Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological SciencesHost
2023 No. 3
Article Contents

Ni Guolong, Wang Shuhuan, Li Qun. Research Status of Slag Corrosion Resistance in Magnesia Chrome Refractories Applied in Copper Metallurgy[J]. Multipurpose Utilization of Mineral Resources, 2023, 44(3): 100-106. doi: 10.3969/j.issn.1000-6532.2023.03.017
Citation: Ni Guolong, Wang Shuhuan, Li Qun. Research Status of Slag Corrosion Resistance in Magnesia Chrome Refractories Applied in Copper Metallurgy[J]. Multipurpose Utilization of Mineral Resources, 2023, 44(3): 100-106. doi: 10.3969/j.issn.1000-6532.2023.03.017

Research Status of Slag Corrosion Resistance in Magnesia Chrome Refractories Applied in Copper Metallurgy

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  • This is a paper in the field of ceramic materials for metallurgy. Magnesia chrome refractory is widely used in copper industry due to its excellent high temperature strength, fine slag corrosion resistance and good performance. In this paper, the research status of corrosion mechanism of magnesia chrome refractories for copper metallurgy is summarized theoretically, and the effect and action mechanism of factors on the service life of metallurgical furnace was clarified, such as slag temperature, grade, Cr2O3 content and additives in magnesia chrome bricks. Finally, according to the research status, the main ways to improve the service life of magnesia chrome refractories are summarized, which will provide guidance and help for the structural design and performance control of magnesia chrome refractories in the future.

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  • [1] 李宏. 耐火材料损伤行为的特征分析[J]. 广东化工, 2019, 46(15):119-120. LI H. The investigation on characteristics of damage performance in refractory[J]. Guangdong Chemical Industry, 2019, 46(15):119-120. doi: 10.3969/j.issn.1007-1865.2019.15.051

    CrossRef Google Scholar

    LI H. The investigation on characteristics of damage performance in refractory[J]. Guangdong Chemical Industry, 2019, 46(15): 119-120. doi: 10.3969/j.issn.1007-1865.2019.15.051

    CrossRef Google Scholar

    [2] 钱凡, 段雪珂, 杨文刚, 等. 镁铬耐火材料及高温装备绿色化应用研究进展[J]. 材料导报, 2019, 33(23):34-43. QIAN F, DUAN X K, YANG W G, et al. Research progress of magnesia chrome refractories and their application in greenization for high temperature furnace[J]. Materials Reports, 2019, 33(23):34-43. doi: 10.11896/cldb.18110166

    CrossRef Google Scholar

    QIAN F, DUAN X K, YANG W G, et al. Research progress of magnesia chrome refractories and their application in greenization for high temperature furnace[J]. Materials Reports, 2019, 33(23): 34-43. doi: 10.11896/cldb.18110166

    CrossRef Google Scholar

    [3] 王晨光, 吴昊天. 炼铜用镁铬质耐火材料破坏机理的分析[J]. 广东化工, 2018, 45(4):113+128. WANG C G, WU H T. Review on corrosion mechanism of magnesia chrome refractory applied in copper convertor[J]. Guangdong Chemical Industry, 2018, 45(4):113+128. doi: 10.3969/j.issn.1007-1865.2018.04.053

    CrossRef Google Scholar

    WANG C G, WU H T. Review on corrosion mechanism of magnesia chrome refractory applied in copper convertor [J]. Guangdong Chemical Industry, 2018, 45(4): 113+128. doi: 10.3969/j.issn.1007-1865.2018.04.053

    CrossRef Google Scholar

    [4] 陈肇友. 炉外精炼用耐火材料提高寿命的途径及其发展动向[J]. 耐火材料, 2007, 41(1):1-12. CHEN Z Y. The way to increase the service life of refractories used in out of furnace refining and its development trend[J]. Refractories, 2007, 41(1):1-12.

    Google Scholar

    CHEN Z Y. The way to increase the service life of refractories used in out of furnace refining and its development trend[J]. Refractories, 2007, 41(1): 1-12.

    Google Scholar

    [5] 王继宝, 梁永和, 李勇, 等. 炼铜诺兰达炉用镁铬砖损毁机理的探讨[J]. 耐火材料, 2007(1):79-81+84. WANG J B, LIANG Y H, LI Y, et al. The discussion on damage mechanism of magnesia chrome bricks used in copper smelting Noranda furnace[J]. Refractories, 2007(1):79-81+84. doi: 10.3969/j.issn.1001-1935.2007.01.018

    CrossRef Google Scholar

    WANG J B, LIANG Y H, LI Y, et al. The discussion on damage mechanism of magnesia chrome bricks used in copper smelting Noranda furnace[J]. Refractories, 2007 (1): 79-81+84. doi: 10.3969/j.issn.1001-1935.2007.01.018

    CrossRef Google Scholar

    [6] 李勇. 高性能镁铬耐火材料的应用研究[D]. 北京: 北京科技大学, 2002.

    Google Scholar

    LI Y. Application of high performance magnesia chrome refractories [D]. Beijing: University of Science and Technology Beijing, 2002.

    Google Scholar

    [7] 赵鹏达, 赵惠忠, 高红军, 等. 澳斯麦特炉用镁铬和铝铬砖抗侵蚀性能对比[J]. 硅酸盐通报, 2018, 37(7):258-262. ZHAO P D, ZHAO H Z, GAO H J, et al. Corrosion resistance comparison between the Al-Cr and Mn-Cr bricks used in Ausmelt furnaces[J]. Bulletin of the Chinese Ceramic Society, 2018, 37(7):258-262. doi: 10.16552/j.cnki.issn1001-1625.2018.07.047

    CrossRef Google Scholar

    ZHAO P D, ZHAO H Z, GAO H J, et al. Corrosion resistance comparison between the Al-Cr and Mn-Cr bricks used in Ausmelt furnaces[J]. Bulletin of the Chinese Ceramic Society, 2018, 37(7): 258-262. doi: 10.16552/j.cnki.issn1001-1625.2018.07.047

    CrossRef Google Scholar

    [8] 于仁红, 李勇, 蒋明学. 镁铬耐火材料的抗侵蚀性研究[C]. 第五届全国有色金属窑炉耐火材料技术研讨会. 中国有色金属学会. 2002.

    Google Scholar

    YU R H, LI Y, JIANG M X. Study on corrosion resistance of magnesia chrome refractories[C]. The 5th National Technical Seminar on Nonferrous Metal Furnace Refractories. China Nonferrous Metals Society. 2002.

    Google Scholar

    [9] 邹明, 蒋明学, 钱跃进, 等. 铝铬砖和镁铬砖抗艾萨炉炉渣蚀损的模拟研究[J]. 耐火材料, 2007(3):180-182. ZOU M, JIANG M X, QIAN Y J, et al. Simulation study on resistance of Al-Cr brick and Mg-Cr brick to slag erosion of ISA furnace[J]. Refractories, 2007(3):180-182. doi: 10.3969/j.issn.1001-1935.2007.03.005

    CrossRef Google Scholar

    ZOU M, JIANG M X, QIAN Y J, et al. Simulation study on resistance of Al-Cr brick and Mg-Cr brick to slag erosion of ISA furnace[J]. Refractories, 2007(3): 180-182. doi: 10.3969/j.issn.1001-1935.2007.03.005

    CrossRef Google Scholar

    [10] 高心魁, 王健东, 杨晓峰, 等. 艾萨炉用耐火材料抗渣侵蚀性能的研究[C]. 中国首届熔池熔炼技术及装备专题研讨会论文集. 2007.

    Google Scholar

    GAO X K, WANG J D, YANG X F, et al. Study on slag erosion resistance of refractories for ISA furnace[C]. Proceedings of the First Symposium on Bath Smelting Technology and Equipment in China. 2007.

    Google Scholar

    [11] 赵文厚, 陈肇友. 有色重金属熔炼用耐火材料的研发与使用[C]. 中国首届熔池熔炼技术及装备专题研讨会论文集, 2007.

    Google Scholar

    ZHAO W H, CHEN Z Y. Development and application of refractories for smelting nonferrous heavy metals[C]. Proceedings of the First Symposium on Bath Smelting Technology and Equipment in China. 2007.

    Google Scholar

    [12] 云斯宁. ISA/Ausmelt炉用镁铬耐火材料侵蚀机理的研究[D]. 西安: 西安建筑科技大学, 2003.

    Google Scholar

    YUN S N. Study on corrosion mechanism of magnesia chrome refractories for ISA/Ausmelt furnace[D]. Xi’an: Xi’an University of Architecture and Technology, 2003.

    Google Scholar

    [13] 陈浩, 王玺堂, 夏涛. 不同类型高温窑炉用镁铬砖损毁机理分析[J]. 武汉科技大学学报(自然科学版), 2009, 32:514-517. CHEN H, WANG X T, XIA T. Analysis of the damage mechanism of magnesium chromium brick for different types of high temperature kilns[J]. Journal of Wuhan University of Science and Technology (Natural Science Edition), 2009, 32:514-517.

    Google Scholar

    CHEN H, WANG X T, XIA T. Analysis of the damage mechanism of magnesium chromium brick for different types of high temperature kilns[J]. Journal of Wuhan University of Science and Technology (Natural Science Edition), 2009, 32: 514-517.

    Google Scholar

    [14] 于仁红. 铜转炉介质对镁铬耐火材料侵蚀机理的研究[D]. 西安: 西安建筑科技大学, 2002.

    Google Scholar

    YU R H. Study on corrosion mechanism of copper converter medium on magnesia chrome refractories[D]. Xi’an: Xi’an University of Architecture and Technology, 2002.

    Google Scholar

    [15] 惠兴欢, 李江平, 张鑫, 等. 影响铜冶炼转炉炉寿的原因分析及生产实践[J]. 中国有色冶金, 2018, 47(2):36-37+42. HUI X H, LI J P, ZHANG X, et al. Cause analysis and production practice of affecting converter life in copper smelting[J]. China Nonferrous Metallurgy, 2018, 47(2):36-37+42. doi: 10.19612/j.cnki.cn11-5066/tf.2018.02.008

    CrossRef Google Scholar

    HUI X H, LI J P, ZHANG X, et al. Cause analysis and production practice of affecting converter life in copper smelting[J]. China Nonferrous Metallurgy, 2018, 47(2): 36-37+42. doi: 10.19612/j.cnki.cn11-5066/tf.2018.02.008

    CrossRef Google Scholar

    [16] 赵洪波, 金鹏, 王继宝, 等. 大冶有色冶炼厂火法炼铜炉窑与耐火材料[J]. 工业炉, 2017, 39(1):69-72. ZHAO H B, JIN P, WANG J B, et al. Furnace and refractories for pyrometallurgy of copper in Daye nonferrous smelter[J]. Industrial Furnace, 2017, 39(1):69-72. doi: 10.3969/j.issn.1001-6988.2017.01.017

    CrossRef Google Scholar

    ZHAO H B, JIN P, WANG J B, et al. Furnace and refractories for pyrometallurgy of copper in Daye nonferrous smelter[J]. Industrial Furnace, 2017, 39(1): 69-72. doi: 10.3969/j.issn.1001-6988.2017.01.017

    CrossRef Google Scholar

    [17] 赫亮亮, 王丽娜. 铜冶炼炉用后的镁铬砖显微结构分析[J]. 河南建材, 2016(1):137+140. HAO L L, WANG L N. Microstructure analysis of magnesia chrome brick used in copper smelting furnace[J]. Henan Building Materials, 2016(1):137+140. doi: 10.16053/j.cnki.hnjc.2016.01.060

    CrossRef Google Scholar

    HAO L L, WANG L N. Microstructure analysis of magnesia chrome brick used in copper smelting furnace[J]. Henan Building Materials, 2016, (1): 137+140. doi: 10.16053/j.cnki.hnjc.2016.01.060

    CrossRef Google Scholar

    [18] 李勇, 于仁红, 陈开献, 等. 铜冶金用镁铬耐火材料[M]. 北京: 冶金工业出版社, 2014: 45-48.

    Google Scholar

    LI Y, YU R H, CHEN K X, et al. Magnesia chrome refractories for copper metallurgy[M]. Beijing: Metallurgical Industry Press, 2014: 45-48.

    Google Scholar

    [19] 朱祖泽, 贺家齐. 现代铜冶金学[M]. 北京: 科学出版社, 2003: 211-487.

    Google Scholar

    ZHU Z Z, HE J Q. Modern copper metallurgy[M]. Beijing: Science Press, 2003, 211-487.

    Google Scholar

    [20] 李连洲. 炼铜转炉用镁铬耐火材料抗侵蚀性的研究[J]. 耐火与石灰, 2015, 40(3):34-35+39. LI L Z. Study on corrosion resistance of magnesia chrome refractories for copper converter[J]. Refractories & Lime, 2015, 40(3):34-35+39. doi: 10.3969/j.issn.1673-7792.2015.03.009

    CrossRef Google Scholar

    LI L Z. Study on corrosion resistance of magnesia chrome refractories for copper converter[J]. Refractories & Lime, 2015, 40(3): 34-35+39. doi: 10.3969/j.issn.1673-7792.2015.03.009

    CrossRef Google Scholar

    [21] 张邦琪, 朱祖泽. 提高云南铜业艾萨炉寿命的实践与探讨[J]. 有色金属工程, 2005, 57(4):47-53. ZHANG B Q, ZHU Z Z. Practice and discussion on improving the service life of ISA furnace in Yunnan copper industry[J]. Nonferrous Metal Engineering, 2005, 57(4):47-53. doi: 10.3969/j.issn.2095-1744.2005.04.014

    CrossRef Google Scholar

    ZHANG B Q, ZHU Z Z. Practice and discussion on improving the service life of ISA furnace in Yunnan copper industry[J]. Nonferrous Metal Engineering, 2005, 57(4): 47-53. doi: 10.3969/j.issn.2095-1744.2005.04.014

    CrossRef Google Scholar

    [22] 郭福杰, 王健东, 杨晓峰. 镁砂和镁铬砂的品位对镁铬砖性能的影响[C]. 2017年全国耐火原料学术交流会暨展览会论文集, 2017.

    Google Scholar

    GUO F J, WANG J D, YANG X F. Influence of grade of magnesia and magnesia chrome sand on properties of magnesia chrome brick[C]. 2017 National Refractory Materials Academic Exchange Conference and Exhibition Papers Collection, 2017.

    Google Scholar

    [23] 宋霞, 蒋明学, 李勇. 隧道窑镁铬砖损毁机理的研究[D]. 西安: 西安建筑科技大学, 2003.

    Google Scholar

    SONG X, JIANG M X, LI Y. Study on damage mechanism of magnesia chrome brick in tunnel kiln[D]. Xi’an: Xi’an University of Architecture and Technology, 2003.

    Google Scholar

    [24] 陈肇友. 有色金属火法冶炼用耐火材料及其发展动向[J]. 耐火材料, 2008(2):81-91. CHEN Z Y. Refractories used for pyrometallurgy of nonferrous metals and their development trend[J]. Refractories, 2008(2):81-91. doi: 10.3969/j.issn.1001-1935.2008.02.001

    CrossRef Google Scholar

    CHEN Z Y. Refractories used for pyrometallurgy of nonferrous metals and their development trend[J]. Refractories, 2008 (2): 81-91. doi: 10.3969/j.issn.1001-1935.2008.02.001

    CrossRef Google Scholar

    [25] 徐宁. 抗渣性耐火材料的研究进展[J]. 现代技术陶瓷, 2010, 31(4):18-22. XU N. Research progress of slag resistant refractories[J]. Modern Technology Ceramics, 2010, 31(4):18-22. doi: 10.3969/j.issn.1005-1198.2010.04.005

    CrossRef Google Scholar

    XU N. Research progress of slag resistant refractories[J]. Modern Technology Ceramics, 2010, 31(4): 18-22. doi: 10.3969/j.issn.1005-1198.2010.04.005

    CrossRef Google Scholar

    [26] Haldar MK, Tripathi HS, Das SK, et al. Effect of compositional variation on the synthesis of magnesite–chrome composite refractory[J]. Ceramics International, 2004, 30(6):911-915. doi: 10.1016/j.ceramint.2003.10.012

    CrossRef Google Scholar

    [27] 张锡平, 薛文东, 孙加林, 等. 添加物对镁铬砖性能的影响[J]. 耐火材料, 2008, 42(2):120-123. ZHANG X P, XUE W D, SUN J L, et al. The effect of additives on properties of magnesia chrome bricks[J]. Refractories, 2008, 42(2):120-123. doi: 10.3969/j.issn.1001-1935.2008.02.009

    CrossRef Google Scholar

    ZHANG X P, XUE W D, SUN J L, et al. The effect of additives on properties of magnesia chrome bricks[J]. Refractories, 2008, 42(2): 120-123. doi: 10.3969/j.issn.1001-1935.2008.02.009

    CrossRef Google Scholar

    [28] 徐琳琳, 翟耀杰, 刘锡俊, 等. 铜冶炼炉用镁铬砖的性能优化研究[J]. 耐火材料, 2016(6):461-463. XU L L, ZHAI Y J, LIU X J, et al. The study on performance optimization of magnesia chrome brick for copper smelting furnace[J]. Refractories, 2016(6):461-463. doi: 10.3969/j.issn.1001-1935.2016.06.016

    CrossRef Google Scholar

    XU L L, ZHAI Y J, LIU X J, et al. The study on performance optimization of magnesia chrome brick for copper smelting furnace[J]. Refractories, 2016(6): 461-463. doi: 10.3969/j.issn.1001-1935.2016.06.016

    CrossRef Google Scholar

    [29] 朱新伟, 邱文冬, 梁永和, 等. α-Al2O3微粉加入量对镁铬材料性能的影响[J]. 耐火材料, 2013, 47(6):430-432. ZHU X W, QIU W D, LIANG Y H, et al. The effect of α-Al2O3 adding amount on properties of magnesia chrome refractories[J]. Refractories, 2013, 47(6):430-432. doi: 10.3969/j.issn.1001-1935.2013.06.008

    CrossRef Google Scholar

    ZHU X W, QIU W D, LIANG Y H, et al. The effect of α-Al2O3 adding amount on properties of magnesia chrome refractories[J]. Refractories, 2013, 47(6): 430-432. doi: 10.3969/j.issn.1001-1935.2013.06.008

    CrossRef Google Scholar

    [30] 徐勇. 添加纳米颗粒对镁铬耐火材料抗侵蚀性能的改善[J]. 耐火与石灰, 2015(4):58-61. XU Y. The improvement of corrosion resistance of magnesia chrome refractories by adding nano particles[J]. Refractories & Lime, 2015(4):58-61. doi: 10.16425/j.cnki.1673-7792.2015.04.018

    CrossRef Google Scholar

    XU Y. The improvement of corrosion resistance of magnesia chrome refractories by adding nano particles[J]. Refractories & Lime, 2015 (4): 58-61. doi: 10.16425/j.cnki.1673-7792.2015.04.018

    CrossRef Google Scholar

    [31] 赵慧忠, 李红, 魏建修, 等. 纳米Fe2O3对镁铬耐火材料烧结及力学性能的影响[J]. 耐火材料, 2003(5):11-13. ZHAO H Z, LI H, WEI J X, et al. The influence of nano-Fe2O3 on the sintering property and mechanical property[J]. Refractories, 2003(5):11-13.

    Google Scholar

    ZHAO H Z, LI H, WEI J X, et al. The influence of nano-Fe2O3 on the sintering property and mechanical property[J]. Refractories, 2003 (5): 11-13.

    Google Scholar

    [32] 尹洪基. TiO2和ZrO2对MgO-Cr2O3合成耐火材料性能和显微结构的影响[J]. 耐火与石灰, 2010, 35(1):53-54. YIN H J. The Effect of TiO2 and ZrO2 on properties and microstructure of MgO-Cr2O3 synthetic refractories[J]. Refractories & Lime, 2010, 35(1):53-54. doi: 10.3969/j.issn.1673-7792.2010.01.017

    CrossRef Google Scholar

    YIN H J. The Effect of TiO2 and ZrO2 on properties and microstructure of MgO-Cr2O3 synthetic refractories[J]. Refractories & Lime, 2010, 35(1): 53-54. doi: 10.3969/j.issn.1673-7792.2010.01.017

    CrossRef Google Scholar

    [33] 张立德, 牟季美. 材料和纳米结构[M]. 北京: 科学出版社, 2001.

    Google Scholar

    ZHANG L D, MOU J M. Materials and nanostructures[M]. Beijing: The Science Publishing Company, 2001.

    Google Scholar

    [34] 黄少波, 蒋明学, 章道运. 纳米Al2O3和Cr2O3对镁铬材料烧结与力学性能的影响[J]. 耐火材料, 2011(4):261-264. HUANG S B, JANG M X, ZHANG D Y. The influence of nano-Al2O3 and nano-Cr2O3 on the sintering property and mechanical property[J]. Refractories, 2011(4):261-264. doi: 10.3969/j.issn.1001-1935.2011.04.005

    CrossRef Google Scholar

    HUANG S B, JANG M X, ZHANG D Y. The influence of nano-Al2O3 and nano-Cr2O3 on the sintering property and mechanical property[J]. Refractories, 2011 (4): 261-264. doi: 10.3969/j.issn.1001-1935.2011.04.005

    CrossRef Google Scholar

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