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LIU Chao, WANG Yalei, ZHANG Zhaowei, LIU Yuegao, HAN Yixiao, DONG Yibo, LENG Xin. 2020. The Genetic Significance of Pentlandite and Pyrrhotite and the Characteristics of Cobalt Occurrence in Xiarihamu Cobalt-Nickel Deposit of Eastern Kunlun. Northwestern Geology, 53(2): 183-199. doi: 10.19751/j.cnki.61-1149/p.2020.02.011
Citation: LIU Chao, WANG Yalei, ZHANG Zhaowei, LIU Yuegao, HAN Yixiao, DONG Yibo, LENG Xin. 2020. The Genetic Significance of Pentlandite and Pyrrhotite and the Characteristics of Cobalt Occurrence in Xiarihamu Cobalt-Nickel Deposit of Eastern Kunlun. Northwestern Geology, 53(2): 183-199. doi: 10.19751/j.cnki.61-1149/p.2020.02.011
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The Genetic Significance of Pentlandite and Pyrrhotite and the Characteristics of Cobalt Occurrence in Xiarihamu Cobalt-Nickel Deposit of Eastern Kunlun

  • 1. Key Laboratory for the Study of Focused Magmatism and Giant Ore Deposits, MNR, Xi'an Center of China Geological Survey/Northwest China Center for Geoscience Innovation, Xi'an 710054, Shaanxi, China;

  • 2. School of Earth Science and Resources, Chang'an University, Xi'an 710054, Shaanxi, China

Received Date:  04 December 2019
Revised Date:  18 March 2020
    Abstract
  • Jinchuan copper-nickel deposit being the world's third-largest deposit found in China, Xirihamu in Eastern Kunlun is another super large magmatic nickel-cobalt-sulfide deposit, and it is also the largest deposit in orogenic belts. Previous mineralogical research focused mainly on silicate minerals, studies on ore-forming materials (sulfide) is relatively less. Through systematic division of the output of pentlandite, based on the atomic ratio of Ni/Fe, the distribution of Co elements and the classification of pyrrhotite types, we infer that Xiarihamu deposit has experienced at least two stages of magmatism. At the first magmatic stage, some high-cobalt content sulfide crystallized at higher temperature; at the second magmatic stage, some sulfide with low-cobalt content crystallized at a relatively low temperature. Combined with the ratio change of metal atom to sulfur atom in pentlandite, we found that the sulfur fugacity increases gradually in the process of sulfide crystallization. This may be affected by such factors as the crystallization of sulfide and silicate minerals and the sulfur contamination. In the Xiarihamu deposit, cobalt exists mainly in pentlandite. In pyrrhotite, cobalt mainly exists in meteorite pyrite and hexagonal pyrrhotite. In arsenide, cobalt mainly exists in cobaltite. The arsenide contains more cobalt than the sulfides. These characteristics give scientific support to the extraction and synthetic use of cobalt.
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  • 曹亚文.金川铜镍硫化物矿床矿物形成演化研究[D].北京:中国地质科学院,1995.

    Google Scholar

    CAO Yawen.A study on the formation and evolution of the minerals in the Jinchuan Ni-Cu deposit[D].Binjing:Chinese Academy of Geological Sciences,1995.

    Google Scholar

    陈殿芬.我国一些铜镍硫化物矿床主要金属矿物的特征[J]. 岩石矿物学杂志,1995,14(4):346-348.

    Google Scholar

    CHEN Dianfen.Characteristics of main metallic in some copper-nickel sulfide deposits of China[J].Acta Petrologica et Mineralogica,1995,14(4):346-348.

    Google Scholar

    陈静,谢智勇,李彬,等.东昆仑拉陵灶火地区泥盆纪侵入岩成因及其地质意义[J].矿物岩石,2013,33(2):26-34.

    Google Scholar

    CHEN Jing,XIE Zhiyong,LI Bin,et al.Petrogenesis of devonian intrusive rocks in Lalingzaohuo area, East Kunlun,and its Geological significance[J].Journal of Mineralogy and Petrology, 2013,33(2):26-34.

    Google Scholar

    陈亮.甘肃金川铜镍硫化物矿床金属硫化物矿物学特征研究[D].北京:中国地质大学(北京),2008.

    Google Scholar

    CHEN Liang.Study on the mineralogy characteristics of metallic sulphide in the Jinchuan Ni-Cu sulfide ore deposit,GanSu Province[D].Beijing:China University of Geosciences,Beijing,2008.

    Google Scholar

    丁奎首,秦克章,许英霞,等.东天山主要铜镍矿床中磁黄铁矿的矿物标型特征及其成矿意义[J].矿床地质,2007,(01):109-119.

    Google Scholar

    DING Kuishou,QIN Kezhang,XU Yingxia,et al. Typomorphic characteristics and ore-forming significance of pyrrhotite in the major Cu-Ni deposits,East Tianshan,Xinjiang.[J].Mineral Deposits,2007,(01):109-119.

    Google Scholar

    丁奎首,吴锋.攀西基性岩中陨硫铁的发现及其意义[J].地质科学,1985,(03):243-250.

    Google Scholar

    DING Kuishou,WU Feng.The discovery and significance of troilite in basic igneous rock of Panzhihuaxichang district.[J].Chinese Journal of Geology,1985,(03):243-250.

    Google Scholar

    杜玮.东昆仑夏日哈木镍矿区镁铁-超镁铁质岩石研究[D].西安:长安大学,2015.

    Google Scholar

    DU Wei.Study on the mafic-ultramafic rocks of Xiarihamu nickel mining area in East Kunlun[D].Xi'an:Chang'an University,2015.

    Google Scholar

    姜常义,凌锦兰,周伟,等.东昆仑夏日哈木镁铁质-超镁铁质岩体岩石成因与拉张型岛弧背景[J].岩石学报,2015,31(4):1117-1136.

    Google Scholar

    JIANG Changyi,LING Jinlan,ZHOU Wei, et al.,Petrogenesis of the Xiarihamu Ni-bearing layered mafic-ultramafic intrusion, East Kunlun:Implications for its extensional island arc environment[J]. Acta Petrologica Sinica.2015,31(4):1117-1136.

    Google Scholar

    何书跃,李东生,白国龙,等.青海祁漫塔格群力矿床矽卡岩中白云母40Ar/39Ar年龄报道[J].中国地质,2018,45(1):201-202.

    Google Scholar

    HE Shuyue,LI Dongsheng,BAI Guolong,et al.The report on 40Ar/39Ar age of muscovite from the Qunli Fe-poly-metallic deposit in the Qimantag area,Qinghai Province[J].Geology in China,2018,45(1):201-202.

    Google Scholar

    郝娜娜,袁万明,张艾奎,等.东昆仑祁漫塔格晚志留-早泥盆世花岗岩:年代学、地球化学及其形成环境[J].地质评论,2014,60(1):201-215.

    Google Scholar

    HAO Nana,YUAN Wanming,ZHANG Aikui.Late Silurian to Early Devonian Granitoids in the Qimantage Area,East Kunlun Mountain:LA-ICP-MS zircon U-Pb Ages,Geochemical Features and Geological Setting[J]. Geological Review,2014,60(1):201-215.

    Google Scholar

    刘彬,马昌前,郭盼,等.东昆仑中泥盆世A型花岗岩的确定及其构造意义[J].地球科学-中国地质大学学报,2013,38(5):947-962.

    Google Scholar

    LIU Bin,MA Changqian,GUO Pan,et al.Discovery of the Middle Devonian A-type granite from the Eastren Kunlun orogen and its tectonic implications[J].Chinese Journal of Geology-Journal of China University of Geosciences,2013,38(5):947-962.

    Google Scholar

    罗照华,柯珊,曹永清,等.东昆仑印支晚期幔源岩浆活动[J].地质通报,2002,21(6):292-297.

    Google Scholar

    LUO Zhaohua,KE Shan,CAO Yongqing,et al.Late indosinian mantle-derived magmatism in the East Kunlun[J]. Geological Bulletin of China,2002,21(6):292-297.

    Google Scholar

    李荣社,计文化,杨永成.昆仑山及邻区地质[M].北京:地质出版社, 2008.

    Google Scholar

    LI Rongshe,JI Wenhua,YANG Yongcheng.Geology of Kunlun Mountain and its adjacent areas[M].BeiJing:Geological Publishing House,2008.

    Google Scholar

    李世金,孙丰月,高永旺,等.小岩体成大矿理论指导与实践-青海东昆仑夏日哈木铜镍矿找矿突破的启示及意义[J].西北地质, 2012;45(4):185-191.

    Google Scholar

    LI Shijin,SUN Fengyue,GAO Yongwang,et al.The theoretical guidance and the practice of small intrusions forming large deposits-The enlightenment and significance for searching breakthrough of Cu Ni sulfide deposit in Xiarihamu, East Kunlun, Qinghai[J]. Northwestern Geology, 2012;45(4):185-191.

    Google Scholar

    李国成,丰成友,王瑞江,等.新疆白干湖钨锡矿矿田东北部花岗岩锆石SIMP U-Pb年龄、地球化学特征及构造意义[J].地球学报,2012,33(2):216-226.

    Google Scholar

    LI Guocheng,FENG Chengyou,WANG Ruijiang,et al.,SIMS Zircon U-Pb Age,Petrochemistry and Tectonic Implication of Granitoids in Northeastern Baiganhue W-Sn Orefield, Xinjiang[J].Acta Geoscientica Sinica,2012,33(2):216-226.

    Google Scholar

    孟繁聪,贾丽辉,任玉峰,等.东昆仑东段温泉地区片麻岩记录的岩浆和变质事件:锆石U-Pb年代学证据[J].岩石学报,2017,33(12):3691-3709.

    Google Scholar

    MENG Fancong,JIA Lihui,REN Yufeng,et al.Magmatic and metamorphic events recorded in the gneisses of the Wenquan region, East Kunlun Mountains, Northwest China:Evidence from the zircon U-Pb geochronology[J].Acta Petrologica Sinica,2017,33(12):3691-3709.

    Google Scholar

    青海省第五地质矿产勘查院.青海省格尔木市夏日哈木铜镍矿区HS26号异常区详查报告[R]. 2014, 1-189.

    Google Scholar

    中华人民共和国国家标准.电子探针和扫描电镜X射线能谱定量分析通则[S].

    Google Scholar

    潘彤,李善平,赵呈祥,等.东昆仑地区夏日哈木铜镍矿床成矿模式及找矿方[J].地质通报,2017,36(07):1276-1287.

    Google Scholar

    PAN Tong,LI Shanping,ZHAO Chengxiang,et al. Metallogenic model and prospecting direction of the Xiarihamu Ni-Cu sulfide deposit in East Kunlun area[J]. Geological Bulletin of China,2017,36(07):1276-1287.

    Google Scholar

    秦克章,丁奎首,许英霞,等.东天山图拉尔根、白石泉铜镍钴矿床钴、镍赋存状态及原岩含矿性研究[J].矿床地质,2007,(01):1-14.

    Google Scholar

    QIN Kezhang,DING Kuishou,XU Yingxia,et al.Ore potential of protoliths and modes of Co-Ni occurrence in Tulargen and Baishiquan Cu-Ni-Co deposits,East Tianshan,Xinjiang[J].Mineral Deposits,2007,(01):1-14.

    Google Scholar

    钱兵,张照伟,张志炳,等.柴达木盆地西北缘牛鼻子梁镁铁-超镁铁质岩体年代学及其地质意义[J].中国地质,2015,42(3):482-493.

    Google Scholar

    QIAN Bing,ZHANG Zhaowei,ZHANG Zhibing,et al. Zircon U-Pb geochronology of Niubiziliang mafic-ultramafic intrusion on the northwest margin of Qaidam Basin,Qinghai[J].Geology in China,2015,42(3):482-493.

    Google Scholar

    宋谢炎,胡瑞忠,陈列锰.铜、镍、铂族元素地球化学性质及其在幔源岩浆起源、演化和岩浆硫化物矿床研究中的意义[J].地学前缘,2009,16(4):287-305.

    Google Scholar

    SONG Xieyan,HU Ruizhong,CHEN Liemeng.Geochemical properties of Ni,Cu,PGE and its significance for mantle magma origin,evolution and magmatic sulfide deposits research[J].Earth Science Frontiers,2009,16(4):287-305.

    Google Scholar

    宋谢炎, 易俊年, 陈列锰, 等. 东昆仑夏日哈木超大型铜镍钴矿床Ni/Cu比值的地质意义[J]. 矿物学报, 2015,35(S1):431.

    Google Scholar

    SONG Xieyan,YI Junnian,CHEN Liemeng,et al.The geological significance of Ni/Cu ratio in Xirihamu superlarge Cu Ni Co deposit, East Kunlun[J].Acta Mineralogica Sinica,2015,35(S1):431.

    Google Scholar

    汤中立,李文渊.金川铜镍硫化物(含铂)矿床成矿模式及地质对比[M].北京:地质出版社,1994,78-82.

    Google Scholar

    TANG Zhongli,LI Wenyuan.Metallogenic model and geological correlation of Jinchuan copper nickel sulfide (containing platinum) deposit[M].BeiJing:Geological Publishing House,1994,78-82.

    Google Scholar

    唐娜娜, 莫伟, 马少健. 钴矿资源及其选矿研究进展[J].有色矿冶, 2006, (S1):5-7.

    Google Scholar

    TANG Nana,MO Wei,MA Shaojian.The research progress of cobalt resources and itsbeneficiation[J].Non-Ferrous Mining and Metallurgy,2006,(S1):5-7.

    Google Scholar

    王冠,孙丰月,李碧乐,等.东昆仑夏日哈木铜镍矿镁铁质-超镁铁质岩体岩相学、锆石U-Pb年代学、地球化学及其构造意义[J].地学前缘, 2014a, 21(6):381-401.

    Google Scholar

    WANG Guan,SUN Fengyue,LI Biyue,et al.Petrography, zircon U-Pb geochronology and geochemistry of the mafic-ultramafic intrusion in Xiarihamu Cu-Ni deposit from East Kunlun, with implications for geodynamic setting[J].Earth Science Frontiers,2014a, 21(6):381-401.

    Google Scholar

    王小东,张铭杰,伏珏蓉,等.稀有气体同位素对岩浆侵入方向的制约:以夏日哈木镍铜硫化物矿床为例[J].岩石学报,2018,34(11):3433-3444.

    Google Scholar

    WANG Xiaodong,ZHANG Mingjie,FU Yuerong, et al.,The magmatic intrusive direction constrains from noble gas isotopic compositions:A case study of the Xiarihamu Ni-Cu sulfide deposit in East Kunlun orogenic belt, China[J].Acta Petrologica Sinica.2018,34(11):3433-3444.

    Google Scholar

    郗爱华,任洪茂,张宝福,等.吉林省红旗岭铜镍硫化物矿床矿石学特征[J].吉林大学学报(地球科学版),2004,(03):338-343.

    Google Scholar

    XI Aihua,REN Hongmao,ZHANG Baofu,et al. Characteristics on ore minerals in Hongqiling CuNi sulfide deposit, Jilin Province[J].Journal of Jilin University:Earth Science, 2004,(03):338-343.

    Google Scholar

    校培喜, 高晓峰, 胡云绪,等.阿尔金-东昆仑西段成矿带地质背景研究[M].北京:地质出版社, 2014,1-261.

    Google Scholar

    XIAO, P., GAO, X., HU, Y., et al. Study on the geological background of the metallogenic belt in the western section of the Altun-East Kunlun Mountains[M]. Beijing:Geological Publishing House, 2014,1-261.

    Google Scholar

    张玉,裴先治,李瑞保,等.东昆仑东段阿拉思木辉长岩锆石U-Pb年代学、地球化学特征及洋盆闭合时限界定[J].中国地质,2017,44(3):526-540.

    Google Scholar

    ZHANG Yu,PEI Xianzhi,LI Ruibao,et al.Zircon U-Pb geochronology,geochemistry of the Alasimu gabbro in eastern section of East Kunlun Mountains and the closing time of Paleo-ocean basin[J].Geology in China,2017,44(3):526-540.

    Google Scholar

    张照伟,钱兵,王亚磊,等.青海省夏日哈木铜镍矿床岩石地球化学特征及其意义[J].西北地质,2016,49(2):45-58.

    Google Scholar

    ZHANG Zhaowei,QIAN Bing,WANG Yalei, et al. Petrogeochemical characteristics of Xiarihamu magmatic Ni-Cu sulfide deposit in Qinghai province and its study for olivine[J].Northwestern Geology,2016,49(2):45-58.

    Google Scholar

    张照伟,王亚磊,钱兵,等.东昆仑冰沟南铜镍矿石锆石SHRIMP U-Pb年龄及构造意义[J].地质学报,2017,91(4):724-735.

    Google Scholar

    ZHANG Zhaowei,WANG Yalei,QIAN Bing,et al.Zircon SHRIMP U-Pb Age of the Binggonan Magmatic Ni-Cu Deposit in East Kunlun Mountains and Its Tectonic Implications[J].Acta Geologica Sinica,2017,91(4):724-735.

    Google Scholar

    张照伟,李文渊,钱兵,等.东昆仑夏日哈木岩浆铜镍硫化物矿床成矿时代的厘定及其找矿意义[J].中国地质,2015,42(03):438-451.

    Google Scholar

    ZHANG Zhaowei, LI Wenyuan, QIAN Bing, et al. Metallogenic epoch of the Xiarihamu magmatic Ni-Cu sulfide deposit in eastern Kunlun orogenic belt and its prospecting significance[J].Geology in China,2015,42(03):438-451.

    Google Scholar

    张照伟,王驰源,刘超,等.东昆仑夏日哈木矿区岩体含矿性特点与形成机理探讨[J].西北地质,2019,52(03):35-45.

    Google Scholar

    ZHANG Zhaowei,WANG Chiyuan,LIU Chao,et al. Mineraliztion characteristics and formation mechanism of the intrusions in Xiarihamu magmatic Ni-Cu sulfide deposit,East Kunlun Orogenic Belt,Northwest China[J]. Northwestern Geology, 2019,52(03):35-45.

    Google Scholar

    张照伟,王驰源,钱兵,等.东昆仑志留纪辉长岩地球化学特征及与铜镍成矿关系探讨[J].岩石学报,2018,34(08):2262-2274.

    Google Scholar

    ZHANG Zhaowei,WANG Chiyuan,QIAN Bing,et al.The geochemistry characteristics of Silurian gabbro in East Kunlun Orogenic Belt and its mineralization relationship with magmatic Ni-Cu sulfide deposit[J].Acta Petrologica Sinica.2018,34(08):2262-2274.

    Google Scholar

    张照伟, 钱兵, 王亚磊. 东昆仑夏日哈木铜镍矿床Re-Os同位素和PGE地球化学特征及对成矿作用的指示[J]. 矿床地质, 2014,(S1):651-652.

    Google Scholar

    ZHANG Zhaowei,QIAN Bian,WANG Yalei.The Re-Os isotopic and PGE geochemicalcharacteristics of Xiaxiahamu Co-Ni deposit in the East Kunlun and their implications for mineralization[J]. Mineral Deposits,2014,(S1):651-652.

    Google Scholar

    张志炳.东昆仑夏日哈木铜镍硫化物矿床矿物成因意义探讨[D].北京:中国地质大学(北京),2016.

    Google Scholar

    ZHANG Zhibing.Genetic significances from Mineralogy of Xiarihamu Ni-Cu sulfide deposit, Eastern Kunlun orogentic belt[D].Beijing:China University of Geosciences,Beijing,2016.

    Google Scholar

    张术根,石得凤,韩世礼,等.福建丁家山铅锌矿区磁黄铁矿成因矿物学特征研究[J].矿物岩石,2011.31(3):11-17.

    Google Scholar

    ZHANG Shugen,SHI Defeng,HAN Shili, et al. Genetic Mineralogical study of pyrrhotite in the Dingjiashan Pn-Zn ore district,Fujian province[J].Journal of Mineralogy and Petrology, 2011, 31(3):11-17.

    Google Scholar

    孔会磊,李金超,国显正,等.青海东昆仑希望沟铜镍矿点发现早泥盆世辉橄岩[J].中国地质,2019,46(1):205-206.

    Google Scholar

    KONG Huilei, LI Jinchao, GUO Xianzheng,et al. The discovery of Early Devonian pyroxene peridotite from the Xiwanggou magmatic Ni-Cu sulfide ore spot in East Kunlun Mountains[J]. Geology in China, 2019, 46(1):205-206(in Chinese with English abstract).

    Google Scholar

    ARNOLD.R.G.,Range in composition and structure of 82 natural terrestrial pyrrhotites[J]. Can. Mineral,1967,9:31-50.

    Google Scholar

    BIAN Q T,LI D H,Psopelov I, et al.,Age,geochemistry and tectonic setting of the Buqingshan ophiolites,North Qinghai-Tibet Plateau,China[J].Journal of Asian Earth Sciences, 2004, 23(4):577-596.

    Google Scholar

    CARPENTER.R.H.& Desborough.G.A.,Range in soild solution and structure of naturally occuring troilite and pyrrhotite.Am.Mineral.,1964,49.1350-65.\Graig,J.R.5 Kullerud,G.Phaserelation in the Cu-Fe-Ni-S system and their application to magmatic ore deposits[J]. Econ. Geol. Mon., 1969,4:344-358.

    Google Scholar

    CHEN, J., XIE, Z.Y., LI, B., et al. Petrogenesis of Devonian intrusive rocks in Lalingzaohuo area, Eastern Kunlun, and its geological significance[J]. Journal of Mineralogy & Petrology, 2013,33(3):26-34.

    Google Scholar

    KANEDAH,Takenouchi S,Shoji T.Stability of pentlandite in Fe-Ni-Co-S system[J].Mineralium Deposita,1986,21(3):169-180.

    Google Scholar

    LI C S,ZHANG Z W,LI W Y, et al. Geochronology,petrology and Hf-S isotope geochemistry of the newly-discovered Xiarihamu magmatic Ni-Cu sulfide deposit in the Qinghai-Tibet plateau,western China[J].Lithos,2015,216-217;224-240.

    Google Scholar

    LIU, B., MA, C.Q., PAN, G., et al.Discovery of the Middle Devonian A-type Granite from the Eastern Kunlun Orogen and Its Tectonic Implications[J].Earth Science (Journal of China University of Geosciences),2013,38(5):947-962.

    Google Scholar

    LIU, Y.G., CHEN, Z.G., LI, W.Y., et al. The Cu-Ni mineralization potential of the Kaimuqi mafic-ultramafic complex and the indicators for the magmatic Cu-Ni sulfide deposit exploration in the East Kunlun Orogenic Belt, Northern Qinghai-Tibet Plateau, China[J]. Journal of Geochemical Exploration, 2019,198:41-53.

    Google Scholar

    LIU, Y.G., LI, W.Y., JIA, Q.Z., et al.The Dynamic Sulfide Saturation Process and a Possible Slab Break-off Model for the Giant Xiarihamu Magmatic Nickel Ore Deposit in the East Kunlun Orogenic Belt, Northern Qinghai-Tibet Plateau, China[J]. Economic Geology,2018, 113(6):1383-1417.

    Google Scholar

    LUO, Z.H., KE, S., CAO, Y.Q., et al.Late Indosinian mantle-derived magmatism in the East Kunlun[J]. Geological Bulletin of China,2002, 21(6):292-297.

    Google Scholar

    MENGASON M J,PICCOLI P M, CANDELA P.An evaluation of the effect of copper on the estimation of sulfur fugacity (f(S2)) from pyrrhotite composition[J]. Econ.Geol.,2010,105:1163-1169.

    Google Scholar

    MENG F G,CUI M H,WU X K,et al.Heishan mafic-ultramafic rocks in the Qimantage area of Eastern Kunlun,NW China:Remnants of an early Paleozoic incipient island arc[J].Gondwants Research,2015,27:745-759.

    Google Scholar

    MENG F C,ZHANG J X,CUI M H.Discovery of Early Paleozoic eclogite from the East Kunlun,Western China and its tectonic significance[J].Gondawana Research, 2013,23(2):825-836.

    Google Scholar

    PENG B, SUN FY, LI BL,et al.The geochemistry and geochronology of the Xiarihamu II mafic-ultramafic complex, Eastern Kunlun, Qinghai Province, China:Implications for the genesis of magmatic Ni-Cu sulfide deposits[J].Ore Geology Reviews, 2016,73:13-28.

    Google Scholar

    SONG XY,YI JN,CHEN LM, et al.The giant Xiarihamu Ni-Co sulfide deposit in the East Kunlun orogenic belt,Northern Tibet Plateau China[J].Economic Geology,2016,111(1):29-55.

    Google Scholar

    SUGAKIA,Kitakaze A.High form of pentlandite and its thermal sta-bility[J].American Mineralogist, 1998,83(1-2):133-140.

    Google Scholar

    TOULMIN P and BARTON P B.A thermodynamic study of the pyrite and pyrrhotite[J].Geochimica et Cosmochimica Acta,1964,28:641-671.

    Google Scholar

    ZHANG Z W,LI W Y,GAO Y B,et al.Sulfide mineralization associated with arc magmatism in the Qilian Block,western China:zircon U-Pb age and Sr-Nd-Os-S isotope constraints from the Yulonggou and Yaqu gabbroic intrusions[J].Mineralium Deposite,2014,49(2):279-292.

    Google Scholar

    ZHANG Z W,TANG Q Y,LI C S,et al.Sr-Nd-Os isotopes and PGE geochemistry of the Xiarihamu magmatic sulfide deposit in the Qinghai-Tibet plateau, China[J]. Miner Deposita,2017, 52:51-68.

    Google Scholar

    ZHANG Zhaowei,WANG Yalei,WANG Chiyuan, et al. Mafic-ultramafic magma activity and copper-nickel sulfide metallogeny during Paleozoic in the Eastern Kunlun Orogenic Belt, Qinghai Province, China[J]. China Geology,2019,2(4):467-477.

    Google Scholar

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