Citation: | WANG Xin, HE Tingshu, YU Bo, HE Hanbing, WANG Yubin. Influence of Ca2+ and Mg2+ on Pyrite Flotation at Different Slurry Temperatures[J]. Multipurpose Utilization of Mineral Resources, 2024, 45(3): 121-128. doi: 10.3969/j.issn.1000-6532.2024.03.019 |
This is an article in the field of mineral processing engineering. Through single mineral flotation test, solution chemistry calculation, Zeta potential detection, XPS detection, the influence and regulation mechanism of Ca2+ and Mg2+ on the flotation of pyrite at different slurry temperatures was studied. The results showed that the low temperature could significantly inhibit the flotation of pyrite, and also could weaken the inhibitory effect of Ca2+ and Mg2+ on the flotation of pyrite. When the slurry temperature dropped from 20 ℃ to 5 ℃, the speed of movement of the charged particles slowed down, the Zeta potential and the critical pH value for the formation of calcium and magnesium hydroxide increased , and the proportion of FeO/OH on the pyrite surface in pyrite pulp decreased , decreasing the reduction rate of FeO/OH content on the pyrite surface in Ca2+ and Mg2+ pulp, reducing the oxidation sites on the pyrite surface, reducing the adsorption of Ca2+, Ca(OH)+, Mg2+and Mg(OH)+on the pyrite surface. However, the low temperature did not change the existence form and adsorption state of Ca2+ and Mg2+ on the pyrite surface. When the pH value was 9, the calcium and magnesium were adsorbed on the pyrite surface in the form of Ca2+, Ca(OH)+, Mg2+and Mg(OH)+.
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XRD pattern of pyrite
Flotation flowsheet of the single mineral
Effect of pH value on pyrite flotation at different slurry temperature
Effect of concentration of Ca2+ and Mg2+ on pyrite flotation at different slurry temperature
LgC-pH of the components of Ca2+ concentration at different slurry temperature
LgC-pH of the components of Mg2+ concentration at different slurry temperature
Zeta potential of pyrite at different temperature
XPS spectrum of pyrite
High resolution XPS of Fe2p and sub-peak fitting