Zhengzhou Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological SciencesHost
2022 Vol. 42, No. 2
Article Contents

XU Yongqiang, ZHANG Zhenxing, BAI Xuejie, SHI Jilan, WANG Haifeng. Research Progress on Purification and Material Preparation of Magnesite[J]. Conservation and Utilization of Mineral Resources, 2022, 42(2): 107-113. doi: 10.13779/j.cnki.issn1001-0076.2022.02.014
Citation: XU Yongqiang, ZHANG Zhenxing, BAI Xuejie, SHI Jilan, WANG Haifeng. Research Progress on Purification and Material Preparation of Magnesite[J]. Conservation and Utilization of Mineral Resources, 2022, 42(2): 107-113. doi: 10.13779/j.cnki.issn1001-0076.2022.02.014

Research Progress on Purification and Material Preparation of Magnesite

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  • Magnesite is one of the important advantageous minerals in China. With the continuous development and utilization, high-quality magnesite ore began to be in shortage, and a large number of low-grade magnesite ores were discarded. Therefore, it is necessary to enhance the separation and purification of low-grade magnesite ores and develop methods for their high-value-added products. This paper summarizes two methods for magnesite purification, namely flotation and chemical beneficiation. In particular, the research progresses of flotation reagent, flotation process and chemical treatment are described in detail. Besides, this paper also reviews the research progress of application of magnesite in high-quality refractories, new building materials and fine chemical materials at home and abroad. This paper could provide a reference for a new way of efficient utilization of magnesite.

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  • [1] 王兆敏. 中国菱镁矿现状与发展趋势[J]. 中国非金属矿工业导刊, 2006(5): 6-8. doi: 10.3969/j.issn.1007-9386.2006.05.002

    CrossRef Google Scholar

    WANG Z M. Status and development trend of magnesite in China[J]. China Non-Metallic Minerals Industry, 2006(5): 6-8. doi: 10.3969/j.issn.1007-9386.2006.05.002

    CrossRef Google Scholar

    [2] 中华人民共和国自然资源部. 中国矿产资源报告[M]. 北京: 地质出版社, 2021: 6-7.

    Google Scholar

    Ministry of Natural and Resources of the People's Republic of China. Mineral resources report of China[M]. Beijing: Geological Publishing House, 2021: 6-7.

    Google Scholar

    [3] 李彩霞, 刘高全, 白阳, 等. 油酸钠体系中菱镁矿-白云石浮选试验研究[J]. 非金属矿, 2018, 41(4): 77-79. doi: 10.3969/j.issn.1000-8098.2018.04.024

    CrossRef Google Scholar

    LI C X, LIU G Q, BAI Y, et al. Experimental study on flotation of magnesite-dolomite in sodium oleate system[J]. Non-metallic Mines, 2018, 41(4): 77-79. doi: 10.3969/j.issn.1000-8098.2018.04.024

    CrossRef Google Scholar

    [4] 张永奎. 我国菱镁矿的开发利用现状及前景分析[J]. 科技信息, 2013(5): 424-425.

    Google Scholar

    ZHANG Y K. Status and prospect analysis of development and utilization of magnesite in China[J]. Science and Technology Information, 2013(5): 424-425.

    Google Scholar

    [5] SUN W, DAI S, LIU W, et al. Effect of Ca (Ⅱ) on anionic/cationic flotation of magnesite ore[J]. Minerals Engineering, 2021, 163(10): 106778.

    Google Scholar

    [6] WANG Q Q, LI X A, WEI D Z, et al. The application of magnesite processing technics[J]. Applied Mechanics & Materials, 2011, 71/78: 2323-2326.

    Google Scholar

    [7] 刘文刚, ,姚广铮, 卢位, 等. 十二胺体系中金属离子对菱镁矿和白云石浮选行为的影响[J]. 矿产保护与利用, 2018(3): 66-70.

    Google Scholar

    LIU W G, YAO G Z, LU W, et al. The effect of metal ions on the flotation behavior of magnesite and dolomite in dodecylamine system[J]. Conservation and Utilization of Mineral Resources, 2018(3): 66-70.

    Google Scholar

    [8] 付亚峰, 印万忠, 肖烈江, 等. 辽宁海城某低品级菱镁矿脱硅脱钙除铁试验[J]. 现代矿业, 2013, 29(7): 21-25. doi: 10.3969/j.issn.1674-6082.2013.07.006

    CrossRef Google Scholar

    FU Y F, YIN W Z, XIAO L J, et al. The desilication, debacing and iron removal tests of low-grade magnesite in Haicheng, Liaoning province[J]. Modern Mining, 2013, 29(7): 21-25. doi: 10.3969/j.issn.1674-6082.2013.07.006

    CrossRef Google Scholar

    [9] SUN H, YIN W, YANG B, et al. Efficiently separating magnesite from quartz using N-hexadecyltrimethylammonium chloride as a collector via reverse flotation[J]. Minerals Engineering, 2021, 166(5): 106899.

    Google Scholar

    [10] 付泳贺, 姜永良, 苏拓宇, 等. 难选菱镁矿分析及组合胺捕收剂的应用[J]. 非金属矿, 2020, 43(6): 77-79. doi: 10.3969/j.issn.1000-8098.2020.06.022

    CrossRef Google Scholar

    FU Y H, JIANG Y L, SU T Y, et al. Analysis of refractory magnesite and application of combined amine collector[J]. Non-Metallic Mines, 2020, 43(6): 77-79. doi: 10.3969/j.issn.1000-8098.2020.06.022

    CrossRef Google Scholar

    [11] TANG Y, YIN W, K S. Molecular dynamics simulation of magnesite and dolomite in relation to flotation with cetyl phosphate[J]. Colloids and Surfaces a Physicochemical and Engineering Aspects, 2021, 610: 125928. doi: 10.1016/j.colsurfa.2020.125928

    CrossRef Google Scholar

    [12] 于连涛, 李晓安, 刘文刚, 等. 捕收剂LKD对某低品位菱镁矿的浮选效果影响[J]. 矿业研究与开发, 2015, 35(9): 32-35.

    Google Scholar

    YU L T, LI X A, LIU W G, et al. Effect of collector-LKD on flotation effect on low-grade magnesite[J]. Mining Research and Development, 2015, 35(9): 32-35.

    Google Scholar

    [13] 朱一民, 孙升, 黄玉梅. 新型捕收剂DYM-1对菱镁矿浮选试验[J]. 金属矿山, 2019(2): 125-128.

    Google Scholar

    ZHU Y M, SUN S, HUANG Y M. Experimental study on flotation of magnesite with a new collector DYM-1[J]. Metal Mine, 2019(2): 125-128.

    Google Scholar

    [14] 钟文兴, 印万忠, 姚金, 等. 聚丙烯酸在细粒菱镁矿反浮选中的选择性抑制作用[J]. 金属矿山, 2021(2): 96-102.

    Google Scholar

    ZHONG W X, YIN W Z, YAO J, et al. The selective inhibition of polyacrylic acid in reverse flotation of fine magnesite[J]. Metal Mine, 2021(2): 96-102.

    Google Scholar

    [15] SUN H, HAN F, YIN W Z, et al. Modification of selectivity in the flotation separation of magnesite from dolomite[J]. Colloids and Surfaces a Physicochemical and Engineering Aspects, 2020: 125460.

    Google Scholar

    [16] YANG B, SUN H, WANG D, et al. Selective adsorption of a new depressant Na2ATP on dolomite: Implications for effective separation of magnesite from dolomite via froth flotation[J]. Separation and Purification Technology, 2020, 250: 117278. doi: 10.1016/j.seppur.2020.117278

    CrossRef Google Scholar

    [17] 印万忠, 王星亮, 韩跃新. 菱镁矿反浮选脱硅试验研究[C]//中国无机盐工业协会专家委员会扩大工作会议暨节能减排研讨会论文集. 北京: 中国无机盐, 2007.

    Google Scholar

    YIN W Z, WANG X L, HAN Y X, et al. Study on antitest of magnesite[C]//Expansion work Conference of Expert Committee of China Inorganic Salt Industry Association and Seminar on Energy Conservation and Emission Reduction. Beijing: inorganic salt in China, 2007.

    Google Scholar

    [18] 王玉斌, 李宗英. 菱镁矿浮选工艺改造试验及降低后序加工能耗探讨[J]. 山东冶金, 2008(2): 25-27. doi: 10.3969/j.issn.1004-4620.2008.02.007

    CrossRef Google Scholar

    WANG Y B, LI Z Y. Study of flotation process and reducing energy consumption[J]. Shandong Metallurgy, 2008(2): 25-27. doi: 10.3969/j.issn.1004-4620.2008.02.007

    CrossRef Google Scholar

    [19] 李晓安, 代淑娟, 周凌嘉, 等. 辽宁某高硅低品位镁矿浮选提纯试验研究[J]. 中国矿业, 2012, 21(2): 63-67. doi: 10.3969/j.issn.1004-4051.2012.02.018

    CrossRef Google Scholar

    LI X A, DAI S J, ZHOU L J, et al. Study on flotation of high-silicon magnesium mine in LIAONING[J]. China Mining Industry, 2012, 21(2): 63-67. doi: 10.3969/j.issn.1004-4051.2012.02.018

    CrossRef Google Scholar

    [20] 董庆国, 白阳, 吴清峰, 等. 辽宁某低品位菱镁矿浮选除杂试验研究[J]. 非金属矿, 2018, 41(3): 100-102. doi: 10.3969/j.issn.1000-8098.2018.03.033

    CrossRef Google Scholar

    DONG Q G, BAI Y, WU Q F, et al. Study on a low-grade magnesite in LIAONING[J]. Non-metallic Mines, 2018, 41(3): 100-102. doi: 10.3969/j.issn.1000-8098.2018.03.033

    CrossRef Google Scholar

    [21] 李银文, 于传敏. 低品位菱镁矿选矿脱杂研究[J]. 轻金属, 2012(8): 8-11. doi: 10.3969/j.issn.1002-1752.2012.08.002

    CrossRef Google Scholar

    LI Y W, YU C M. Study on mineral ation of low grade magnesite[J]. Light Metal, 2012(8): 8-11. doi: 10.3969/j.issn.1002-1752.2012.08.002

    CrossRef Google Scholar

    [22] BUNYAMIN, DONMEZ. Leaching kinetics of calcined magnesite in acetic acid solutions[J]. Journal of Industrial & Engineering Chemistry, 2009, 15(6): 865-869.

    Google Scholar

    [23] 郑水林. 非金属矿加工与应用[M]. 北京: 化学工业出版社, 2009.

    Google Scholar

    ZHENG S L. Nonmetallic mineral processing and application[M]. Beijing: Chemical Industry Press, 2009.

    Google Scholar

    [24] PAVEL RASCHMAN. Leaching of calcined magnesite using ammonium chloride at constant pH[J]. Hydrometallurgy, 2000, 56(1): 109-123. doi: 10.1016/S0304-386X(00)00078-5

    CrossRef Google Scholar

    [25] SHEILA D, SANKARAN C, KHANGAOKA P R. Studies on the extraction of magnesia from low grade magnesites by carbon dioxide pressure leaching of hydrated magnesia[J]. Minerals Engineering, 1991, 4(1): 79-88. doi: 10.1016/0892-6875(91)90120-K

    CrossRef Google Scholar

    [26] DEMIR F, ORAL LACIN. Leaching kinetics of calcined magnesite in citric acid solutions[J]. Industrial & Engineering Chemistry Research, 2006, 45(4): 1307-1311.

    Google Scholar

    [27] 孙文瀚, 代淑娟, 罗娜, 等. 基于矿石溶解性差异的菱镁矿酸浸脱钙[J]. 中国有色金属学报, 2019, 29(8): 1733-1739.

    Google Scholar

    SUN W H, DAI S J, LUO N, et al. Magnesite acid oleaching calcium based on differences in ore solubility[J]. Chinese Journal of Nonferrous Metals, 2019, 29(8): 1733-1739.

    Google Scholar

    [28] 李鹏程, 代淑娟, 邓立佳, 等. 海城某低品位菱镁矿石浸出试验研究[J]. 化工矿物与加工, 2018(7): 11-14.

    Google Scholar

    LI P C, DAI S J, DENG L J, et al. Experimental study on leaching of a low-grade magnesite mine in HAICHENG[J]. Industrial Minerals and Processing, 2018(7): 11-14.

    Google Scholar

    [29] WANG J F, LI Z B, PARK AHA et al. Thermodynamic and kinetic studies of the MgCl2-NH4Cl-NH3-H2O system for the production of high purity MgO from calcined low-grade magnesite[J]. AICHE Journal, 2015, 61(6): 1933-1946. doi: 10.1002/aic.14789

    CrossRef Google Scholar

    [30] 易小祥, 杨大兵, 李亚伟. 碳化法处理巴盟隐晶质菱镁矿[J]. 矿冶工程, 2008(4): 63-65.

    Google Scholar

    YI X X, YANG D B, LI Y W. Carbonization treatment of the hidden crystalline magnesite[J]. Mining and metallurgy Engineering, 2008(4): 63-65.

    Google Scholar

    [31] AMER A M. Hydrometallurgical processing of low grade egyptian magnesite[J]. Physicochemical Problems of Mineral Processing, 2010, 44: 5-12.

    Google Scholar

    [32] THOMAIDIS E, KOSTAKIS G. Synthesis of cordieritic materials using raw kaolin, bauxite, serpentinite/olivinite and magnesite[J]. Ceramics International, 2015, 41(8): 9701-9707. doi: 10.1016/j.ceramint.2015.04.039

    CrossRef Google Scholar

    [33] 罗旭东, 曲殿利, 张国栋. 二氧化钛对菱镁矿风化石制备镁铝尖晶石组成结构的影响[J]. 硅酸盐通报, 2011, 30(5): 1151-1154.

    Google Scholar

    LUO X D, QU D L, ZHANG G D. Effect of titanium dioxide on the composition structure of magnesite wind fossil preparation of magnesite aluminum spinel[J]. Bulletin of the Chinese Ceramic Society, 2011, 30(5): 1151-1154.

    Google Scholar

    [34] 罗旭东, 曲殿利, 张国栋. 氧化镧对菱镁矿风化石制备镁铝尖晶石组成结构的影响[J]. 稀土, 2012, 33(4): 59-63. doi: 10.3969/j.issn.1004-0277.2012.04.012

    CrossRef Google Scholar

    LUO X D, QU D L, Zhang G D. Effect of lanthanum oxide on the composition and structure of magnesia alumina spinel prepared from magnesite wind fossil[J]. Chinese Rare Earth, 2012, 33(4): 59-63. doi: 10.3969/j.issn.1004-0277.2012.04.012

    CrossRef Google Scholar

    [35] 钟鑫宇, 罗旭东, 张国栋, 等. 低品位菱镁矿与工业铝灰制备镁铝尖晶石[J]. 无机盐工业, 2012, 44(12): 32-35. doi: 10.3969/j.issn.1006-4990.2012.12.010

    CrossRef Google Scholar

    ZHONG X Y, LUO X D, ZHANG G D, et al. Preparation of magnesia alumina spinel from low-grade magnesite and industrial aluminum ash[J]. Inorganic salt industry, 2012, 44(12): 32-35. doi: 10.3969/j.issn.1006-4990.2012.12.010

    CrossRef Google Scholar

    [36] WANG F, YE J K, HE G, et al. Preparation and characterization of porous MgAl2O4 spinel ceramic supports from bauxite and magnesite[J]. Ceramics International, 2015, 41(6): 7374-7380. doi: 10.1016/j.ceramint.2015.02.044

    CrossRef Google Scholar

    [37] MANNI A, HARRATI A, HADDAR A E, et al. Effects of lizardite addition on technological properties of forsterite-monticellite rich white ceramics prepared from natural magnesite and dolomite[J]. Journal of Construction Research, 2020, 2(1): 9-20.

    Google Scholar

    [38] 罗旭东, 曲殿利, 张国栋, 等. 氧化铬对镁橄榄石材料结构及性能的影响[J]. 材料热处理学报, 2013, 34(1): 21-25.

    Google Scholar

    LUO X D, QU D L, Zhang G D, et al. Effect of chromium oxide on the structure and properties of forsterite[J]. Transactions of material heat treatment, 2013, 34(1): 21-25.

    Google Scholar

    [39] 陈后维, 章祥林, 靳廷甲, 等. 低品级菱镁矿制耐水氯氧镁胶凝材料的研制[J]. 安徽建筑大学学报, 2015, 23(1): 48-51.

    Google Scholar

    CHEN H W, ZHANG X Q, JIN T Q, et al. Development of water-resistant magnesium oxychloride cementitious material made from low-grade magnesite[J]. Journal of Anhui Jianzhu University, 2015, 23(1): 48-51.

    Google Scholar

    [40] GAO H, JIAO C, HAN Y, et al. Experimental study on mix proportion and the strength of law-grade magnesite hollow block[J]. IOP Conference Series Earth and Environmental Science, 2019, 304: 052026. doi: 10.1088/1755-1315/304/5/052026

    CrossRef Google Scholar

    [41] 吕志道, 李超奇, 等. 一种菱镁复合材料及其制备方法: CN108383481A[P]. 2018.

    Google Scholar

    LV Z D, LI C Q, et al. A magnesite composite material and its preparation method: CN108383481A[P]. 2018.

    Google Scholar

    [42] 凌观爽, 宗俊. 影响微晶质菱镁矿制备纳米氢氧化镁的工艺研究[J]. 盐科学与化工, 2021, 50(9): 11-16. doi: 10.3969/j.issn.2096-3408.2021.09.004

    CrossRef Google Scholar

    LING G S, ZONG J. Study on the process affecting the preparation of nano magnesium hydroxide from microcrystalline magnesite[J]. Journal of Salt Science and chemical industry, 2021, 50(9): 11-16. doi: 10.3969/j.issn.2096-3408.2021.09.004

    CrossRef Google Scholar

    [43] 刘振. 溶胶-凝胶法由菱镁矿制备纳米氧化镁[J]. 应用化工, 2012, 41(5): 837-839. doi: 10.3969/j.issn.1671-3206.2012.05.025

    CrossRef Google Scholar

    LIU Z. Preparation of nano magnesium oxide[J]. Applied chemical industry, 2012, 41(5): 837-839. doi: 10.3969/j.issn.1671-3206.2012.05.025

    CrossRef Google Scholar

    [44] NGULUBE T, GUMBO J R, MASINDI V, et al. Preparation and characterisation of high performing magnesite-halloysite nanocomposite and its application in the removal of methylene blue dye[J]. Journal of Molecular Structure, 2019, 1184: 389-399. doi: 10.1016/j.molstruc.2019.02.043

    CrossRef Google Scholar

    [45] VHAHANGWELE, MASINDI, WILSON, et al. Kinetics and equilibrium studies for removal of fluoride from underground water using cryptocrystalline magnesite[J]. Journal of Water Reuse and Desalination, 2015, 5(3): 282-292. doi: 10.2166/wrd.2015.080

    CrossRef Google Scholar

    [46] BEKESHEV A Z, MOSTOVOY A S, KADYKOVA Y A. Study of the magnesite effect on the physicochemical and mechanical properties of modified epoxy composites[J]. Russian Journal of Applied Chemistry, 2021, 94(5): 666-673. doi: 10.1134/S1070427221050153

    CrossRef Google Scholar

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