A Study on Rare Earth Elements Geochemistry of the Makeng Skarn Fe-Mo Deposit and Its Geological Significance in Fujian Province

Cheng-shuai ZHANG; Li LI; Chang-qing ZHANG

2013 Vol. 32, No. 1

Article Contents

Article navigation > Rock and Mineral Analysis > 2013 > 32(1): 145-156

Next Article Previous Article

Cheng-shuai ZHANG, Li LI, Chang-qing ZHANG. A Study on Rare Earth Elements Geochemistry of the Makeng Skarn Fe-Mo Deposit and Its Geological Significance in Fujian Province[J]. Rock and Mineral Analysis, 2013, 32(1): 145-156.

Citation:

A Study on Rare Earth Elements Geochemistry of the Makeng Skarn Fe-Mo Deposit and Its Geological Significance in Fujian Province

1.
CCCC Investment Co., Ltd., Beijing 100088, China
2.
China Geological Library, Beijing 100083, China
3.
Institute of Mineral Resources, Chinese Academy of Geological Sciences, Beijing 100037, China

Received Date: 22 February 2012

Accepted Date: 12 November 2012

Abstract

Abstract

The Makeng Fe-Mo deposit is a large skarn-type magnetite deposit hosted by interbedded structural fracture zone between limestone in the Huanglong formation (C₂h) and clastic rocks in the Lindi formation (C₁l) in the vicinity of the outer aureole of the Juzhou-Dayang granite intrusion. The rare earth elements (REEs) in garnet, pyroxene, pyrite and magnetite from the Makeng deposit were studied by Inductively Coupled Plasma-Mass Spectrometry (ICP-MS). The results demonstrate that garnet, pyroxene, pyrite and magnetite have similar chondrite-normalized REEs distribution patterns with light REEs (LREEs) enrichment, moderate Eu positive anomaly and no Ce anomaly. It implies a genetic relation between ores and skarns, which were formed in an oxidation environment. The REEs characteristics of nearby marble and altered rocks varied regularly, which indicates that they were influenced by the metasomatism of post-magmatic hydrothermal fluids, and the ore-forming materials were partially derived from surrounding clastic rocks and diabase.
- rare earth elements /
- skarn /
- Makeng Fe-Mo deposit

FullText(HTML)

References

[1]	赵一鸣,谭惠静,许振南.闽西南地区马坑式钙矽卡岩型铁矿床[J].中国地质科学院矿床地质研究所所刊,1983,1(1): 1-141. Google Scholar
[2]	韩发,葛朝华.福建马坑铁矿床海相火山热液-沉积成因-地质地球化学特征[J].中国地质科学院矿床地质研究所所刊,1983,1(2): 1-118. Google Scholar
[3]	张承帅.福建马坑铁钼多金属矿床地质特征研究[J].矿床地质,2010,29(Z1): 123-124. Google Scholar
[4]	陈述荣,谢家亨,许超南,郭维伍.福建马坑铁矿床成因的探讨[J].地球化学,1985,82(4): 350-357. Google Scholar
[5]	梁祥济,曲国林.福建马坑铁矿床形成温度和压力实验的初步研究[J].中国地质科学院院报, 1982,4(1): 83-94. Google Scholar
[6]	赵一鸣,林文蔚,毕承思.中国矽卡岩矿床[M].北京: 地质出版社,1990: 164-171. Google Scholar
[7]	毛景文.桂北BT锡矿稀土元素特征及其与成矿的关系[J].河北地质学院学报,1987,10(3): 273- 287. Google Scholar
[8]	邱瑞龙.贵池铜山铜矿矽卡岩稀土元素地球化学[J].地质学报,1987,61(1): 91- 100. Google Scholar
[9]	王中刚,于学元,赵振华.REE稀土元素地球化学[M].北京: 科学出版社,1989: 1-535. Google Scholar
[10]	陈骏.柿竹园矽卡岩型钨锡钼铋矿床主要造岩矿物中REE的分布特征及成岩意义[J].地球化学,1994(Z1): 84-92. doi: 10.3321/j.issn:0379-1726.1994.z1.011 CrossRef Google Scholar
[11]	吴言昌.论岩浆矽卡岩——一种新类型矽卡岩[J].安徽地质,1992,2(1): 12-26. Google Scholar
[12]	赵斌,赵松,刘海臣.长江中下游若干Cu (Au), Cu-Fe(Au)和Fe矿床中钙质矽卡岩的稀土元素地球化学[J].地球化学,1999,28(2): 113-125. Google Scholar
[13]	肖成东,刘学武.东蒙地区矽卡岩石榴子石稀土元素地球化学及其成因[J].中国地质,2002,29(3): 311-316. Google Scholar
[14]	凌其聪,刘丛强.层控矽卡岩及有关矿床形成过程的稀土元素行为——以安徽冬瓜山矿床为例[J].岩石学报,2002,19(1): 192-200. Google Scholar
[15]	王莉娟,王京彬,王玉往,岛崎英彦.内蒙黄岗梁矽卡岩型铁锡矿床稀土元素地球化学[J].岩石学报,2002,18(4): 575-584. Google Scholar
[16]	贾润幸,方维萱,赫英,高振敏,李红阳.个旧超大型锡多金属矿稀土元素地球化学特征[J].中国稀土学报,2005,23(2): 228-234. Google Scholar
[17]	梁婷,王登红,屈文俊,蔡明海,韦可利,黄惠民,吴德成.广西大厂锡多金属矿床方解石的REE地球化学特征[J].岩石学报,2007,23(10): 2493-2503. doi: 10.3969/j.issn.1000-0569.2007.10.017 CrossRef Google Scholar
[18]	杨富全,毛景文,徐林刚,张岩,刘锋,黄成林,周刚,刘国仁,代军治.新疆蒙库铁矿床稀土元素地球化学及对铁成矿作用的指示[J].岩石学报,2007,23(10): 2443-2456. doi: 10.3969/j.issn.1000-0569.2007.10.013 CrossRef Google Scholar
[19]	赵劲松,邱学林,赵斌,涂湘林,虞珏,芦铁山.大冶-武山矿化矽卡岩的稀土元素地球化学研究[J].地球化学,2007,36(4): 400-412. Google Scholar
[20]	徐晓春,赵丽丽,谢巧勤,褚平利,房海波,王文俊.铜陵狮子山矿田金矿床和铜矿床矿石稀土元素地球化学[J].高校地质学报,2009,24(1): 35-47. Google Scholar
[21]	张志欣,杨富全,柴凤梅,刘锋.新疆阿尔泰乌吐布拉克铁矿床稀土元素地球化学研究[J].矿床地质,2010,30(1): 83-101. Google Scholar
[22]	吴凎国,张达,陈柏林,吴建设.中国东南大陆中生代构造域的转换及其与成矿的关系——以闽西南地区为例[J].地质科学,2000,25(4): 390-396. Google Scholar
[23]	毛建仁,陶奎元,谢芳贵.闽西南地区成岩成矿作用与构造环境[J].岩石矿物学杂志,2001, 20(3): 329-336. Google Scholar
[24]	毛景文,谢桂青,程彦博.华南地区中生代主要金属矿床模型[J].地质论评,2009,55(3): 346-354. Google Scholar
[25]	毛建仁,陈荣,李寄隅,叶海敏,赵希林.闽西南地区晚中生代花岗质岩石的同位素年代学、地球化学及其构造演化[J].岩石学报,2006,22(6): 1723-1734. Google Scholar
[26]	毛建仁,许乃政,胡青.福建省上杭-大田地区中生代成岩成矿作用与构造环境演化[J].岩石学报,2004,20(2): 285-296. Google Scholar
[27]	张达.闽西南地区构造演化与锡多金属区域成矿作用[D].北京: 中国地质科学院,1999: 1-145. Google Scholar
[28]	李萌清,陈伟十.马坑铁矿流体包裹体研究及成矿作用探讨[J].中国地质科学院矿床地质研究所所刊,1983,1(1): 91-101. Google Scholar
[29]	张承帅,苏慧敏,于淼,胡兆国.福建龙岩大洋-莒舟花岗岩锆石U-Pb年龄和Sr-Nd-Pb同位素特征及其地质意义[J].2012,28(1): 225-242. Google Scholar
[30]	罗铭玖,张辅民,董群英,许永仁,黎世美,李昆华.中国钼矿床[M].郑州: 河南科学技术出版社,1991: 155-163. Google Scholar
[31]	葛朝华,韩发.马坑铁矿床稀土元素地球化学研究[J].矿床地质,1984,3(1): 1-10. Google Scholar
[32]	Whitney P R, Olmsted J F. Rare earth element metaso-matism in hydrothermal systems: The Willsboro-Lewis wollastonite ores, New York, USA[J]. Geochimica et Cosmochimica Acta,1998,62(17): 2965-2977. doi: 10.1016/S0016-7037(98)00230-0 CrossRef Google Scholar
[33]	Miguel G, Charles K, Lawrence M, Roberto M. REE in skarn systems: A LA-ICP-MS study of garnets from the Crown Jewel gold deposit[J]. Geochimica et Cosmochimica Acta,2008, 72: 185-205. doi: 10.1016/j.gca.2007.09.033 CrossRef Google Scholar
[34]	丁振举,刘丛强,姚书振,周宗桂,杨明国.东沟坝多金属矿床矿质来源的稀土元素地球化学限制[J].吉林大学学报: 地球科学版,2003,33(4): 437-442. Google Scholar
[35]	丁振举,刘丛强,姚书振,周宗桂.海底热液沉积物稀土元素组成及其意义[J].地质科技情报, 2000,19(1): 27-30,34. Google Scholar
[36]	丁振举,刘丛强,姚书振.海底热液系统高温流体的稀土元素组成及其控制因素[J].地球科学进展,2000,15(3): 307-312. Google Scholar
[37]	Joseph L G. Rare earth elements as hydrothermal tracers during the formation of massive sulfide deposits in volcanic rocks[J].Economic Geology,1977,77(4): 527-548. Google Scholar
[38]	沈其韩,宋会侠,赵子然.山东韩旺新太古代条带状铁矿的稀土和微量元素特征[J].地球学报,2009,30(6): 693-699. Google Scholar
[39]	余金杰,毛景文.宁芜玢岩铁矿磷灰石的稀土元素特征[J].矿床地质,2002,21(1): 65-73. Google Scholar
[40]	王登红,李华芹,陈毓川,屈文俊,梁婷,应立娟,韦可利,刘孟宏.桂西北南丹地区大厂超大型锡多金属矿床中发现高稀土元素方解石[J].地质通报,2005,24(2): 176-180. Google Scholar
[41]	毕献武,胡瑞忠,彭建堂,吴开兴.黄铁矿微量元素地球化学特征及其对成矿流体性质的指示[J].矿物岩石地球化学通报,2004,23(1): 1-4. Google Scholar
[42]	Lottermoser B G. Rare-earth elements and hydrothermal ore formation processes[J].Ore Geology Reviews,1992,7: 25-41. doi: 10.1016/0169-1368(92)90017-F CrossRef Google Scholar
[43]	赵振华.微量元素地球化学[M].北京: 科学出版社,1997: 1-153. Google Scholar
[44]	Anders E, Grevess N. Abundances of the elements: Meteoritic and solar[J]. Geochimica et Cosmochimica Acta,1989,53: 197-214. doi: 10.1016/0016-7037(89)90286-X CrossRef Google Scholar
[45]	杨耀民,涂光炽,胡瑞忠.迤纳厂稀土铁铜矿床稀土元素地球化学[J].矿物学报,2004, 24(3): 301-308. Google Scholar
[46]	张承帅.福建马坑铁矿床地质与地球化学[D].北京: 中国地质大学(北京),2012: 1-200. Google Scholar