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WANG Shiqi, YE Xiantao, ZHANG Chuanlin, SHI Xuefa. Characteristics of phosphatization and its effects on the geochemical compositions of basalts from the Mid-Pacific Mountains[J]. Marine Geology & Quaternary Geology, 2024, 44(1): 67-80. doi: 10.16562/j.cnki.0256-1492.2022111401
Citation: WANG Shiqi, YE Xiantao, ZHANG Chuanlin, SHI Xuefa. Characteristics of phosphatization and its effects on the geochemical compositions of basalts from the Mid-Pacific Mountains[J]. Marine Geology & Quaternary Geology, 2024, 44(1): 67-80. doi: 10.16562/j.cnki.0256-1492.2022111401
shu

Characteristics of phosphatization and its effects on the geochemical compositions of basalts from the Mid-Pacific Mountains

  • 1.

    College of Oceanography, Hohai University, Nanjing 210098, China

  • 2.

    First Institute of Oceanography, Ministry of Natural Resources, Qingdao 266061, China

More Information
Received Date:  14 November 2022
Revised Date:  18 January 2023
Accepted Date:  18 January 2023
Publish Date:  28 February 2024
    Abstract

  • Oceanic basalts are ideal samples in deciphering geodynamics, mantle heterogeneity, and magma origin and evolution. However, due to its long-term interaction with the surrounding seawater, it is easy to undergo alteration and secondary alteration. Phosphatization is one of the most common secondary alteration in oceanic basalts, which can affect the geochemical compositions of basalt and there is no effective method to eliminate it yet. Therefore, it is important to evaluate the effect of phosphatization on the geochemical compositions of basalt. The mapping of element distribution by energy spectrum surface scanning with energy dispersive spectrometer, and analyses of major and trace elements of the phosphatized basalts from the Mid-Pacific Mountains were conducted. The elemental mapping shows that the phosphatization occurred mainly around the vesicles and fissures of basalts. It metasomatized the early-formed carbonated matrix by which fine phosphate minerals were formed. Phosphatization would change the major elements and trace elements of basalt. For example, phosphatization could decrease the contents of MgO, CaO, Na2O and MnO, and increase the contents of K2O and Fe2O3T in the basalt. Meanwhile, it also affected the compatible elements (such as Cr, Co, Ni, etc.), large ion lithophile elements (Rb, Ba, Cs, etc.), and rare earth elements. It is noted that Al2O3, SiO2, and high field strength elements (Nb, Ta, Zr, Hf and Ti) of the basalts are nearly unaffected the the phosphatization.

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  • [1] White W M. Isotopes, DUPAL, LLSVPs, and Anekantavada [J]. Chemical Geology, 2015, 419: 10-28. doi: 10.1016/j.chemgeo.2015.09.026

    CrossRef Google Scholar

    [2] White W M, Hofmann A W. Sr and Nd isotope geochemistry of oceanic basalts and mantle evolution [J]. Nature, 1982, 296(5860): 821-825. doi: 10.1038/296821a0

    CrossRef Google Scholar

    [3] Zindler A, Hart S. Chemical geodynamics [J]. Annual Review of Earth and Planetary Sciences, 1986, 14: 493-571. doi: 10.1146/annurev.ea.14.050186.002425

    CrossRef Google Scholar

    [4] 卜文瑞, 石学法, 彭建堂, 等. 大洋岛屿玄武岩低温蚀变作用及其对大洋过渡金属循环的贡献[J]. 海洋学报, 2007, 29(5):55-68

    Google Scholar

    BU Wenrui, SHI Xuefa, PENG Jiantang, et al. Low-temperature alteration of oceanic island basalts and their contribution to transition metal cycle of the ocean [J]. Acta Oceanologica Sinica, 2007, 29(5): 55-68.

    Google Scholar

    [5] 卜文瑞, 李力, 朱爱美, 等. 海底蚀变玄武岩中次生组分去除实验研究[J]. 地球科学进展, 2012, 27(10):1167-1172

    Google Scholar

    BU Wenrui, LI Li, ZHU Aimei, et al. Leaching experiments of secondary components in altered submarine basalts [J]. Advances in Earth Science, 2012, 27(10): 1167-1172.

    Google Scholar

    [6] Guy C, Daux V, Schott J. Behaviour of rare earth elements during seawater/basalt interactions in the Mururoa Massif [J]. Chemical Geology, 1999, 158(1-2): 21-35. doi: 10.1016/S0009-2541(99)00019-4

    CrossRef Google Scholar

    [7] Alt J C, Teagle D A H. Hydrothermal alteration of upper oceanic crust formed at a fast-spreading ridge: mineral, chemical, and isotopic evidence from ODP Site 801 [J]. Chemical Geology, 2003, 201(3-4): 191-211. doi: 10.1016/S0009-2541(03)00201-8

    CrossRef Google Scholar

    [8] 陈建林, 马维林, 高水土, 等. 中太平洋结壳区海山燧石岩成因研究[J]. 海洋学报, 2003, 25(3):53-58

    Google Scholar

    CHEN Jianlin, MA Weilin, GAO Shuitu, et al. Genetic study on flint from the crust area of the central Pacific Ocean mountains [J]. Acta Oceanologica Sinica, 2003, 25(3): 53-58.

    Google Scholar

    [9] 陈建林, 马维林, 武光海, 等. 中太平洋海山富钴结壳与基岩关系的研究[J]. 海洋学报(中文版), 2004, 26(4):71-79

    Google Scholar

    CHEN Jianlin, MA Weilin, WU Guanghai, et al. Research on the relationships between cobalt-rich crusts and substrate rocks in the Mid-Pacific Mountains [J]. Acta Oceanologica Sinica, 2004, 26(4): 71-79.

    Google Scholar

    [10] 初凤友, 陈建林, 马维林, 等. 中太平洋海山玄武岩的岩石学特征与年代[J]. 海洋地质与第四纪地质, 2005, 25(4):55-59 doi: 10.16562/j.cnki.0256-1492.2005.04.010

    CrossRef Google Scholar

    CHU Fengyou, CHEN Jianlin, MA Weilin, et al. Petrologic characteristics and ages of basalt in Middle Pacific Mountains [J]. Marine Geology & Quaternary Geology, 2005, 25(4): 55-59. doi: 10.16562/j.cnki.0256-1492.2005.04.010

    CrossRef Google Scholar

    [11] Melson W G, Thompson G. Glassy abyssal basalts, Atlantic sea floor near St. Paul's Rocks: petrography and composition of secondary clay minerals [J]. Geological Society of America Bulletin, 1973, 84(2): 703-716. doi: 10.1130/0016-7606(1973)84<703:GABASF>2.0.CO;2

    CrossRef Google Scholar

    [12] Thompson G. A geochemical study of the low-temperature interaction of seawater and oceanic igneous rocks [J]. Transactions-American Geophysical Union, 1973, 54: 1015-1019.

    Google Scholar

    [13] 鄢全树, 张平阳, 石学法, 等. 海底熔岩风化作用及其地质意义[J]. 海洋科学进展, 2017, 35(3):369-381

    Google Scholar

    YAN Quanshu, ZHANG Pingyang, SHI Xuefa, et al. Weathering of seafloor lavas and its geological significance [J]. Advances in Marine Science, 2017, 35(3): 369-381.

    Google Scholar

    [14] Koppers A A P, Staudigel H, Pringle M S, et al. Short‐lived and discontinuous intraplate volcanism in the South Pacific: Hot spots or extensional volcanism? [J]. Geochemistry, Geophysics, Geosystems, 2003, 4(10): 1089.

    Google Scholar

    [15] Corliss J B. The origin of metal‐bearing submarine hydrothermal solutions [J]. Journal of Geophysical Research, 1971, 76(33): 8128-8138. doi: 10.1029/JC076i033p08128

    CrossRef Google Scholar

    [16] Hart S R. K, Rb, Cs contents and K/Rb, K/Cs ratios of fresh and altered submarine basalts [J]. Earth and Planetary Science Letters, 1969, 6(4): 295-303. doi: 10.1016/0012-821X(69)90171-X

    CrossRef Google Scholar

    [17] Thompson G. Metamorphic and hydrothermal processes: basalt-seawater interactions[M]//Floyd P A. Oceanic Basalts. Dordrecht: Springer, 1991: 148-173.

    Google Scholar

    [18] 刘晖, 卢正权, 梅燕雄, 等. 海洋磷块岩形成环境与资源分布[J]. 海洋地质与第四纪地质, 2014, 34(3):49-56

    Google Scholar

    LIU Hui, LU Zhengquan, MEI Yanxiong, et al. Depositional environment and world distribution of marine phosphorites [J]. Marine Geology & Quaternary Geology, 2014, 34(3): 49-56.

    Google Scholar

    [19] 王吉中. 磷酸盐化对中太平洋海山富钴结壳物质组分的影响[D]. 中国地质大学(北京)博士学位论文, 2005

    Google Scholar

    WANG Jizhong. Effects of phosphatization on composition of Co-rich crusts on central pacific seamounts[D]. Doctor Dissertation of China University of Geosciences (Beijing), 2005.

    Google Scholar

    [20] 李江山, 石学法, 刘季花, 等. 西太平洋富钴结壳中磷酸盐化的制约因素探讨[J]. 矿物学报, 2011, 31(S1):693-694 doi: 10.16461/j.cnki.1000-4734.2011.s1.465

    CrossRef Google Scholar

    LI Jiangshan, SHI Xuefa, LIU Jihua, et al. Restriction factors of phosphorylation in cobalt-rich crusts in the Western Pacific Ocean [J]. Acta Mineralogica Sinica, 2011, 31(S1): 693-694. doi: 10.16461/j.cnki.1000-4734.2011.s1.465

    CrossRef Google Scholar

    [21] 崔迎春, 石学法, 刘季花, 等. 磷酸盐化作用对富钴结壳元素相关性的影响[J]. 地质科技情报, 2008, 27(3):61-67

    Google Scholar

    CUI Yingchun, SHI Xuefa, LIU Jihua, et al. Effects of phosphatization on the elemental association of cobalt-rich crusts [J]. Bulletin of Geological Science and Technology, 2008, 27(3): 61-67.

    Google Scholar

    [22] 刘家岐, 兰晓东. 中太平洋莱恩海山富钴结壳元素地球化学特征及成因[J]. 海洋地质与第四纪地质, 2022, 42(2):81-91

    Google Scholar

    LIU Jiaqi, LAN Xiaodong. Element geochemistry and genesis of cobalt-rich crust on the Line Seamount of the Central Pacific [J]. Marine Geology & Quaternary Geology, 2022, 42(2): 81-91.

    Google Scholar

    [23] 任向文, 刘季花, 石学法, 等. 西太平洋Lamont海山中新世以来富钴结壳成矿环境的演化[J]. 海洋科学进展, 2006, 24(1):17-29

    Google Scholar

    REN Xiangwen, LIU Jihua, SHI Xuefa, et al. Evolution of ore-forming condition of Co-rich crusts from Lamont Guyot in the western Pacific since the Miocene [J]. Advances in Marine Science, 2006, 24(1): 17-29.

    Google Scholar

    [24] Hein J R, Koschinsk A, Bau M, et al. Cobalt-rich ferromanganese crusts in the Pacific[M]//Cronan D S. Handbook of Marine Mineral Deposits. Boca Raton: CRC Press, 2017: 239-279.

    Google Scholar

    [25] Ji L H, Liu G S, Huang Y P, et al. The distribution of iodine and effects of phosphatization on it in the ferromanganese crusts from the Mid-Pacific Ocean [J]. Acta Oceanologica Sinica, 2015, 34(8): 13-19. doi: 10.1007/s13131-015-0704-x

    CrossRef Google Scholar

    [26] Nishi K, Usui A, Nakasato Y, et al. Formation age of the dual structure and environmental change recorded in hydrogenetic ferromanganese crusts from Northwest and Central Pacific seamounts [J]. Ore Geology Reviews, 2017, 87: 62-70. doi: 10.1016/j.oregeorev.2016.09.004

    CrossRef Google Scholar

    [27] Jeong K S, Jung H S, Kang J K, et al. Formation of ferromanganese crusts on northwest intertropical Pacific seamounts: electron photomicrography and microprobe chemistry [J]. Marine Geology, 2000, 162(2-4): 541-559. doi: 10.1016/S0025-3227(99)00091-2

    CrossRef Google Scholar

    [28] 潘家华, 刘淑琴, Decarlo E. 大洋磷酸盐化作用对富钴结壳元素富集的影响[J]. 地球学报, 2002, 23(5):403-407

    Google Scholar

    PAN Jiahua, LIU Shuqin, Decarlo E. The effects of marine phospharization on element concentration of Cobalt-rich crusts [J]. Acta Geoscientia Sinica, 2002, 23(5): 403-407.

    Google Scholar

    [29] 武光海, 周怀阳, 凌洪飞, 等. 富钴结壳中的磷酸盐岩及其古环境指示意义[J]. 矿物学报, 2005, 25(1):39-44 doi: 10.16461/j.cnki.1000-4734.2005.01.007

    CrossRef Google Scholar

    WU Guanghai, ZHOU Huaiyang, LING Hongfei, et al. Phosphorites in Co-rich crusts and their palaeooceanographic singificance [J]. Acta Mineralogica Sinica, 2005, 25(1): 39-44. doi: 10.16461/j.cnki.1000-4734.2005.01.007

    CrossRef Google Scholar

    [30] 王洋, 方念乔. 多金属结壳生长间断期与磷酸盐化事件的关系[J]. 海洋学报, 2021, 43(1):102-109 doi: 10.12284/hyxb2021017

    CrossRef Google Scholar

    WANG Yang, FANG Nianqiao. The relationship between the growth discontinuity of polymetallic crusts and phosphatization events [J]. Acta Oceanologica Sinica, 2021, 43(1): 102-109. doi: 10.12284/hyxb2021017

    CrossRef Google Scholar

    [31] 朱佛宏. 太平洋海山玄武岩的磷酸盐化[J]. 海洋地质动态, 1988(7):9-10

    Google Scholar

    ZHU Fohong. Phosphatization of Pacific seamount basalts [J]. Marine Geology Frontiers, 1988(7): 9-10.

    Google Scholar

    [32] 朱克超. 麦哲伦海山区MA、MC、MD、ME、MF海山结壳基岩的岩石学[J]. 海洋地质与第四纪地质, 2002, 22(1):49-56 doi: 10.16562/j.cnki.0256-1492.2002.01.008

    CrossRef Google Scholar

    ZHU Kechao. Petrology of the substrate in seamounts MA, MC, MD, ME and MF from Magellan seamounts [J]. Marine Geology & Quaternary Geology, 2002, 22(1): 49-56. doi: 10.16562/j.cnki.0256-1492.2002.01.008

    CrossRef Google Scholar

    [33] 潘家华, 刘淑琴, 杨忆, 等. 太平洋水下海山磷酸盐的成因及形成环境[J]. 地球学报, 2004, 25(4):453-458

    Google Scholar

    PAN Jiahua, LIU Shuqin, YANG Yi, et al. The origin and formation environment of phosphates on submarine guyots of the Pacific ocean [J]. Acta Geoscientica Sinica, 2004, 25(4): 453-458.

    Google Scholar

    [34] 汪在聪, 李胜荣, 刘鑫, 等. 中太平洋WX海山富钴结壳磷酸盐矿物学研究及成因类型分析[J]. 岩石矿物学杂志, 2007, 26(5):441-448

    Google Scholar

    WANG Zaicong, LI Shengrong, LIU Xin, et al. A mineralogical study and genetic analysis of phosphate in Co-rich crusts from the Central Pacific WX seamount [J]. Acta Petrologica et Mineralogica, 2007, 26(5): 441-448.

    Google Scholar

    [35] Kellogg J N, Ogujiofor I J. Gravity field analysis of Sio Guyot: An isostatically compensated seamount in the Mid-Pacific Mountains [J]. Geo-Marine Letters, 1985, 5(2): 91-97. doi: 10.1007/BF02233933

    CrossRef Google Scholar

    [36] Nemoto K, Kroenke L W. Sio Guyot: a complex volcanic edifice in the western Mid-Pacific Mountains [J]. Geo-Marine Letters, 1985, 5(2): 83-89. doi: 10.1007/BF02233932

    CrossRef Google Scholar

    [37] Kroenke L W, Kellogg J N, Nemoto K. Mid-Pacific Mountains revisited [J]. Geo-Marine Letters, 1985, 5(2): 77-81. doi: 10.1007/BF02233931

    CrossRef Google Scholar

    [38] Wilson P A, Jenkyns H C, Elderfield H, et al. The paradox of drowned carbonate platforms and the origin of Cretaceous Pacific guyots [J]. Nature, 1998, 392(6679): 889-894. doi: 10.1038/31865

    CrossRef Google Scholar

    [39] Thiede J, Dean W E, Rea D K, et al. The geologic history of the Mid-Pacific Mountains in the central North Pacific Ocean; a synthesis of deep-sea drilling studies [J]. Initial Reports of the Deep Sea Drilling Project, 1981, 62: 1073-1120.

    Google Scholar

    [40] Hamilton E L. Sunken Islands of the Mid-Pacific Mountains[M]. New York: Geological Society of America, 1956.

    Google Scholar

    [41] Winterer E L, Metzler C V. Origin and subsidence of Guyots in Mid‐Pacific Mountains [J]. Journal of Geophysical Research:Solid Earth, 1984, 89(B12): 9969-9979. doi: 10.1029/JB089iB12p09969

    CrossRef Google Scholar

    [42] Larson R L, Chase C G. Late Mesozoic evolution of the western Pacific Ocean [J]. Geological Society of America Bulletin, 1972, 83(12): 3627-3644. doi: 10.1130/0016-7606(1972)83[3627:LMEOTW]2.0.CO;2

    CrossRef Google Scholar

    [43] Ozima M, Honda M, Saito K. 40Ar-39Ar ages of guyots in the western Pacific and discussion of their evolution [J]. Geophysical Journal of the Royal Astronomical Society, 1977, 51(2): 475-485. doi: 10.1111/j.1365-246X.1977.tb06930.x

    CrossRef Google Scholar

    [44] Pringle M S, Duncan R A. Radiometric ages of basaltic lavas recovered at Sites 865, 866, and 869: Northwest Pacific atolls and guyots[C]//Proceedings of the Ocean Drilling Program. Scientific results. 1995, 142: 277-283.

    Google Scholar

    [45] Winterer E L, Natland J H, Van Waasbergen R J, et al. Cretaceous guyots in the northwest Pacific: An overview of their geology and geophysics[M]//Pringle M S, Sager W W, Sliter W V, et al. The Mesozoic Pacific: Geology, Tectonics, and Volcanism. Washington: American Geophysical Union, 1993, 77: 307-334.

    Google Scholar

    [46] Larson R L, Moberly R, Lancelot Y. Initial Reports of the Deep Sea Drilling Project 32[M]. Washington: U. S. Government Printing Office, 1975.

    Google Scholar

    [47] Larson R L, Lancelot Y, Gardner J V. Magnetic, bathymetric, seismic reflection, and positioning data collected underway on Glomar Challenger, Leg 32[M]//Larson R L, Moberly R. Initial Reports of the Deep Sea Drilling Project 32. Washington: U. S. Government Printing Office, 1975: 393-427.

    Google Scholar

    [48] Baker P E, Castillo P R, Condliffe E. Petrology and geochemistry of igneous rocks from Allison and Resolution guyots, Sites 865 and 866: Northwest Pacific atolls and guyots[C]//Proceedings of the Ocean Drilling Program. Scientific Results. 1995, 142: 245-261.

    Google Scholar

    [49] 何欣, 孙国胜, 初凤友, 等. 中太平洋CA海山玄武岩中斜长石化学成分特征及地质意义[J]. 海洋学研究, 2017, 35(2):23-32

    Google Scholar

    HE Xin, SUN Guosheng, CHU Fengyou, et al. Chemical characteristics and geological implication of plagioclase in CA Seamount basalts from the Middle Pacific [J]. Journal of Marine Sciences, 2017, 35(2): 23-32.

    Google Scholar

    [50] Chen S S, Liu J Q. Geochemical characteristics and geological significance of Cretaceous phonotephrite from the Mid-Pacific Mountains [J]. Science China Earth Sciences, 2018, 61(6): 745-764. doi: 10.1007/s11430-017-9172-4

    CrossRef Google Scholar

    [51] 中国大洋矿产资源研究开发协会办公室. 中国大洋海底地理实体名录-2016[M]. 北京: 海洋出版社, 2016

    Google Scholar

    China Ocean Mineral Resources Research and Development Association Office. Chinese Gazetteer of Undersea Features on the International Seabed, 2016[M]. Beijing: China Ocean Press, 2016.

    Google Scholar

    [52] Li X H, Sun M, Wei G J, et al. Geochemical and Sm-Nd isotopic study of amphibolites in the Cathaysia Block, southeastern China: evidence for an extremely depleted mantle in the Paleoproterozoic [J]. Precambrian Research, 2000, 102(3-4): 251-262. doi: 10.1016/S0301-9268(00)00067-X

    CrossRef Google Scholar

    [53] Qi L, Hu J, Gregoire D C. Determination of trace elements in granites by inductively coupled plasma mass spectrometry [J]. Talanta, 2000, 51(3): 507-513. doi: 10.1016/S0039-9140(99)00318-5

    CrossRef Google Scholar

    [54] Gurenko A A, Hoernle K A, Hauff F, et al. Major, trace element and Nd–Sr–Pb–O–He–Ar isotope signatures of shield stage lavas from the central and western Canary Islands: insights into mantle and crustal processes [J]. Chemical Geology, 2006, 233(1-2): 75-112. doi: 10.1016/j.chemgeo.2006.02.016

    CrossRef Google Scholar

    [55] 苏蓉. 中太平洋CNW海山玄武岩岩石地球化学特征及对富钴结壳生长的影响[D]. 吉林大学硕士学位论文, 2015

    Google Scholar

    SU Rong. Geochemical characteristics of basalt and effect of cobalt-rich crusts growth in the Mid-Pacific CNW Seamount[D]. Master Dissertation of Jilin University, 2015.

    Google Scholar

    [56] 李超. 中太平洋CH海山玄武岩地球化学特征及富钴结壳成因[D]. 吉林大学硕士学位论文, 2013

    Google Scholar

    LI Chao. Geochemical characteristics of basalt and research on Co-rich crust formation in the Mid-Pacific CH Seamount[D]. Master Dissertation of Jilin University, 2013.

    Google Scholar

    [57] Sun S S, McDonough W F. Chemical and isotopic systematics of oceanic basalts: Implications for mantle composition and processes [J]. Geological Society, London, Special Publications, 1989, 42(1): 313-345. doi: 10.1144/GSL.SP.1989.042.01.19

    CrossRef Google Scholar

    [58] Boynton W V. Cosmochemistry of the rare earth elements: meteorite studies [J]. Developments in Geochemistry, 1984, 2: 63-114.

    Google Scholar

    [59] Wei X, Zhang Y, Shi X F, et al. Co-occurrence of HIMU and EM1 components in a single Magellan seamount: implications for the formation of west pacific seamount province [J]. Journal of Petrology, 2022, 63(4): egac022. doi: 10.1093/petrology/egac022

    CrossRef Google Scholar

    [60] 任向文. 西太平洋富钴结壳成矿系统[D]. 中国科学院研究生院博士学位论文, 2005

    Google Scholar

    REN Xiangwen. The metallogenic system of Co-rich manganese crusts in Western Pacific[D]. Doctor Dissertation of University of Chinese Academy of Sciences, 2005.

    Google Scholar

    [61] Bau M, Koschinsky A, Dulski P, et al. Comparison of the partitioning behaviours of yttrium, rare earth elements, and titanium between hydrogenetic marine ferromanganese crusts and seawater [J]. Geochimica et Cosmochimica Acta, 1996, 60(10): 1709-1725. doi: 10.1016/0016-7037(96)00063-4

    CrossRef Google Scholar

    [62] 刘佳辉, 曲扬, 李伟强, 等. 西太平洋铁锰结壳中两类不同成因磷酸盐的元素特征、形成机制及指示意义[J]. 海洋地质与第四纪地质, 2022, 42(2):36-45 doi: 10.16562/j.cnki.0256-1492.2021052701

    CrossRef Google Scholar

    LIU Jiahui, QU Yang, LI Weiqiang, et al. Elemental distribution pattern and forming mechanism of the two types of phosphates in ferromanganese crust in Western Pacific Ocean and their implications [J]. Marine Geology & Quaternary Geology, 2022, 42(2): 36-45. doi: 10.16562/j.cnki.0256-1492.2021052701

    CrossRef Google Scholar

    [63] Koschinsky A, Hein J R. Marine ferromanganese encrustations: archives of changing oceans [J]. Elements, 2017, 13(3): 177-182. doi: 10.2113/gselements.13.3.177

    CrossRef Google Scholar

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