Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological SciencesHost
2024 No. 2
Article Contents

LI Mingdong, FU Dejin, GOU Bibo, WANG Jiawei, WANG Haifeng. Preparation of No Burning Building Materials by Phosphogypsum Heat Treatment[J]. Multipurpose Utilization of Mineral Resources, 2024, 45(2): 23-29. doi: 10.3969/j.issn.1000-6532.2024.02.004
Citation: LI Mingdong, FU Dejin, GOU Bibo, WANG Jiawei, WANG Haifeng. Preparation of No Burning Building Materials by Phosphogypsum Heat Treatment[J]. Multipurpose Utilization of Mineral Resources, 2024, 45(2): 23-29. doi: 10.3969/j.issn.1000-6532.2024.02.004

Preparation of No Burning Building Materials by Phosphogypsum Heat Treatment

More Information
  • This is an article in the field of ceramics and composites. Phosphogypsum has a large discharge and low utilization rate,and resource utilization is imminent. The heat treatment of phosphogypsum under different temperatures was studied. The influence of heat treatment temperature on the physical phase and microstructure of phosphogypsum, and the compressive strength, phase and microstructure of non burningsample of building materials by the treated phosphogypsum were studied. The results show that with the increase of heat treatment temperature, the crystallinity of gypsum increases and the crystal form changes. After heat treatment at 80 ℃, the crystal of gypsum is dense, and part of it is converted into hemihydrate gypsum. The Gypsum dihydrate formed by hydration recrystallization of hemihydrate gypsum fills the void, forming the internal microstructure of dense and mutual bonding of crystals, so the compressive strength of no burning building materials is greatly improved. After curing for 7 days and 28 days, the compressive strength of non burningsample (the mass ratio of phosphogypsum to cement is 4∶1) reaches 36.45 MPa and 38.12 MPa. The compressive strength of the sample soaked in water for 24 hours is still 21.03 MPa.

  • 加载中
  • [1] 马丽萍. 云南磷石膏资源化综合利用现状及发展思考[J]. 云南化工, 2019, 46(11):48-56.MA L P. Yunnan phosphogypsum resource utilization status quo and development thinking[J]. Yunnan Chemical Industry, 2019, 46(11):48-56.

    Google Scholar

    MA L P. Yunnan phosphogypsum resource utilization status quo and development thinking[J]. Yunnan Chemical Industry, 2019, 46(11):48-56.

    Google Scholar

    [2] 唐湘平, 李超, 黄云阶, 等. 四川某地磷石膏开发利用试验研究[J]. 矿产综合利用, 2019(5): 28-31.TANG X P, LI C , HUANG Y J, et al. Experimental study on development and utilization of phosphogypsum in Sichuan[J]. Multipurpose Utilization of Mineral Resources, 2019(5): 28-31.

    Google Scholar

    TANG X P, LI C , HUANG Y J, et al. Experimental study on development and utilization of phosphogypsum in Sichuan[J]. Multipurpose Utilization of Mineral Resources, 2019(5): 28-31.

    Google Scholar

    [3] 胡敏, 彭丽, 郭娜, 等. 磷石膏- 炭化污泥胶凝材料力学性能试验研究[J]. 矿产综合利用, 2020(4):196-201.HU M, PENG L, GUO N, et al. Study on mechanical properties of phosphogypsum-carbonized sludge composite cementitious materials[J]. Multipurpose Utilization of Mineral Resources, 2020(4):196-201.

    Google Scholar

    HU M, PENG L, GUO N, et al. Study on mechanical properties of phosphogypsum-carbonized sludge composite cementitious materials[J]. Multipurpose Utilization of Mineral Resources, 2020(4):196-201.

    Google Scholar

    [4] 牛福生, 吴海军, 吴根, 等. 铁尾矿地砖的制备及其机理分析[J]. 再生资源研究, 2007(4):41-44.NIU F S, WU H J, WU G, et al. Preparation of iron tailings floor tile and its mechanism analysis[J]. Renewable Resources Research, 2007(4):41-44.

    Google Scholar

    NIU F S, WU H J, WU G, et al. Preparation of iron tailings floor tile and its mechanism analysis[J]. Renewable Resources Research, 2007(4):41-44.

    Google Scholar

    [5] 赵士豪, 王桂明, 孙涛, 等. 过硫磷石膏水泥砌筑用免烧砖的制备及养护制度研究[J]. 建材世界, 2017, 38(2):18-21.ZHAO S H, WANG G M, SUN T, et al. Research on the preparation and maintenance system of free-fired bricks for masonry with persulfurized phosphogypsum cement[J]. Building materials world, 2017, 38(2):18-21.

    Google Scholar

    ZHAO S H, WANG G M, SUN T, et al. Research on the preparation and maintenance system of free-fired bricks for masonry with persulfurized phosphogypsum cement[J]. Building materials world, 2017, 38(2):18-21.

    Google Scholar

    [6] 郭小雨, 樊传刚, 裴立宅, 等. 磷石膏免烧砖的性能及其重金属离子固定研究[J]. 新型建筑材料, 2020, 47(10): 127-131.GUO X Y , FAN C G, PEI L Z, et al. Study on the properties of phosphogypsum no-burn bricks and their heavy metal ion immobilization[J]. New Building Materials, 2020, 47(10): 127-131.

    Google Scholar

    GUO X Y , FAN C G, PEI L Z, et al. Study on the properties of phosphogypsum no-burn bricks and their heavy metal ion immobilization[J]. New Building Materials, 2020, 47(10): 127-131.

    Google Scholar

    [7] 田佳瑜, 王海峰, 尤晓宇, 等. 磷石膏激发预处理及其制备免烧建材的研究[J]. 硅酸盐通报, 2020, 39(12):3897-3904.TIAN J Y, WANG H F, YOU X Y, et al. Research on phosphogypsum excitation pretreatment and its preparation of no-burn building materials[J]. Silicate Bulletin, 2020, 39(12):3897-3904.

    Google Scholar

    TIAN J Y, WANG H F, YOU X Y, et al. Research on phosphogypsum excitation pretreatment and its preparation of no-burn building materials[J]. Silicate Bulletin, 2020, 39(12):3897-3904.

    Google Scholar

    [8] Haifeng Wang , Xiaoyu You, Jiayu Tian, et al. Study on pretreatment of phosphogypsum and preparation of non burning building materials[J]. Earth and Environmental Science. 2021, 668: 012076

    Google Scholar

    [9] 高辉. 高掺量磷石膏免烧砖制备新工艺及机理研究[D]. 武汉: 中国地质大学(武汉), 2012.GAO H. Research on new process and mechanism of preparation of high dosage phosphogypsum no-burn bricks [D]. Wuhan: China University of Geosciences (Wuhan), 2012.

    Google Scholar

    GAO H. Research on new process and mechanism of preparation of high dosage phosphogypsum no-burn bricks [D]. Wuhan: China University of Geosciences (Wuhan), 2012.

    Google Scholar

    [10] 茹晓红. 磷石膏基胶凝材料的制备理论及应用技术研究[D]. 武汉: 武汉理工大学, 2013.RU X H. Research on the preparation theory and application technology of phosphogypsum-based cementitious materials[D]. Wuhan: Wuhan University of Technology, 2013.

    Google Scholar

    RU X H. Research on the preparation theory and application technology of phosphogypsum-based cementitious materials[D]. Wuhan: Wuhan University of Technology, 2013.

    Google Scholar

  • 加载中
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Figures(8)

Tables(1)

Article Metrics

Article views(504) PDF downloads(72) Cited by(0)

Access History

Other Articles By Authors

Catalog

    /

    DownLoad:  Full-Size Img  PowerPoint