Citation: | Nan Ning, Cui Xiaowei, Sun Qiangqiang, Zhao Wei, Wang Zhiyu, Li Feng, He Ben. Investigation on Preparation of Glass-ceramics with Iron Tailings[J]. Multipurpose Utilization of Mineral Resources, 2022, 43(3): 47-50. doi: 10.3969/j.issn.1000-6532.2022.03.009 |
The glass-ceramics were prepared by sintering method from an iron tailings in Shangluo area. The optimum process parameters of melting base glass were optimized. The effects of the crystallization temperature on the compressive strength, density and thermal expansivity of glass-ceramics were investigated. The results show that optimal performance of the base glass melted can be obtained at the melting temperature of 1400℃ and melting time of 2 h. Moreover the best properties of the glass-ceramics such as compressive strength of 158.32 MPa, density of 2.74 g/cm3, thermal expansivity of 6.8×10-6K-1 could be obtained at the crystallization temperature of 900℃ and holding time of 2 h.
[1] | 张景书. 商洛市尾矿资源综合利用现状及其对策[J]. 商洛学院学报, 2013, 27(4):3-7. ZHANG J S. Present situation and countermeasures of comprehensive utilization of tailings resources in Shangluo[J]. Journal of Shangluo University, 2013, 27(4):3-7. |
[2] | 刘淑鹏, 张小伟. 我国金属矿山尾矿综合利用现状及对策[J]. 中国资源综合利用, 2020, 38(3):75-78. LIU S P, ZHANG X W. Current situation and countermeasures of comprehensive utilization of metal mine tailings in China[J]. China Resources Comprehensive Utilization, 2020, 38(3):75-78. |
[3] | 吕绍伟, 姜屏, 钱彪, 等. 铁尾矿砂力学特性及再生利用研究进展[J]. 硅酸盐通报, 2020, 39(2):466-470. LV S W, JIANG P, QIAN B, et al. Advances in mechanical properties and recycling of iron tailing sand[J]. Bulletin of the Chinese Ceramic Society, 2020, 39(2):466-470. |
[4] | 李红霞, 李保卫, 邓磊波, 等. 微波热处理温度对尾矿微晶玻璃晶化过程及性能的影响[J]. 材料导报, 2019, 33(20): 3401-3407. LI H X, LI B W, DENG L B, et al. Effect of microwave heat treatment temperature on crystallization process and properties of tailings glass-ceramics[J]. Materials Review, 2019, 33(20): 3401-3407. |
[5] | 南宁, 刘萍, 孙强强, 等. 利用铁尾矿制备微晶玻璃试验研究[J]. 当代化工, 2019, 48(10):2199-2201. NAN N, LIU P, SUN Q Q, et al. Experimental study on preparation of glass-ceramics from iron tailings[J]. Contemporary Chemical Industry, 2019, 48(10):2199-2201. |
[6] | 李红霞, 李保卫, 徐鹏飞, 等. 热处理时间对透辉石系尾矿微晶玻璃析晶及其性能的影响[J]. 材料研究学报, 2020, 34(03):209-216. LI H X, LI B W, XU P F, et al. Effect of heat treatment time on crystallization and properties of glass-ceramics of diopside tailings[J]. Journal of Materials Research, 2020, 34(03):209-216. |
[7] | 潘德安, 逯海洋, 刘晓敏, 等. 高硅铁尾矿制备轻质闭孔泡沫陶瓷研究[J]. 中国陶瓷, 2020, 56(3):51-58. PAN D A, LU H Y, LIU X M, et al. Study on preparation of lightweight closed-cell foam ceramics from high silicone iron tailings[J]. China Ceramics, 2020, 56(3):51-58. |
[8] | 佟志芳, 范佳乐, 曾庆钋, 等. 利用金属尾矿制备泡沫微晶玻璃的研究现状及展望[J]. 有色金属科学与工程, 2020, 11(2):34-41. TONG Z F, FAN J L, ZENG Q P, et al. Research status and prospects of foam glasses prepared from metal tailings[J]. Nonferrous Metals Science and Engineering, 2020, 11(2):34-41. |
[9] | 李保庆, 郭艳平, 党海峰. MgO对飞灰屏玻璃协同制备微晶玻璃析晶及性能的影响[J]. 矿产综合利用, 2020(1):135-139. LI B Q, GUO Y P, DANG H F. Effect of MgO on crystallization and properties of glass ceramics from fly ash and waste glass[J]. Multipurpose Utilization of Mineral Resources, 2020(1):135-139. |
[10] | 廖力. 利用铜矿尾矿制备微晶玻璃试验研究[J]. 矿产综合利用, 2017(6):82-85. LIAO L. Experimental study on preparation of glass-ceramics from copper tailings[J]. Multipurpose Utilization of Mineral Resources, 2017(6):82-85. |
Flow diagram of experiments
XRD patterns of base glass before and after crystallization
Effect of crystallization temperature on compressive strength of glass-ceramics
Effect of crystallization temperature on the density of glass-ceramics
Effect of crystallization temperature on the thermal expansivity of glass-ceramics