Citation: | JIANG Feng, LIU Jianfei, REN Hui, GE Wencheng. Recovery of Dolomite from Tailings of Baiyun Ebo Processing Plant by Flotation with a Novel Collector[J]. Conservation and Utilization of Mineral Resources, 2022, 42(2): 85-90. doi: 10.13779/j.cnki.issn1001-0076.2022.02.011 |
In order to realize the comprehensive recovery of dolomite in the tailings after fluorite separation of Baiyun Ebo tailings, the tailings after fluorite roughing were used as flotation feed, the experiments were carried out in detail with DWZ-2 as collector and sodium silicate as depressant. The results showed thatthe dolomite content in the concentrate obtained by closed-circuit flotation with one-stage roughing and four-stage cleaning process was 83.62%, the recovery rate was 80.49%, the SiO2 content was 0.86%, the removal rate of SiO2 rate was 84.10%, and the whiteness was 45.7%. Modified dolomite may be a raw material for preparing dark rubber filler materials. This study is of great significance to improve the comprehensive utilization of dolomite resources, reduce the emission of tailings and improve the environment.
[1] | 第五界别活动组——白云鄂博矿区矿产资源及稀土产业调研报告[J]. 稀土信息, 2020(4): 26-27. The fifth sector activity group-research report on mineral resources and rare earth industry in baiyun ebo mining area[J]. Rare Earth Information, 2020(4): 26-27. |
[2] | 胡俊. 尾矿综合利用技术探讨[J]. 铜业工程, 2021(1): 45-47. doi: 10.3969/j.issn.1009-3842.2021.01.012 HU J. Comprehensive utilization technology of tailings[J]. Copper Engineering, 2021(1): 45-47. doi: 10.3969/j.issn.1009-3842.2021.01.012 |
[3] | 石晓莉, 杜根杰, 张铭, 等. 尾矿综合利用产业存在的问题及建议[J]. 现代矿业, 2022.38(2): 38-40+44. SHI X L, DU G J, ZHANG M, et al. Problems and suggestions of tailings comprehensive utilization industry[J]. Modern Mining, 2022, 38(2): 38-40+44. |
[4] | 秦玉芳, 李娜, 马莹, 等. 白云鄂博选铁尾矿优先浮选稀土试验研究[J]. 矿冶, 2021, 30(1): 32-37. QIN Y F, LI N, MA Y. WANG Q W. Experimental study on preferential flotation of rare earths from iron ore processing tailings in Baiyun Ebo[J]. Mining and Metallurgy, 2021, 30(1): 32-37. |
[5] | 钱淑慧, 李宏静, 高俊德. 白云鄂博氧化矿尾矿中萤石资源回收试验[J]. 现代矿业, 2014, 30(9): 47-51. doi: 10.3969/j.issn.1674-6082.2014.09.019 QIAN S H. LI H J. GAO J D. Experimental recovery of fluorite resources from the tailings of Baiyun Ebo oxide mine[J]. Modern Mining, 2014, 30(9): 47-51. doi: 10.3969/j.issn.1674-6082.2014.09.019 |
[6] | 姚志明, 宋传兵, 张齐. 从白云鄂博尾矿中浮选回收稀土[J]. 金属矿山, 2014(9): 39-42. YAO Z M, SONG C B, ZHANG Q. Recovery of rare earths from Baiyun Ebo tailings by flotation[J]. Metal Mining, 2014(9): 39-42. |
[7] | 李宏静, 钱淑慧. 白云鄂博稀选尾矿中萤石资源回收工艺研究[C]//中国稀土学会2020学术年会暨江西(赣州)稀土资源绿色开发与高效利用大会摘要集, 2020: 64. LI H J, QIAN S H. Study on the recovery process of fluorite resources from Baiyun Ebo diluted tailings[C]// China Rare Earth Society 2020 Annual Academic Conference and Jiangxi (Ganzhou) Rare Earth Resources Green Development and Efficient Utilization Conference Abstracts Collection, 2020: 64. |
[8] | 黄小宾. 白云鄂博稀土尾矿萤石提质降杂试验研究[D]. 包头: 内蒙古科技大学, 2019. HUANG X B. Experimental study on fluorite quality reduction of Baiyun Ebo rare earth tailings[D]. Baotou: Inner Mongolia University of Science and Technology, 2019. |
[9] | 郑强, 边雪, 吴文远. 白云鄂博稀土尾矿的工艺矿物学研究[J]. 东北大学学报(自然科学版), 2017, 38(8): 1107-1111. ZHENG Q, BIAN X, WU W Y. Process mineralogy of Baiyun Ebo rare earth tailings[J]. Journal of Northeastern University (Natural Science Edition), 2017, 38(8): 1107-1111. |
[10] | 贺宇龙. 白云鄂博尾矿综合回收稀土、萤石、铌、钪选矿新工艺[D]. 包头: 内蒙古科技大学, 2020. HE Y L. New process for comprehensive recovery of rare earth, fluorite, niobium and scandium beneficiation from Baiyun Ebo tailings[D]. Baotou: Inner Mongolia University of Science and Technology, 2020. |
[11] | 汤家焰, 王文才, 祝雯. 白云鄂博尾矿中萤石浮选工艺研究[J]. 化工矿物与加工, 2018, 47(9): 22-26. TANG J Y, WANG W C, ZHU W. Research on fluorite flotation process in Baiyun Ebo tailings[J]. Chemical Minerals and Processing, 2018, 47(9): 22-26. |
[12] | 李梅. 白云鄂博尾矿萤石浮选新技术[D]. 包头: 内蒙古科技大学, 2015-10-28. LI M. New technology of fluorite flotation in Baiyun Ebo tailings[D]. Baotou: Inner Mongolia University of Science and Technology, 2015-10-28. |
[13] | 李梅. 高凯. 柳召刚. 等. 白云鄂博尾矿萤石浮选工艺研究[J]. 有色金属(选矿部分), 2014(6): 55-58. doi: 10.3969/j.issn.1671-9492.2014.06.014 LI M, GAO K, LIU Z G, et al. Research on fluorite flotation process of Baiyun Ebo tailings[J]. Non-ferrous metals (mineral processing part), 2014(6): 55-58. doi: 10.3969/j.issn.1671-9492.2014.06.014 |
[14] | 边雪, 岑鹏. 白云鄂博弱磁尾矿中铁、稀土、氟和磷的研究[C]//中国稀土学会2021学术年会论文摘要集, 2021: 40. BIAN X, CEN P. Study of iron, rare earths, fluorine and phosphorus in the weakly magnetic tailings of Baiyun Ebo[C]//Proceedings of the 2021 Annual Academic Conference of the Chinese Rare Earth Society, 2021: 40. |
[15] | 张巍. 白云石的应用进展[J/OL]. 矿产保护与利用, 2018(2): 130-144. ZHANG W. Progress in the application of dolomite[J/OL]. Mineral Conservation and Utilization, 2018(2): 130-144. |
[16] | 蒋为, 蒋述兴. 苛性白云石与菱苦土复合镁质胶凝材料的制备及其应用[J]. 桂林理工大学学报, 2012, 32(4): 588-595. doi: 10.3969/j.issn.1674-9057.2012.04.026 JIANG W, JIANG S X. Preparation of caustic dolomite and rhodochrosite composite magnesium cementitious materials and their applications[J]. Journal of Guilin University of Technology, 2012, 32(4): 588-595. doi: 10.3969/j.issn.1674-9057.2012.04.026 |
[17] | 贾建业, 宁平. 活性白云石粉替代轻钙在塑料和热塑性弹性体中的应用[J]. 非金属矿, 2001(1): 15-17. JIA J Y, NING P. Application of active dolomite powder as a substitute for light calcium in plastics and thermoplastic elastomers[J]. Nonmetallic Minerals, 2001(1): 15-17. |
[18] | 李彩霞, 刘高全, 白阳, 等.油酸钠体系中菱镁矿-白云石浮选试验研究[J]. 非金属矿, 2018, 41(4): 77-79. LI C X. LIU G Q. BAI Y. WANG F F. Experimental study on magnesite-dolomite flotation in sodium oleate system[J]. Nonmetallic Minerals, 2018, 41(4): 77-79. |
[19] | 王雪. 陈平. 王晓军. 黎艳. 油酸钠体系下白云石、高岭土、石英的浮选性能[J]. 非金属矿, 2016, 39(4): 80-83. WANG X. CHEN P. WANG X J. LI Y. Flotation performance of dolomite, kaolinite and quartz in the sodium oleate system[J]. Nonmetallic Minerals, 2016, 39(4): 80-83. |
[20] | 祁宗. 孙传尧. 脂肪酸作捕收剂白云石浮选规律及其机理研究[J]. 中国矿业大学学报, 2013, 42(3): 461-465. QI Z. SUN C Y. Study on the flotation law of dolomite with fatty acid as trapping agent and its mechanism[J]. Journal of China University of Mining and Technology, 2013, 42(3): 461-465. |
[21] | 陈永弟. 白云石的热分解规律及其应用[D]. 长春: 吉林大学, 2012. CHEN YD. Thermal decomposition law of dolomite and its application[D]. Changchun: Jilin University, 2012. |
[22] | 李思阳. 重晶石伴生型萤石矿新型浮选药剂的浮选性能研究[D]. 沈阳: 东北大学2021. LI S Y. Study on the flotation performance of a new flotation agent for barite associated fluorite ore[D]. Shenyang: Northeastern University 2021. |
Results of particle size analysis of experimental samples
Effect of Sodium oleate dosage on flotation performance
Effect of DWZ-2 dosage on flotation performance
Effect of Sodium silicate dosage on flotation performance
Flosheet of closed-circuit flotation tests
Morphology and backscattered electron map of flotation concentrate
Results of elemental surface scan analysis