Application of Specific Surface Area Nitrogen Adsorption Method to Characterize the Alkaline Dissolution of Montmorillonite

Zhen LIU; Xi-yu QU; Wei-qing WANG; Yong-chang LIN; Yuan GAO

doi:10.15898/j.cnki.11-2131/td.2016.06.006

2016 Vol. 35, No. 6

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Zhen LIU, Xi-yu QU, Wei-qing WANG, Yong-chang LIN, Yuan GAO. Application of Specific Surface Area Nitrogen Adsorption Method to Characterize the Alkaline Dissolution of Montmorillonite[J]. Rock and Mineral Analysis, 2016, 35(6): 603-611. doi: 10.15898/j.cnki.11-2131/td.2016.06.006

Citation:

Zhen LIU, Xi-yu QU, Wei-qing WANG, Yong-chang LIN, Yuan GAO. Application of Specific Surface Area Nitrogen Adsorption Method to Characterize the Alkaline Dissolution of Montmorillonite[J]. Rock and Mineral Analysis, 2016, 35(6): 603-611. doi: 10.15898/j.cnki.11-2131/td.2016.06.006

Application of Specific Surface Area Nitrogen Adsorption Method to Characterize the Alkaline Dissolution of Montmorillonite

1.
School of Geosciences, China University of Petroleum, Qingdao 266555, China
2.
Shengli Petroleum Exploration and Development Institute, Dongying 257015, China

More Information

Corresponding author: Xi-yu QU, quxiyu@upc.edu.cn

Received Date: 25 June 2016

Revised Date: 27 October 2016

Accepted Date: 08 November 2016

Abstract

Abstract

Montmorillonite is characterized by small particle size, large specific surface area and strong water sensitivity, which results in blocking the pore and throat of the reservoir and in turn affecting its quality. Dissolution characteristics of montmorillonite under alkaline conditions are common concerns in the development of oil fields. Mass contrast, X-ray Diffraction, solution concentration analysis and value analysis of pH methods are commonly used to characterize dissolution of montmorillonite. However, the quality comparison method is complex. Calculation of diffraction pattern by the X-ray Diffraction involves large manual operation errors. The ion concentration analysis method shows a large detection error for infusible elements. Value analysis of the pH method is influenced by temperature changes. The specific surface area, pore volume, pore diameter change, adsorption-desorption curve measured by nitrogen adsorption method was used to characterize the dissolution of montmorillonite under alkaline conditions and is reported in this paper. The experimental conditions were optimized, including the concentration of NaOH solution and filling time (reaction time). The best concentration of NaOH solution was 0.05 mol/L and the best reaction time was 3 h. Results show that the dissolved results of montmorillonite by the nitrogen adsorption method characterized by specific surface area, pore volume, pore diameter and adsorption desorption curve are consistent with the results by the change of the pH value and the concentration of the solution (such as Si⁴⁺). Therefore, the method is feasible and can be used to characterize the dissolution of minerals with multiple pores and large specific surface area.
- specific surface area-nitrogen adsorption method /
- specific surface area characteristics /
- pore size characteristics /
- dissolution characteristics /
- NaOH solution

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References

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