. Hydrogen−based Mineral Phase Transformation−low Intensity Magnetic Separation−reverse Flotation of an Iron Ore Abroad[J]. Conservation and Utilization of Mineral Resources, 2025, 45(1): 53-59. doi: 10.13779/j.cnki.issn1001-0076.2024.08.025 |
China's iron ore is heavily dependent on imports. In order to solve the problem of import dependence, enterprises are actively searching for available iron ore resources and developing independent innovation technologies. The hydrogen−based mineral phase conversion technology uses hydrogen or hydrogen−rich gas as a reducing agent to chemically react the ore in a suspended state and at a certain temperature, so that the weakly magnetic iron minerals in the ore are converted into strong magnetic magnetite or maghemite, and then magnetic separation is performed using magnetic differences between minerals. The iron grade of an iron ore is 52. 11%. Iron mainly exists in the form of hematite/limonite, accounting for 85. 54% of total iron. The main gangue mineral is quartz, with a content of 20. 87%. In order to determine the reasonable utilization process of the ore, the experimental study of hydrogen−based mineral phase transformation−low intensity magnetic separation−reverse flotation was carried out. The results show that when the reduction temperature is 540 ℃, the reduction time is 20 min, the reduction gas volume concentration is 25%, the reduction atmosphere V(CO)∶V(H2)=1∶3, the grinding fineness −0. 074 mm content accounts for 72%, and the magnetic field strength is
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Raw ore XRD pattern
Effect of reduction temperature on magnetic separation index
Effect of reduction time on magnetic separation index
Effect of volume concentration of reducing gas on magnetic separation index
Effect of different reducing atmosphere on the separation index
Effect of grinding fineness on separation index
XRD analysis results of main products
Reverse flotation flow chart