2024 Vol. 44, No. 1
Article Contents

LIU Zining, LI Tong, MO Bin, JIA Lei, ZHAO Yi, ZHAO Libo, WU Junyi. 2024. Selenium-rich soils in the area of Ruyuan, Guangdong, China: Se geochemistry and evaluation of factors controlling Se enrichment. Sedimentary Geology and Tethyan Geology, 44(1): 185-193. doi: 10.19826/j.cnki.1009-3850.2023.08004
Citation: LIU Zining, LI Tong, MO Bin, JIA Lei, ZHAO Yi, ZHAO Libo, WU Junyi. 2024. Selenium-rich soils in the area of Ruyuan, Guangdong, China: Se geochemistry and evaluation of factors controlling Se enrichment. Sedimentary Geology and Tethyan Geology, 44(1): 185-193. doi: 10.19826/j.cnki.1009-3850.2023.08004

Selenium-rich soils in the area of Ruyuan, Guangdong, China: Se geochemistry and evaluation of factors controlling Se enrichment

More Information
  • A survey of 422 surface soil samples in the Ruyuan Yao Autonomous County of Guangdong Province was done to determine the geochemistry and spatial distribution of Se, and to evaluate factors that could influence Se distributions in soils in the study area. Results showed that the average content of Se in soil of the study area was 0.65 mg·kg1, which was 1.97, 2.71 and 2.95 times that of the background values of Shaoguan City, Guangdong Province, and the national average, respectively. The selenium-rich soil is mainly distributed in the central and western regions of the study area, and a total area of 2061.31 km2 of selenium-rich soil is delineated, accounting for 89.66% of the total study area. Soil Se concentrations vary by land use type: forest land > garden land > grassland > cultivated land. The enrichment of Se in the soil of the study area is mainly controlled by the parent material. The type of parent material with the highest soil Se content is soil formed by the weathering of argillaceous rocks, where soil selenium is enriched 93.33% relative to parent rock. Secondly, it is affected by the supergene geochemistry and the adsorption and fixation of S, N and other elements in the study area, which is conducive to the enrichment of Se in soil. There was a significant negative correlation between Se and pH in the soil of the study area, that is, the lower the pH value, the higher the Se content. These insights provide a scientific basis for the rational planning and utilization of local selenium-rich land resources, especially for considering agricultural land uses. Se can provide an essential nutrient or adversely affect crops, depending on Se concentrations and chemical form.

  • 加载中
  • [1] 敖亚平, 陈伟, 2013. 常德地区部分食品硒含量分析[J]. 微量元素与健康研究, 30(2): 25-27

    Google Scholar

    Ao Y P, Chen W, 2013. Determination of selenium content in partial food of Changde by atomic fluorescence spectrometry method[J]. Studies of trace elements and health, 30(2): 25-27.

    Google Scholar

    [2] Bridges C C, Zalups R K., Molecular and ionic mimicry and the transport of toxic metals[J]. Toxicology and applied pharmacology, 2005, 204(3), 274−308.

    Google Scholar

    [3] Ding Q T, Cui Z, Huang J, et al. , 2018. Selenium distribution in the Chinese environment and its relationship with human health: A review[J]. Environment International, 112: 294-309. doi: 10.1016/j.envint.2017.12.035

    CrossRef Google Scholar

    [4] Gailer J., Arsenic–selenium and mercury–selenium bonds in biology[J]. Coordination Chemistry Reviews, 2007, 251(1−2), 234−254.

    Google Scholar

    [5] 何振立. 1998. 污染及有益元素的土壤化学平衡[M]. 北京: 中国环境科学出版社.

    Google Scholar

    He Z L. 1998. Chemical equilibrium of Contaminated and Beneficial Elements in Soil[M]. Beijing: China Environmental Science Press(in Chinese with English abstract).

    Google Scholar

    [6] Jiang T, Yu T, Qi H, et al. , 2022. Analysis of phosphorus and sulfur effect on soil selenium bioavailability based on diffusive gradients in thin films technique and sequential extraction[J]. Chemosphere, 302: 134831. doi: 10.1016/j.chemosphere.2022.134831

    CrossRef Google Scholar

    [7] 姜磊. 2010. 万源富硒区土壤中硒元素环境化学特征研究[D]. 成都: 成都理工大学.

    Google Scholar

    Jiang L. 2010. Study on Environmental chemistry Characteristics of Selenium in Soil of Wanyuan Selenium rich Area[D]. Chengdu: Chengdu University of Technology(in Chinese with English abstract).

    Google Scholar

    [8] Keshavarzi B, Moore F., Najmeddin A, et al., 2012. The role of selenium and selected trace elements in the etiology of esophageal cancer in high risk Golestan province of Iran[J]. Science of the total environment, 433, 89−97.

    Google Scholar

    [9] Kohrle J, Jakob F, Contempré B, et al., 2005. Selenium, the thyroid, and the endocrine system[J]. Endocrine reviews, 26(7), 944−984.

    Google Scholar

    [10] 李家熙, 张光弟, 葛晓立, 等, 2000. 人体硒缺乏与过剩的地球化学环境特征及其预测[M]. 北京: 地质出版社

    Google Scholar

    [11] 李帅, 李樋, 邢欢, 等, 2023. 内蒙古东来地区土壤养分空间分布特征及评价[J]. 地质学刊, 47(3): 314 − 321.

    Google Scholar

    Li S, Li T, Xing H, et al., 2023. Spatial distribution characteristics and evaluation of soil nutrients in Donglai area of Inner Mongolia[J]. Journal of Geology, 47(3): 314 − 321(in Chinese with English abstract).

    Google Scholar

    [12] 李樋, 李随民, 王轶, 等, 2020. 基于地球化学基线的内蒙古东来地区土壤重金属污染评价[J]. 土壤通报, 51(2): 462-472

    Google Scholar

    Li T, Li S M, Wang Y, et al. , 2020. Assessment of Soil Heavy Metal Pollution in Donglai area of Inner Mongolia Based on Geochemical Baseline[J]. Chinese Journal of Soil Science, 51(2): 462-472

    Google Scholar

    [13] 李樋, 刘洪, 李佑国, 等, 2022. 基于地统计学及GIS的西昌地区中生代红层区紫色土营养元素空间变异性及影响因素研究[J]. 地球科学进展, 37(6): 627-640

    Google Scholar

    Li T, Liu H, Li Y G, et al. , 2022. Study on spatial variability and influencing factors of nutrient elements in purple soil in mesozoic red layer region in Xichang area based on geostatistics and GIS[J]. Advances in Earth Science, 37(6): 627-640.

    Google Scholar

    [14] 李樋, 刘小念, 刘洪, 等, 2021a. 基于地质建造的土壤营养元素空间分布特征研究—以大凉山区为例[J]. 安全与环境工程, 28(6): 127-137

    Google Scholar

    Li T, Liu X N, Liu H, et al. , 2021a. Study on spatial distribution characteristics of soil nutrient elements based on geological construction[J]. Safety and Environmental engineering, 28(6): 127-137.

    Google Scholar

    [15] 李樋, 刘小念, 刘洪, 等, 2023. 西昌普诗地区中−下白垩统小坝组岩石−紫色土剖面稀土元素地球化学特征分析[J]. 沉积与特提斯地质, 43(4): 829 − 843.

    Google Scholar

    Li T, Liu X N, Liu H, et al., 2023. Geochemistry of rare earth elements of purple soil layers in the Middle−Lower Cretaceous Xiaoba Formation, Pushi area, Xichang[J]. Sedimentary Geology and Tethyan Geology, 43(4): 829 − 843(in Chinese with English abstract).

    Google Scholar

    [16] Li T, Li Y G, Liu H, et al., 2022. Chemical weathering intensity and geochemical characteristics of Cretaceous terrigenous clastic rock-purple soil profiles in the Pushi area, Xichang[J]. Geological Journal, 57(9), 3587−3600.

    Google Scholar

    [17] Li T, Li Y G, Liu H, et al., Spatial distribution and ecological risk assessment of heavy metal elements in rock-soil in the mountainous areas of Southwest China: A case study of Xichang[J]. Geological Journal, 2023, 58(10), 3866-3878.

    Google Scholar

    [18] 李永华, 王五一, 雒昆利, 等, 2004. 大巴山区土壤中的硒和氟[J]. 土壤学报, 41(1): 61-67

    Google Scholar

    Li Y H, Wang W Y, Luo K L, et al. , 2004. Distribution of selenium and fluorine in soils of Daba Mountains[J]. Acta pedologica sinica, 41(1): 61-67.

    Google Scholar

    [19] 李玉超, 王诚煜, 于成广, 辽宁丹东地区土壤Se元素地球化学特征及其影响因素[J]. 吉林大学学报(地球科学版), 2020, 50(6): 1766−1775

    Google Scholar

    Li Y C, Wang C Y, Yu C G, Geochemical Characteristics and influencing factors of selenium in soil from Dandong area, Liaoning Province [J]. Journal of Jilin University:Earth Science Edition, 2020, 50(6): 1766−1775(in Chinese with English abstract).

    Google Scholar

    [20] 郦逸根, 董岩翔, 郑洁, 等, 2005. 浙江富硒土壤资源调查与评价[J]. 第四纪研究, 25(3): 323-330

    Google Scholar

    Li Y G, Dong Y X, Zheng J, et al. , 2005. Selenium: Abundant soil survey and assessment in Zhejiang[J]. Quaternary Sciences, 25(3): 323-330.

    Google Scholar

    [21] Li Z, Liang, D, Peng Q, et al., Interaction between selenium and soil organic matter and its impact on soil selenium bioavailability: A review[J]. Geoderma, 2017, 295, 69−79.

    Google Scholar

    [22] Litov R E, Combs G F. 1991. Selenium in pediatric nutrition[J]. Pediatrics, 87(3 ): 339—357.

    Google Scholar

    [23] 刘聪. 2020. 西京古道历史街区乳源洲街研究[D]. 广州: 华南理工大学.

    Google Scholar

    Liu C. 2020. Research on Ruyuan Zhou street in historic district of wayside Pavilion[D]. Guangzhou: South China University of Technology(in Chinese with English abstract).

    Google Scholar

    [24] 刘洪, 黄瀚霄, 欧阳渊, 等, 2020. 基于地质建造的土壤地质调查及应用前景分析—以大凉山区西昌市为例[J]. 沉积与特提斯地质, 40(1): 91-105

    Google Scholar

    Liu H, Huang H X, Ouyang Y, et al. , 2020. Soil’s geologic investigation in Daliangshan, Xichang, Sichuan[J]. Sedimentary Geology and Tethyan Geology, 40(1): 91-105.

    Google Scholar

    [25] 刘永林, 吴梅, 刘睿, 等, 2022. 地质高背景区成土母岩对表土硒含量及其生物有效性的影响[J]. 土壤, 54(4): 834-840

    Google Scholar

    Liu Y L, Wu M, Liu R, et al. , 2022. Effect of Pedogenic Rock on Soil Selenium and Its Bioavailability in High Geological Background Area[J]. Soils, 54(4): 834-840.

    Google Scholar

    [26] 刘子宁, 窦磊, 游远航, 珠江三角洲台山地区硒的地球化学特征[J]. 现代地质, 2014, 28(5), 928−934

    Google Scholar

    Liu Z N, Dou L, You Y H, Geochemical characteristics of selenium in Taishan region of pearl river Delta[J]. Geoscience, 2014, 28(5), 928−934(in Chinese with English abstract).

    Google Scholar

    [27] 刘子宁, 李婷婷, 罗思亮, 2017. 珠江三角洲台山地区富硒土壤资源评价[J]. 地质学刊, 41(4): 672-677

    Google Scholar

    Liu Z N, Li M M, Luo S L, 2017. Resource evaluation of selenium-rich in Taishan region of the Pearl River Delta[J]. Journal of Geology, 41(4): 672-677.

    Google Scholar

    [28] 雒昆利, 潘云唐, 王五一, 等, 2001. 南秦岭早古生代地层含硒量及硒的分布规律[J]. 地质论评, 47(2): 211-217

    Google Scholar

    Luo K L, Pan Y T, Wang W Y, et al. , 2001. Selenium content and distribution pattern in the palaeozoic strata in the Southern Qinling Mountains[J]. Geological review, 47(2): 211-217.

    Google Scholar

    [29] 雒昆利, 谭见安, 王五一, 向连华, 等, 2002. 大巴山区早古生代地层和石煤中硒的化学活动性的初步研究[J]. 环境科学学报, 22(1): 86-91

    Google Scholar

    Luo K L, Tan J A, Wang W Y, Xiang L H, et al, 2002. Chemical mobility of selenium in early paleozoic rock and stone coal in Daba Mountain South Qinling[J]. Acta science circumstantiae, 22(1): 86-91.

    Google Scholar

    [30] 毛香菊, 刘璐, 程新涛, 等, 2021. 河南新密典型富硒区土壤Se元素地球化学特征及空间分布规律[J]. 地质通报, 40(10): 1664-1670

    Google Scholar

    Mao X J, Liu L, Cheng X T, et al, 2021. Geochemistry and spatial distribution of se element in soils of typical Se-rich area in Xinmi, Henan Province[J]. Geological bulletin of China, 40(10): 1664-1670.

    Google Scholar

    [31] 覃建勋, 付伟, 郑国东, 等, 2020. 广西岩溶区表层土壤硒元素分布特征与影响因素探究——以武鸣县为例[J]. 土壤学报, 57(5): 1299-1310

    Google Scholar

    Zhao J X, Fu W, Zheng G D, et al. , 2020. Exploration on the distribution characteristics and influencing factors of selenium elements in surface soil of karst regions in Guangxi: A Case Study of Wuming County[J]. Journal of Soil Science, 57(5): 1299-1310.

    Google Scholar

    [32] Rayman M P. 2000. The importance of selenium to human health[J]. The Lancet, 356(9225): 233—241 .

    Google Scholar

    [33] Supriatin S, Weng L, Comans R N., Selenium−rich dissolved organic matter determines selenium uptake in wheat grown on Low−selenium arable land soils[J]. Plant and Soil, 2016, 408(1), 73−94.

    Google Scholar

    [34] Wang Y., Shao M A, Liu Z, et al., Regional spatial pattern of deep soil water content and its influencing factors[J]. Hydrological Sciences Journal, 2012, 57(2), 265−281.

    Google Scholar

    [35] Wang Z, Gao Y, Biogeochemical cycling of selenium in Chinese environments[J]. Applied geochemistry, 2001, 16(11−12), 1345−1351.

    Google Scholar

    [36] 王锐, 余涛, 杨忠芳, 等, 2018. 富硒土壤硒生物有效性及影响因素研究[J]. 长江流域资源与环境, 27(7): 1647-1654

    Google Scholar

    Wang R, Yu T, Yang Z F, et al, 2018. Bioavailability of Soil Selenium and Its Influencing Factors in Selenium-Enriched Soil[J]. Resources and environment in the Yangtze Basin, 27(7): 1647-1654.

    Google Scholar

    [37] 王世杰, 季宏兵, 欧阳自远, 等, 1999. 碳酸盐岩风化成土作用的初步研究[J]. 中国科学(D辑: 地球科学), 29(5): 441-449

    Google Scholar

    Wang S J, Ji H B, Ouyang Z Y, et al. , 1999. A preliminary study on weathering Soil formation of Carbonate rock[J]. Chinese Science (Part D: Earth Science), 29(5): 441-449.

    Google Scholar

    [38] 王政权. 1999. 地统计学及在生态学中的应用[M]. 北京: 科学出版社: 98−102

    Google Scholar

    Wang Z Q. 1999. Geostatistics and its application in ecology[M]. Beijing: Science Press: 98−102(in Chinese with English abstract).

    Google Scholar

    [39] 温汉捷, 裘愉卓, 凌宏文, 等, 2003. 中国早古生代若干高硒黑色岩系中层状硅质岩的地球化学特征及其成因意义[J]. 沉积学报, 21(4): 619-626

    Google Scholar

    Wen H J, Qiu Y Z, Ling H W, et al. , 2003. Geochemistry and genesis of bedded cherts in some typical eopaleozoic high selenium black shales, China[J]. Acta sedimentologica sinica, 21(4): 619-626.

    Google Scholar

    [40] 杨磊, 周泽, 李鸿磊, 2020. 贵州省花溪区耕地土壤硒元素分布特征及富硒资源评价[J]. 贵州地质, 37(3): 340-344+357

    Google Scholar

    Yang L, Zhou Z, Li H L, 2020. Distribution Characteristics of Soil Selenium and Evaluation of Selenium-rich Resources of Huaxi District, Guizhou Province[J]. Guizhou geology, 37(3): 340-344+357.

    Google Scholar

    [41] 杨志强, 李杰, 郑国东, 等, 2014. 广西北部湾沿海经济区富硒土壤地球化学特征[J]. 物探与化探, 38(6): 1260-1264+1269

    Google Scholar

    Yang Z Q, Li J, Zheng G D, et al. , 2014. Geochemical characteristics of selenium-rich soil in Beibu Gulf coastal economic zone of Guangxi[J]. Geophysical and Geochemical Exploration, 38(6): 1260-1264+1269.

    Google Scholar

    [42] 杨忠芳, 余涛, 侯青叶, 等, 2012. 海南岛农田土壤Se的地球化学特征[J]. 现代地质, 26(5): 837-849

    Google Scholar

    Yang Z F, Yu T, Hou Y Q, et al. , 2012. Geochemical characteristics of soil selenium in farmland of Hainan Island[J]. Geoscience, 26(5): 837-849.

    Google Scholar

    [43] 曾庆良, 余涛, 王锐, 2018. 土壤硒含量影响因素及富硒土地资源区划研究——以湖北恩施沙地为例[J]. 现代地质, 32(1): 105-112

    Google Scholar

    Zeng Q L, Yu T, Wang R, 2018. The Influencing Factors of Selenium in Soils and Classifying the Selenium-rich Soil Resources in the Typical Area of Enshi, Hubei[J]. Geoscience, 32(1): 105-112.

    Google Scholar

    [44] 张光弟, 葛晓立, 张绮玲, 等, 2001. 湖北恩施硒中毒区土壤硒的分布及其控制因素[J]. 中国地质, 28(9): 37-40+36

    Google Scholar

    Zhang G D, Ge X L, Zhagn Q L, et al. , 2001. The distribution and control factors of soil selenium in the selenium poisoning area of Enshi, Hubei Province[J]. China geology, 28(9): 37-40+36.

    Google Scholar

    [45] 张飘飘, 张湜溪, 夏梦婵, 等, 2022. 陕南石煤分布区天然水中硒元素的含量特征及成因分析[J]. 中国煤炭地质, 34(1): 45-51

    Google Scholar

    Zhang P P, Zhang S X, Xia M C, et al. , 2022. Natural water selenium content features and genetic analysis in Southern Shaanxi Stone coal distributed Area[J]. Coal geology of China, 34(1): 45-51.

    Google Scholar

    [46] 张伟, 刘子宁, 贾磊, 等, 2021. 广东省韶关市土壤环境背景值[M]. 武汉: 中国地质大学出版社. 77−78.

    Google Scholar

    Zhang W, Liu Z N, Jia L, et al., 2021. Background value of soil environment in Shaoguan City, Guangdong Province[M]. Wuhan: China University of Geosciences Press 77−78(in Chinese with English abstract).

    Google Scholar

    [47] 张志坚, 刘苑秋, 吴春生, 等, 2018. 基于地统计学和GIS的江西省森林土壤养分空间分布特征[J]. 水土保持研究, 25(1): 38-46

    Google Scholar

    Zhang Z J, Liu W Q, Wu C S, et al. , 2018. Spatial distribution characteristics of forest soil nutrients in Jiangxi Province based on Geostatistics and GIS[J]. Research of soil and water conservation, 25(1): 38-46.

    Google Scholar

    [48] 朱建明, 梁小兵, 凌宏文, 等, 2003. 环境中硒存在形式的研究现状[J]. 矿物岩石地球化学通报, 22(1): 75-81

    Google Scholar

    Zhu J M, Liang X B, Ling H W, et al. , 2003. Advances in studying occurrence modes of selenium in environment[J]. Bulletin of mineralogy, Petrology and geochemistry, 22(1): 75-81.

    Google Scholar

    [49] 朱建明, 秦海波, 罗泰义, 等, 2007. 西南寒武、二叠系富硒碳质岩中硒结合态的比较研究[J]. 高校地质学报, 13(1): 69-74

    Google Scholar

    Zhu J M, Qin H B, Luo T Y, et al. , 2007. A comparative study of selenium fractionation in se-rich carbonaceous rocks of lower cambrian and permian in Southwest China[J]. Geological Journal of china universities, 13(1): 69-74.

    Google Scholar

  • 加载中
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Figures(6)

Tables(4)

Article Metrics

Article views(344) PDF downloads(169) Cited by(0)

Access History

Other Articles By Authors

Catalog

    /

    DownLoad:  Full-Size Img  PowerPoint