Citation: | LI Bowen, YANG Heng, CHENG Shaoyi, GAO Zhiyong, CAO Jian. Research on the Flotation Reagent Regime of Jinchuan Copper-Nickel Sulfide Ore in Acidic Medium[J]. Conservation and Utilization of Mineral Resources, 2022, 42(2): 25-32. doi: 10.13779/j.cnki.issn1001-0076.2022.07.002 |
The content of magnesium silicate gangue minerals in Jinchuan sulfide copper-nickel ore is high. It affects the enrichment of nickel and copper in concentrates through heterogeneous condensation and mechanical entrainment after grinding. Related researches and foreign industrial practices have proved that acidic medium flotation can promote the decomposition of magnesium silicate gangue minerals, which significantly improved the recovery of useful minerals in copper-nickel sulfide ore and reduced the content of magnesium oxide in concentrates. At present, however, there are few researches on the suitable reagent system for the acidic medium flotation of sulfide minerals in China. To solve this issue, feed of the second stage processing production line of the third flotation plant of Jinchuan Group Co. (Ni and Cu grade of ore was 0.42% and 0.32% respectively) was regarded as the research object. The open circuit flotation tests studied the new reagent system suitable for the acid medium, and compared and analyzed the performance of different frothers by using the foam tester. Under acid flotation condition (pH value = 4), with sodium isobutyl xanthanate (NaIBX) as the collector, O-isopropyl-N-ethylthiocarbamate (Z-200) as the co-collector and terpineol as the frother, after one roughing, two cleaning and two scavenging, the recovery of Ni and Cu are 58.92%, 45.60% and the grade of Ni and Cu are 3.54%, 2.03% respectively. Compared with comparative system (according with industrial process), the recovery of Ni and Cu are increased by 7.54%, 24.40% and the grade of Cu is increased by 0.70%. The new reagent system significantly improved the comprehensive utilization rate of copper-nickel sulfide resources in Jinchuan.
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Illustration of the foam tester
Flowsheet of open circuit tests (grey part had already been completed in the third flotation plant)
Flowsheet of close circuit tests (grey part had already been conducted in the third flotation plant)
Maximum foam volumes of different frothers as a function of frother concentrations (at pH value of 4)
Gas-liquid ratios as a function of frother concentrations
Effect of the different pH values of rougher pulp slurry on metal grade and recovery of flotation concentrates in comparative system
Effect of collectors on metal grade and recovery under different conditions (entry 1 is comparative system carried out at normal pH value of 9.8; entry 2 is comparative system carried out at pH value of 4; based on entry 2, 80 g/t the industrial mixed collector was replaced with 100 g/t NaIBX in entry 3; based on entry 3, 42 g/t ADD was replaced with 15.1 g/t MIBC in entry 4; based on entry 4, additional 12.7 g/t PNX was added in entry 5)
Effect of NaIBX dosage on metal grade and recovery (the NaIBX dosage was 50 g/t, 75 g/t, 100 g/t, 125 g/t, respectively; and the NaIBX dosage for scavenger flotation was 40% of that in corresponding rougher flotation)
Efects of different frothers on metal grade and recovery (two drops of TPGBE, MIBC and Terp were added to each flotation test, respectively, and the dosage of three frothers was 18.9 g/t, 15.1 g/t, 13.4 g/t, respectively)
Effect of Terp dosage on metal grade and recovery (Tosage of Terp was 6.7 g/t, 13.4 g/t, 20.1 g/t, 26.8 g/t, respectively)
Effects of different co-collectors on metal grade and recovery (The dosage of Z-200, EET, EPT, LJX-1, PPX and PNX was 12.7 g/t, 11.4 g/t, 17.1 g/t, 15.6 g/t, 13.1 g/t and 12.7 g/t, respectively)
Effect of Z-200 dosage on metal grade and recovery (The dosage of Z-200 was 6.4 g/t, 12.7 g/t, 19.1 g/t, 25.4 g/t, 31.8 g/t, respectively)