Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological SciencesHost
2024 No. 1
Article Contents

CAO Yaohua, WANG Wei, LIU Hongzhao, LIU Lin, ZHANG Bo. A New Process of Leaching Copper and Cobalt from Copper Cobalt Oxide Ore in DR Congo[J]. Multipurpose Utilization of Mineral Resources, 2024, 45(1): 135-138. doi: 10.3969/j.issn.1000-6532.2024.01.016
Citation: CAO Yaohua, WANG Wei, LIU Hongzhao, LIU Lin, ZHANG Bo. A New Process of Leaching Copper and Cobalt from Copper Cobalt Oxide Ore in DR Congo[J]. Multipurpose Utilization of Mineral Resources, 2024, 45(1): 135-138. doi: 10.3969/j.issn.1000-6532.2024.01.016

A New Process of Leaching Copper and Cobalt from Copper Cobalt Oxide Ore in DR Congo

More Information
  • This is an article in the field of metallurgical engineering. A copper cobalt ore Congo is an oxide ore with Cu 3.43% and Co 0.42% respectively. In this paper, the five stage cycle leaching process of leaching solution was used for the copper and cobalt leaching. The optimum conditions were as follows: the amount of sulfuric acid was 7.4% of the ore mass, the amount of sodium sulfite was 1.68 times of the theoretical amount, the grinding particle size of -74 μm accounts for 75%, leaching temperature was 45 ℃, the single-stage leaching time was 4 hours, and the liquid-solid volume mass ratio was between 2/1 and 3/1, the results showed that the leaching rate of copper and cobalt were 96.85% and 95.67% respectively. According to this leaching process, the amount of sulfuric acid was reduced by 6 kg/t compared with the primary leaching, and the total solution amount in the leaching process was reduced by about 1/4, which made the amount of subsequent cobalt precipitation and copper extraction solution was reduced.

  • 加载中
  • [1] 张汉彪, 薛伟. 刚果(金)某复杂难选氧化铜矿选矿试验研究[J]. 矿产综合利用, 2020(3):117-120. ZHANG H B, XUE W. Experimental study on beneficiation of a complex refractory copper oxide ore in Congo (DRC)[J]. Multipurpose Utilization of Mineral Resources, 2020(3):117-120.

    Google Scholar

    ZHANG H B, XUE W. Experimental study on beneficiation of a complex refractory copper oxide ore in Congo (DRC) [J]. Multipurpose Utilization of Mineral Resources, 2020(3): 117-120.

    Google Scholar

    [2] 张兴勋, 康锦程, 谭希发, 等. 刚果(金)某铜钴资源综合利用生产调试总结[J]. 有色金属(冶炼部分), 2020(7):20-25. ZHANG X X, KANG J C, TAN X F, et al. Production debugging summary of copper and cobalt resource comprehensive utilization in Congo(DRC)[J]. Nonferrous Metals (Extractive Metallurgy), 2020(7):20-25.

    Google Scholar

    ZH ANG X X , KANG J C , TAN X F, et al. Production debugging summary of copper and cobalt resource comprehensive utilization in Congo(DRC) [J]. Nonferrous Metals (Extractive Metallurgy), 2020(7): 20 -25.

    Google Scholar

    [3] 于文圣. 从刚果(金)某铜钴氧化矿石中直接还原浸出铜钴[J]. 湿法冶金, 2019, 38(2):88-91. YU W S. Direct reduction leaching of copper and cobalt in oxide ore from Congo(Kinshasa)[J]. Hydrometallurgy of China, 2019, 38(2):88-91.

    Google Scholar

    YU W S. Direct reduction leaching of copper and cobalt in oxide ore from Congo(Kinshasa) [J]. Hydrometallurgy of China, 2019, 38(2): 88-91

    Google Scholar

    [4] 卢苏君, 王书友, 诸葛福瑜, 等. Co(Ⅲ)- Na2SO3-H2SO4体系浸出钴的研究[J]. 有色金属(冶炼部分), 2013(5):17-19. LU S J, WANG S Y, ZHUGE F Y, et al. Study on cobalt leaching in Co(Ⅲ)-Na2SO3-H2SO4 system[J]. Nonferrous Metals ( Extractive Metallurgy), 2013(5):17-19.

    Google Scholar

    LU S J, WANG S Y, ZHUGE F Y, et al. Study on cobalt leaching in Co(Ⅲ)-Na2SO3-H2SO4 system[J]. Nonferrous Metals ( Extractive Metallurgy), 2013(5): 17 -19.

    Google Scholar

    [5] 郭学益, 姚标, 李晓静, 等. 水钴矿中选择性提取铜和钴的新工艺[J]. 中国有色金属学报, 2012, 22(6):1778-1784. GUO X Y, YAO B, LI X J, et al. Novel process of selective extraction of copper and cobalt from heterogenite[J]. The Chinese Journal of Nonferrous Metals, 2012, 22(6):1778-1784.

    Google Scholar

    GUO X Y, YAO B, LI X J, et al. Novel process of selective extraction of copper and cobalt from heterogenite[J]. The Chinese Journal of Nonferrous Metals, 2012, 22(6): 1778-1784.

    Google Scholar

    [6] 张兴勋. 从非洲某铜钴矿石中浸出铜钴实验研究[J]. 湿法冶金, 2019, 38(4):259-262. ZHANG X X. Leaching of copper and cobalt in a copper-cobalt ore from Africa[J]. Hydrometallurgy of China, 2019, 38(4):259-262.

    Google Scholar

    ZHANG X X. Leaching of copper and cobalt in a copper-cobalt ore from Africa. [J]. Hydrometallurgy of China, 2019, 38(4): 259-262.

    Google Scholar

    [7] 刘大学, 王云, 袁朝新, 等. 某铜钴矿的硫酸还原浸出研究[J]. 有色金属(冶炼部分), 2013(6):18-21. LIU D X, WANG Y, YUAN C X, et al. Study onsulfuric acid reduction leaching on copper-cobalt ore[J]. Nonferrous Metals ( Extractive Metallurgy), 2013(6):18-21.

    Google Scholar

    LIU D X, WANG Y, YUAN C X, et al. Study onsulfuric acid reduction leaching on copper-cobalt ore[J]. Nonferrous Metals ( Extractive Metallurgy), 2013 ( 6 ): 18-21.

    Google Scholar

    [8] 李强, 郜伟, 阮书峰. 低品位氧化铜钴矿的直接还原浸出[J]. 矿冶, 2019, 28(3):60-63. LI Q, GAO W, RUAN S F. Direct reduction leaching of a low-grade copper-cobalt oxide ore[J]. Ming& Metallurgy, 2019, 28(3):60-63.

    Google Scholar

    LI Q, GAO W, RUAN S F. Direct reduction leaching of a low-grade copper-cobalt oxide ore[J]. Ming& Metallurgy, 2019, 28(3): 60-63.

    Google Scholar

    [9] 曹耀华, 王威, 刘红召, 等. 从某铜、钴氧化矿石中浸出铜钴试验研究[J]. 湿法冶金, 2020, 39(6):478-482. CAO Y H, WANG W, LIU H Z, et al. Leaching of copper and cobalt from copper-cobalt oxide Ore[J]. Hydrometallurgy of China, 2020, 39(6):478-482.

    Google Scholar

    CAO Y H, WANG W, LIU H Z, et al. Leaching of copper and cobalt from copper-cobalt oxide Ore[J]. Hydrometallurgy of China, 2020, 39(6): 478-482.

    Google Scholar

  • 加载中
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Figures(1)

Tables(5)

Article Metrics

Article views(938) PDF downloads(140) Cited by(0)

Access History

Other Articles By Authors

Catalog

    /

    DownLoad:  Full-Size Img  PowerPoint