Adsorption Characteristics of Iron Ion Activated Quartz in Sodium Oleate System

Zhao Tonglin; Liu Shuyong; Han Baisui; Li Longfei

doi:10.3969/j.issn.1000-6532.2023.06.005

2023 No. 6

Article Contents

Article navigation > Multipurpose Utilization of Mineral Resources > 2023 > 44(6): 30-35

Next Article Previous Article

Zhao Tonglin, Liu Shuyong, Han Baisui, Li Longfei. Adsorption Characteristics of Iron Ion Activated Quartz in Sodium Oleate System[J]. Multipurpose Utilization of Mineral Resources, 2023, 44(6): 30-35. doi: 10.3969/j.issn.1000-6532.2023.06.005

Citation:

Zhao Tonglin, Liu Shuyong, Han Baisui, Li Longfei. Adsorption Characteristics of Iron Ion Activated Quartz in Sodium Oleate System[J]. Multipurpose Utilization of Mineral Resources, 2023, 44(6): 30-35. doi: 10.3969/j.issn.1000-6532.2023.06.005

Adsorption Characteristics of Iron Ion Activated Quartz in Sodium Oleate System

1.
School of Mining Engineering, University of Science and Technology Liaoning, Anshan, Liaoning, China
2.
Donganshan Sintering Plant，Ansteel Group Corporation，Anshan, Liaoning, China
3.
Barun Mining Co., Ltd., Baogang Steel Group, Baotou, Inner Mongolia, China

More Information

Corresponding author: Liu Shuyong, 2392532945@qq.com

Received Date: 16 November 2021

Publish Date: 25 December 2023

Abstract

Abstract

This is an essay in the field of mineral processing engineering. The effect of Fe²⁺ and Fe³⁺ on the flotation behavior of quartz in the oleic acid anionic collector system was studied by pure mineral flotation test, and the mechanism of Fe³⁺ activated quartz was studied by infrared spectroscopy, atomic force microscopy imaging analysis and Zeta potential measurement analysis. The results of pure mineral flotation test showed that the activation effect of Fe³⁺ was stronger than that of Fe²⁺, and the capture effect of sodium oleate was stronger than that of sodium linoleate under the condition of Fe³⁺ as the activation ion. The results of infrared spectroscopy and atomic force microscopy showed that sodium oleate could not effectively adsorb on the surface of unactivated quartz minerals, but could effectively adsorb on the surface of quartz activated by Fe³⁺. The results of Zeta potential analysis showed that the positive potential of quartz surface activated by Fe³⁺ reached the maximum at pH 6.0, and the activated quartz was basically positive.
- Mineral processing engineering /
- Flotation /
- Quartz /
- Iron ion /
- Anion collector /
- Activation

FullText(HTML)

References

[1]	刘泽伟, 邹玄, 赵阳, 等. 某石英砂矿制取高纯石英工艺的研究[J]. 矿产综合利用, 2020(4):111-115. LIU Z W, ZOU X, ZHAO Y, et al. Study on the process of producing high-purity quartz from a quartz sand mine[J]. Multipurpose Utilization of Mineral Resources, 2020(4):111-115. doi: 10.3969/j.issn.1000-6532.2020.04.018 CrossRef Google Scholar LIU Z W, ZOU X, ZHAO Y, et al. Study on the process of producing high-purity quartz from a quartz sand mine[J]. Multipurpose Utilization of Mineral Resources, 2020(4): 111-115. doi: 10.3969/j.issn.1000-6532.2020.04.018 CrossRef Google Scholar
[2]	王杨, 陈留慧. 某金矿尾矿提纯石英应用对比实验研究[J]. 矿产综合利用, 2021(2):159-162. WANG Y, CHEN L H. Study on comparative test for the application of purified quartz from a gold ore tailings[J]. Multipurpose Utilization of Mineral Resources, 2021(2):159-162. doi: 10.3969/j.issn.1000-6532.2021.02.027 CrossRef Google Scholar WANG Y, CHEN L H. Study on comparative test for the application of purified quartz from a gold ore tailings [J]. Multipurpose Utilization of Mineral Resources, 2021(2): 159-162. doi: 10.3969/j.issn.1000-6532.2021.02.027 CrossRef Google Scholar
[3]	León M, Martín P, Vila R, et al. Neutron irradiation effects on optical absorption of KU1 and KS-4V quartz glasses and Infrasil 301[J]. Fusion Engineering & Design, 2009, 84(7-11):1174-1178. Google Scholar
[4]	Pyo, Sukhoon, Tafesse, et al. Effects of quartz-based mine tailings on characteristics and leaching behavior of ultra-high performance concrete[J]. Construction and Building Materials, 2018. Google Scholar
[5]	林敏, 裴振宇, 熊康, 等. 我国高纯石英制备技术现状[J]. 矿产综合利用, 2017(5):18-21. LIN M, PEI Z Y, XIONG K, et al. Situation of high-purity quartz preparation in China[J]. Multipurpose Utilization of Mineral Resources, 2017(5):18-21. doi: 10.3969/j.issn.1000-6532.2017.05.004 CrossRef Google Scholar LIN M, PEI Z Y, XIONG K, et al. Situation of high-purity quartz preparation in China[J]. Multipurpose Utilization of Mineral Resources, 2017(5): 18-21. doi: 10.3969/j.issn.1000-6532.2017.05.004 CrossRef Google Scholar
[6]	吴中贤, 姜效军, 陶东平. 新型胶磷矿反浮选脱硅阳离子捕收剂实验研究[J]. 矿产综合利用, 2020(5):92-100. WU Z X, JIANG X J, TAO D P. Experimental study on a novel cationic collector for reverse flotation of collophane for silica removal[J]. Multipurpose Utilization of Mineral Resources, 2020(5):92-100. doi: 10.3969/j.issn.1000-6532.2020.05.013 CrossRef Google Scholar WU Z X, JIANG X J, TAO D P. Experimental study on a novel cationic collector for reverse flotation of collophane for silica removal[J]. Multipurpose Utilization of Mineral Resources, 2020(5): 92-100. doi: 10.3969/j.issn.1000-6532.2020.05.013 CrossRef Google Scholar
[7]	徐廷航, 龙秉文, 张逸, 等. 磷矿反浮选脱硅药剂的合成与应用[J]. 矿产综合利用, 2021(3):57-63. XU T H, LONG B W, ZHANG Y, et al. Synthesis and application of silicon removal reagent for reverse flotation of phosphate rock[J]. Multipurpose Utilization of Mineral Resources, 2021(3):57-63. Google Scholar XU T H, LONG B W, ZHANG Y, et al. Synthesis and application of silicon removal reagent for reverse flotation of phosphate rock[J]. Multipurpose Utilization of Mineral Resources, 2021(3): 57-63. Google Scholar
[8]	Filippov L O, Severov V V, Filippova I V. An overview of the beneficiation of iron ores via reverse cationic flotation[J]. International Journal of Mineral Processing, 2014, 127:62-69. doi: 10.1016/j.minpro.2014.01.002 CrossRef Google Scholar
[9]	陈俐全, 张凌燕, 陈志强, 等. 铝离子对油酸钠浮选石英的影响及作用机理[J]. 金属矿山, 2018(1):120-124. CHEN L Q, ZHANG L Y, CHEN Z Q, et al. Effect and mechanism of aluminum ion on quartz flotation in the system of sodium oleate[J]. Metal Mine, 2018(1):120-124. doi: 10.19614/j.cnki.jsks.201801024 CrossRef Google Scholar CHEN L Q, ZHANG L Y, CHEN Z Q, et al. Effect and mechanism of aluminum ion on quartz flotation in the system of sodium oleate[J]. Metal Mine, 2018(1): 120-124. doi: 10.19614/j.cnki.jsks.201801024 CrossRef Google Scholar
[10]	Zhang J, Wang W, Liu J, et al. Fe(III) as an activator for the flotation of spodumene, albite, and quartz minerals[J]. Minerals Engineering, 2014. Google Scholar
[11]	Liu A, Fan J C, Fan M Q. Quantum chemical calculations and molecular dynamics simulations of amine collector adsorption on quartz ( 0 1) surface in the aqueous solution[J]. International Journal of Mineral Processing, 2015, 134:1-10. doi: 10.1016/j.minpro.2014.11.001 CrossRef Google Scholar
[12]	Potapova E, Grahn M, Holmgren A, et al. The effect of calcium ions and sodium silicate on the adsorption of a model anionic flotation collector on magnetite studied by ATR-FTIR spectroscopy[J]. Journal of Colloid & Interface Science, 2010, 345(1):96-102. Google Scholar
[13]	欧乐明, 叶家笋, 曾维伟, 等. 铁离子和亚铁离子对菱锌矿和石英浮选的影响[J]. 有色金属(选矿部分), 2012(6):79-82. OU L M, YE J S, ZENG W W, et al. Influence and mechanism of ferric and ferrous ions on flotation of smithsonite and quartz[J]. Nonferrous Metals(Mineral Processing Section), 2012(6):79-82. Google Scholar OU L M, YE J S, ZENG W W, et al. Influence and mechanism of ferric and ferrous ions on flotation of smithsonite and quartz[J]. Nonferrous Metals(Mineral Processing Section), 2012(6): 79-82. Google Scholar
[14]	唐劭禹, 张凌燕, 张冲, 等. Fe³⁺对十二烷基磺酸钠捕收石英的活化作用研究[J]. 非金属矿, 2017, 40(5):79-81. TANG S Y, ZHANG L Y, ZHANG C, et al. Study on activation of sodium dodecyl sulfonate collecting quartz by Fe³⁺[J]. Non-Metallic Mines, 2017, 40(5):79-81. doi: 10.3969/j.issn.1000-8098.2017.05.024 CrossRef Google Scholar TANG S Y, ZHANG L Y, ZHANG C, et al. Study on activation of sodium dodecyl sulfonate collecting quartz by Fe³⁺[J]. Non-Metallic Mines, 2017, 40(5): 79-81. doi: 10.3969/j.issn.1000-8098.2017.05.024 CrossRef Google Scholar
[15]	周海玲, 刘永胜. 油酸钠在红柱石与粉石英表面的吸附机理[J]. 矿产综合利用, 2020(2):198-202. ZHOU H L, LIU Y S. Adsorption mechanism of sodium oleate on andalusite[J]. Multipurpose Utilization of Mineral Resources, 2020(2):198-202. doi: 10.3969/j.issn.1000-6532.2020.02.036 CrossRef Google Scholar ZHOU H L, LIU Y S. Adsorption mechanism of sodium oleate on andalusite[J]. Multipurpose Utilization of Mineral Resources, 2020(2): 198-202. doi: 10.3969/j.issn.1000-6532.2020.02.036 CrossRef Google Scholar
[16]	寇珏, 郭玉, 孙体昌, 等. 2种阴离子捕收剂在石英表面的吸附机理[J]. 中南大学学报(自然科学版), 2015, 46(11):4005-4014. KOU J, GUO Y, SUN T C, et al. Adsorption mechanism of two different anionic collectors on quartz surface[J]. Journal of Central South University(Science and Technology), 2015, 46(11):4005-4014. Google Scholar KOU J, GUO Y, SUN T C, et al. Adsorption mechanism of two different anionic collectors on quartz surface[J]. Journal of Central South University(Science and Technology), 2015, 46(11): 4005-4014. Google Scholar
[17]	吴卫国, 孙传尧, 朱永楷. 有机螯合剂对活化石英的抑制及其作用机理[J]. 金属矿山, 2007(2):33-37. WU W G, SUN C Y, ZHU Y K. Depression of organic chelating agents on activated quartz its mechanism[J]. Metal Mine, 2007(2):33-37. doi: 10.3321/j.issn:1001-1250.2007.02.010 CrossRef Google Scholar WU W G, SUN C Y, ZHU Y K. Depression of organic chelating agents on activated quartz its mechanism[J]. Metal Mine, 2007(2): 33-37. doi: 10.3321/j.issn:1001-1250.2007.02.010 CrossRef Google Scholar