2021 Vol. 48, No. 2
Article Contents

YU Tao, JIANG Tianyu, LIU Xu, MA Xudong, YANG Zhongfang, HOU Qingye, XIA Xueqi, LI Fengyan. 2021. Research progress in current status of soil heavy metal pollution and analysis technology[J]. Geology in China, 48(2): 460-476. doi: 10.12029/gc20210208
Citation: YU Tao, JIANG Tianyu, LIU Xu, MA Xudong, YANG Zhongfang, HOU Qingye, XIA Xueqi, LI Fengyan. 2021. Research progress in current status of soil heavy metal pollution and analysis technology[J]. Geology in China, 48(2): 460-476. doi: 10.12029/gc20210208

Research progress in current status of soil heavy metal pollution and analysis technology

    Fund Project: Supported by the geological survey achievement conversion foundation of China University of Geosciences (Beijing) and the Program of China Geological Survey (No. DD20190524-06)
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  • Author Bio: YU Tao, male, born in 1979, associate professor, mainly engaged in ecogeochemistry teaching and research; E-mail: yutao@cugb.edu.cn
  • Corresponding author: YANG Zhongfang, female, born in 1961, PhD supervisor, mainly engaged in ecogeochemistry teaching and research; E-mail: yangzf@cugb.edu.cn 
  • Soil heavy metal pollution is currently the most prominent soil environmental pollution problem in China. The total national soil pollution exceedance rate is 16.1%, mainly heavy metal pollution, including cadmium point exceedance rate of 7%, which is threatening on the food security. We introduced the status of soil heavy metal pollution, sorted the traditional and emerging methods and technologies of soil heavy metal pollution detection and analysis, and described the technical trends such as the detection of heavy metals at the molecular level and the application of biosensing technology to the detection of heavy metals. Considering the complexity of the soil system, the focus of future development should be to achieve the intersection of geoscience, chemistry, and biology, strengthen the theoretical research on the bioavailability of heavy metals, form a biological effectiveness analysis and detection indicators for soil heavy metals pollution, and make the evaluation method scientific, standardized, and unified. Make further efforts to promote integration of national heavy metals analysis standards with international standards.

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  • Arai Yuji, Elzinga Evert J, Sparks Donald L. 2001. X-ray absorption spectroscopic investigation of arsenite and arsenate adsorption at the aluminum oxide-water interface[J]. Journal of Colloid and Interface Science, 235(1): 80-88. doi: 10.1006/jcis.2000.7249

    CrossRef Google Scholar

    Bao Liran, Deng Hai, Jia Zhongmin, Li Yu, Dong Jinxiu, Yan Mingshu, Zhang Fenglei. 2020. Ecological and health risk assessment of heavy metals in farmland soil of northwest Xiushan, Chongqing[J]. Geology in China, 47(6): 1625-1636(in Chinese with English abstract).

    Google Scholar

    Brown Gordon, Calas Georges. 2012. Mineral-aqueous solution interfaces and their impact on the environment[J]. Geochemical Perspectives, 1(4/5): 483-742.

    Google Scholar

    Chen Huamain, Zheng Chunrong, Tu Cong, Zhu Yongguan. 1999. Heavy metal pollution in soils in China: Status and countermeasures[J]. Ambio, 28(2): 130-134.

    Google Scholar

    Cheng Hangxin, Li Min, Zhao Chuandong, Li Kuo, Peng Min, Qin Aihua, Cheng Xiaomeng. 2014. Overview of trace metals in the urban soil of 31 metropolises in China[J]. Journal of Geochemical Exploration, 139: 31-52. doi: 10.1016/j.gexplo.2013.08.012

    CrossRef Google Scholar

    Cheng Hangxin, Yang Zhongfang, Xi Xiaohuan, Zhao Chuandong, Xie Xuejin. 2008. A new round of global geochemical mapping: Opportunity and challenge to China[J]. Earth Science Frontiers, 15(5): 9-22. doi: 10.1016/S1872-5791(09)60001-4

    CrossRef Google Scholar

    Cheng Shuiping. 2003. Heavy metal pollution in China: Origin, pattern and control[J]. Environmental Science and Pollution Research, 10(3): 192-198. doi: 10.1065/espr2002.11.141.1

    CrossRef Google Scholar

    China Geological Survey. 2005. DD2005-03 Technical Requirements for Sample Analysis of Ecological Geochemical Assessment[S]. Beijing, September, 2005(in Chinese).

    Google Scholar

    CNEPA, MLR. 2014. The Bulletin of National Survey on Soil Pollution Status[EB/OL]. (2014-04-17)[2020-10-12]. https://www.mee.gov.cn/gkml/sthjbgw/qt/201404/W020140417558995804588.pdf (in Chinese).

    Google Scholar

    Cui Xingtao, Wang Xueqiu, Luan Wenlou. 2015. An analysis of modes of occurrence and biological availability of the heavy metal elements in soil of the central and southern plain in Hebei[J]. Geology in China, 42(2): 655-663(in Chinese with English abstract).

    Google Scholar

    Dai Yunchao, Nasir Mubasher, Zhang Yulin, Wu Haiming, Guo Honghong, Lü Jialong. 2017. Comparison of DGT with traditional methods for assessing cadmium bioavailability to Brassica chinensis in different soils[J]. Scientific Reports, 7(1): 14206. doi: 10.1038/s41598-017-13820-3

    CrossRef Google Scholar

    Duan Yiren, Yang Zhongfang, Yu Tao, Yang Qiong, Liu Xu, Ji Wenbing, Jiang Hongyu, Zhuo Xiaoxiong, Wu Tiansheng, Qin Jianxun, Wang Lei. 2020. Geogenic cadmium pollution in multi-medians caused by black shales in Luzhai, Guangxi[J]. Environmental Pollution, 260: 113905. doi: 10.1016/j.envpol.2019.113905

    CrossRef Google Scholar

    Fedotov Petr S., Kördel Werner, Miró Manuel, Peijnenburg Willie J G M, Wennrich Rainer, Huang Panming. 2012. Extraction and fractionation methods for exposure assessment of trace metals, metalloids, and hazardous organic compounds in terrestrial environments[J]. Critical Reviews in Environmental Science and Technology, 42(11): 1117-1171. doi: 10.1080/10643389.2011.556544

    CrossRef Google Scholar

    Gankhurel Baasansuren, Fukushi Keisuke, Akehi Akitoshi, Takahashi Yoshio, Zhao Xiaolan, Kawasaki Kazuo. 2020. Comparison of chemical speciation of lead, arsenic, and cadmium in contaminated soils from a historical mining site: Implications for different mobilities of heavy metals[J]. ACS Earth and Space Chemistry, 4(7): 1064-1077. doi: 10.1021/acsearthspacechem.0c00087

    CrossRef Google Scholar

    Gao Yanxin, Feng Jinguo, Tang Lei, Zhu Xianfang, Liu Wenqing, Ji Hongbing. 2012. Fraction distribution and risk sssessment of heavy metals in iron and gold mine soil of Miyun Reservoir upstream[J]. Chinese Journal of Environmental Science, 33(5): 1707-1717(in Chinese with English abstract).

    Google Scholar

    Gu Qiubei, Yang Zhongfang, Yu Tao, Ji Junfeng, Hou Qingye, Zhang Qizuan. 2019a. Application of ecogeochemical prediction model to safely exploit seleniferous soil[J]. Ecotoxicology and Environmental Safety, 177: 133-139. doi: 10.1016/j.ecoenv.2019.03.084

    CrossRef Google Scholar

    Gu Qiubei, Yu Tao, Yang Zhongfang, Ji Junfeng, Hou Qingye, Wang Lei, Wei Xueji, Zhang Qizuan. 2019b. Prediction and risk assessment of five heavy metals in maize and peanut: A case study of Guangxi, China[J]. Environmental Toxicology and Pharmacology, 70: 103199. doi: 10.1016/j.etap.2019.103199

    CrossRef Google Scholar

    Guo Xiaoxiao, Liu Congqiang, Zhu Zhaozhou, Wang Zhongliang, Li Jun. 2011. Evaluation methods for soil heavy metals contamination: A review[J]. Chinese Journal of Ecology, 30(5): 889-896(in Chinese with English abstract).

    Google Scholar

    Han Chunmei, Wang Linshan, Gong Zongqiang, Xu Huaxia. 2005. Chemical forms of soil heavy metals and their environmental significance[J]. Chinese Journal of Ecology, 24(12): 1499-1502(in Chinese with English abstract).

    Google Scholar

    He Bin, Jiang Guibin. 2002. Methods of pretreatment in mercury speciation analysis[J]. Journal of Instrumental Analysis, 21(1): 89-94(in Chinese with English abstract).

    Google Scholar

    Hou Qihui, Ma Anzhou, Zhuang Xuliang, Zhuang Guoqiang. 2013. Advance in the bioavailability monitoring of heavy metal based on microbial whole-cell sensor[J]. Chinese Journal of Environmental Science, 34(1): 347-356(in Chinese with English abstract).

    Google Scholar

    Hou Qingye, Yang Zhongfang, Ji Junfeng, Yu Tao, Chen Guoguang, Li Juan, Xia Xueqi, Zhang Ming, Yuan Xuyin. 2014. Annual net input fluxes of heavy metals of the agro-ecosystem in the Yangtze River delta, China[J]. Journal of Geochemical Exploration, 139: 68-84. doi: 10.1016/j.gexplo.2013.08.007

    CrossRef Google Scholar

    Hou Qingye, Yang Zhongfang, Yu Tao, You Yuanhang, Dou Lei, Li Kuo. 2020. Impacts of parent material on distributions of potentially toxic elements in soils from Pearl River Delta in South China[J]. Scientific Reports, 10(1): 17394. doi: 10.1038/s41598-020-74490-2

    CrossRef Google Scholar

    Jia Xiyue, O'Connor David, Shi Zhou, Hou Deyi. 2021. VIRS based detection in combination with machine learning for mapping soil pollution[J]. Environmental Pollution, 268: 115845. doi: 10.1016/j.envpol.2020.115845

    CrossRef Google Scholar

    Jiang Wei, Hou Qingye, Yang Zhongfang, Yu Tao, Zhong Cong, Yang Yi, Fu Yangrong. 2014. Annual input fluxes of heavy metals in agricultural soil of Hainan Island, China[J]. Environmental Science and Pollution Research, 21(13): 7876-7885. doi: 10.1007/s11356-014-2679-0

    CrossRef Google Scholar

    Kim Rog-Young, Yoon Jeong-Ki, Kim Tae-Seung, Yang Jae E, Owens Gary, Kim Kwon-Rae. 2015. Bioavailability of heavy metals in soils: Definitions and practical implementation-a critical review[J]. Environmental Geochemistry and Health, 37(6): 1041-1061. doi: 10.1007/s10653-015-9695-y

    CrossRef Google Scholar

    Kodom K, Preko K, Boamah D. 2012. X-ray Fluorescence (XRF) Analysis of soil heavy metal pollution from an industrial area in Kumasi, Ghana[J]. Soil & Sediment Contamination, 21(8): 1006-1021.

    Google Scholar

    Kunene Sikhumbuzo Charles, Lin Kuensong, Mdlovu Ndumiso Vukile, Lin Yousheng, Mdlovu Ncobile Bagezile. 2020. Speciation and fate of toxic cadmium in contaminated paddy soils and rice using XANES/EXAFS spectroscopy[J]. Journal of Hazardous Materials, 383: 121167. doi: 10.1016/j.jhazmat.2019.121167

    CrossRef Google Scholar

    Lai Xuehui, Liu Zijing, Yan Cai, Zhang Yuwei, Cheng Zhi. 2020. Morphological characteristics and risk analysis of heavy metals in farmland soil in the suburb of Taiyuan[J]. Journal of Shandong Agricultural University(Natural Science Edition), 51(2): 242-248(in Chinese with English abstract).

    Google Scholar

    Lal Rattan, Stewart B. A. 2010. Food Security and Soil Quality[M]. Boca Raton: CRC Press, 408.

    Google Scholar

    Lei Ming, Liao Bohan, Qin Pufeng. 2007. Assessment of bioavailability of heavy metal in contaminated soils with chemical fractionation[J]. Ecology and Environment, 16(5): 1551-1556(in Chinese with English abstract).

    Google Scholar

    Li Bin, Wang Maohua, Liu Gang. 2011. Analysis of the status and problems of heavy metal pollution detection technology in farmland soil[C]//Proceedings of the 2011 Heavy Metal Pollution Prevention and Control Technology and Risk Assessment Seminar. Beijing: 165-172(in Chinese).

    Google Scholar

    Li Cai, Ren Mingyi, Shi Dan, Wang Yan, Yang Liyuan, Ding Shimin. 2018. Diffusive gradient in thin films(DGT): Technological progress and prospects[J]. Journal of Agro-Environment Science, 37(12): 2613-2628(in Chinese with English abstract).

    Google Scholar

    Li Cheng, Yang Zhongfang, Yu Tao, Hou Qingye, Liu Xu, Wang Jue, Zhang Qizuan, Wu Tiansheng. 2021. Study on safe usage of agricultural land in karst and non-karst areas based on soil Cd and prediction of Cd in rice: A case study of Heng County, Guangxi[J]. Ecotoxicology and Environmental Safety, 208: 111505. doi: 10.1016/j.ecoenv.2020.111505

    CrossRef Google Scholar

    Li Feili, Liu Congqiang, Song Zhaoliang. 2005. A review of fractionation of heavy metals in soils[J]. Environmental Monitoring in China, 21(4): 21-27(in Chinese with English abstract).

    Google Scholar

    Li Kuo, Peng Min, Zhao Chuandong, Yang Ke, Zhou Yalong, Liu Fei, Tang Shiqi, Yang Fan, Han Wei, Yang Zheng, Cheng Xiaomeng, Xia Xueqi, Guan Tao, Luo Jianlan, Cheng Hangxin. 2019. Vicennial implementation of geochemical survey of land quality in China[J]. Earth Science Frontiers, 26(6): 128-158(in Chinese with English abstract).

    Google Scholar

    Li Ting, Wu Minghui, Wang Yue, Yang Huaju, Tang Chundong, Duan Changqun. 2020. Advances in research on the effects of human disturbance on biogeochemical processes of heavy metals and remediation[J]. Acta Ecologica Sinica, 40(13): 4679-4688(in Chinese with English abstract).

    Google Scholar

    Li Wei, Harrington Richard, Tang Yuanzhi, Kubicki James D, Aryanpour Masoud, Reeder Richard J, Parise John B, Phillips Brian L. 2011. Differential pair distribution function study of the structure of arsenate adsorbed on nanocrystalline γ-alumina[J]. Environmental Science & Technology, 45(22): 9687-9692.

    Google Scholar

    Li Wei, Livi Kenneth J T, Xu Wenqian, Siebecker Matthew G, Wang Yujun, Phillips Brian L, Sparks Donald L. 2012. Formation of crystalline Zn-Al layered double hydroxide precipitates on gamma-Alumina: The role of mineral dissolution[J]. Environmental Science & Technology, 46(21): 11670-11677.

    Google Scholar

    Li Zhiyuan, Ma Zongwei, van der Kuijp Tsering Jan, Yuan Zengwei, Huang Lei. 2014. A review of soil heavy metal pollution from mines in China: Pollution and health risk assessment[J]. Science of the Total Environment, 468-469: 843-853. doi: 10.1016/j.scitotenv.2013.08.090

    CrossRef Google Scholar

    Liao Vivian Hsiu-Chuan, Chien Mingte, Tseng Yuenyi, Ou Kunlin. 2006. Assessment of heavy metal bioavailability in contaminated sediments and soils using green fluorescent protein-based bacterial biosensors[J]. Environmental Pollution, 142(1): 17-23. doi: 10.1016/j.envpol.2005.09.021

    CrossRef Google Scholar

    Lin Chengqi, Huang Huabin, Hu Gongren, Yu Ruilian, Hao Chunli, Lin Ying. 2019. Assessment of the speciation and pollution of heavy metals in paddy soils from the Jiulong River Basin[J]. Chinese Journal of Environmental Science, 40(1): 453-460(in Chinese with English abstract).

    Google Scholar

    Liu Dongsheng, Yang Zhongfang, Xia Xueqi, Hou Qingye, Yu Tao. 2008. Geochemical characteristics and fluxes of elements in rain water and soil leaching water in the Chengdu economic region[J]. Earth Science Frontiers 15(5): 74-81(in Chinese with English abstract).

    Google Scholar

    Liu Guodong, Yang Ze, Dai Huimin, Zhang Yihe, Xiao Hongye, Chen Jiang. 2020. Geochemical evaluation of land quality and development suggestion of land in Hailun City of Heilongjiang Province[J]. Geology and Resources, 29(6): 533-542(in Chinese with English abstract).

    Google Scholar

    Liu Huafeng, Zhang Surong, Dai Jierui, Wang Zenghui, Ren Wenkai. 2020. Characteristics and influencing factors of total nitrogen and alkaline-hydrolyzed nitrogen in surface soil from Diaozhen town and Xinzhai town in Zhangqiu district[J]. Geological Survey and Research, 43(3): 240-245(in Chinese with English abstract).

    Google Scholar

    Liu Jin, Tu Yaoren, Duan Yanping, Zhang Hao. 2020. Research progresses of Cu-Isotope-Tracer technique in environmental applications[J]. Environmental Protection Science, 46(2): 85-92(in Chinese with English abstract).

    Google Scholar

    Liu Sijia, Wang Xuedong, Guo Guanlin, Yan Zengguang. 2021. Status and environmental management of soil mercury pollution in China: A review[J]. Journal of Environmental Management, 277: 111442. doi: 10.1016/j.jenvman.2020.111442

    CrossRef Google Scholar

    Liu Xiaohui. 2015. Zhao Qiguo talks about China's soil heavy metal pollution and the countermeasures[EB/OL]. (2015-10-29)[2020-10-12]. http://www.mnr.gov.cn/dt/ywbb/201810/t20181030_2280298.html (in Chinese)

    Google Scholar

    Liu Yizhang, Xiao Tangfu, Zhu Jianming. 2015. Cadmium isotopes and environmental tracing[J]. Earth and Environment, 43(6): 687-696(in Chinese with English abstract).

    Google Scholar

    Luo Yongming, Teng Ying. 2018. Regional difference in soil pollution and strategy of soil zonal governance and remediation in China[J]. Bulletin of the Chinese Academy of Sciences, 33(2): 145-152(in Chinese with English abstract).

    Google Scholar

    Ma Qiang, Zhao Wanfu, Guan Dongxing, Teng H. Henry, Ji Junfeng, Ma Lena Q. 2020. Comparing CaCl2, EDTA and DGT methods to predict Cd and Ni accumulation in rice grains from contaminated soils[J]. Environmental Pollution, 260: 114042. doi: 10.1016/j.envpol.2020.114042

    CrossRef Google Scholar

    Ma Xuemei, Tian Dazheng, Li Wei, He Jin. 2020. Geochemical evaluation of land quality in Qvyang County[J]. Geological Survey and Research, 43(3): 230-239(In Chinese with English abstract).

    Google Scholar

    McNear D H, Tappero R, Sparks D L. 2005. Shining light on metals in the environment[J]. Elements, 1(4): 211-216. doi: 10.2113/gselements.1.4.211

    CrossRef Google Scholar

    Meng Bo, Feng Xinbin, Qiu Guangle, Anderson Christopher W N, Wang Jianxu, Zhao Lei. 2014. Localization and speciation of mercury in brown rice with implications for Pan-Asian public health[J]. Environmental Science & Technology, 48(14): 7974-7981.

    Google Scholar

    Moor Christoph, Lymberopoulou Theopisti, Dietrich Volker J. 2001. Determination of heavy metals in soils, sediments and geological materials by ICP-AES and ICP-MS[J]. Microchimica Acta, 136(3): 123-128. doi: 10.1007/s006040170041

    CrossRef Google Scholar

    Peralta Elena, Pérez Gustavo, Ojeda Gerardo, Alcañiz Josep Maria, Valiente Manuel, López-Mesas Montserrat, Sánchez-Martín María-Jesús. 2020. Heavy metal availability assessment using portable X-ray fluorescence and single extraction procedures on former vineyard polluted soils[J]. Science of the Total Environment, 726: 138670. doi: 10.1016/j.scitotenv.2020.138670

    CrossRef Google Scholar

    Priyadarshi Himanshu, Alam Absar, Gireesh-Babu P, Das Rekha, Kishore Pankaj, Kumar Shivendra, Chaudhari Aparna. 2012. A GFP-based bacterial biosensor with chromosomally integrated sensing cassette for quantitative detection of Hg(Ⅱ) in environment[J]. Journal of Environmental Sciences, 24(5): 963-968. doi: 10.1016/S1001-0742(11)60820-6

    CrossRef Google Scholar

    Rasmussen L D, Sorensen S J, Turner R R, Barkay T. 2000. Application of a merlux biosensor for estimating bioavailable mercury in soil[J]. Soil Biology & Amp; Biochemistry, 32(5): 639-646.

    Google Scholar

    Shan Yushu, Tysklind Mats, Hao Fanghua, Ouyang Wei, Chen Siyang, Lin Chunye. 2013. Identification of sources of heavy metals in agricultural soils using multivariate analysis and GIS[J]. Journal of Soils and Sediments, 13(4): 720-729. doi: 10.1007/s11368-012-0637-3

    CrossRef Google Scholar

    Siebecker Matthew, Li Wei, Khalid Syed, Sparks Donald L. 2014. Real-time QEXAFS spectroscopy measures rapid precipitate formation at the mineral-water interface[J]. Nature Communications, 5: 5003. doi: 10.1038/ncomms6003

    CrossRef Google Scholar

    Smith David B, Smith Steven M, Horton John D. 2013. History and evaluation of national-scale geochemical data sets for the United States[J]. Geoscience Frontiers, 4(2): 167-183. doi: 10.1016/j.gsf.2012.07.002

    CrossRef Google Scholar

    Soodan Rajneet Kour, Pakade Yogesh B, Nagpal Avinash, Katnoria Jatinder Kaur. 2014. Analytical techniques for estimation of heavy metals in soil ecosystem: A tabulated review[J]. Talanta, 125: 405-410. doi: 10.1016/j.talanta.2014.02.033

    CrossRef Google Scholar

    Sparks Donald L. 2015. Advances in coupling of kinetics and molecular scale tools to shed light on soil biogeochemical processes[J]. Plant and Soil, 387(1/2): 1-19. doi: 10.1007/s11104-014-2251-1

    CrossRef Google Scholar

    Tang Qifeng, Yang Zhongfang, Zhang Benren, Jin Lixin, Liu Aihua. 2007. Cadmium flux in soils of the agroecosystem in the Chengdu economic region, Sichuan, China[J]. Geological Bulletin of China, 26(7): 869-877(in Chinese with English abstract).

    Google Scholar

    Tessier A, Campbell P G C, Bisson M. 1979. Sequential extraction procedure for the speciation of particulate trace metals[J]. Analytical Chemistry, 51(7): 844-851. doi: 10.1021/ac50043a017

    CrossRef Google Scholar

    Wang Jianhua, Tao Peifeng, Yuan Yue, Li Zhizhong, Yang Jiajia. 2020. PSR-based evaluation of the cultivated land quality in Hailun City of Heilongjiang Province[J]. Geology and Resources, 29(6): 525-532(in Chinese with English abstract).

    Google Scholar

    Wang Liyuan, Peng Xianglian, Fu Hongjun, Huang Chao, Li Yaping, Liu Zhiming. 2020. Recent advances in the development of electrochemical aptasensors for detection of heavy metals in food[J]. Biosensors & Bioelectronics, 147: 111777.

    Google Scholar

    Wang Xueqiu, Zhou Jian, Xu Shanfa, Chi Qinghua, Nie Lanshi, Zhang Bimin, Yao Wensheng, Wang Wei, Liu Hanliang, Liu Dongsheng, Han Zhixuan, Liu Qingqing. 2016. China soil geochemical baselines networks: Data characteristics[J]. Geology in China, 43(5): 1469-1480(in Chinese with English abstract).

    Google Scholar

    Wen Yubo, Li Wei, Yang Zhongfang, Zhuo Xiaoxiong, Guan Dongxing, Song Yinxian, Guo Chao, Ji Junfeng. 2020. Evaluation of various approaches to predict cadmium bioavailability to rice grown in soils with high geochemical background in the karst region, Southwestern China[J]. Environmental Pollution, 258: 113645. doi: 10.1016/j.envpol.2019.113645

    CrossRef Google Scholar

    Wu Chunlin, Wang Ruiting, Ding Kun, Han Ling. 2018. Geochemical survey and evaluation on soil quality in China: Research status and advances[J]. Northwestern Geology, 251(3): 240-252(in Chinese with English abstract).

    Google Scholar

    Wu Guanghai, Wang Chensheng, Chen Honghan. 2020. Eco-environmental assessment and genetic analysis of heavy metal pollution in the soil around the abandoned tungsten-molybdenum mine area in Inner Mongolia[J]. Geology in China, 47(6): 1838-1852(in Chinese with English abstract).

    Google Scholar

    Xi Xiaohuan. 2008. Ecological geochemistry: From a geochemical survey to an applied theory[J]. Earth Science Frontiers, 15(5): 1-8(In Chinese with English abstract).

    Google Scholar

    Xi Xiaohuan. 2004. Eco-geochemical research and eco-geochemical evaluation[J]. Geophysical and Geochemical Exploration, 28(1): 10-15(in Chinese with English abstract).

    Google Scholar

    Yang Qianqi, Li Zhiyuan, Lu Xiaoning, Duan Qiannan, Huang Lei, Bi Jun. 2018. A review of soil heavy metal pollution from industrial and agricultural regions in China: Pollution and risk assessment[J]. Science of the Total Environment, 642: 690-700. doi: 10.1016/j.scitotenv.2018.06.068

    CrossRef Google Scholar

    Yang Zhongfang, Yu Tao, Hou Qingye, Xia Xueqi, Feng Haiyan, Huang Chunlei, Wang Lisheng, Lü Yaoyao, Zhang Meng. 2014. Geochemical evaluation of land quality in China and its applications[J]. Journal of Geochemical Exploration, 139: 122-135. doi: 10.1016/j.gexplo.2013.07.014

    CrossRef Google Scholar

    Zhang Hao, Zhao Fangjie, Sun Bo, Davison William, Mcgrath Steve P. 2001. A new method to measure effective soil solution concentration predicts copper availability to plants[J]. Environmental Science & Technology, 35(12): 2602-2607.

    Google Scholar

    Zhang Hongzhen, Luo Yongming, Song Jing, Yu Haibo, Wu Longhua, Weng Liping, Zhao Qiguo. 2010. Solid-solution partitioning of soil heavy metals and free-ion concentration measurement in neutral salt extractions[J]. Acta Scientiae Circumstantiae, 30(1): 124-132(in Chinese with English abstract).

    Google Scholar

    Zhang Jie, Xu Zhengqi, Huang Huan, Tian Jianmin, Zhang Guodong. 2020. Characteristics and speciation analysis of heavy metals in soils around a phosphate mining area in Mabian, Sichuan[J]. Sichuan Environment, 39(2): 9-15(in Chinese with English abstract).

    Google Scholar

    Zhang Lei, Wu Yongning, Zhao Yunfeng. 2007. Study on the stability of different forms of arsenic compounds and sample pretreatment technology in the analysis of arsenic[J]. Foreign Medical Sciences (Section Hygiene), 34(4): 238-244 (in Chinese).

    Google Scholar

    Zhang Qiaochu, Wang Chengchen. 2020. Natural and human factors affect the distribution of soil heavy metal pollution: A review[J]. Water, Air, & Soil Pollution, 231(7). https://doi.org/10.1007/s11270-020-04728-2. doi: 10.1007/s11270-020-04728-2

    CrossRef Google Scholar

    Zhang Qin. 2005. A complete set of analytical schemes and analytical data monitoring systems for determinations of 54 components in multi-purpose geochemical mapping[J]. Quaternary Research, 25(3): 292-297(in Chinese with English abstract).

    Google Scholar

    Zhao Fangjie, Ma Yibing, Zhu Yongguan, Tang Zhong, McGrath Steve P. 2015. Soil Contamination in China: Current status and mitigation strategies[J]. Environmental Science & Technology, 49(2): 750-759.

    Google Scholar

    Zhong Cong, Yang Zhongfang, Jiang Wei, Yu Tao, Hou Qingye, Li Desheng, Wang Jianwu. 2014. Annual input fluxes and source identification of trace elements in atmospheric deposition in Shanxi Basin: The largest coal base in China[J]. Environmental Science and Pollution Research, 21(21): 12305-12315. doi: 10.1007/s11356-014-3052-z

    CrossRef Google Scholar

    Zhong Xiaolan, Zhou Shenglu, Huang Mingli, Zhao Qiguo. 2009. Chemical form distribution characteristic of soil heavy metals and its influencing factors[J]. Ecology and Environmental Sciences, 18(4): 1266-1273(in Chinese with English abstract).

    Google Scholar

    Zhou Weihong, Zhang Jingjing, Zou Mengmeng, Du Xiaolong, Zhang Ying, Yang Yue, Li Jianlong. 2017. The detection and monitoring of available heavy metal content in soil: A review[J]. Chinese Journal of Eco-Agriculture, 25(4): 605-615(in Chinese with English abstract).

    Google Scholar

    Zhou Weihong, Zhang Jingjing, Zou Mengmeng, Liu Xiaoqing, Du Xiaolong, Wang Qian, Liu Yangyang, Liu Ying, Li Jianlong. 2019. Feasibility of using rice leaves hyperspectral data to estimate CaCl2 extractable concentrations of heavy metals in agricultural soil[J]. Scientific Reports, 9(1): 16084. doi: 10.1038/s41598-019-52503-z

    CrossRef Google Scholar

    Zhou Jianjun, Zhou Jie, Feng Renguo. 2014. Current status of soil heavy metal pollution and its control strategy in China[J]. Bulletin of the Chinese Academy of Sciences, 29(3): 310-315, 350(in Chinese).

    Google Scholar

    鲍丽然, 邓海, 贾中民, 李瑜, 董金秀, 严明书, 张风雷. 2020. 重庆秀山西北部农田土壤重金属生态健康风险评价[J]. 中国地质, 47(6): 1625-1636.

    Google Scholar

    崔邢涛, 王学求, 栾文楼. 2015. 河北中南部平原土壤重金属元素存在形态及生物有效性分析[J]. 中国地质, 42(2): 655-663. doi: 10.3969/j.issn.1000-3657.2015.02.023

    CrossRef Google Scholar

    高彦鑫, 冯金国, 唐磊, 朱先芳, 刘文清, 季宏兵. 2012. 密云水库上游金属矿区土壤中重金属形态分布及风险评价[J]. 环境科学, 33(5): 1707-1717.

    Google Scholar

    郭笑笑, 刘丛强, 朱兆洲, 王中良, 李军. 2011. 土壤重金属污染评价方法[J]. 生态学杂志, 30(5): 889-896.

    Google Scholar

    韩春梅, 王林山, 巩宗强, 许华夏. 2005. 土壤中重金属形态分析及其环境学意义[J]. 生态学杂志, 24(12): 1499-1502. doi: 10.3321/j.issn:1000-4890.2005.12.025

    CrossRef Google Scholar

    何滨, 江桂斌. 2002. 汞形态分析中的前处理技术[J]. 分析测试学报, 21(1): 89-94. doi: 10.3969/j.issn.1004-4957.2002.01.029

    CrossRef Google Scholar

    侯启会, 马安周, 庄绪亮, 庄国强. 2013. 微生物全细胞传感器在重金属生物可利用度监测中的研究进展[J]. 环境科学, 34(1): 347-356.

    Google Scholar

    环境保护部, 国土资源部. 2014. 全国土壤污染状况调查公报[EB/OL]. (2014-04-17)[2020-10-12]. https://www.mee.gov.cn/gkml/sthjbgw/qt/201404/W020140417558995804588.pdf

    Google Scholar

    来雪慧, 刘子婧, 闫彩, 张玉薇, 程志. 2020. 太原市郊区农田土壤重金属的形态特征及其风险分析[J]. 山东农业大学学报(自然科学版), 51(2): 242-248.

    Google Scholar

    雷鸣, 廖柏寒, 秦普丰. 2007. 土壤重金属化学形态的生物可利用性评价[J]. 生态环境, 16(5): 1551-1556. doi: 10.3969/j.issn.1674-5906.2007.05.043

    CrossRef Google Scholar

    李斌, 汪懋华, 刘刚. 2011. 农田土壤重金属污染及检测技术现状与问题分析[C]//2011年重金属污染防治技术及风险评价研讨会论文集. 北京: 165-172.

    Google Scholar

    李财, 任明漪, 石丹, 王燕, 杨丽原, 丁士明. 2018. 薄膜扩散梯度(DGT)-技术进展及展望[J]. 农业环境科学学报, 37(12): 2613-2628. doi: 10.11654/jaes.2018-1403

    CrossRef Google Scholar

    李非里, 刘丛强, 宋照亮. 2005. 土壤中重金属形态的化学分析综述[J]. 中国环境监测, 21(4): 21-27. doi: 10.3969/j.issn.1002-6002.2005.04.007

    CrossRef Google Scholar

    李括, 彭敏, 赵传冬, 杨柯, 周亚龙, 刘飞, 唐世琪, 杨帆, 韩伟, 杨峥, 成晓梦, 夏学齐, 关涛, 骆检兰, 成杭新. 2019. 全国土地质量地球化学调查二十年[J]. 地学前缘, 26(6): 128-158.

    Google Scholar

    李婷, 吴明辉, 王越, 杨化菊, 唐春东, 段昌群. 2020. 人类扰动对重金属元素的生物地球化学过程的影响与修复研究进展[J]. 生态学报, 40(13): 4679-4688.

    Google Scholar

    林承奇, 黄华斌, 胡恭任, 于瑞莲, 郝春莉, 林颖. 2019. 九龙江流域水稻土重金属赋存形态及污染评价[J]. 环境科学, 40(1): 453-460.

    Google Scholar

    刘东盛, 杨忠芳, 夏学齐, 侯青叶, 余涛. 2008. 成都经济区天降水与下渗水元素地球化学特征及土壤元素输入输出通量[J]. 地学前缘, 15(5): 74-81. doi: 10.3321/j.issn:1005-2321.2008.05.008

    CrossRef Google Scholar

    刘国栋, 杨泽, 戴慧敏, 张一鹤, 肖红叶, 陈江. 2020. 黑龙江省海伦市长发镇土地质量地球化学评价及开发建议[J]. 地质与资源, 29(6): 533-542.

    Google Scholar

    刘华峰, 张素荣, 代杰瑞, 王增辉, 任文凯. 2020. 章丘区刁镇和辛寨镇表层土壤全氮与碱解氮特征及影响因素[J]. 地质调查与研究, 43(3): 240-245. doi: 10.3969/j.issn.1672-4135.2020.03.007

    CrossRef Google Scholar

    刘靳, 涂耀仁, 段艳平, 张浩. 2020. Cu同位素示踪技术应用于环境领域的研究进展[J]. 环境保护科学, 46(2): 85-92.

    Google Scholar

    刘晓慧. 2015. 赵其国谈我国土壤重金属污染问题与治理的对策[EB/OL]. (2015-10-29)[2020-10-12]. http://www.mnr.gov.cn/dt/ywbb/201810/t20181030_2280298.html

    Google Scholar

    刘意章, 肖唐付, 朱建明. 2015. 镉同位素及其环境示踪[J]. 地球与环境, 43(6): 687-696.

    Google Scholar

    骆永明, 滕应. 2018. 我国土壤污染的区域差异与分区治理修复策略[J]. 中国科学院院刊, 33(2): 145-152.

    Google Scholar

    马雪梅, 田大争, 李伟, 何锦. 2020. 曲阳县土地质量地球化学评价[J]. 地质调查与研究, 43(3): 230-239. doi: 10.3969/j.issn.1672-4135.2020.03.006

    CrossRef Google Scholar

    汤奇峰, 杨忠芳, 张本仁, 金立新, 刘爱华. 2007. 成都经济区农业生态系统土壤镉通量研究[J]. 地质通报, 26(7): 869-877. doi: 10.3969/j.issn.1671-2552.2007.07.011

    CrossRef Google Scholar

    [英] Ure A M, Davidson C M. 著. 2010. 环境中的化学形态(第二版)[M]. 王亚平, 许春雪, 王苏明, 安子怡, 王岚, 李艳艳, 译. 北京: 中国标准出版社, 1-393.

    Google Scholar

    王建华, 陶培峰, 袁月, 李志忠, 杨佳佳. 2020. PSR框架下的黑龙江省海伦市耕地质量评价[J]. 地质与资源, 29(6): 525-532.

    Google Scholar

    王学求, 周建, 徐善法, 迟清华, 聂兰仕, 张必敏, 姚文生, 王玮, 刘汉粮, 刘东盛, 韩志轩, 柳青青. 2016. 全国地球化学基准网建立与土壤地球化学基准值特征[J]. 中国地质, 43(5): 1469-1480.

    Google Scholar

    武春林, 王瑞廷, 丁坤, 韩玲. 2018. 中国土壤质量地球化学调查与评价的研究现状和进展[J]. 西北地质, 51(3): 240-252. doi: 10.3969/j.issn.1009-6248.2018.03.023

    CrossRef Google Scholar

    邬光海, 王晨昇, 陈鸿汉. 2020. 内蒙古废弃钨钼矿区周围土壤重金属污染生态环境评价及成因分析[J]. 中国地质, 47(6): 1838-1852.

    Google Scholar

    奚小环. 2008. 生态地球化学: 从调查实践到应用理论的系统工程[J]. 地学前缘, 15(5): 1-8. doi: 10.3321/j.issn:1005-2321.2008.05.001

    CrossRef Google Scholar

    奚小环. 2004. 生态地球化学与生态地球化学评价[J]. 物探与化探, 28(1): 10-15. doi: 10.3969/j.issn.1000-8918.2004.01.002

    CrossRef Google Scholar

    张红振, 骆永明, 宋静, 余海波, 吴龙华, 翁丽萍, 赵其国. 2010. 基于中性盐提取的土壤重金属固液分配与自由态金属离子浓度测定[J]. 环境科学学报, 30(1): 124-132.

    Google Scholar

    张杰, 徐争启, 黄寰, 田建民, 张国栋. 2020. 四川马边某磷矿区土壤重金属特征及形态分析[J]. 四川环境, 39(2): 9-15.

    Google Scholar

    张磊, 吴永宁, 赵云峰. 2007. 不同形态砷化合物稳定性研究和砷形态分析中样品前处理技术[J]. 国外医学(卫生学分册), 34(4): 238-244.

    Google Scholar

    张勤. 2005. 多目标地球化学填图中的54种指标配套分析方案和分析质量监控系统[J]. 第四纪研究, 25(3): 292-297. doi: 10.3321/j.issn:1001-7410.2005.03.004

    CrossRef Google Scholar

    中国地质调查局. 2005. DD 2005-03生态地球化学评价样品分析技术要求(试行)[S]. 北京: 2005年10月.

    Google Scholar

    钟晓兰, 周生路, 黄明丽, 赵其国. 2009. 土壤重金属的形态分布特征及其影响因素[J]. 生态环境学报, 18(4): 1266-1273. doi: 10.3969/j.issn.1674-5906.2009.04.013

    CrossRef Google Scholar

    周建军, 周桔, 冯仁国. 2014. 我国土壤重金属污染现状及治理战略[J]. 中国科学院院刊, 29(3): 310-315, 350.

    Google Scholar

    周卫红, 张静静, 邹萌萌, 杜小龙, 张颖, 杨悦, 李建龙. 2017. 土壤重金属有效态含量检测与监测现状、问题及展望[J]. 中国生态农业学报, 25(4): 605-615.

    Google Scholar

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