Citation: | Li Yonghui, Xian Yuanhua, Chen Dexia, Zhong Yi, Wu Xiujie. Process Optimization on Preparation of Composite Portland Cement with Low-grade Pyrite Cinder[J]. Multipurpose Utilization of Mineral Resources, 2023, 44(3): 78-81, 87. doi: 10.3969/j.issn.1000-6532.2023.03.013 |
This is a paper in the field of mineral materials. In order to seek for a new feasible way to utilize low-grade pyrite cinder under local conditions, to solve bottleneck problems of large reserves, and to relieve soil and water pollution, a research on the process optimization on preparation of composite portland cement with low-grade pyrite cinder was conducted. Pyrite cinder as a special kind of industrial solid waste with higher iron content, was used as additive, and was incorporated with portland cement clinker, flue gas desulfurization gypsum and fly ash to prepare composite portland cement. Their efficacy was compared by testing the compressive strength and flexural strength of composite portland cement, based on the analysis of physical indices, and then orthogonal tests were carried out to optimize the preparation. The results showed that the optimum preparation conditions were: mass fraction of portland cement clinker of 55%, Ca to Si ratio of 2.5, fly ash to pyrite cinder ratio of 1.0, and water to material ratio of 0.4. And then, 28-day compressive strength was 43.9 MPa. According to the national standard named as Common Portland Cement, the cement mark can reach the level of P·C 42.5.
[1] | 叶树滋. 硫酸生产工艺[M]. 北京: 化学工业出版社, 2011: 225-226. YE S Z. Production technology of sulfuric acid[M]. Beijing: Chemical Industry Press Co. , Ltd, 2011: 225-226. |
[2] | 国家环境保护局. 工业污染治理技术丛书 固体废弃物卷[M]. 北京: 中国环境科学出版社, 1991: 262-273. Ministry of Ecology and Environment of the People's Republic of China. Technical series on industrial pollution control, solid waste part[M]. Beijing: China Environment Pubishing Group, 1991: 262-273. |
[3] | 李崇. 2018年中国硫酸行业生产运行情况[J]. 硫酸工业, 2019(5):11-14,23. LI C. 2018 Operational status of sulfuric acid industry[J]. Sulphuric acid industry, 2019(5):11-14,23. doi: 10.3969/j.issn.1002-1507.2019.05.003 LI C. 2018 Operational status of sulfuric acid industry[J]. Sulphuric acid industry , 2019, (5): 11-14, 23. doi: 10.3969/j.issn.1002-1507.2019.05.003 |
[4] | 生态环境部. 2019年全国大、中城市固体废物污染环境防治年报[OL]. 中华人民共和国生态环境部. 2019-12-31. http://www.mee.gov.cn/hjzl/sthjzk/gtfwwrfz. Ministry of Ecology and Environment of the People's Republic of China. 2019 statistical bulletin on prevention and control of solid waste pollution in large and medium cities. 2019-12-31. http://www.mee.gov.cn/hjzl/sthjzk/gtfwwrfz. |
[5] | 田锋. 硫铁矿烧渣综合利用实验研究[J]. 矿产综合利用, 2010(1):38-42. TIAN F. Experimental research on comprehensive utilization of roasted pyrite[J]. Multipurpose Utilization of Mineral Resources, 2010(1):38-42. doi: 10.3969/j.issn.1000-6532.2010.01.011 TIAN F. Experimental research on comprehensive utilization of roasted pyrite[J]. Multipurpose Utilization of Mineral Resources, 2010, (1): 38-42. doi: 10.3969/j.issn.1000-6532.2010.01.011 |
[6] | 黄长春. 从硫铁矿烧渣回收铁精粉的研究[D]. 厦门: 厦门大学, 2013. HUANG C C. Study on recovering iron concentrate from pyrite slag [D]. Xiamen: Xiamen University, 2013. |
[7] | 傅开彬, 焦宇, 徐信, 等. 山东某硫铁矿烧渣硫酸浸出液制备铁红工艺研究[J]. 应用化工, 2018, 47(2):293-295. FU K B, JIAO Y, XU X, et al. Preparation of iron oxide red from sulfuric acid solution of a pyrite cinder from Shandong Province[J]. Applied Chemical Industry, 2018, 47(2):293-295. doi: 10.3969/j.issn.1671-3206.2018.02.021 FU K B, JIAO Y, XU X, et al. Preparation of iron oxide red from sulfuric acid solution of a pyrite cinder from Shandong Province[J]. Applied Chemical Industry, 2018, 47(2): 293-295. doi: 10.3969/j.issn.1671-3206.2018.02.021 |
[8] | 陈吉春, 陈永亮. 硫铁矿烧渣还原酸浸制取硫酸亚铁[J]. 矿产综合利用, 2004(3):42-45. CHEN J C, CHEN Y L. The preparation of ferrous sulfate from pyrite cinder by reduction roasting method[J]. Multipurpose Utilization of Mineral Resources, 2004(3):42-45. doi: 10.3969/j.issn.1000-6532.2004.03.011 CHEN J C , CHEN Y L. The preparation of ferrous sulfate from pyrite cinder by reduction roasting method[J]. Multipurpose Utilization of Mineral Resources, 2004, (3): 42-45. doi: 10.3969/j.issn.1000-6532.2004.03.011 |
[9] | 姜凌, 董亚妮, 田萍. 用硫铁矿烧渣制取聚合硫酸铁的实验研究[J]. 环境科学与技术, 2010, 33(8):148-151,166. JIANG L, DONG Y N, TIAN P. Preparation of polyferric sulfate by pyrite cinder[J]. Environmental Science & Technology, 2010, 33(8):148-151,166. JIANG L, DONG Y N, TIAN P. Preparation of polyferric sulfate by pyrite cinder[J]. Environmental Science& Technology, 2010, 33(8): 148-151, 166. |
[10] | 史继斌, 李树安, 徐蕙. 混合酸溶法浸取硫铁矿烧渣制聚硅氯化硫酸铁[J]. 化工矿物与加工, 2007(11):17-20. SHI J B, LI S A, XU H. Preparation of poly-silicic-ferric chloride sulfate from leaching pyrite cinder with mixed acid dissolution method[J]. Industrial minerals & processing, 2007(11):17-20. doi: 10.3969/j.issn.1008-7524.2007.11.005 SHI J B, LI S A, XU H. Preparation of poly-silicic-ferric chloride sulfate from leaching pyrite cinder with mixed acid dissolution method[J]. Industrial minerals & processing, 2007, (11): 17-20. doi: 10.3969/j.issn.1008-7524.2007.11.005 |
[11] | 赵静立. 硫铁矿烧渣为原料合成磷酸铁锂的工艺研究[D]. 武汉: 华中科技大学, 2016. ZHAO J L. Preparation of LiFePO4 from pyrite cinder using hydrometallurgical and hydrothermal process[D]. Wuhan: Huazhong University of Science and Technology, 2016. |
[12] | 常耀超, 徐晓辉, 王云. 高砷硫酸烧渣脱砷及高温氯化回收金银[J]. 有色金属(冶炼部分), 2015(6):46-49. CHANG Y C, XU X H, WANG Y. Arsenic removal and recovery of gold and silver by chloridizing roasting from high arsenic-bearing pyrite cinder[J]. Nonferrous Metals(Extractive Metallurgy), 2015(6):46-49. CHANG Y C, XU X H, WANG Y. Arsenic removal and recovery of gold and silver by chloridizing roasting from high arsenic-bearing pyrite cinder[J]. Nonferrous Metals(Extractive Metallurgy), 2015, (6): 46-49. |
[13] | 范晓正, 严云, 胡志华, 等. 低品位硫铁矿烧渣制备吸波陶瓷的研究[J]. 陶瓷学报, 2015, 36(6):634-639. FAN X Z, YAN Y, HU Z H, et al. Preparation technology of microwave absorbing ceramics with low-grade pyrite cinder[J]. Journal of Ceramics, 2015, 36(6):634-639. doi: 10.13957/j.cnki.tcxb.2015.06.011 FAN X Z, YAN Y, HU Z H, et al. Preparation technology of microwave absorbing ceramics with low-grade pyrite cinder[J]. Journal of Ceramics, 2015, 36(6): 634-639. doi: 10.13957/j.cnki.tcxb.2015.06.011 |
[14] | 谢鹏, 黄阳, 王凡非, 等. 高岭石型硫铁矿烧渣超细粉作高强高性能混凝土用矿物外加剂的性能研究[J]. 非金属矿, 2014, 37(3):22-24. XIE P, HUANG Y, WANG F F, et al. Research on properties of ultrafine kaolinite-pyrite cinder as mineral admixture of high performance concrete[J]. Non-Metallic Mines, 2014, 37(3):22-24. doi: 10.3969/j.issn.1000-8098.2014.03.008 XIE P, HUANG Y, Wang F F, et al. Research on properties of ultrafine kaolinite-pyrite cinder as mineral admixture of high performance concrete[J]. Non-Metallic Mines, 2014, 37(3): 22-24. doi: 10.3969/j.issn.1000-8098.2014.03.008 |
[15] | 生态环境部. 硫酸工业污染防治技术政策[OL]. 中华人民共和国生态环境部. 2013-05-24. http://www.mee.gov.cn/ywgz/fgbz/bz/bzwb/wrfzjszc/201306/t20130603_253124.shtml Ministry of Ecology and Environment of the People's Republic of China. Technical policy for pollution control in sulphuric acid industry[OL]. Ministry of Ecology and Environment of the People's Republic of China. 2013-05-24. http://www.mee.gov.cn/ywgz/fgbz/bz/bzwb/wrfzjszc/201306/t20130603_253124.shtml. |