Citation: | ZHANG Xiaohui, FENG Yuhuan, ZHANG Yong, MAITUOHUTI Abuduwayiti. Characterization of Yellow-Green Hetian Jade in Qiemo—Ruoqiang, Xinjiang[J]. Rock and Mineral Analysis, 2022, 41(4): 586-597. doi: 10.15898/j.cnki.11-2131/td.202111210180 |
The Hetian nephrite belt in Xinjiang is the largest nephrite ore belt in the world, with a length of about 1300km. In addition to white, gray, black and brown nephrite, the Qiemo—Ruoqiang zone, Xinjiang also produces a yellow-green nephrite. There are few studies on the color origin and characterization of this kind of Hetian nephrite, which affects the understanding of the color and genesis of this kind of Hetian nephrite.
To understand the color genesis, genetic types and formation age of the yellow-green nephrite in Qiemo—Ruoqiang deposit.
Electron probe microanalysis (EPMA), backscattered electron (BSE) image, X-ray fluorescencespectrometry (XRF), and high resolution inductively coupled plasma-mass spectrometry (HR-ICP-MS) were used to investigate mineral and chemical composition. The FeO content was determined by titration method to explore its color origin and genetic type, and the zircon U-Pb isotope dating by sensitive high-resolution ion microprobe (SHRIMP) was used to constrain its mineralization age.
Yellow-green nephrite in Qiemo—Ruoqiang was predominately composed of apatite, calcite, dolomite, diopside, epidote, sphene and zircon. The yellow-green nephrite whole rock had low total REE (∑REE=2.61-19.1μg/g) with obvious Eu negative anomaly (δEu < 0.05), LREE right dipping, and HREE flat pattern. According to the distribution pattern of rare earth and the content of Cr and Ni, it was inferred that it was a magnesia skarn type Hetian nephrite. Compared with other nephrite in the world, the average value of Fe3+/Fe2+ of the yellow-green nephrite in Qiemo—Ruoqiang (average=0.16) overlapped with nephrite in other regions. The ratio is slightly higher (0.07-0.26), while the content of Fe3+ and Fe2+ was not significantly different between the yellow-green nephrite and other color nephrite. The SHRIMP U-Pb dating of zircon in the yellow-green nephrite yielded ages of 461.7±6.1Ma (MSWD=1.6) and 498.1±4.6Ma (MSWD=1.16).
The color genesis of the yellow-green nephrite in Qiemo is probably related to the ratio of Fe3+/Fe2+, but not to the content of Fe3+ and Fe2+. The SHRIMP U-Pb dating results of zircon in yellow-green nephrite represent the formation age of the yellow-green nephrite. These new data provide geochronological constraints for the magmatism of Hetian nephrite belt and the tectonic evolution of the West Kunlun orogenic belt.
[1] | Gil G, Barnes J D, Boschi C, et al. Origin of serpentinite-related nephrite from Jordanów and adjacent areas (SW Poland) and its comparison with selected nephrite occurrences[J]. Geological Quarterly, 2015, 59(3): 457-472. |
[2] | Korybska-Sadło I, Gil G, Gunia P, et al. Raman and FTIR spectra of nephrites from the Złoty Stok and Jordanów Slski (the Sudetes and Fore-Sudetic Block, SW Poland)[J]. Journal of Molecular Structure, 2018, 1166: 40-47. doi: 10.1016/j.molstruc.2018.04.020 |
[3] | Grapes R H, Yun S T. Geochemistry of a New Zealand nephrite weathering rind[J]. New Zealand Journal of Geology and Geophysics, 2010, 53: 413-426. doi: 10.1080/00288306.2010.514929 |
[4] | Liu Y, Deng J, Shi G H, et al. Chemical zone of nephrite in Alamas, Xinjiang, China[J]. Resource Geology, 2010, 60: 249-259. doi: 10.1111/j.1751-3928.2010.00135.x |
[5] | Liu Y, Deng J, Shi G H, et al. Geochemistry and petrogenesis of placer nephrite from Hetian, Xinjiang, northwest China[J]. Ore Geology Reviews, 2011, 41: 122-132. doi: 10.1016/j.oregeorev.2011.07.004 |
[6] | Liu Y, Deng J, Shi G H, et al. Geochemistry and petrology of nephrite from Alamas, Xinjiang, NW China[J]. Journal of Asian Earth Sciences, 2011, 42: 440-451. doi: 10.1016/j.jseaes.2011.05.012 |
[7] | Liu Y, Zhang R, Abuduwayiti M, et al. SHRIMP U-Pb zircon ages, mineral compositions and geochemistry of placer nephrite in the Yurungkash and Karakash River deposits, West Kunlun, Xinjiang, northwest China: Implication for a Magnesium skarn[J]. Ore Geology Reviews, 2016, 72: 699-727. doi: 10.1016/j.oregeorev.2015.08.023 |
[8] | Liu Y, Zhang R, Zhang Z, et al. Mineral inclusions and SHRIMP U-Pb dating of zircons from the Alamas nephrite and granodiorite: Implications for the genesis of a magnesian skarn deposit[J]. Lithos, 2015, 212-215: 128-144. doi: 10.1016/j.lithos.2014.11.002 |
[9] | Liu X F, Gil G, Liu Y, et al. Timing of formation and cause of coloration of brown nephrite from the Tiantai Deposit, South Altyn Tagh, northwestern China[J]. Ore Geology Reviews, 2021, 131: 103972. doi: 10.1016/j.oregeorev.2020.103972 |
[10] | 刘喜锋, 刘琰, 李自静, 等. 新疆皮山镁质矽卡岩矿床(含糖玉)成因及锆石SHRIMP U-Pb定年[J]. 岩石矿物学杂志, 2017, 36(2): 259-273. Liu X F, Liu Y, Li Z J, et al. The genesis of Mg-skarn deposit (bearing brown nephrite) and its Ar-Ar dating of phlogopite and SHRIMP U-Pb dating of zircon, Pishan, Xinjiang[J]. Acta Petrologica et Mineralogica, 2017, 36(2): 259-273. |
[11] | 张勇, 魏华, 陆太进, 等. 新疆奥米夏和田玉矿床成因及锆石LA-ICP-MS定年研究[J]. 岩矿测试, 2018, 37(6): 695-704. Zhang Y, Wei H, Lu T J, et al. The genesis and LA-ICP-MS zircon ages of Omixia nephrite deposit, Xinjiang, China[J]. Rock and Mineral Analysis, 2018, 37(6): 695-704. |
[12] | 刘喜锋, 张红清, 刘琰, 等. 世界范围内代表性碧玉的矿物特征和成因研究[J]. 岩矿测试, 2018, 37(5): 479-489. Liu X F, Zhang H Q, Liu Y, et al. Mineralogical characteristics and genesis of green nephrite from the world[J]. Rock and Mineral Analysis, 2018, 37(5): 479-489. |
[13] | Gao K, Shi G H, Wang M L, et al. The Tashisayi nephrite deposit from South Altyn Tagh, Xinjiang, northwest China[J]. Geoscience Frontiers, 2019, 10(4): 1597-1612. doi: 10.1016/j.gsf.2018.10.008 |
[14] | Harlow G E, Sorensen S S. Jade (nephrite and jadeitite) and serpentinite: Metasomatic connections[J]. International Geology Review, 2005, 47: 113-146. doi: 10.2747/0020-6814.47.2.113 |
[15] | Burtseva M V, Ripp G S, Posokhov V F, et al. Nephrites of East Siberia: Geochemical features and problems of genesis[J]. Russian Geology & Geophysics, 2015, 56(3): 402-410. |
[16] | Adamo I, Bocchio R. Nephrite jade from Val Malenco, Italy: Review and update[J]. Gems & Gemology, 2013, 49(2): 98-106. |
[17] | 刘喜锋, 贾玉衡, 刘琰. 新疆若羌—且末戈壁料软玉的地球化学特征及成因类型研究[J]. 岩矿测试, 2019, 38(3): 316-325. Liu X F, Jia Y H, Liu Y. Geochemical characteristics and genetic types of Gobi nephrite in Ruoqiang—Qiemo, Xinjiang[J]. Rock and Mineral Analysis, 2019, 38(3): 316-325. |
[18] | Gao S, Bai F, Heide G. Mineralogy, geochemistry and petrogenesis of nephrite from Tieli, China[J]. Ore Geology Reviews, 2019, 107(5): 155. |
[19] | Bai F, Du J M, Li J J, et al. Mineralogy, geochemistry and petrogenesis of green nephrite from Dahua, Guangxi, southern China[J]. Ore Geology Reviews, 2020, 118: 103362. doi: 10.1016/j.oregeorev.2020.103362 |
[20] | Bai F, Li G, Lei J, et al. Mineralogy, geochemistry and petrogenesis of nephrite from Panshi, Jilin, northeast China[J]. Ore Geology Reviews, 2019, 115: 103171. doi: 10.1016/j.oregeorev.2019.103171 |
[21] | Siqin B, Qian R, Zhuo S, et al. Glow discharge mass spectrometry studies on nephrite minerals formed by different metallogenic mechanisms and geological environments[J]. International Journal of Mass Spectrometry, 2012, 309: 206-211. doi: 10.1016/j.ijms.2011.10.003 |
[22] | Kostov R I, Protochristov C, Stoyanov C, et al. Micro-PIXE geochemical fingerprinting of nephrite Neolithic artifacts from southwest Bulgaria[J]. Geoarchaeology, 2012, 27: 457-469. doi: 10.1002/gea.21417 |
Pictures of hand specimens of the yellow-green nephrite from Qiemo—Ruoqiang area, Xinjiang
Cross-polarized light microscope photographs of the yellow-green nephrite from Qiemo—Ruoqiang area
Backscattered electron (BSE) images of the yellow-green nephrite from Qiemo—Ruoqiang area
(a) Chondrite-normalized REE patterns of the yellow-green nephrite from Qiemo—Ruoqiang area; (b) Primitive mantle-normalized trace element diagrams for the yellow-green nephrite from Qiemo—Ruoqiang area. Normalizing values of rare earth and trace elements are after Sun and McDonough (1989)
Cathodoluminescence images of zircon grains in the yellow-green nephrite from Qiemo—Ruoqiang area
Two SHRIMP U-Pb concordia age diagrams (a and b) of zircon in the yellow-green nephrite of sample QM20-8 from Qiemo—Ruoqiang area