Professional Committee of Rock and Mineral Testing Technology of the Geological Society of China, National Geological Experiment and Testing CenterHost
2019 Vol. 38, No. 2
Article Contents

Jiang-hong GE, Ying-kai WANG, Xu ZHANG, Yan-mei GE. Phase State Analysis Method and Application of Molybdenum in Soil Samples of Special Landscape Exploration in Heilongjiang Province[J]. Rock and Mineral Analysis, 2019, 38(2): 222-227. doi: 10.15898/j.cnki.11-2131/td.201611100206
Citation: Jiang-hong GE, Ying-kai WANG, Xu ZHANG, Yan-mei GE. Phase State Analysis Method and Application of Molybdenum in Soil Samples of Special Landscape Exploration in Heilongjiang Province[J]. Rock and Mineral Analysis, 2019, 38(2): 222-227. doi: 10.15898/j.cnki.11-2131/td.201611100206

Phase State Analysis Method and Application of Molybdenum in Soil Samples of Special Landscape Exploration in Heilongjiang Province

  • BACKGROUNDOver the years, the total anomaly analysis results of geochemical exploration have found that there are not many deposits. Under the conditions of epigenetic conditions, different elements have different migration and deposition laws and primitive occurrence states. The geochemical analysis gives the full analysis of the elements cannot accurately reflect the mineralization anomalies situation. Therefore, the existence form and existence state of the elements are crucial for judging whether it is a metallogenic anomaly. OBJECTIVESThis paper establishes the phase analysis method of molybdenum in geochemical soil samples from the characteristics of Heilongjiang geological landscape. METHODSThe phase states of molybdenum are divided into five phases:water extraction phase, weak organic binding phase, oxide binding phase, Fe-binding phase, and residue phase. The detection limits of molybdenum phases determined by ICP-MS are:water extraction phase 0.0011μg/g, weak organic binding phase 0.020μg/g, oxide binding phase 0.100μg/g, Fe-binding phase 0.100μg/g, the residue phase is 0.100μg/g. RESULTSThe method was used to analyze the samples with molybdenum anomaly in a certain part of Heilongjiang Province. The results showed that molybdenum was mainly composed of Fe-binding phase, which belonged to the vein type and conformed to one of the types of molybdenum deposits. CONCLUSIONSThe method improves the accuracy of prospecting using geochemical anomalies.
  • 加载中
  • [1] 刘崇民, 胡树起, 马声明, 等.成矿元素相态对地球化学异常的作用[J].物探与化探, 2013, 37(6):1049-1055.

    Google Scholar

    Liu C M, Hu S Q, Ma S M, et al.Phase behavior of geochemical anomaly of ore-forming elements[J].Geophysics and Geochemistry, 2013, 37(6):1049-1055.

    Google Scholar

    [2] 龚美菱.相态分析与地质找矿(第一版)[M].北京:地质出版社, 1994.

    Google Scholar

    Gong M L.Phase Analysis and Geological Prospecting (First Edition)[M].Beijing:Geological Publishing House, 1994.

    Google Scholar

    [3] 迟永坤, 张鹰.相态研究在化探异常评价中的应用[J].地质与资源, 2003, 12(1):48-53. doi: 10.3969/j.issn.1671-1947.2003.01.008

    CrossRef Google Scholar

    Chi Y K, Zhang Y.Application of phase state study in geochemical anomaly evaluation[J].Geology and Resources, 2003, 12(1):48-53. doi: 10.3969/j.issn.1671-1947.2003.01.008

    CrossRef Google Scholar

    [4] 周天泽.无机微量元素形态分析方法学简介[J].分析试验室, 1991, 10(3):44-50.

    Google Scholar

    Zhou T Z.Inorganic trace element morphology analysis methodology introduction[J].Chinese Journal of Analysis Laboratory, 1991, 10(3):44-50.

    Google Scholar

    [5] 王亚平, 黄毅, 王苏明, 等.土壤和水系沉积物中元素的化学形态及其顺序提取法[J].地质通报, 2005, 24(8):728-733. doi: 10.3969/j.issn.1671-2552.2005.08.009

    CrossRef Google Scholar

    Wang Y P, Huang Y, Wang S M, et al.Chemical morphology and sequential extraction of elements in soil and water sediments[J].Geological Bulletin of China, 2005, 24(8):728-733. doi: 10.3969/j.issn.1671-2552.2005.08.009

    CrossRef Google Scholar

    [6] 赵伟, 王玉林, 钟莅湘, 等.土壤样品中贵金属活动态提取技术[J].岩矿测试, 2016, 35(2):212-216.

    Google Scholar

    Zhao W, Wang Y L, Zhong L X, et al.Precious metal forms in soil sample extraction[J].Rock and Mineral Analysis, 2016, 35(2):212-216.

    Google Scholar

    [7] 刘红艳, 张瑞鹏, 刘淑芹, 等.金川铜镍矿区土壤多元素相态分析方法[J].实验室研究与探索, 2013, 32(9):28-33. doi: 10.3969/j.issn.1006-7167.2013.09.008

    CrossRef Google Scholar

    Liu H Y, Zhang R P, Liu S Q, et al.Method of phase analysis of soil elements in Jinchuan copper-nickel mine[J].Laboratory Research and Exploration, 2013, 32(9):28-33. doi: 10.3969/j.issn.1006-7167.2013.09.008

    CrossRef Google Scholar

    [8] 黄宝贵, 张志勇, 杨林, 等.中国化学物相分析研究的新成就(下)[J].中国无机分析化学, 2011, 1(3):8-15. doi: 10.3969/j.issn.2095-1035.2011.03.0002

    CrossRef Google Scholar

    Huang B G, Zhang Z Y, Yang L, et al.Achievements of study on chemical phase analysis in China (Ⅱ)[J].Chinese Journal of Inorganic Analytical Chemistry, 2011, 1(3):8-15. doi: 10.3969/j.issn.2095-1035.2011.03.0002

    CrossRef Google Scholar

    [9] 许俊蕾, 张晓娟, 邱海鸥, 等.铅锌矿中硫的相态分析[J].分析试验室, 2014, 33(4):404-407.

    Google Scholar

    Xu J L, Zhang X J, Qiu H O, et al.Phase state analysis of sulphur in lead and zinc mine[J].Analysis Laboratory, 2014, 33(4):404-407.

    Google Scholar

    [10] 刘文彧, 祁士江, 陆继龙, 等.甘肃阳山金矿安坝矿段土壤中金的相态分析[J].世界地理, 2014, 33(1):112-118.

    Google Scholar

    Liu W Y, Qi S J, Lu J L, et al.Phase analysis on Au in the soil of Anba ore block, Yangshan gold deposit, Gansu Province[J].World Geography, 2014, 33(1):112-118.

    Google Scholar

    [11] 胡一珠, 邓天龙, 胡志中, 等.土壤样品中汞的形态分析研究进展[J].广东微量元素科学, 2010, 17(11):19-21. doi: 10.3969/j.issn.1006-446X.2010.11.002

    CrossRef Google Scholar

    Hu Y Z, Deng T L, Hu Z Z, et al.Research progress on speciation analysis of mercury in soil samples[J].Guangdong Microelement Science, 2010, 17(11):19-21. doi: 10.3969/j.issn.1006-446X.2010.11.002

    CrossRef Google Scholar

  • 加载中
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Figures(1)

Tables(4)

Article Metrics

Article views(1957) PDF downloads(68) Cited by(0)

Access History

Other Articles By Authors

Catalog

    /

    DownLoad:  Full-Size Img  PowerPoint