2020 Vol. 3, No. 1
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Li-jian Shen, Nuchit Siritongkham, 2020. The characteristics, formation and exploration progress of the potash deposits on the Khorat Plateau, Thailand and Laos, Southeast Asia, China Geology, 3, 67-82. doi: 10.31035/cg2020009
Citation: Li-jian Shen, Nuchit Siritongkham, 2020. The characteristics, formation and exploration progress of the potash deposits on the Khorat Plateau, Thailand and Laos, Southeast Asia, China Geology, 3, 67-82. doi: 10.31035/cg2020009

The characteristics, formation and exploration progress of the potash deposits on the Khorat Plateau, Thailand and Laos, Southeast Asia

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  • The giant potash deposit on the Khorat Plateau is one of the most promising targets for exploitation of potassium salts. So far, many researches and geologic survey have been conducted on the giant potash deposits. Hence, it is necessary to make an overall review on the potash deposits. The potash deposit on the Khorat Plateau was formed during the Middle to Late Cretaceous, during which seawater was enriched in Ca2+ and depleted in SO42- compared with those of modern seawater. In addition to seawater, continental water and hydrothermal fluids could have affected the evaporite basins. The seawater was probably derived from Tethys ocean, and the brine should have evaporated to some extent before entering into the basin systems based on the evidence of absence of carbonates and unproportionate sulphate compared with chloride salts. The paleo-climate during Middle to Late Cretaceous was characterized as high temperature and extremely arid environment, which is favourable for deposition of potassium-magnesium saline minerals. The major saline minerals are of anhydrite, halite, carnallite, sylvite and, tachyhydrite, with trace amounts of borates. The resources of the potash deposit on the Khorat Plateau could be approximately as much as 400×109 t of carnallite and 7×109 t of sylvite. The evaporite sequences have been deformed and altered by postdepositinal processes, including tectonic movements and chemical alteration. Salt domes were formed in the postdepositional processes. Based on the analyses of geophysical surveys and drilling projects, high-quality sylvinite ores are commonly found at the flanks of those salt domes due to incongruent dissolution of carnallite. The future potential prospecting areas for the high-quality sylvinite ores would be on the edges of the Khorat Plateau.

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  • [1] Buffetaut E, Ingavat R. 1986. The succession of vertebrate faunas in the continental Mesozoic of Thailand. GEOSEA V Proceedings. Vol. Ⅰ. Geological Society of Malaysia Bulletin, 19, 167–172. doi: 10.7186/bgsm19198613

    CrossRef Google Scholar

    [2] Bunopas S. 1981. Paleogeographic history of western Thailand and adjacent parts of Southeast Asia-a plate tectonics interpretation. Ph.D. thesis, Victoria University of Wellington, New Zealand.

    Google Scholar

    [3] Cheng HD, Hai QY, Ma HZ, Zhang XY, Tang QL, Fan QS, Li YS, Miao WL. 2016. Implications for the origin of secondary sylvite from a simulation of carnallite dissolution. Journal of Geochemical Exploration, 165, 189–198. doi: 10.1016/j.gexplo.2016.03.016

    CrossRef Google Scholar

    [4] Claypool GE, Holser WT, Kaplan IR, Sakai H, Zak I. 1980. The age curves of sulfur and oxygen isotopes in marine sulfate and their mutual interpretation. Chemical Geology, 28, 199–260. doi: 10.1016/0009-2541(80)90047-9

    CrossRef Google Scholar

    [5] El Tabakh M, Schreiber BC, Utha-Aroon C, Coshell L, Warren JK. 1998. Diagenetic origin of basal anhydrite in the Cretaceous Maha Sarakham salt: Khorat Plateau, NE Thailand. Sedimentology, 45(3), 579–594. doi: 10.1046/j.1365-3091.1998.00162.x

    CrossRef Google Scholar

    [6] El Tabakh M, Utha-Aroon C, Schreiber BC. 1999. Sedimentology of the Cretaceous Maha Sarakham evaporites in the Khorat Plateau of northeastern Thailand. Sedimentary Geology, 123(1−2), 31–62. doi: 10.1016/S0037-0738(98)00083-9

    CrossRef Google Scholar

    [7] Frakes LA, Francis JE, Syktus JI. 2005. Climate modes of the Phanerozoic. New York, Cambridge University Press, 285. doi: 10.1017/CBO9780511628948.

    Google Scholar

    [8] Gardner LS, Hayworth PN. 1967. Salt Resources of Thailand, Report of Investigation No.11. Thailand, Bangkon, Department of Mineral Resources, 100.

    Google Scholar

    [9] Gradstein FM, Ogg JG, Hilgen FJ. 2012. On the geologic time scale. Newsletters on Stratigraphy, 45(2), 171–188. doi: 10.1127/0078-0421/2012/0020

    CrossRef Google Scholar

    [10] Graustein WC. 1989. 87Sr/86Sr ratios measure the sources and flow of strontium in terrestrial ecosystems. In: Stable isotopes in ecological research. 28, 491-512.

    Google Scholar

    [11] Hansen BT, Wemmer K, Eckhardt M, Putthapiban P, Assavapatchara S. 2016. Isotope Dating of the Potash and Rock Salt Deposit at Bamnet Narong, NE-Thailand. Open Journal of Geology, 6(8), 875–894. doi: 10.4236/ojg.2016.68067

    CrossRef Google Scholar

    [12] Hansen BT, Wemmer K, Pawlig S, Klaus J, Assavapatchara S, Nontaso M, Chairangsee C, Putthapiban. 2002. Isotopic evidence for a late Cretaceous age of the potash and rock salt deposit at Bamnet Narong, NE Thailand. The Symposium on Geology of Thailand, 26-31 August 2002, Bangkok, Thailand.

    Google Scholar

    [13] Haq BU, Hardenbol J, Vail PR. 1987. Chronology of fluctuating sea levels since the Triassic. Science, 235(4793), 1156–1167. doi: 10.1126/science.235.4793.1156

    CrossRef Google Scholar

    [14] Hardie LA. 1984. Evaporites: marine or non-marine? American Journal of Science, 284(3), 193–240. doi: 10.2475/ajs.284.3.193

    CrossRef Google Scholar

    [15] Hardie LA. 1990. The roles of rifting and hydrothermal CaCl2 brines in the origin of potash evaporites: An hypothesis. American Journal of Science, 290(1), 43–106. doi: 10.2475/ajs.290.1.43

    CrossRef Google Scholar

    [16] Harris Jr RW. 1977. Palynological analyses of outcrop and well samples from the Khorat Basin, Central Thailand. Mineral Fuels Division.

    Google Scholar

    [17] Hasegawa H, Imsamut S, Charusiri P, Tada R, Horiuchi Y, Hisada KI. 2010. ‘Thailand was a desert’ during the mid-Cretaceous: Equatorward shift of the subtropical high-pressure belt indicated by eolian deposits (Phu Thok Formation) in the Khorat Basin, northeastern Thailand. Island Arc, 19(4), 605–621. doi: 10.1111/j.1440-1738.2010.00728.x

    CrossRef Google Scholar

    [18] Hite RJ. 1974. evaporite deposits of the Khorat Plateau, northeastern Thailand, in Coogan AH (ed.), Fourth Symposium on salt. V.1 Houston, Texas, Geological Society of Northern Texas, 1973, 135−146.

    Google Scholar

    [19] Hite RJ. 1982. Progress report on the potash deposits of the Khorat Plateau, Thailand (No. 82-1096). US Geological Survey.

    Google Scholar

    [20] Hite RJ, Japakasetr T. 1979. Potash deposits of the Khorat plateau, Thailand and Laos. Economic Geology, 74(2), 448–458. doi: 10.2113/gsecongeo.74.2.448

    CrossRef Google Scholar

    [21] Holser WT. 1966. Bromide geochemistry of salt rocks, in Rau JH, (ed.), Second symposium on salt. V.1. Cleveland, Ohio, Geological Society Northern Ohio, 1965, 248−275.

    Google Scholar

    [22] Huber BT, Norris RD, MacLeod KG. 2002. Deep-sea paleotemperature record of extreme warmth during the Cretaceous. Geology, 30(2), 123–126. doi: 10.1130/0091-7613(2002)030<0123:DSPROE>2.0.CO;2

    CrossRef Google Scholar

    [23] Jacobson HS, Pierson CT, Danusawad T, Japakasetr T, Inthuputi B, Siriratanamongkol C, Prapassornkul S, Pholphan N. 1967. Mineral investigations in northeastern Thailand (No. 67-121). US Geological Survey.

    Google Scholar

    [24] Li MH, Yan MD, Fang XM, Zhang ZJ, Wang ZR, Sun SR, Li J, Liu XM. 2018. Origins of the Mid-Cretaceous evaporite deposits of the Sakhon Nakhon Basin in Laos: Evidence from the stable isotopes of halite. Journal of Geochemical Exploration, 184, 209–222. doi: 10.1016/j.gexplo.2017.11.001

    CrossRef Google Scholar

    [25] Liang GH, Xu XW, Liu XJ, Li DH, Gao C. 2019. Structural deformation and deep ore prediction for Satani Potash Deposit in Vientiane Basin, Laos. Geotectonica et Metallogenia, 43(5), 934–942 (in Chinese with English abstract).

    Google Scholar

    [26] Liu CL, Jiao PC, Chen YZ, Wang ML. 2010. Formation Mechanism of potash-bearing brine in fault belts of Lop Nur Lake, Xinjiang. Mineral Deposits, 29(4), 602–608 (in Chinese with English abstract).

    Google Scholar

    [27] Liu CL, Wang LC, Yan MD, Zhao YJ, Cao YT, Fang XM, Shen LJ, Wu CH, Lv FL, Ding T. 2018. The Mesozoic-Cenozoic tectonic settings, paleogeography and evaoritic sedimentation of Tethyan blocks within China: Implications for potash formation. Ore Geology Reviews, 102, 406–425. doi: 10.1016/j.oregeorev.2018.09.002

    CrossRef Google Scholar

    [28] Maranate S, Vella P. 1986. Paleomagnetism of the Khorat Group, Mesozoic, Northeast Thailand. Journal of Southeast Asian earth sciences, 1(1), 23–31. doi: 10.1016/0743-9547(86)90004-8

    CrossRef Google Scholar

    [29] Meesook A. 2000. Cretaceous environments of northeastern Thailand. In Developments in Palaeontology and Stratigraphy, 17, 207–223. doi: 10.1016/S0920-5446(00)80034-5

    CrossRef Google Scholar

    [30] Miao ZY, Zhang Z, Zheng MP, Niu XS, Zhang XF. 2017. Tectonic evolution of eastern Tethys and formation of evaporite in Lanping-Simao Basin, Southwest China. Acta Geoscientica Sinica, 38(6), 883–896 (in Chinese with English abstract).

    Google Scholar

    [31] Patterson RJ, Kinsman DJJ. 1977. Marine and continental groundwater sources in a Persian Gulf coastal sabkha. Studies in Geology, 4, 381–397.

    Google Scholar

    [32] Pisutha-Arnond V, Chiba H, Yumuang S. 1986. A preliminary sulphur and oxygen isotope study of the Maha Sarakham evaporitic anhydrite from the Bamnet Narong Area of Northeastern Thailand. GEOSEA Ⅴ Proceedings Vol. Ⅰ. Geological Society of Malaysia Bultetin, 19, 209–222. doi: 10.7186/bgsm19198617

    CrossRef Google Scholar

    [33] Qian ZQ, Qu YH, Liu Q. 1994. Potash deposits. Beijing, Geological Publishing House, 273 (in Chinese).

    Google Scholar

    [34] Qin ZJ, Li QK, Zhang XR, Fan QS, Wang JP, Du YS, Ma YQ, Wei HC, Yuan Q, Shan FS. 2020. Origin and recharge model of the Late Cretaceous evaporites in the Khorat Plateau. Ore Geology Reviews, 116, 103226. doi: 10.1016/j.oregeorev.2019.103226

    CrossRef Google Scholar

    [35] Qu YH. 1997. On affinity of potassium bearing brine in Lanpingsimao basin, China to that in Ale Basin, Thailand, and location of target areas for potassium hunting in former basin. Geology of Chemical Minerals, 19(2), 81–85 (in Chinese with English abstract).

    Google Scholar

    [36] Racey A, Goodall JG. 2009. Palynology and stratigraphy of the Mesozoic Khorat Group red bed sequences from Thailand. Geological Society, London, Special Publications, 315(1), 69–83. doi: 10.1144/SP315.6

    CrossRef Google Scholar

    [37] Racey A, Goodall JGS, Love MA, Polachan S, Jones PD. 1994. November. New age data for the Mesozoic Khorat Group of northeast Thailand. In Proceedings of the International Symposium on Stratigraphic Correlation of Southeast Asia. Bangkok,Department of Mineral Resources, 245-252.

    Google Scholar

    [38] Racey A, Love MA, Canham AC, Goodall JGS, Polachan S, Jones PD. 1996. Stratigraphy and reservoir potential of the Mesozoic Khorat Group, NE Thailand: Part 1: stratigraphy and sedimentary evolution. Journal of Petroleum Geology, 19(1), 5–39. doi: 10.1111/j.1747-5457.1996.tb00511.x

    CrossRef Google Scholar

    [39] Ren QH, Du YS, Gao DL, Li BK, Zhang XY, Liu XT, Yuan XL. 2018. A Multi-fluid Constrain for the Forming of Potash Deposits in the Savannakhet Basin: Geochemical Evidence from Halite. Acta Geologica Sinica (English Edition), 92(2), 755–768. doi: 10.1111/1755-6724.13552

    CrossRef Google Scholar

    [40] Royer DL. 2006. CO2-forced climate thresholds during the Phanerozoic. Geochimica et Cosmochimica Acta, 70(23), 5665–5675. doi: 10.1016/j.gca.2005.11.031

    CrossRef Google Scholar

    [41] Sattayarak N, Polachan S. 1990. Rock Salt Beneath the Khorat Plateau. Proceedings on Mineral Management. Bangkok, Department of Mineral Resources, 2-6 July 1990, 1−14.

    Google Scholar

    [42] Sattayarak N, Polachan S, Charusirisawad R. 1991. November. Cretaceous rock salt in the northeastern part of Thailand. In Proceedings of the 7th Regional Conference Geology and Mineral Resources Southeast Asia (GEOSEA VII).

    Google Scholar

    [43] Schouten S, Hopmans EC, Forster A, van Breugel Y, Kuypers MM, Damsté JSS. 2003. Extremely high sea-surface temperatures at low latitudes during the middle Cretaceous as revealed by archaeal membrane lipids. Geology, 31(12), 1069–1072. doi: 10.1130/G19876.1

    CrossRef Google Scholar

    [44] Suwanich P. 1985. Potash and rock salt in Thailand. Department of Mineral Resources. Bangkok.

    Google Scholar

    [45] Suwanich P. 2007. Potash-evaporite deposits in Thailand, Proceedings of the International Conference on Geology of Thailand, 252−262.

    Google Scholar

    [46] Taberner C, Cendón DI, Pueyo JJ, Ayora C. 2000. The use of environmental markers to distinguish marine vs. continental deposition and to quantify the significance of recycling in evaporite basins. Sedimentary Geology, 137(3−4), 213–240. doi: 10.1016/S0037-0738(00)00105-6

    CrossRef Google Scholar

    [47] Tan HB, Ma HZ, Li BK, Zhang XY, Xiao YK. 2010. Strontium and boron isotopic constraint on the marine origin of the Khammuane potash deposits in southeastern Laos. Chinese Science Bulletin, 55(27-28), 3181–3188. doi: 10.1007/s11434-010-4010-x

    CrossRef Google Scholar

    [48] Tarduno JA, Brinkman DB, Renne PR, Cottrell RD, Scher H, Castillo P. 1998. Evidence for extreme climatic warmth from Late Cretaceous Arctic vertebrates. Science, 282(5397), 2241–2243. doi: 10.1126/science.282.5397.2241

    CrossRef Google Scholar

    [49] Timofeeff MN, Lowenstein TK, Da Silva MAM, Harris NB. 2006. Secular variation in the major-ion chemistry of seawater: Evidence from fluid inclusions in Cretaceous halites. Geochimica et Cosmochimica Acta, 70(8), 1977–1994. doi: 10.1016/j.gca.2006.01.020

    CrossRef Google Scholar

    [50] U.S. Geological Survey (USGS), 2019. Potash, in Mineral Commodity Summaries 2019. 126−127. https://www.usgs.gov/centers/nmic/potash-statistics-and-information.

    Google Scholar

    [51] Utha-Aroon C. 1993. Continental origin of the Maha Sarakham evaporites, northeastern Thailand. Journal of Southeast Asian Earth Sciences, 8(1−4), 193–203. doi: 10.1016/0743-9547(93)90021-G

    CrossRef Google Scholar

    [52] Utha-Aroon C, Coshell L, Warren JK. 1995. November. Early and late dissolution in the Maha Sarakham Formation: implications for basin stratigraphy. In International Conference on Geology, Geochronology and Mineral resources in Indochina, 275-286.

    Google Scholar

    [53] Valyashko MG. 1956. Geochemistry of bromine in the processes of salt deposition and the use of the bromine content as a genetic and prospecting criterion. Geochemistry, 6, 570–589.

    Google Scholar

    [54] Vengosh A, Starinsky A, Kolodny Y, Chivas AR, Raab M. 1992. Boron isotope variations during fractional evaporation of sea water: New constraints on the marine vs. nonmarine debate. Geology, 20(9), 799–802. doi: 10.1130/0091-7613(1992)020<0799:BIVDFE>2.3.CO;2

    CrossRef Google Scholar

    [55] Wang JY, Lowenstein TK. 2017. Anomalously High Cretaceous Paleobrine Temperatures: Hothouse, Hydrothermal or Solar Heating? Minerals, 7(12), 245,1–19.

    Google Scholar

    [56] Wang LC, Liu CL, Gao X, Zhang H. 2014. Provenance and paleogeography of the Late Cretaceous Mengyejing Formation, Simao Basin, southeastern Tibetan Plateau: Whole-rock geochemistry, U-Pb geochronology, and Hf isotopic constraints. Sedimentary Geology, 304, 44–58. doi: 10.1016/j.sedgeo.2014.02.003

    CrossRef Google Scholar

    [57] Wang LC, Liu CL, Shen LJ, Bo Y. 2018. Research advances in potash forming of the Simao Basin, eastern Tethyan Realm. Acta Geologica Sinica, 92(8), 1707–1723 (in Chinese with English abstract).

    Google Scholar

    [58] Wardlaw NC. 1968. Carnallite-sylvite relationships in the Middle Devonian Prairie evaporite formation, Saskatchewan. Geological Society of America Bulletin, 79(10), 1273–1294. doi: 10.1130/0016-7606(1968)79[1273:CRITMD]2.0.CO;2

    CrossRef Google Scholar

    [59] Wang YD, Huang CM, Sun BN, Quan C, Wu JY, Lin ZC. 2014. Paleo-CO2 variation trends and the Cretaceous greenhouse climate. Earth-Science Reviews, 129, 136–147. doi: 10.1016/j.earscirev.2013.11.001

    CrossRef Google Scholar

    [60] Warren JK. 2016. Evaporites: A geological compendium. Springer. doi: 10.1007/978-3-319-13512-0

    Google Scholar

    [61] Yumuang S, Khantaprab C, Taiyagupt M. 1986. The evaporite deposits in Bamnet Narong area, northeastern Thailand. GEOSEA V Proceedings. Vol. Ⅱ. Geological Society of Malaysia Bultetin, 20, 249–267. doi: 10.7186/bgsm20198614

    CrossRef Google Scholar

    [62] Zhang DW, Yan MD, Fang XM, Yang YB, Zhang T, Zan JB, Zhang WL, Liu CL, Yang Q. 2018. Magnetostratigraphic study of the potash-bearing strata from drilling core ZK2893 in the Sakhon Nakhon Basin, eastern Khorat Plateau. Palaeogeography, Palaeoclimatology, Palaeoecology, 489, 40–51. doi: 10.1016/j.palaeo.2017.08.030

    CrossRef Google Scholar

    [63] Zhang H, Liu C, Wang L, Fang X. 2014. Characteristics of evaporites sulfur isotope from potash deposit in Thakhek Basin, Laos, and its implication for potash formation. Geological Review, 60(4), 851–857 (in Chinese with English abstract).

    Google Scholar

    [64] Zhang H, Liu CL, Zhao YJ, Mischke S, Fang XM, Ding T. 2015. Quantitative temperature records of mid Cretaceous hothouse: Evidence from halite fluid inclusions. Palaeogeography, Palaeoclimatology, Palaeoecology, 437, 33–41. doi: 10.1016/j.palaeo.2015.07.022

    CrossRef Google Scholar

    [65] Zhang XY, Cheng HD, Tan HB, Yuan XL, Li YS, Miao WL, Li TW, Ma HZ. 2015. Late Cretaceous potash evaporites in Savannakhet Basin of middle Laos: Geochemical eficences of non-marine inputs. Acta Petrologica Sinica, 31(9), 2789–2793.

    Google Scholar

    [66] Zhang XY, Ma HZ, Ma YQ, Tang QL, Yuan XL. 2013. Origin of the late Cretaceous potash-bearing evaporites in the Vientiane Basin of Laos: δ11B evidence from borates. Journal of Asian Earth Sciences, 62, 812–818. doi: 10.1016/j.jseaes.2012.11.036

    CrossRef Google Scholar

    [67] Zhang XY, Ma HZ, Tan HB, Gao DL, Li BK, Wang MX, Tang QL, Yuan XL. 2010. Preliminary studies of on geochemistry and post-depositional change of Dong Tai potash deposit in Laos. Mineral Deposits, 29(4), 713–721 (in Chinese with English abstract).

    Google Scholar

    [68] Zheng MP, Hou XH, Zhang YS, Xing EY, Li HP, Yin HW, Yu CQ, Wang NJ, Deng XL, Wei Z, Miao ZY, Zhong JA, Wang F, Fan F, Zhang XF, Wang XB, Liu TQ, Kong WG. 2018. Progress in the investigation of potash resources in western China. China Geology, 1, 392–401.

    Google Scholar

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