Citation: | SHI Jingyang, LUO Na, TANG Jiayan. Three Dispersants Enhance Dispersion Behavior and Mechanism of Fine Dolomite[J]. Conservation and Utilization of Mineral Resources, 2023, 43(1): 92-97. doi: 10.13779/j.cnki.issn1001−0076.2023.01.009 |
In order to study the dispersion behavior of fine dolomite pulp system, through the single mineral sedimentation experiment, solution pH and dispersant type (ZSC, ZSS, ZSP-1, ZSP-2, ZSP-3) and dosages on the influence of dolomite dispersion. In this study, the effect of dispersant on the Zeta potential, infrared spectrum analysis and wetting contact angle measurement of fine dolomite were investigated. Results indicated that the pH value had a great influence on the dispersion of the system without adding dispersant. The dispersion rate of alkaline conditions (20%) was about 15% higher than that of acidic conditions (5%). The order of dispersing ability of dispersant to dolomite minerals was ZSP-1>ZSP-2>ZSP-3>ZSS>ZSC. The analysis showed that different kinds of dispersants mainly acted together in the form of physical adsorption and chemical adsorption on the surface of fine dolomite. The dispersant increased the electrostatic repulsion of the fine dolomite, while enhanced the hydrophobicity of the fine dolomite, thereby improving the dispersion of dolomite.
[1] | 李冬莲, 汪桥, 马孝爽. 一种高分子絮凝剂对细粒胶磷矿浮选的影响[J]. 武汉工程大学学报, 2015(11): 1−5. doi: 10.3969/j.issn.1674-2869.2015.11.001 LI D L, WANG Q, MA X S. Effect of high-polymer flocculant on flotation of fine-grained collophane[J]. Journal of Wuhan Institute of Technology, 2015(11): 1−5. doi: 10.3969/j.issn.1674-2869.2015.11.001 |
[2] | 宋少先, 李长根, 崔洪山. 细粒矿物絮团浮选的理论和应用[J]. 国外金属矿选矿, 2007(5): 4−9. SONG S X, LI C G, CUI H S. Theory and application of fine mineral floc flotation[J]. Metallic Ore Dressing Abroad, 2007(5): 4−9. |
[3] | 张静茹, 汤家焰, 任建辉, 等. 四种分散剂对萤石和石英分散行为的影响[J]. 内蒙古科技大学学报, 2020, 39(3): 217−221. doi: 10.16559/j.cnki.2095-2295.2020.03.004 ZHANG J R, TANG J Y, REN J H, et al. Effects of four dispersants on the dispersion behavior of fluorite and quartz[J]. Journal of Inner Mongolia University of Science and Technology, 2020, 39(3): 217−221. doi: 10.16559/j.cnki.2095-2295.2020.03.004 |
[4] | 张占兵,胡佩伟,谢志诚,等. 分散剂强化细粒级含钒页岩的钒浸出及作用机理[J]. 中国有色金属学报, 2022, 32(9):11. ZHANG Z B, HU P W, XIE Z C, et al. Vanadium leaching enhanced by dispersant and its mechanism in fine vanadium shale[J]. Chinese Journal of Nonferrous Metals, 2022, 32(9): 11. |
[5] | 王飞, 张芹, 邓冰, 等. 3种调整剂对微细粒胶磷矿分散行为的影响[J]. 金属矿山, 2011(2): 57−59. WANG F, ZHANG Q, DENG B, et al. Effects of three kinds of regulators on dispersion behavior of ultrafine collophanite[J]. Metal Mine, 2011(2): 57−59. |
[6] | 卢毅屏, 丁鹏, 冯其明, 等. 不同结构的磷酸盐对蛇纹石的分散作用[J]. 中南大学学报(自然科学版), 2011(12): 3599−3604. LU Y P, DING P, FENG Q M, et al. Dispersing effect of phosphate with different structure on serpentine[J]. Journal of Central South University (Natural Science), 2011(12): 3599−3604. |
[7] | 唐鑫. 安宁地区低镁风化磷矿分选试验研究[D]. 徐州: 中国矿业大学, 2014 TANG X. Experimental study on the separation of low magnesium weathered phosphate rock in Anning area[D]. Xuzhou: China University of Mining and Technology, 2014. |
[8] | SUBRAHMANYAM T V, FORSSBERG K S E. Fine particles processing: shear-flocculation and carrier flotation — a review[J]. International Journal of Mineral Processing, 1990, 30(3/4): 265-286. |
[9] | 赵文婷, 郭坤, 李志红, 等. 无机磷酸盐对高灰煤泥浮选的作用研究[J]. 煤炭技术, 2016, 35(10): 310−313. doi: 10.13301/j.cnki.ct.2016.10.123 ZHAO W T, GUO K, LI Z H, et al. Study on the effect of inorganic phosphate on flotation of high ash slime[J]. Coal Science and Technology, 2016, 35(10): 310−313. doi: 10.13301/j.cnki.ct.2016.10.123 |
[10] | 王毓华, 陈兴华, 胡业民, 等. 磷酸盐对细粒铝硅酸盐矿物分散行为的影响[J]. 中南大学学报(自然科学版), 2007(2): 238−244. WANG Y H, CHEN X H, HU Y M, et al. Effect of phosphate on dispersion behavior of fine aluminosilicate minerals[J]. Journal of Central South University (Natural Science), 2007(2): 238−244. |
[11] | 邱冠周,胡岳华,王淀佐. 颗粒间相互作用与细粒浮选[M]. 长沙: 中南工业大学出版社, 1993 QIU G Z, HU Y H, WANG D Z. Particle interaction and fine particle flotation[M]. Changsha: Central South University of Technology Press, 1993. |
[12] | 肖坤明. 胶磷矿与白云石及石英的浮选分离[D]. 赣州: 江西理工大学, 2011. XIAO K M. Flotation separation of collophanite from dolomite and quartz[D]. Ganzhou: Jiangxi University of Science and Technology, 2011. |
Results of X-ray powder diffraction for dolomite
Dispersion behaviour of dolomite as a function of pulp pH
Dispersion behaviour of dolomite as a function of ZSC、ZSS concentration
Dispersion behaviour of dolomite as a function of ZSP-1、ZSP-2、ZSP-3 concentration
Zeta potential of dolomite as a function of pulp pH
Zeta potential of dolomite as a function of ZSC、ZSS concentration
Zeta potential of dolomite as a function of ZSP-1、ZSP-2、ZSP-3 concentration
Surface contact angle of dolomite as a function of ZSC、ZSS concentration
Surface contact angle of dolomite as a function of ZSP-1、ZSP-2、ZSP-3 concentration
Infrared spectrum analysis of dispersant before and after its action on the surface of fine dolomite