Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological SciencesHost
2024 No. 2
Article Contents

JIANG Changju, LEI Zhanchang, FAN Zhiping. Study on Leaching of Gallium and Scandium from a Gibbsite-Type Bauxite[J]. Multipurpose Utilization of Mineral Resources, 2024, 45(2): 185-189. doi: 10.3969/j.issn.1000-6532.2024.02.030
Citation: JIANG Changju, LEI Zhanchang, FAN Zhiping. Study on Leaching of Gallium and Scandium from a Gibbsite-Type Bauxite[J]. Multipurpose Utilization of Mineral Resources, 2024, 45(2): 185-189. doi: 10.3969/j.issn.1000-6532.2024.02.030

Study on Leaching of Gallium and Scandium from a Gibbsite-Type Bauxite

  • This is an article in the field of metallurgical engineering. There are high contents of gallium and scandium in bauxite, which has great recovery value. The study on the leaching behavior of gallium and scandium in bauxite leaching process is of great significance for the extraction and utilization of gallium and scandium. The leaching behavior of gallium and scandium from gibbsite bauxite was studied. The results showed that gallium was easy to be leached into the solution. Increasing the temperature, prolonging the reaction time and increasing the mass concentration of sodium hydroxide were conducive to the leaching of gallium. The leaching rate of gallium could reach over 73%, and adding calcium oxide reduced the leaching rate of gallium. The gallium content in the solution was accumulated during the cyclic digestion process. After 3 cycles, the gallium concentration in the decomposition mother liquor reached 24.2 mg/L. Both red mud and decomposition mother liquor had high gallium content and had recycling value. Scandium was not easy to be leached. After digestion, 97.4% of scandium was enriched in red mud. The object of scandium recovery and extraction was mainly red mud.

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  • [1] 王红伟, 徐素鹏, 马科友, 等. 中低品位高铁铝土矿溶出性能研究[J]. 矿产综合利用, 2021(5):92-96+85.WANG H W, XU S P, MA K Y, et al. Research on dissolution performance of lower-medium grade high ferrous bauxite[J]. Multipurpose Utilization of Mineral Resources, 2021(5):92-96+85.

    Google Scholar

    WANG H W, XU S P, MA K Y, et al. Research on dissolution performance of lower-medium grade high ferrous bauxite[J]. Multipurpose Utilization of Mineral Resources, 2021(5):92-96+85.

    Google Scholar

    [2] 刘子宁. 拜耳-烧结串联法氧化铝生产工艺简析[J]. 世界有色金属, 2018(21): 7+9.LIU Z N. Brief analysis of alumina production process by Bayer-sintering series process [J]. World Nonferrous Metals, 2018(21): 7+9.

    Google Scholar

    LIU Z N. Brief analysis of alumina production process by Bayer-sintering series process [J]. World Nonferrous Metals, 2018(21): 7+9.

    Google Scholar

    [3] 王恒玉, 赵瑜, 房辉. 石灰对三水铝土矿溶出氧化铝的影响[J]. 湿法冶金, 2020, 39(5):376-379.WANG H Y, ZHAO Y, FANG H. Influence of lime on leaching of alumina in bauxite[J]. Hydrometallurgy of China, 2020, 39(5):376-379.

    Google Scholar

    WANG H Y, ZHAO Y, FANG H. Influence of lime on leaching of alumina in bauxite[J]. Hydrometallurgy of China, 2020, 39(5):376-379.

    Google Scholar

    [4] 王明理, 皮溅清, 王一霖, 等. 广西某地区沉积型和堆积型铝土矿溶出性能分析[J]. 矿冶工程, 2021, 41(4):84-87+92.WANG M L, PI J Q, WANG Y L, et al. Analysis of dissolubility of sedimentary bauxite and accumulative bauxite from Guangxi[J]. Mining and Metallurgical Engineering, 2021, 41(4):84-87+92.

    Google Scholar

    WANG M L, PI J Q, WANG Y L, et al. Analysis of dissolubility of sedimentary bauxite and accumulative bauxite from Guangxi[J]. Mining and Metallurgical Engineering, 2021, 41(4):84-87+92.

    Google Scholar

    [5] 丁国峰, 吕振福. 镓—战略性矿产家族的新成员[J]. 地球, 2021 (4): 62-67.DING G F, LYU Z F. Gallium -- a new member of the strategic mineral family [J]. Earth, 2021(4): 62-67.

    Google Scholar

    DING G F, LYU Z F. Gallium -- a new member of the strategic mineral family [J]. Earth, 2021(4): 62-67.

    Google Scholar

    [6] 满剑奇, 程立媛, 李文慧, 等. 用高温焙烧—盐酸浸出法从粉煤灰中浸出镓[J]. 湿法冶金, 2022, 41(1): 14-19.MAN J Q, CHENG L Y, LI W H, et al. Leaching of gallium from fly ash by high temperature roasting-hydrochloric acid leaching method [J]. Hydrometallurgy of China, 2022, 41(1): 14-19.

    Google Scholar

    MAN J Q, CHENG L Y, LI W H, et al. Leaching of gallium from fly ash by high temperature roasting-hydrochloric acid leaching method [J]. Hydrometallurgy of China, 2022, 41(1): 14-19.

    Google Scholar

    [7] 武秋杰, 吕振福, 曹进成, 等. 国内外镓资源分布供需及镓产业链发展现状研究[J]. 矿产综合利用, 2021(5):38-44.WU Q J, LYU Z F, CAO J C, et al. Study on distribution and supply of gallium resources domestically and abroad and the present situation of the industry chain of gallium[J]. Multipurpose Utilization of Mineral Resources, 2021(5):38-44.

    Google Scholar

    WU Q J, LYU Z F, CAO J C, et al. Study on distribution and supply of gallium resources domestically and abroad and the present situation of the industry chain of gallium[J]. Multipurpose Utilization of Mineral Resources, 2021(5):38-44.

    Google Scholar

    [8] 路梦雨, 王智勇, 戴惠新, 等. 从赤泥中回收钪研究进展[J]. 矿产综合利用, 2021(5):9-16.LU M Y, WANG Z Y, DAI H X, et al. Research progress of recovering scandium from red mud[J]. Multipurpose Utilization of Mineral Resources, 2021(5):9-16.

    Google Scholar

    LU M Y, WANG Z Y, DAI H X, et al. Research progress of recovering scandium from red mud[J]. Multipurpose Utilization of Mineral Resources, 2021(5):9-16.

    Google Scholar

    [9] 董方, 高利坤, 陈龙, 等. 钪的资源及回收提取技术发展现状[J]. 矿产综合利用, 2016(4):21-26.DONG F, GAO L K, CHEN L, et al. Scandium resources and status of scandium extraction and recycling technology[J]. Multipurpose Utilization of Mineral Resources, 2016(4):21-26.

    Google Scholar

    DONG F, GAO L K, CHEN L, et al. Scandium resources and status of scandium extraction and recycling technology[J]. Multipurpose Utilization of Mineral Resources, 2016(4):21-26.

    Google Scholar

    [10] 罗星, 马荣锴, 李勇, 等. 从广西某赤泥中盐酸浸出钪实验研究[J]. 矿冶工程, 2020, 40(2):98-100.LUO X, MA R K, LI Y, et al. Experimental study on hydrochloric acid leaching of scandium from red mud in Guangxi[J]. Mining and Metallurgical Engineering, 2020, 40(2):98-100.

    Google Scholar

    LUO X, MA R K, LI Y, et al. Experimental study on hydrochloric acid leaching of scandium from red mud in Guangxi[J]. Mining and Metallurgical Engineering, 2020, 40(2):98-100.

    Google Scholar

    [11] 赵艺森, 王海芳, 魏阳. 赤泥的综合利用研究进展[J]. 现代化工, 2019, 39(3):55-58.ZHAO Y S, WANG H F, WEI Y. Advances in comprehensive utilization of red mud[J]. Modern Chemical Industry, 2019, 39(3):55-58.

    Google Scholar

    ZHAO Y S, WANG H F, WEI Y. Advances in comprehensive utilization of red mud[J]. Modern Chemical Industry, 2019, 39(3):55-58.

    Google Scholar

    [12] 张海坤, 胡鹏, 姜军胜, 等. 铝土矿分布特点、主要类型与勘查开发现状[J]. 中国地质, 2021, 48(1):68-81.ZHANG H K, HU P, JIANG J S, et al. Distribution, genetic types and current situation of exploration and development of bauxite resources[J]. Geology in China, 2021, 48(1):68-81.

    Google Scholar

    ZHANG H K, HU P, JIANG J S, et al. Distribution, genetic types and current situation of exploration and development of bauxite resources[J]. Geology in China, 2021, 48(1):68-81.

    Google Scholar

    [13] 韩一杰, 房晓红, 曾凡桂. 氧化镓在铝土矿中吸附的分子模拟[J]. 煤炭技术, 2016, 35(8):298-299.HAN Y J, FANG X H, ZENG F G, et al. Molecular simulation of gallium oxide adsorption in bauxite[J]. Coal Technology, 2016, 35(8):298-299.

    Google Scholar

    HAN Y J, FANG X H, ZENG F G, et al. Molecular simulation of gallium oxide adsorption in bauxite[J]. Coal Technology, 2016, 35(8):298-299.

    Google Scholar

    [14] 韩一杰. 镓在铝土矿中赋存形态的分子模拟[D]. 太原: 太原理工大学, 2016.HAN Y J. Molecular simulation of the occurrences of gallium in bauxite [D]. Taiyuan: Taiyuan University of Technology, 2016.

    Google Scholar

    HAN Y J. Molecular simulation of the occurrences of gallium in bauxite [D]. Taiyuan: Taiyuan University of Technology, 2016.

    Google Scholar

    [15] 崔保河. 氧化铝生产过程中金属镓回收现状及展望[J]. 轻金属, 2020(12):14-16+39.CUI B H. Current situation and prospect of gallium recovery in alumina production[J]. Light Metals, 2020(12):14-16+39.

    Google Scholar

    CUI B H. Current situation and prospect of gallium recovery in alumina production[J]. Light Metals, 2020(12):14-16+39.

    Google Scholar

    [16] 徐梦, 辛志峰, 李婷, 等. 水热碱溶法从粉煤灰中浸出镓的研究[J]. 矿冶工程, 2016, 36(4):68-71.XU M, XIN Z F, LI T, et al. Extraction of gallium from fly ash by hydrothermal process with alkali dissolution[J]. Mining and Metallurgical Engineering, 2016, 36(4):68-71.

    Google Scholar

    XU M, XIN Z F, LI T, et al. Extraction of gallium from fly ash by hydrothermal process with alkali dissolution[J]. Mining and Metallurgical Engineering, 2016, 36(4):68-71.

    Google Scholar

    [17] 陈福亮, 雷霆, 万多稳, 等. 氧化铝生产过程中金属镓的回收[J]. 云南冶金, 2010, 39(4):40-42.CHEN F L, LEI T, WAN D W, et al. Recycling of metallic gallium in the production of alumina[J]. Yunnan Metallurgy, 2010, 39(4):40-42.

    Google Scholar

    CHEN F L, LEI T, WAN D W, et al. Recycling of metallic gallium in the production of alumina[J]. Yunnan Metallurgy, 2010, 39(4):40-42.

    Google Scholar

    [18] 陈硕, 李兵, 谭海军, 等. 高压密闭消解-ICP-OES法同时测定赤泥中主量、次量与痕量元素[J]. 现代化工, 2021, 41(5):241-244.CHEN S, LI B, TAN H J, et al. Simultaneous determination of major, minor and trace elements in red mud by high-pressure closed digestion and ICP-OES[J]. Modern Chemical Industry, 2021, 41(5):241-244.

    Google Scholar

    CHEN S, LI B, TAN H J, et al. Simultaneous determination of major, minor and trace elements in red mud by high-pressure closed digestion and ICP-OES[J]. Modern Chemical Industry, 2021, 41(5):241-244.

    Google Scholar

    [19] 顾振华, 卿山, 张玉辉, 等. 赤泥特性及资源化应用现状[J]. 应用化工, 2020, 49(8):2087-2090.GU Z H, QING S, ZHANG Y H, et al. Characteristics and comprehensive utilization status of red mud[J]. Applied Chemical Industry, 2020, 49(8):2087-2090.

    Google Scholar

    GU Z H, QING S, ZHANG Y H, et al. Characteristics and comprehensive utilization status of red mud[J]. Applied Chemical Industry, 2020, 49(8):2087-2090.

    Google Scholar

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