Citation: | Xiao Junjie, Kuang Jingzhong, Yu Mingming, Qiu Tingsheng, Zhang Shaoyan, Wang Xiaoyuan. Research Progress on Comprehensive Utilization of Tungsten Tailings[J]. Multipurpose Utilization of Mineral Resources, 2023, 44(5): 120-126. doi: 10.3969/j.issn.1000-6532.2023.05.021 |
This is an essay in the field of mining engineering, which summarized the current situation and characteristics of tungsten tailings resources, and expounds the urgency and necessity of comprehensive utilization of tungsten tailings resources under the requirements of current economic development and environmental protection. The research status of recovery of valuable metal and valuable non-metals in tungsten tailings was comprehensively evaluated. The application and application prospects of tungsten tailings in new building materials were introduced in detail. Combined with the current research focus on tungsten tailings resources in China, the development direction of comprehensive utilization of tungsten tailings is proposed.
[1] | 范景莲, 李鹏飞, 刘涛, 等. 高性能细晶钨及钨合金的研究进展[J]. 中国钨业, 2015, 30(2):41-48. FAN J L, LI P F, LIU T, et al. Advances in fine grained tungsten and tungsten alloys with high performance[J]. China Tungsten Industry, 2015, 30(2):41-48. FAN J L, LI P F, LIU T, et al. Advances in fine grained tungsten and tungsten alloys with high performance[J]. China Tungsten Industry, 2015, 30(2): 41-48. |
[2] | J. Liu, J. Mao, H. Ye, W. Zhang. Geology, geochemistry and age of the Hukeng tungsten deposit, Southern China[J]. Ore Geol. Rev. 43 (2011) 50–61. |
[3] | N. Liu, C. Yu. Complexity of ore-controlling fracture system of Dajishan tungsten deposit, China[J]. Front. Earth Sci. 16 (2009) 320–325. |
[4] | 阎赞, 王想, 徐名特, 等. 尾矿资源化研究在铅锌尾矿中的应用[J]. 矿产综合利用, 2017(1):1-5. YAN Z, WANG X, XU M T, et al. Utilization situation and development trend of lead and zinc tailing resources[J]. Multipurpose Utilization of Mineral Resources, 2017(1):1-5. doi: 10.3969/j.issn.1000-6532.2017.01.001 YAN Z, WANG X, XU M T, et al. Utilization situation and development trend of lead and zinc tailing resources[J]. Multipurpose Utilization of Mineral Resources, 2017(1): 1-5. doi: 10.3969/j.issn.1000-6532.2017.01.001 |
[5] | 彭康, 伦惠林, 李阿鹏, 等. 钨尾矿综合利用的研究进展[J]. 中国资源综合利用, 2013, 31(2):35-38. PENG K, LUN H L, LI A P, et al. Research progress on the comprehensive utilization of tungsten tailings[J]. China Resources Comprehensive Utilization, 2013, 31(2):35-38. doi: 10.3969/j.issn.1008-9500.2013.02.011 PENG K, LUN H L, LI A P, et al. Research progress on the comprehensive utilization of tungsten tailings [J]. China Resources Comprehensive Utilization, 2013, 31(2): 35-38. doi: 10.3969/j.issn.1008-9500.2013.02.011 |
[6] | 中华人民共和国国土资源部. 中国矿产资源报告[R]. 北京: 地质出版社, 2019. Ministry of Land and Resources of the People's Republic of China. China mineral resources report[R]. Beijing: Geological Publishing House, 2019. |
[7] | 兰志强, 蓝卓越, 张镜翠. 钨尾矿资源综合利用研究进展[J]. 中国钨业, 2016, 31(2): 37-42. LAN Z Q, LAN Z Y, ZHANG J C, Research Progress on the comprehensive utilization of tungsten tailings[J]. China Tungsten Industry, 2016, 31(2): 37-42. |
[8] | 苟瑜. 钨业之变[J]. 中国有色金属, 2018(7):27-28. GOU Y. Changes in the tungsten industry[J]. China Nonferrous Metals, 2018(7):27-28. GOU Y. Changes in the tungsten industry[J]. China Nonferrous Metals, 2018(7): 27-28. |
[9] | 袁博, 李钟山, 刘良先, 等. 我国钨资源储备规划形势分析[J]. 中国矿业, 2016, 25(1):15-18. YUAN B, LI Z S, LIU L X, et al. Analysis of the tungsten resources reserve plan in China[J]. China Mining Magazine, 2016, 25(1):15-18. doi: 10.3969/j.issn.1004-4051.2016.01.004 YUAN B, LI Z S, LIU L X, et al. Analysis of the tungsten resources reserve plan in China[J]. China Mining Magazine, 2016, 25(1): 15-18. doi: 10.3969/j.issn.1004-4051.2016.01.004 |
[10] | Liu N, Yu C. Analysis of onset and development of ore formation in Dajishan Tungsten Ore Area, Jiangxi Province, China[J]. Journal of Earth Science, 2011, 22(1):67-74. doi: 10.1007/s12583-011-0158-9 |
[11] | 彭康. 钨尾矿高值化加工与利用的研究[D]. 长沙: 中南大学, 2014. PENG K. Research on high-value processing and utilization of tungsten tailings[D]. Changsha: Central South University, 2014. |
[12] | 张利珍, 赵恒勤, 马化龙, 等. 我国矿山固体废物的资源化利用及处置[J]. 现代矿业, 2012(10):1-5. ZHANG L Z, ZHAO H Q, MA H L, et al. Resource utilization and disposal of mine solid waste in China[J]. Modern Mining, 2012(10):1-5. doi: 10.3969/j.issn.1674-6082.2012.10.001 ZHANG L Z, ZHAO H Q, MA H L, et al. Resource utilization and disposal of mine solid waste in China[J]. Modern Mining, 2012(10) : 1-5. doi: 10.3969/j.issn.1674-6082.2012.10.001 |
[13] | 李涛. 改性钨尾矿地聚合物的制备及其性能研究[D]. 赣州: 江西理工大学, 2017. LI T. Preparation and performance of modified tungsten tailings geopolymer[D]. Ganzhou: Jiangxi University of Science and Technology, 2017. |
[14] | 陈沛云, 冯秀娟. 钨尾矿农田重金属空间分布特征研究[J]. 安徽农业科学, 2011, 39(23):14039-14040. CHEN P Y, FENG X J. Study on spatial distribution of heavy metals in farmland around tungsten tailings[J]. Journal of Anhui Agricultural Sciences, 2011, 39(23):14039-14040. doi: 10.3969/j.issn.0517-6611.2011.23.057 CHEN P Y, FENG X J. Study on spatial distribution of heavy metals in farmland around tungsten tailings[J]. Journal of Anhui Agricultural Sciences, 2011, 39(23): 14039-14040. doi: 10.3969/j.issn.0517-6611.2011.23.057 |
[15] | Liu C P, Luo C L, Gao Y, et al. Arsenic contamination and potential health risk implications at an abandoned tungsten mine, southern China.[J]. Environmental Pollution, 2010, 158(3):820-826. doi: 10.1016/j.envpol.2009.09.029 |
[16] | Petrunic B M, Al T A, Weaver L, et al. Identification and characterization of secondary minerals formed in tungsten mine tailings using transmission electron microscopy[J]. Applied Geochemistry, 2009, 24(12):2222-2233. doi: 10.1016/j.apgeochem.2009.09.014 |
[17] | 卢友中. 选冶联合工艺从钨尾矿及细泥中回收钨的实验研究[J]. 江西理工大学学报, 2009, 30(3):70-73. LU Y Z. Experimental research on recovery of tungsten from tungsten tailings and fine mud by combined process of beneficiation and metallurgy[J]. Journal of Jiangxi University of Science and Technology, 2009, 30(3):70-73. LU Y Z. Experimental research on recovery of tungsten from tungsten tailings and fine mud by combined process of beneficiation and metallurgy[J]. Journal of Jiangxi University of Science and Technology, 2009, 30(3): 70-73. |
[18] | 何桂春, 肖策环. 江西某钨尾矿浮选实验[J]. 有色金属科学与工程, 2015, 6(6):82-87. HE G C, XIAO C H. Experimental study on flotation of wolframite tailings in a Jiangxi tungsten mine[J]. Nonferrous Metals Science and Engineering, 2015, 6(6):82-87. HE G C, XIAO C H. Experimental study on flotation of wolframite tailings in a Jiangxi tungsten mine[J]. Nonferrous Metals Science and Engineering, 2015, 6(6): 82-87. |
[19] | 张光斌, 艾光华. 某白钨浮选尾矿钨再回收利用实验研究[J]. 有色金属(选矿部分), 2018(1):65-69. ZHANG G B, AI G H. Experimental research on recycling and utilizing of scheelite from the flotation tailings in a scheelite mine[J]. Nonferrous Metals Mieral Processing Section, 2018(1):65-69. ZHANG G B, AI G H. Experimental research on recycling and utilizing of scheelite from the flotation tailings in a scheelite mine[J]. Nonferrous Metals Mieral Processing Section, 2018(1): 65-69. |
[20] | 温小毛, 王金敏, 田敏. 悬振锥面选矿机在江西铁山垅钨尾矿中回收细粒级钨的应用[J]. 矿产综合利用, 2020(5):153-157. WEN X M, WANG J M, TIAN M. Application of suspending and vibrating cone concentrator to concentration of micro-fine tungsten of Tieshanlong tungsten tailings in Jiangxi Province[J]. Multipurpose Utilization of Mineral Resources, 2020(5):153-157. doi: 10.3969/j.issn.1000-6532.2020.05.024 WEN X M, WANG J M, TIAN M. Application of suspending and vibrating cone concentrator to concentration of micro-fine tungsten of Tieshanlong tungsten tailings in Jiangxi province[J]. Multipurpose Utilization of Mineral Resources, 2020(5): 153-157. doi: 10.3969/j.issn.1000-6532.2020.05.024 |
[21] | 管建红, 沈新春, 李平, 等. 钨细泥回收工艺研究与应用[J]. 矿产综合利用, 2014(5):38-41. GUAN J H, SHEN X C, LI P, et al. Study and application of the recycling technology of tungsten fine mud[J]. Multipurpose Utilization of Mineral Resources, 2014(5):38-41. doi: 10.3969/j.issn.1000-6532.2014.05.010 GUAN J H, SHEN X C, LI P, et al. Study and application of the recycling technology of tungsten fine mud[J]. Multipurpose Utilization of Mineral Resources, 2014(5): 38-41. doi: 10.3969/j.issn.1000-6532.2014.05.010 |
[22] | 邓巧娟, 车小奎, 郑其, 等. 某钨尾矿综合回收钨铜锌的实验研究[J]. 稀有金属, 2019(5): 541-550. DENG Q J, CHE X K, ZHENG Q, et al. Comprehensive recovery of tungsten, copper and zinc from tungsten tailings[J]. Chinese Journal of Rare Metals, 2019(5): 541-550. |
[23] | Zhao Z, Cao C, Chen X, et al. Separation of macro amounts of tungsten and molybdenum by selective precipitation[J]. Hydrometallurgy, 2011, 108(3):229-232. |
[24] | 袁宪强, 罗仙平, 王笑蕾, 等. 从某钨重选尾矿中回收钼的浮选试验[J]. 金属矿山, 2010(12):171-174. YUAN X Q, LUO X P, WANG X L, et al. Flotation experiments on comprehensive recovery of molybdenum from tungsten gravity tailings[J]. Metal Mine, 2010(12):171-174. YUAN X Q, LUO X P, WANG X L, et al. Flotation experiments on comprehensive recovery of molybdenum from tungsten gravity tailings[J]. Metal Mine, 2010(12): 171-174. |
[25] | 王晨亮, 邱显扬, 邹坚坚, 等. 从钨重选尾矿中回收铋钼选矿试验研究[J]. 矿山机械, 2016, 44(8):53-57. WANG C L, QIU X Y, ZOU J J, et al. Beneficiation test study on recovery of bismuth and molybdenum from tailings of tungsten gravity separation[J]. Mining & Processing Equipment, 2016, 44(8):53-57. WANG C L, QIU X Y, ZOU J J, et al. Beneficiation test study on recovery of bismuth and molybdenum from tailings of tungsten gravity separation[J]. Mining & Processing Equipment, 2016, 44(8): 53-57. |
[26] | 杨斌清. 钨尾矿综合回收铋钼新工艺的研究[J]. 矿产保护与利用, 1997(5):51-53. YANG B Q. A Study on new process of comprehensive of Bi and Mo from a tailings separated of tungsten[J]. Conservation and Utilization of Minerals Resources, 1997(5):51-53. YANG B Q. A Study on new process of comprehensive of Bi and Mo from a tailings separated of tungsten[J]. Conservation and Utilization of Minerals Resources, 1997(5): 51-53. |
[27] | 艾光华, 李继福, 邬海滨, 等. 从某黑白钨尾矿中回收萤石的试验研究[J]. 非金属矿, 2016, 39(3):33-35. AI G H, LI J F, WU H B, et al. Experimental research on recovery of flourite from a tungsten tailings[J]. Non-Metallic Mines, 2016, 39(3):33-35. doi: 10.3969/j.issn.1000-8098.2016.03.011 AI G H, LI J F, WU H B, et al. Experimental research on recovery of flourite from a tungsten tailings[J]. Non-Metallic Mines, 2016, 39(3): 33-35. doi: 10.3969/j.issn.1000-8098.2016.03.011 |
[28] | 邵辉, 赵义, 薛亮. 湖北某钨尾矿中萤石的分选试验[J]. 金属矿山, 2016, V45(1): 190-192. SHAO H, ZHAO Y, XUE L. Experiments on beneficiation of fluorite from tailings in Hubei[J]. Metal Mine, 2016, V45(1): 190-192. |
[29] | 朱一民, 陈文胜, 张晓峰, 等. 白钨浮选尾矿回收萤石低温浮选试验研究[J]. 矿产综合利用, 2014(1):25-27+39. ZHU Y M, CHEN W S, ZHANG X F, et al. Experimental research on recovering fluorite from the scheelite by low temperature[J]. Multipurpose Utilization of Mineral Resources, 2014(1):25-27+39. doi: 10.3969/j.issn.1000-6532.2014.01.006 ZHU Y M, CHEN W S, ZHANG X F, et al. Experimental research on recovering fluorite from the scheelite by low temperature[J]. Multipurpose Utilization of Mineral Resources, 2014(1): 25-27+39. doi: 10.3969/j.issn.1000-6532.2014.01.006 |
[30] | 龙冰. 从湖南某常温浮钨尾矿中浮选回收萤石实验[J]. 金属矿山, 2019(9):195-198. LONG B. Experimental study on recovery of fluorite by flotation from the tailings of tungsten flotation at room temperature in Hunan Province[J]. Metal Mine, 2019(9):195-198. LONG B. Experimental study on recovery of fluorite by flotation from the tailings of tungsten flotation at room temperature in Hunan Province[J]. Metal Mine, 2019(9): 195-198. |
[31] | 吴福初, 刘子帅. 从广西某钨锡尾矿中回收长石与石英[J]. 矿业研究与开发, 2016, 36(7): 18-21. WU F C, LIU Z S. Recovery of feldspar and quartz from tungsten-tin tailings in Guangxi Province[J]. Mining Research and Development, 2016, 36(7): 18-21. |
[32] | 张志峰. 滇西某选钨尾矿中回收绿柱石的研究[J]. 矿产综合利用, 2014(4):56-59. ZHANG Z F. Research on beryl recovery from wolfram tailings in Western Yunnan[J]. Multipurpose Utilization of Mineral Resources, 2014(4):56-59. doi: 10.3969/j.issn.1000-6532.2014.04.013 ZHANG Z F. Research on beryl recovery from wolfram tailings in Western Yunnan[J]. Multipurpose Utilization of Mineral Resources, 2014(4): 56-59. doi: 10.3969/j.issn.1000-6532.2014.04.013 |
[33] | 朱一民, 周菁. 从黄沙坪低品位钼、铋、钨、萤石浮选尾矿中回收石榴石的回收和应用试验研究[J]. 有色矿冶, 2012, 28(3):31-33. ZHU Y M, ZHOU J. The experiment study of recovering and appling garnet from the low grade Mo、Bi 、WO3 and fluorite flotation tailings of Huangshaping[J]. Non-ferrous Mining and Metallurgy, 2012, 28(3):31-33. doi: 10.3969/j.issn.1007-967X.2012.03.010 ZHU Y M, ZHOU J. The experiment study of recovering and appling garnet from the low grade Mo、Bi 、WO3 and fluorite flotation tailings of Huangshaping[J]. Non-ferrous Mining and Metallurgy, 2012, 28(3): 31-33. doi: 10.3969/j.issn.1007-967X.2012.03.010 |
[34] | 匡敬忠, 熊淑华. 钨尾矿微晶玻璃的组成及制备[J]. 矿产综合利用, 2003(3): 37-40. KUANG J Z, XIONG S H. The composition of tungsten tailings glass-ceramics and its manufacture[J]. Multipurpose Utilization of Mineral Resources, 2003(3): 37-40. |
[35] | 王承遇, 陶瑛, 郝彦武. 乳白色钨尾矿微晶玻璃的研制[J]. 新型建筑材料, 2001(10):38-39. WANG C Y, TAO Y, HAO Y W. Development of milky white tungsten tailings glass-ceramic[J]. New Builing Materials, 2001(10):38-39. doi: 10.3969/j.issn.1001-702X.2001.10.019 WANG C Y, TAO Y, HAO Y W. Development of milky white tungsten tailings glass-ceramic[J]. New Builing Materials, 2001(10): 38-39. doi: 10.3969/j.issn.1001-702X.2001.10.019 |
[36] | 孙孝华, 李章大. 一种新型钨尾矿微晶玻璃[J]. 中南大学学报:自然科学版, 1997(5):448-451. SUN X H, LI Z D. A new type of tungsten tailings glass-creamics[J]. Journal of Central South University:Natural Science Edition, 1997(5):448-451. SUN X H, LI Z D. A new type of tungsten tailings glass-creamics[J]. Journal of Central South University: Natural Science Edition, 1997(5): 448-451. |
[37] | P Alfonso, D Castro, M Garcia-Valles, et al. Recycling of tailings from the Barruecopardo tungsten deposit for the production of glass[J]. Journal of Thermal Analysis & Calorimetry, 2016, 125(2):681-687. |
[38] | Peng K, Lv C, Yang H. Novel preparation of glass ceramics from amorphized tungsten tailings[J]. Ceramics International, 2014, 40(7):10291-10296. doi: 10.1016/j.ceramint.2014.02.121 |
[39] | Yun W C, Yong J K, Choi O, et al. Utilization of tailings from tungsten mine waste as a substitution material for cement[J]. Construction & Building Materials, 2009, 23(7):2481-2486. |
[40] | Peng K, Yang H, Ouyang, J. Tungsten tailing powders activated for use as cementitious material[J]. Powder Technology, 2015, 286:678-683. doi: 10.1016/j.powtec.2015.09.012 |
[41] | 司加保, 李琳, 黄震. 用钨尾矿制备水泥混合材实验[J]. 现代矿业, 2016(7):222-225. SI J B, LI L, HUANG Z. Test on preparation of cement admixture using tungsten tailings[J]. Modern Mining, 2016(7):222-225. SI J B, LI L, HUANG Z. Test on preparation of cement admixture using tungsten tailings[J]. Modern Mining, 2016(7): 222-225. |
[42] | 朱刚雄, 王海. 钨尾矿在水泥胶砂中的应用[J]. 矿产保护与利用, 2017(5):82-86. ZHU G X, WANG H. Application of tungsten tailings in cement mortar[J]. Conservation and Utilization of Mineral Resources, 2017(5):82-86. ZHU G X, WANG H. Application of tungsten tailings in cement mortar[J]. Conservation and Utilization of Mineral Resources, 2017(5): 82-86. |
[43] | 匡敬忠, 施芳, 邱廷省, 等. 钨尾矿制备矿物聚合材料影响因素研究[J]. 混凝土, 2009(11):71-73. KUANG J Z, SHI F, QIU T S, et al. Study on influence factors of geopolymerin preparation with tungsten-tailing[J]. Concrete, 2009(11):71-73. KUANG J Z, SHI F, QIU T S, et al. Study on influence factors of geopolymerin preparation with tungsten-tailing[J]. Concrete, 2009(11): 71-73. |
[44] | 李涛, 罗仙平, 钱有军. 加水一体化合成钨尾矿基地聚合物研究[J]. 矿产综合利用, 2019(1):83-87. LI T, LUO X P, QIAN Y J. Investigation on synthesis of tungsten tailings base geopolymer by water integration[J]. Multipurpose Utilization of Mineral Resources, 2019(1):83-87. LI T, LUO X P, QIAN Y J. Investigation on synthesis of tungsten tailings base geopolymer by water integration[J]. Multipurpose Utilization of Mineral Resources, 2019(1): 83-87. |
[45] | 焦向科, 罗仙平, 袁程方, 等. 不同骨料掺量与级配下白钨尾矿-偏高岭土基地聚合物的制备及其早期强度[J]. 硅酸盐通报, 2015, 34(12):3418-3424. JIAO X K, LUO X P, YUAN C F, et al. Preparation of scheelite tailing-metakaolin based geopolymer with different aggregate content & gradation and its early strength[J]. Bulletin of the Chinese Ceramic Society, 2015, 34(12):3418-3424. doi: 10.16552/j.cnki.issn1001-1625.2015.12.002 JIAO X K, LUO X P, YUAN C F, et al. Preparation of scheelite tailing-metakaolin based geopolymer with different aggregate content & gradation and its early strength[J]. Bulletin of the Chinese Ceramic Society, 2015, 34(12): 3418-3424. doi: 10.16552/j.cnki.issn1001-1625.2015.12.002 |
[46] | 冯秀娟, 余育新. 钨尾砂生物陶粒的制备及性能研究[J]. 金属矿山, 2008, 38(4):146-148. FENG X J, YU Y X. Research on preparation of biological ceramsite from tungsten tailing and its performance[J]. Metal Mine, 2008, 38(4):146-148. doi: 10.3321/j.issn:1001-1250.2008.04.040 FENG X J, YU Y X. Research on preparation of biological ceramsite from tungsten tailing and its performance[J]. Metal Mine, 2008, 38(4): 146-148. doi: 10.3321/j.issn:1001-1250.2008.04.040 |
[47] | Liu W, Wu T, Li Z, et al. Preparation and characterization of ceramic substrate from tungsten mine tailings[J]. Construction & Building Materials, 2015(77):139-144. |
[48] | 卢安贤, 吴婷, 刘涛涌, 等. 一种以钨尾矿为主要原料的高强度陶瓷及其制备方法: CN104496433A[P]. 2015-04-08. LU A X, WU T, LIU T Y, et al. A high-strength ceramic with tungsten tailings as the main raw material and its preparation method: CN104496433A[P]. 2015-04-08. |