Professional Committee of Rock and Mineral Testing Technology of the Geological Society of China, National Geological Experiment and Testing CenterHost
2016 Vol. 35, No. 6
Article Contents

Shi-tou WU, Ya-ping WANG, Xiu-chun ZHAN, Kronz Andreas, Simon Klaus, Chun-xue XU, Huan TIAN. Study on the Elemental Fractionation Effect of CGSG Reference Materials and the Related Within-Unit Homogeneity of Major and Trace Elements[J]. Rock and Mineral Analysis, 2016, 35(6): 612-620. doi: 10.15898/j.cnki.11-2131/td.2016.06.007
Citation: Shi-tou WU, Ya-ping WANG, Xiu-chun ZHAN, Kronz Andreas, Simon Klaus, Chun-xue XU, Huan TIAN. Study on the Elemental Fractionation Effect of CGSG Reference Materials and the Related Within-Unit Homogeneity of Major and Trace Elements[J]. Rock and Mineral Analysis, 2016, 35(6): 612-620. doi: 10.15898/j.cnki.11-2131/td.2016.06.007

Study on the Elemental Fractionation Effect of CGSG Reference Materials and the Related Within-Unit Homogeneity of Major and Trace Elements

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  • Studies on elemental fractionation and homogeneity of CGSG reference materials (CGSG-1, CGSG-2, CGSG-4 and CGSG-5) promote quality assessment and application. The elemental fractionation and within-unit homogeneity of CGSG reference materials were evaluated using Electron Microprobe and Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry (LA-ICP-MS). Meanwhile, the major and trace element contents were also reported. The results showed that the elemental fractionation of CGSG reference materials was negligible for 50 μm spot size. Electron Microprobe homogeneity index illustrated that the homogeneity of major elements in CGSG reference materials is approvingly acceptable, and most trace elements possess same homogeneity grade with MPI-DING reference materials. Analytical results of major elements by Electron Microprobe and LA-ICP-MS are consistent with published data within 2% and 5% errors, respectively. Analytical results of trace elements by LA-ICP-MS are generally in agreement with the published data. Some elements such as Cr, Ge, Cd, As and Tl show a larger deviation due to the large uncertainties of the analytical technique. In general, the analysis data reported here could supplement the CGSG value database.
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