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WANG Zhenzhen, LI Jinxiao, ZHANG Ke, MA Jialiang, ZHANG Shaowei, Blokhin MaksimG, ZHANG Piaopiao, LIN Jingyan, SUN Mingxiao, SHEN Weigang, ZHAO Cunliang. 2021. Distribution and occurrence of rare earth elements in No.15 coal in Shouyangshan Mine, Qinshui Coalfield, Shanxi Province and its indication to the coal-forming environment[J]. Geology in China, 48(3): 777-784. doi: 10.12029/gc20210308
Citation: WANG Zhenzhen, LI Jinxiao, ZHANG Ke, MA Jialiang, ZHANG Shaowei, Blokhin MaksimG, ZHANG Piaopiao, LIN Jingyan, SUN Mingxiao, SHEN Weigang, ZHAO Cunliang. 2021. Distribution and occurrence of rare earth elements in No.15 coal in Shouyangshan Mine, Qinshui Coalfield, Shanxi Province and its indication to the coal-forming environment[J]. Geology in China, 48(3): 777-784. doi: 10.12029/gc20210308
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Distribution and occurrence of rare earth elements in No.15 coal in Shouyangshan Mine, Qinshui Coalfield, Shanxi Province and its indication to the coal-forming environment

  • 1.

    Department of Geoscience and Engineering, Hebei University of Engineering, Handan 056038, Hebei, China

  • 2.

    Department of Environmental Analytical Chemistry, Institute for Atmospheric and Environmental Sciences, Goethe-University Frankfurt am Main, Frankfurt am Main, 60438 Germany

  • 3.

    Shanxi Institute of Geology and Mineral Resources, Taiyuan 030000, Shanxi, China

  • 4.

    Far East Geological Institute, Russian Academy of Sciences Far Eastern Branch, Vladivostok 690022, Russia

    • Fund Project: Funded by the Natural Science Foundation of Hebei Province (No.D2016402104) and Science and Technology Research Project of Higher Education of Hebei Province (No.BJ2017022)
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  • Author Bio: WANG Zhenzhen, female, born in 1995, master candidate, engaged in lithium isotope in coal; E-mail: wzz90620512@163.com
  • Corresponding author: ZHAO Cunliang, male, born in 1982, professor, engaged in research of coal geochemistry; Email: Zhaocunliang@hebeu.edu.cn
Received Date:  23 February 2020
Revised Date:  20 May 2020
Publish Date:  25 June 2021
    Abstract

  • Inductively coupled plasma mass spectrometry (ICP-MS) and X-ray fluorescence (XRF) were used to quantitatively analyze rare earth elements of the No. 15 Coal in Changzhi Shouyang Mine, Qinshui Coalfield for discussing its enrichment mechanism, distribution pattern, occurrence state and coal-forming environment. The results show that the average content of rare earth elements in the coal seam of the study area is 49.28 μg/g, and the overall content is relatively low. Except for SYS15-2, the rare earth elements of No.15 coal seam and gangue are all enriched in light rare earth (LREY), and the accumulation of light rare earth in gangue is more obvious. Rare earth elements occur mainly in clay minerals. On the whole, the coal-forming environment is dominated by weak reduction environment, and the source of rare earth elements is mainly terrigenous debris.

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    • References
  • An Yonglong, Huang Yong, Zhang Yanling, Qu Xueyan. 2020. Bioavailability and source analyses of Se-enriched soil in the south of Fangshan district, Beijing[J] Geological Bulletion of China, 39(2/3): 387-399 (in Chinese with English abstract).

    Google Scholar

    Boynton W V. 1984. Cosmoehemistry of the rare earth elements: Meteorites studies[J]. Development in Geochemistry, 63-114.

    Google Scholar

    Chen Song, Gui Herong, Sun Linhua, Liu Xianghong, Ma Yanping. 2011. Geochemical characteristics of REE in limestone of Jiudingshan Formation, northern Anhui Province and their constraint on the seawater[J]. Geology in China, 38(3): 664-672(in Chinese with English abstract).

    Google Scholar

    Cun Xiaonan, Huang Wenhui, Ao Weihua, Zhou Hongpu, Liang Fei. 2016. Study on the geochemistry of rare earth elements in the Permian coal from Xiayukou, Weibei Coalfieid[J]. Earth Science Frontiers, 23(3): 90-96(in Chinese with English abstract).

    Google Scholar

    Dai S F, Ren D Y, Chou C L, Finkelman R B, Seredin V V, Zhou Y P. 2012. Geochemistry of trace elements in Chinese coals: A review of abundances, genetic types, impacts on human health, and industrial utilization[J]. International Journal of Coal Geology, 94: 3-21. doi: 10.1016/j.coal.2011.02.003

    CrossRef Google Scholar

    Dai S F, Ren D Y. 2012. Geochemistry of trace elemnts in Chise coals: A review of abundances, genetic types, impacts on human health, and industrical utilization[J]. International Journal of Coal Geology, 94: 3-21(in Chinese). doi: 10.1016/j.coal.2011.02.003

    CrossRef Google Scholar

    Dai Shifeng, Ren Deyi, Li Shengsheng. 2003. Models of occurrence of rare earth elements in some Late Paleozoic Coals of North China[J]. Acta Geoscientica Sinica, (3): 273-278(in Chinese with English abstract).

    Google Scholar

    Finkelman R B. 1993. Trace and Minor Elements in Coal[M]. New York: Plenum, 593-607.

    Google Scholar

    Guo Jangfeng, Yao Duoxi, Chen Jian, Chen Ping. 2016. Geochemistry of the rare earth elements of coals from the Longtan Formation in Chongqig and its geological implication[J]. Earth Science Frontiers, 23(3): 51-58(in Chinese with English abstract).

    Google Scholar

    Herrmann A G, Pottsm J, Knake D. 1974. Geochemistry of the earth element in spilites from oceanic and continental crust[J]. Contributions Mineralogy and Petrology, 44: 1-66. doi: 10.1007/BF00373128

    CrossRef Google Scholar

    Huang Shusen. 2019. Rocks and coal seams correlation and coal accumulation environment analysis in Yangtouya general exploration area, Shouyang County, Qinshui Coalfield[J]. Coal Geology of China, 31(6): 23-28(in Chinese with English abstract).

    Google Scholar

    Huang W H, Yang Q, Tang D Z, Tang X Y, Zhao Z G. 2000. Rare earth element geochemistry of Late Palaeozoic coals in North China[J]. Acta Geologica Sinica, 74(1): 74-83.

    Google Scholar

    Ketris M P, Yudovich Y E. 2009. Estimations of Clarkes for carbonaceous biolithes World averages for trace element contents in black shales and coals[J]. International Journal of Coal Geology, 78: 135-148. doi: 10.1016/j.coal.2009.01.002

    CrossRef Google Scholar

    Li Weiwei, Tang Yuegang. 2013. Characteristics of the rare earth elements in a high organic sulfur coal from Chenxi, Hunan Province[J]. Journal of Fuel Chemistry and Technology, 41(5): 540-549(in Chinese with English abstract).

    Google Scholar

    Lin Longbin. 2108. REE geochemical features of main mineable coal seams in Northern Hedong coalfield[J]. Coal Geology of China, 30(11): 18-23(in Chinese with English abstract).

    Google Scholar

    Liu B J, Zhao C L, Ma J L, Sun Y Z, Püttmann W. 2018. The origin of pale and dark layers in Pliocene lignite deposits from Yunnan Province, Southwest China, based on coal petrological and organic geochemical analyses[J]. International Journal of Coal Geology, 195: 172-188. doi: 10.1016/j.coal.2018.06.003

    CrossRef Google Scholar

    Lü Wensheng. 2018. Geochemical characteristics of rare earth elements No. 2 Coal in Xiangning Mine, Hedong coalfield, Shanxi Province[J]. Huabei Land and Resources, (4): 18-21, 24(in Chinese with English abstract).

    Google Scholar

    Murray R W, Brink M R, Jones D L, Gerlach D C, Russ G P. 1990. Rare earth Elements as indications of different marine depositional Environments in chert and shale[J]. Geology, 18(3): 268-271. doi: 10.1130/0091-7613(1990)018<0268:REEAIO>2.3.CO;2

    CrossRef Google Scholar

    Qin Yong, Wang Wenfeng, Li Zhuangfu, Xia Xiaohong, Wu Yanyan. 2008. High-resolution coal facies sequence and peat paleo-Bog pattern during the Transgression[J]. Acta Geologica Sinica, 82(2): 234-246(in Chinese with English abstract).

    Google Scholar

    Qin Yong, Yi Tongsheng. 2010. Enrichment of rare earth elemenfs in high sulfur coal of Liangshan Formation from Kaili, Guizhou, China and Geological Origin[J]. Acta Geologica Sinica, 84(2): 280-285(in Chinese with English abstract). doi: 10.1111/j.1755-6724.2010.00086.x

    CrossRef Google Scholar

    Ren Deyi, Zhao Fenghua, Dai shifeng, Zhang Junying. 2006. Trace Element Geochemistry of Coal[M]. Beijing: Science Press, 1-556(in Chinese).

    Google Scholar

    Seredin V V, Dai S F. 2012. Coal deposits as potential alternative sources for lanthanides and yttrium[J]. International Journal of Coal Geology, 94: 67-93. doi: 10.1016/j.coal.2011.11.001

    CrossRef Google Scholar

    Seredin V V. 1996. Rare earth elements bearing coals from the Russian Far East deposits[J]. International Journal Coal Geology, 30 (2): 101-129.

    Google Scholar

    Seredin V, Dai S F. 2012. Coal deposits as potential alternative sources for lanthanides and yttrium[J]. International Journal of Coal Geology, 94(5): 67-93(in Chinese).

    Google Scholar

    Shao Longyi, Xiao Zhenghui, He Zhiping, liu Yongfu, Shang Lujun, Zhang Pengfei. 2006. Palaeogeography and coal accumulation for coal measures of the Carboniferous-Permian in Qinshui Basin, sourtheasten Shanxi Province[J]. Journal of Palaeogeography(Chinese Edition), 8(1): 43-52(in Chinese with English abstract).

    Google Scholar

    Sun Yuzhuang, Zhao Cunliang, Li Yanheng, Wang Jinxi. 2014. Minimum mining grade of the selected trace elements in Chinese coal[J]. Journal of China Coal Society, 39(4): 744-748(in Chinese with English abstract).

    Google Scholar

    Taylor R S, Mclennan S M. 1985. The Continental Crust: Its Composition and Evolution[M]. Oxford: Blackwell, 312.

    Google Scholar

    Wang Wenfeng, Qin Yong, Sang Shuxun, Zhu Yanming, Wang Chaoyong, Dominik J Weiss. 2008. Geochemistry of rare earth elements in a marine influenced coal and its organic solvent extracts from the Antaibao mining district, Shanxi, China[J]. International Journal of Coal Geology, 76(4): 309-317. doi: 10.1016/j.coal.2008.08.012

    CrossRef Google Scholar

    Wei Rongzhu, Zhuang Qitian, Yan Jiyuan, Wei Yunfeng, Du Yanwei, Fan Junhui. 2020. The stratigraphic division, sedimentary environment, climate and lake evolution of the late Cenozoic in jinzhong basin, Shanxi Province[J]. Geology in China, 1-19. http://kns.cnki.net/kcms/detail/11.1167.P.20200417.1116.002.html (in Chinese with English abstract).

    Google Scholar

    Wu Dun, Sun Ruoyu, Liu Guijian. 2013. Characteration of REY geochemistry of the Permian coals from the Zhuji coal mine, Huainan coalfield and its geological implication[J]. Acta Geologica Sinica, 87(8): 1158-1163(in Chinese with English abstract).

    Google Scholar

    Xu Naizheng, Kuang Fuxiang, Ye Juan, Zhang Linxi, Wei Xinxiang, Zeng Wenle, Zhong Qilong. 2020. Evaluation of natural radioactivity level of coal-bearing rock series in east China[J], Geology in China, 1-16 http://kns.cnki.net/kcms/detail/11.1167.P.20200109.1805.002.html (in Chinese with English abstract).

    Google Scholar

    Yang Guang. 2011. Evolution of sedimentary environment of coal bearing strata in Taiyuan Formation, Shouyang field[J]. Coal, 20(7): 48-50(in Chinese with English abstract).

    Google Scholar

    Zhang Guotao, Peng Zhongqin, Wang Chuanshan, Li Zhihong. 2016. Geochemical characteristics of the Lower Permian Liangshan Formation in Dushan area of Guizhou Province and their implications for the paleoenvironment[J]. Geology in China, 43(4): 1291-1303(in Chinese with English abstract).

    Google Scholar

    Zhang Yufen, Li Changan, Xiu Deqiang, Zhang Dai, Wang Jietao, Sun Xilin, Hu Xulong. 2020. The characteristics of rare earth elements and its paleoclimatic environmental significance in Wushan loess of the three gorges of the Yangtze river[J]. Geology in China, http://kns.cnki.net/kcms/detail/11.1167.P.20200421.1251.004.html (in Chinese with English abstract).

    Google Scholar

    Zhao C L, Liu B J, Ma J L, Liu S M, Blokhin M.G. 2017. Occurrence of rubidium and cesium in Iqe coal, Qinghai-Tibet Plateau: Evidence from sequential chemical extraction experiment[J]. Energy Exploration & Exploitation, 35(3): 376-387.

    Google Scholar

    Zhao C L, Liu B J, Xiao L, Li Y H, Liu S M, Li Z S, Sun Y Z. 2017. Significant enrichment of Ga, Rb, Cs, REEs and Y in the Jurassic No. 6 coal in the Iqe Coalfield, northern Qaidam Basin, China-A hidden gem[J]. Ore Geology Reviews, 83: 1-13. doi: 10.1016/j.oregeorev.2016.12.012

    CrossRef Google Scholar

    Zhao Cunliang. 2015. Distribution and Enrichment Mechanism of Multimetallic Elements Associated with Coal in Ordos Basin[D]. China University of Mining and Technology, Beijing, 1-145(in Chinese with English abstract).

    Google Scholar

    Zhao Zhigen. 2000. Effect of different Chondrite on the Parameter of Rare earth Elements[J]. Reporting of Standardization, 21(3): 15-16(in Chinese with English abstract)

    Google Scholar

    Zhao Zhigen. 2002. Geochemical Study of Rare Earth Elements in Coal-bearing Rocks[M]. Beijing: China Coal Industry Publishing House, 60-67(in Chinese).

    Google Scholar

    Zou Jianhua, Liu Dong, Tian Heming. 2013. Geochemistry of trace and rare earth elements in the Late Paleozoic Coal from Adaohai Mine, Inner Mongolia[J]. Journal of China Coal Society, 38(6): 1012-1019(in Chinese with English abstract).

    Google Scholar

    安永龙, 黄勇, 张艳玲, 曲雪妍. 2020. 北京房山南部地区富硒土壤生物有效性特征及来源[J]. 地质通报, 39(2/3): 387-399.

    Google Scholar

    陈松, 桂和荣, 孙林华, 刘向红, 马艳平. 2011. 皖北九顶山组灰岩稀土元素地球化学特征及对古海水的制约[J]. 中国地质, 38(3): 664-672. doi: 10.3969/j.issn.1000-3657.2011.03.014

    CrossRef Google Scholar

    崔晓南, 黄文辉, 敖卫华, 周鸿璞, 梁飞. 2016. 渭北煤田下峪口矿二叠纪煤中稀土元素地球化学研究[J]. 地学前缘, 23(3): 90-96.

    Google Scholar

    代世峰, 任德贻, 李生盛. 2003. 华北若干晚古生代煤中稀土元素的赋存特征[J]. 地球学报, (3): 273-278. doi: 10.3321/j.issn:1006-3021.2003.03.013

    CrossRef Google Scholar

    郭江峰, 姚多喜, 陈健, 陈萍. 2016. 重庆龙潭组煤中稀土元素地球化学及地质成因分析[J]. 地学前缘, 23(3): 51-58.

    Google Scholar

    黄树森. 2019. 沁水煤田寿阳县羊头崖详查区煤系地层对比及聚煤环境分析[J]. 中国煤炭地质, 31(6): 23-28. doi: 10.3969/j.issn.1674-1803.2019.06.05

    CrossRef Google Scholar

    李薇薇, 唐跃刚. 2013. 湖南辰溪特高有机硫煤的稀土元素特征及其成因[J]. 燃料化学学报, 41(5): 540-549. doi: 10.3969/j.issn.0253-2409.2013.05.004

    CrossRef Google Scholar

    林龙斌. 2018. 河东煤田北部主采煤中稀土元素地球化学特征[J]. 中国煤炭地质, 30(11): 18-23. doi: 10.3969/j.issn.1674-1803.2018.11.05

    CrossRef Google Scholar

    吕文生. 2018. 乡宁矿区2号煤稀土元素地球化学特征[J]. 华北国土资源, (4): 18-21, 24. doi: 10.3969/j.issn.1672-7487.2018.04.009

    CrossRef Google Scholar

    秦勇, 王文峰, 李壮福, 夏筱红, 吴艳艳. 2008. 海侵作用影响下的高分辨煤相序列及其古泥炭沼泽发育模式: 以山西北部安太堡上石炭统太原组11号煤层为例[J]. 地质学报, 82(2): 234-246. doi: 10.3321/j.issn:0001-5717.2008.02.009

    CrossRef Google Scholar

    秦勇, 易同生. 2010. 贵州凯里梁山组高硫煤中稀土元素的富集及其地质成因[J]. 地质学报, 84(2): 280-285.

    Google Scholar

    邵龙义, 肖正辉, 何志平, 刘永福, 尚潞君, 张鹏飞. 2006. 晋东南沁水盆地石炭二叠纪含煤岩系古地理及聚煤作用研究[J]. 古地理学报, 8(1): 43-52. doi: 10.3969/j.issn.1671-1505.2006.01.005

    CrossRef Google Scholar

    孙玉壮, 赵存良, 李彦恒, 王金喜. 2014. 煤中某些伴生金属元素的综合利用指标探讨[J]. 煤炭学报, 39(4): 744-748.

    Google Scholar

    魏荣珠, 庄其天, 闫纪元, 魏云峰, 杜艳伟, 范俊辉. 2020. 山西晋中盆地晚新生代地层划分、沉积环境及其先秦以来气候和湖泊演化[J]. 中国地质, 1-19. http://kns.cnki.net/kcms/detail/11.1167.P.20200417.1116.002.html.

    Google Scholar

    吴盾, 孙若愚, 刘桂建. 2013. 淮南朱集井田二叠纪煤中稀土元素地球化学特征及其地质解释[J]. 地质学报, 87(8): 1158-1163. doi: 10.3969/j.issn.0001-5717.2013.08.010

    CrossRef Google Scholar

    许乃政, 匡福祥, 叶隽, 张麟熹, 魏信祥, 曾文乐, 钟启龙. 2020. 华东地区含煤岩系天然放射性水平评价[J]. 中国地质, 1-16 http://kns.cnki.net/kcms/detail/11.1167.P.20200109.1805.002.html.

    Google Scholar

    杨光. 2011. 试论首阳井田太原组含煤地层沉积环境的演化[J]. 煤, 20(7): 48-50.

    Google Scholar

    张国涛, 彭中勤, 王传尚, 李志宏. 2016. 贵州独山下二叠统梁山组地球化学特征及其沉积环境意义[J]. 中国地质, 43(4): 1291-1303.

    Google Scholar

    张玉芬, 李长安, 熊德强, 张岱, 王节涛, 孙习林, 胡绪龙. 2020. 长江三峡巫山黄土稀土元素特征及古气候环境意义[J]. 中国地质, http://kns.cnki.net/kcms/detail/11.1167.P.20200421.1251.004.html.

    Google Scholar

    赵存良. 2015. 鄂尔多斯盆地与煤伴生多金属元素的分布规律和富集机理[D]. 北京: 中国矿业大学, 1-145.

    Google Scholar

    赵志根. 2000. 不同球粒陨石平均值对稀土元素参数的影响-兼论球粒陨石标准[J]. 标准化报道, 21(3): 15-16.

    Google Scholar

    赵志根. 2002. 含煤岩系稀土元素地球化学研究[M]. 北京: 煤炭工业出版社, 60-67.

    Google Scholar

    邹建华, 刘东, 田和明, 等. 2013. 内蒙古阿刀亥矿晚古生代煤的微量元素和稀土元素地球化学特征[J]. 煤炭学报38(6): 1012-1019.

    Google Scholar

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