Citation: | TUO Biyang, DU Ruikang, GU Dianfa, WANG Jianli, NIE Guanghua, TANG Yun. Enhanced Flotation of Coal Slime with ST-diesel Microemulsion[J]. Conservation and Utilization of Mineral Resources, 2023, 43(4): 24-32. doi: 10.13779/j.cnki.issn1001-0076.2023.04.003 |
As a collector for coal slime flotation, diesel oil has poor dispersion and collection effect and large dosage. In order to improve the dispersion and collection performance of diesel oil. Two surfactants, Span80 and Tween80, are used to emulsify diesel collector for coal slime flotation. A new collector ST-diesel microemulsion with droplet size less than 100 nm is being prepared. The improvement effect of slime flotation index is studied by unit flotation test. The mechanism of microemulsion on the surface of coal slime is discussed by means of contact angle test, Zeta potential analysis, infrared spectrum analysis and EDLVO theoretical calculation. When ST-diesel microemulsion is used as coal slime collector, the flotation effect is better, and the recovery rate of combustible body can reach 68.13% which is 9.23 percent higher than diesel collector. The contact angle of pure coal surface increased by 17.3° after ST-diesel microemulsion treatment compared with diesel. The absolute value of surface Zeta potential decreases. The energy barrier of the total energy VT of the interaction between coal particles is reduced, which is beneficial to the agglomeration between particles. The physical adsorption of surfactant and oxygen-containing functional groups on the surface of coal slime improves the surface hydrophobicity of coal particles. The ST-diesel microemulsion can be used as a new and efficient collector for coal slime flotation.
[1] | 李琳, 刘炯天, 王运来, 等. 阴-非离子表面活性剂微乳捕收剂的制备及应用[J]. 煤炭学报, 2014, 39(11): 2315−2320. LI L, LIU J T, WANG Y L, et al. Preparation and application of anionic-nonionic surfactant microemulsified collector[J]. Journal of China Coal Society, 2014, 39(11): 2315−2320. |
[2] | Arriagada S, Acua C, Vera M. New technology to improve the recovery of fine particles in froth flotation based on using hydrophobized glass bubbles[J]. Minerals Engineering, 2020, 156. |
[3] | 陈奎, 宋璨奡, 曹曦, 等. 废轮胎热解制备煤泥浮选捕收剂的试验研究[J]. 煤炭科学技术, 2011, 39(2): 115−118. CHEN K, SONG C A, CAO X, et al. Experiment study on waste tyre pyrolysis to prepare collector of slime floatation[J]. Coal Science and Technology, 2011, 39(2): 115−118. |
[4] | 杨自立. 基于细泥絮凝的高灰细粒煤脱灰过程界面作用机制[D]. 徐州: 中国矿业大学, 2022. YANG Z L. Interface mechanism of high-ash coal slime deashing process based on fine mud flocculation[D]. Xuzhou: China University of Mining and Technology, 2022. |
[5] | XIA W, ZHOU C, PENG Y. Enhancing flotation cleaning of intruded coal dry-ground with heavy oil[J]. Journal of Cleaner Production, 2017, 161. |
[6] | ATESOK G, BOYLU F, CELIK M S. Carrier flotation for desulfurization and deashing of difficult-to-float coals[J]. Minerals Engineering, 2001(6): 14. |
[7] | 于跃先, 马力强, 张仲玲, 等. ZS乳化药剂对褐煤半焦浮选结果的影响及机理分析[J]. 煤炭科学技术, 2016, 44(3): 184−187. YU Y X, MA L Q, ZHANG Z L, et al. Analysis of emulsified ZS reagent effect on flotation results of lignite semi-coke and its mechanism[J]. Coal Science and Technology, 2016, 44(3): 184−187. |
[8] | WANG T, XIA W, LIANG L, et al. The coalescence of bubbles immersed in liquid and at the liquid–gas interface[J]. Minerals Engineering, 2019, 142: 105924. doi: 10.1016/j.mineng.2019.105924 |
[9] | 白娅娜, 朱书全, 解维伟, 等. 乳化柴油捕收剂的浮选试验研究[J]. 煤炭科学技术, 2009, 37(1): 117−121. BAI Y N, ZHU S Q, XIE W W, et al. Research on flotation test of emulsified diesel collector[J]. Coal Science and Technology, 2009, 37(1): 117−121. |
[10] | 任聪, 樊民强, 李志红, 等. 复配药剂浮选低阶煤泥的效能研究[J]. 煤炭科学技术, 2020, 48(S1): 242−247. REN C, FAN M Q, LI Z H, et al. Efficiency of compound reagents flotation of low-rank coal slime[J]. Coal Science and Technology, 2020, 48(S1): 242−247. |
[11] | 王驰, 崔广文. Gemini表面活性剂在地沟油制备微乳捕收剂中的应用[J]. 煤炭工程, 2019, 51(3): 130−135. WANG C, CUN G W. Application of gemini surfactant in preparation of micro-emulsion collector made from swill-cooked dirty oil[J]. Coal Engineering, 2019, 51(3): 130−135. |
[12] | 李志斌. 柴油乳化及其对浮选影响的研究[D]. 北京: 煤炭科学研究总院, 2017. LI Z B. Study on the emulsification of diesel oil and its effects on floation efficiency[D]. Beijing: Coal Research Institute, 2017. |
[13] | 张瑞英. 新型煤用捕收剂PCF捕收性能试验研究[J]. 煤炭科学技术, 2011, 39(6): 125−128. ZHANG R Y. Experiment study on capture performance of new coal capturer PCF[J]. Coal Science and Technology, 2011, 39(6): 125−128. |
[14] | CHANG Z, CHEN X, PENG Y. The interaction between diesel and surfactant Triton X-100 and their adsorption on coal surfaces with different degrees of oxidation[J]. Powder Technology, 2019, 342: 840−847. doi: 10.1016/j.powtec.2018.10.047 |
[15] | 李琳, 贺萌, 李晓腾, 等. 生物基微乳捕收剂的制备及其在煤泥浮选中的应用[J]. 中国矿业大学学报, 2022, 51(4): 779−790. LI L, HE M, LI X T, et al. Preparation of bio-based microemulsion collector and its application in coal slime flotation[J]. Journal of China University of Mining & Technology, 2022, 51(4): 779−790. |
[16] | 黄波, 徐宏祥, 李旭林. 微乳型捕收剂的稳定性和浮选性能的试验研究[J]. 煤炭学报, 2019, 44(9): 2878−2885. HUANG B, XUN H X, LI X L. Experimental study on stability and flotation performance of micro-emulsion collector[J]. Journal of China Coal Society, 2019, 44(9): 2878−2885. |
[17] | ZHAO X, TANG Y, ZHAO B, et al. Collecting behaviors of high internal phase (HIP) emulsion in flotation of ultrafine high-ash content coal slime[J]. International Journal of Coal Preparation and Utilization, 2022, 42(9). |
[18] | 赵学敏. 基于煤油与起泡剂的微乳液配制及其煤泥浮选效果研究[D]. 太原: 太原理工大学, 2017. ZHAO X M. Preparation of microemulsified collector based on kerosene and foaming agent and application in coal flotation[D], Taiyuan: Taiyuan University of Technology, 2017. |
[19] | 刘腾飞, 冯莉. 添加剂对乳化柴油捕收剂稳定性的影响[J]. 实验室研究与探索, 2012, 31(12): 19-23. LIU T F, FENG L. Effect of additives on the stability of emulsified diesel collector[J]. Research and Exploration in Laboratory, 2012, 31(12): 19-23. |
[20] | 史建平. WL浮选捕收剂的研制及应用[J]. 煤炭加工与综合利用, 2009(2): 17−21. SHI J P. Development and application of WL flotation collector[J]. Coal Processing & Comprehensive Utilization, 2009(2): 17−21. |
[21] | XIE W, CAO G, REN X, et al. Effect of flotation promoter on the rate of coal slime flotation[J]. Journal of Mining Scinece, 2014, 50(3). |
[22] | YOU X, LI L, LIU J, et al. Investigation of particle collection and flotation kinetics within the Jameson cell downcomer[J]. Powder Technology, 2017, 310. |
[23] | 解维伟. 煤乳化浮选药剂的制备与应用机理研究[D]. 北京: 中国矿业大学, 2009. XIE W W. Research on the preparation and application mechanism of the emulsified coal floatation agent[D]. Beijing: China University of Mining and Technology, 2009. |
Experimental results of small screening of coal samples
XRD spectrum of coal slime
Contact angle test results of pure coal (a) pure coal, (b) pure coal + diesel oil, (c) pure coal + ST microemulsion
Contact angle test results of slime (a) slime, (b) slime + diesel oil, (c) slime + ST microemulsion
Zeta potential analysis of pure coal
Infrared spectra of slime surface
Ternary phase diagram of ST microemulsion at HLB=6
The ternary phase diagram of ST microemulsion at HLB=7
Ternary phase diagram of ST microemulsion at HLB=8
The ternary phase diagram of ST microemulsion at HLB = 9
Drop size distribution
Changes of combustible recovery and ash content with collector dosage in flotation of coal slime with different collectors
Potential energy curve of interaction between coal particles