Zhengzhou Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological SciencesHost
2022 Vol. 42, No. 6
Article Contents

ZHANG Yafeng, AN Luyang, CUI Xiaodong, YANG Shuang. Advances in Comprehensive Utilization of Magnesite Tailings[J]. Conservation and Utilization of Mineral Resources, 2022, 42(6): 128-140. doi: 10.13779/j.cnki.issn1001-0076.2022.01.034
Citation: ZHANG Yafeng, AN Luyang, CUI Xiaodong, YANG Shuang. Advances in Comprehensive Utilization of Magnesite Tailings[J]. Conservation and Utilization of Mineral Resources, 2022, 42(6): 128-140. doi: 10.13779/j.cnki.issn1001-0076.2022.01.034

Advances in Comprehensive Utilization of Magnesite Tailings

  • The reserves, production and exports of China's magnesite rank first in the world, and thus producing a large amount of magnesite tailings during the development and utilization of magnesite mining. The mineral and chemical composition of magnesite tailings were introduced in outline, and the comprehensive utilization of magnesite tailings was summarized in detail, including building materials (cement, concrete, expansion agents, wall materials and glass-ceramics), refractories (magnesia, forsterite and converter protecting modifier for slag splashing), chemical products (magnesium oxide, magnesium hydroxide and magnesium salts), and environmental agents (water treatment agents, flue gas purifying agents and soil remediation agents). Furthermore, the existing problems were pointed out in the comprehensive utilization of magnesite tailings, and suggestions for its future development were put forward accordingly.

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  • [1] 邸素梅. 我国菱镁矿资源及市场[J]. 非金属矿, 2001, 24(1): 4−6. doi: 10.3969/j.issn.1000-8098.2001.01.001

    CrossRef Google Scholar

    DI S M. Magnesite resources and market in China[J]. Non-Metallic Mines, 2001, 24(1): 4−6. doi: 10.3969/j.issn.1000-8098.2001.01.001

    CrossRef Google Scholar

    [2] 何勇, 姜明. 我国菱镁矿资源的开采利用现状及存在的问题[J]. 耐火与石灰, 2012, 37(3): 25−28. doi: 10.3969/j.issn.1673-7792.2012.03.007

    CrossRef Google Scholar

    HE Y, JIANG M. Present situation of mining and utilizationand existing problems of magnesite resource of our country[J]. Refractories & Lime, 2012, 37(3): 25−28. doi: 10.3969/j.issn.1673-7792.2012.03.007

    CrossRef Google Scholar

    [3] 王兆敏. 中国菱镁矿现状与发展趋势[J]. 中国非金属矿工业导刊, 2006(5): 6−9. doi: 10.3969/j.issn.1007-9386.2006.05.002

    CrossRef Google Scholar

    WANG Z M. Present situation and development trend of magnesite in China[J]. China Non-metallic Minerals Industry, 2006(5): 6−9. doi: 10.3969/j.issn.1007-9386.2006.05.002

    CrossRef Google Scholar

    [4] 张兴业. 提高我国菱镁矿资源利用率的途径[J]. 矿产保护与利用, 2008(4): 23−25. doi: 10.3969/j.issn.1001-0076.2008.04.006

    CrossRef Google Scholar

    ZHANG X Y. Ways of improving utilization level of magnesite resource in China[J]. Conservationand Utilization of Mineral Resources, 2008(4): 23−25. doi: 10.3969/j.issn.1001-0076.2008.04.006

    CrossRef Google Scholar

    [5] 李振. 菱镁矿尾矿与硼泥合成橄榄石研究[D]. 鞍山: 辽宁科技大学, 2013.

    Google Scholar

    LI Z. Magnesite tailings with boron mud synthetic peridot research[D]. Anshan: University of Science and Technology Liaoning, 2013.

    Google Scholar

    [6] SHANMUGASUNDARAM V, SHANMUGAM B. Characterisation of magnesite mine tailings as a construction material[J]. Environmental Science and Pollution Research International, 2021, 28(33): 45557−45570. doi: 10.1007/s11356-021-13890-x

    CrossRef Google Scholar

    [7] EROL S, ÖZDEMIR M. Removal of nickel from aqueous solution using magnesite tailing[J]. Desalination and Water Treatment, 2015, 57(13): 5810−5820.

    Google Scholar

    [8] 刘子源. 焙烧菱镁尾矿对水泥砂浆膨胀及抗碳化性能研究[D]. 鞍山: 辽宁科技大学, 2020.

    Google Scholar

    LIU Z Y. Study on the impact of calcined magnesite tailings on the expansion and carbonation resistance performance of cement mortar[D]. Anshan: University of Science and Technology Liaoning, 2020.

    Google Scholar

    [9] 刘永杰, 孙杰璟, 孟庆凤. 利用菱镁矿尾矿制备镁硅酸盐水泥的研究[J]. 硅酸盐通报, 2013, 32(6): 1126−1130. doi: 10.16552/j.cnki.issn1001-1625.2013.06.028

    CrossRef Google Scholar

    LIU Y J, SUN J J, MENG Q F. Study on magnesite tailing for preparing magnesium silicate cement[J]. Bulletin of the Chinese Ceramic Society, 2013, 32(6): 1126−1130. doi: 10.16552/j.cnki.issn1001-1625.2013.06.028

    CrossRef Google Scholar

    [10] 李承元. 国内外菱镁矿资源开发应用现状及展望[J]. 世界有色金属, 1997(12): 30−34.

    Google Scholar

    LI C Y. Present situation and prospect of magnesite resources development and application at home and abroad[J]. World Nonferrous Metals, 1997(12): 30−34.

    Google Scholar

    [11] 黄明喜, 薛建军, 高培伟, 等. 菱镁矿尾矿制备高活性MgO的性能表征[J]. 环境工程学报, 2012, 6(4): 1315−1319.

    Google Scholar

    HUANG M X, XUE J J, GAO P W, et al. Preparation and properties of high-active MgO from magnesite tailings[J]. Chinese Journal of Environmental Engineering, 2012, 6(4): 1315−1319.

    Google Scholar

    [12] 王玉斌. 菱镁矿浮选尾矿及废水的再利用[J]. 山东冶金, 2011, 33(5): 165−166. doi: 10.3969/j.issn.1004-4620.2011.05.062

    CrossRef Google Scholar

    WANG Y B. Recycle of magnesite flotation tailings and wastewater[J]. Shandong Metallurgy, 2011, 33(5): 165−166. doi: 10.3969/j.issn.1004-4620.2011.05.062

    CrossRef Google Scholar

    [13] 刘成龙, 邓敏, 莫立武, 等. 用菱镁矿尾矿制备的MgO膨胀剂对砂浆强度与膨胀性能的影响[J]. 南京工业大学学报(自然科学版), 2018, 40(6): 26−31.

    Google Scholar

    LIU C L, DENG M, MO L W, et al. Effects of MgO expansive agents from magnesite tailingson expansion and strength of mortars[J]. Journal of Nanjing Tech University (Natural Science Edition), 2018, 40(6): 26−31.

    Google Scholar

    [14] SIBANDA Z, AMPONSAH-DACOSTA F, MHLONGO S E. Characterization and evaluation of magnesite tailings for their potential utilization: A case study of Nyala magnesite mine, Limpopo province of South Africa[J]. ARPN Journal of Engineering and Applied Sciences, 2013, 8(8): 606−613.

    Google Scholar

    [15] 俞景林. 利用菱镁矿尾矿制备含镁铝尖晶石胶凝材料的研究[D]. 济南: 济南大学, 2014.

    Google Scholar

    YU J L. Study on preparation of spinel contained cementitious material using magnesite tailings[D]. Ji’nan: University of Ji’nan, 2014.

    Google Scholar

    [16] ISMAILOV A, MERILAITA N, SOLISMAA S, et al. Utilizing mixed-mineralogy ferroan magnesite tailings as the source of magnesium oxide in magnesium potassium phosphate cement[J]. Construction and Building Materials, 2020, 231: 1−11.

    Google Scholar

    [17] LIU Z, WANG S, HUANG J, et al. Experimental investigation on the properties and microstructure of magnesium oxychloride cement prepared with caustic magnesite and dolomite[J]. Construction and Building Materials, 2015, 85: 247−255. doi: 10.1016/j.conbuildmat.2015.01.056

    CrossRef Google Scholar

    [18] XU K, XI J, GUO Y, et al. Effects of a new modifier on the water-resistance of magnesite cement tiles[J]. Solid State Sciences, 2012, 14(1): 10−14. doi: 10.1016/j.solidstatesciences.2011.08.009

    CrossRef Google Scholar

    [19] 陈后维, 章祥林, 李曼, 等. 聚丙烯纤维及废弃陶瓷对低品级菱镁矿制氯氧镁水泥性能的影响[J]. 硅酸盐通报, 2015, 34(4): 1165−1170.

    Google Scholar

    CHEN H W, ZHANG X L, LI M, et al. Influence of polypropylene fiber and ceramic waste on the properties ofmagnesium oxychloride cement made by low-grade magnesite[J]. Bulletin ofthe Chinese Ceramic Society, 2015, 34(4): 1165−1170.

    Google Scholar

    [20] 洪雷. 菱镁尾矿在混凝土中应用研究[J]. 混凝土, 2012(11): 54−56. doi: 10.3969/j.issn.1002-3550.2012.11.018

    CrossRef Google Scholar

    HONG L. Application and research of magnesia tailings in concrete[J]. Concrete, 2012(11): 54−56. doi: 10.3969/j.issn.1002-3550.2012.11.018

    CrossRef Google Scholar

    [21] 于万增, 赵海翰. 菱镁矿粉对混凝土性能影响的试验研究[J]. 新型建筑材料, 2017, 44(12): 45−47. doi: 10.3969/j.issn.1001-702X.2017.12.013

    CrossRef Google Scholar

    YU W Z, ZHAO H H. Experimental study on the effect of magnesite powder on concrete performance[J]. New Building Materials, 2017, 44(12): 45−47. doi: 10.3969/j.issn.1001-702X.2017.12.013

    CrossRef Google Scholar

    [22] 张畅. 磷石膏与菱镁矿尾矿粉对砂浆及混凝土收缩性能的影响[D]. 长春: 吉林建筑大学, 2020.

    Google Scholar

    ZHANG C. Effect of phosphogypsum and magnesite tailing powder on shrinkage of mortar and concrete[D]. Changchun: Jilin Jianzhu University, 2020.

    Google Scholar

    [23] 刘子源, 毕万利, 关岩, 等. 焙烧菱镁尾矿制MgO膨胀剂对水泥砂浆膨胀性能的影响[J]. 建筑材料学报, 2021, 24(3): 466−472. doi: 10.3969/j.issn.1007-9629.2021.03.004

    CrossRef Google Scholar

    LIU Z Y, BI W L, GUAN Y, et al. Impact of expansive agent from calcinating magnesite tailings on expansion performance of cement motar[J]. Journal of Builing Materials, 2021, 24(3): 466−472. doi: 10.3969/j.issn.1007-9629.2021.03.004

    CrossRef Google Scholar

    [24] 国家发展和改革委员会, 国土资源部, 建设部, 等. 关于印发进一步做好禁止使用实心粘土砖工作的意见的通知[EB/OL]. [2004-02-13]. https://www.ndrc.gov.cn/fggz/hjyzy/zyzhly/200509/t20050912_1135548.html.code=&state=123.

    Google Scholar

    National Development and Reform Comission, Ministry of Land and Resources, Ministry of Housing and Urban-Rural Development, et al. Notice on issuing the opinions on further improving the work of prohibiting the use of solid clay bricks[EB/OL]. [2004-02-13]. https://www.ndrc.gov.cn/fggz/hjyzy/zyzhly/200509/t20050912_1135548.html.code=&state=123.

    Google Scholar

    [25] 姜庄园, 高华国, 刘春阳, 等. 菱镁矿尾矿空心砌块及砌体力学与保温性能研究[J]. 辽宁科技大学学报, 2021, 44(4): 151−157.

    Google Scholar

    JIANG Z Y, GAO H G, LIU C Y, et al. Study on mechanics and thermal insulation properties ofmagnesite tailings hollow block and masonry[J]. Journal of University of Science and Technology Liaoning, 2021, 44(4): 151−157.

    Google Scholar

    [26] 李静, 汪琦, 路艳国. 一种菱镁石尾矿生产蓄热砖的方法: CN102603337A[P]. 2012-07-25.

    Google Scholar

    LI J, WANG Q, LU Y G. A method for producing heat storage brick from magnesite tailings: CN102603337A[P]. 2012-07-25.

    Google Scholar

    [27] 陶冶, 赵竹玉, 李晓, 等. 低品位菱镁矿尾矿的水热固化工艺研究[J]. 矿产综合利用, 2018(1): 92−95.

    Google Scholar

    TAO Y, ZHAO Z Y, LI X, et al. Study on the hydrothermal solidification of low grade magnesite tailings[J]. Multipurpose Utilization of Mineral Resources, 2018(1): 92−95.

    Google Scholar

    [28] 吕长征, 彭康, 杨华明. 尾矿制备微晶玻璃的研究进展[J]. 硅酸盐通报, 2014, 33(9): 2236−2242.

    Google Scholar

    LV C Z, PENG K, YANG H M. Research progress on preparation of tailings glass-ceramics[J]. Bulletin of the Chinese Ceramic Society, 2014, 33(9): 2236−2242.

    Google Scholar

    [29] 雷岩, 汪琦, 刘焕春, 等. 铁尾矿、菱镁石尾矿制备微晶玻璃的研究[J]. 矿产综合利用, 2011(2): 41−44. doi: 10.3969/j.issn.1000-6532.2011.02.012

    CrossRef Google Scholar

    LEI Y, WANG Q, LIU H C, et al. Experimental research on preparing glass-ceramics by using iron and magnesite tailings[J]. Multipurpose Utilization of Mineral Resources, 2011(2): 41−44. doi: 10.3969/j.issn.1000-6532.2011.02.012

    CrossRef Google Scholar

    [30] AŞKIN A, TATAR İ, KILINÇ Ş, et al. The utilization of waste magnesite in the production of the cordierite ceramic[J]. Energy Procedia, 2017, 107: 137−143. doi: 10.1016/j.egypro.2016.12.151

    CrossRef Google Scholar

    [31] 王政, 冯爱玲, 赵磊, 等. 利用菱镁矿粉状尾矿制备氧化镁工艺研究[J]. 无机盐工业, 2016, 48(5): 55−57.

    Google Scholar

    WANG Z, FENG A L, ZHAO L, et al. Study on preparation process of magnesium oxide from pulverous magnesite tailings[J]. Inorganic Chemicals Industry, 2016, 48(5): 55−57.

    Google Scholar

    [32] 周宝余, 李志坚, 吴锋, 等. 用菱镁矿碎矿生产烧结镁砂的试验研究[J]. 耐火材料, 2015, 49(2): 137−139. doi: 10.3969/j.issn.1001-1935.2015.02.015

    CrossRef Google Scholar

    ZHOU B Y, LI Z J, WU F, et al. Experimental study on producing sintered magnesia from crushed magnesite[J]. Refractories, 2015, 49(2): 137−139. doi: 10.3969/j.issn.1001-1935.2015.02.015

    CrossRef Google Scholar

    [33] 徐徽, 蔡勇, 陈白珍, 等. 用低品位菱镁矿制取高纯镁砂[J]. 中南大学学报(自然科学版), 2006, 37(4): 698−702.

    Google Scholar

    XU H, CAI Y, CHEN B Z, et al. Preparation of high purity magnesia from low-grade magnesite[J]. Journal of Central South University(Science and Technology), 2006, 37(4): 698−702.

    Google Scholar

    [34] 李振, 曲殿利, 郭玉香, 等. 菱镁矿尾矿与硼泥合成橄榄石研究[J]. 硅酸盐通报, 2014, 33(2): 248−252. doi: 10.16552/j.cnki.issn1001-1625.2014.02.005

    CrossRef Google Scholar

    LI Z, QU D L, GUO Y X, et al. Research on forsterite material prepared from magnesite tailing and boron mud[J]. Bulletin of the Chinese Ceramic Society, 2014, 33(2): 248−252. doi: 10.16552/j.cnki.issn1001-1625.2014.02.005

    CrossRef Google Scholar

    [35] 郭玉香, 曲殿利, 李振, 等. 氧化硼对菱镁矿尾矿合成镁橄榄石晶体结构与性能的影响[J]. 硅酸盐通报, 2016, 48(5): 55−57.

    Google Scholar

    GUO Y X, QU D L, LI Z, et al. Effect of boria on crystal structure and properties of forsterite synthesied from magnesite tailings[J]. Bulletin of the Chinese Ceramic Society, 2016, 48(5): 55−57.

    Google Scholar

    [36] 张斯博, 汪琦. 用铁尾矿和菱镁石尾矿制备镁橄榄石轻质隔热耐火材料工艺方法[J]. 科技信息, 2009(3): 132−133. doi: 10.3969/j.issn.1001-9960.2009.03.094

    CrossRef Google Scholar

    ZHANG S B, WANG Q. Process method for preparing forsterite lightweight heat-insulating refractory material from iron tailings and magnesite tailings[J]. Science & Technology Information, 2009(3): 132−133. doi: 10.3969/j.issn.1001-9960.2009.03.094

    CrossRef Google Scholar

    [37] 刘锡俊, 徐琳琳, 刘昭, 等. 以菱镁矿尾矿合成镁橄榄石研究[C]//2017年全国耐火原料学术交流会论文集, 1-3.

    Google Scholar

    LIU X J, XU L L, LIU Z, et al. Study on synthesis of forsterite from magnesite tailings[C]//Proceedings of 2017 National Symposium on Refractory Materials, 1-3.

    Google Scholar

    [38] 丁达飞, 李志坚, 栾旭. 用菱镁石尾矿合成高纯镁橄榄石[J]. 耐火材料, 2015, 49(S3): 538−540.

    Google Scholar

    DING D F, LI Z J, LUAN X. Synthesis of high-purity forsterite from magnesite tailings[J]. Refractories, 2015, 49(S3): 538−540.

    Google Scholar

    [39] 郭玉香, 曲殿利, 李振. Fe2O3对菱镁矿尾矿合成镁橄榄石材料晶体结构与性能的影响[J]. 人工晶体学报, 2016, 45(2): 412−416. doi: 10.3969/j.issn.1000-985X.2016.02.022

    CrossRef Google Scholar

    GUO Y X, QU D L, LI Z. Effects of Fe2O3 on crystal structure and properties of forsterite synthesized from magnesite tailings[J]. Journal of Synthetic Crystals, 2016, 45(2): 412−416. doi: 10.3969/j.issn.1000-985X.2016.02.022

    CrossRef Google Scholar

    [40] LUO X, QU D, XIE Z, et al. Effect of CeO2 on the crystalline structure of forsterite synthesized from low-grade magnesite[J]. Refractories and Industrial Ceramics, 2013, 54(4): 291−294. doi: 10.1007/s11148-013-9595-6

    CrossRef Google Scholar

    [41] 罗旭东, 曲殿利, 张国栋, 等. Al2O3对低品位菱镁矿与天然硅石合成制备镁橄榄石的影响[J]. 人工晶体学报, 2012, 41(2): 496−501. doi: 10.3969/j.issn.1000-985X.2012.02.045

    CrossRef Google Scholar

    LUO X D, QU D L, ZHANG G D, et al. Effects of alumina on synthesis of forsterite from low-grade magnesite and natural silica[J]. Journal of Synthetic Crystals, 2012, 41(2): 496−501. doi: 10.3969/j.issn.1000-985X.2012.02.045

    CrossRef Google Scholar

    [42] 罗旭东, 曲殿利, 张国栋, 等. 氧化锆对低品位菱镁矿制备镁橄榄石的影响[J]. 无机盐工业, 2013, 45(6): 11−14. doi: 10.3969/j.issn.1006-4990.2013.06.004

    CrossRef Google Scholar

    LUO X D, QU D L, ZHANG G D, et al. Effects of zirconia on synthesis of forsterite from low-grade magnesite[J]. Inorganic Chemicals Industry, 2013, 45(6): 11−14. doi: 10.3969/j.issn.1006-4990.2013.06.004

    CrossRef Google Scholar

    [43] 李小明, 王冠甫, 杨军. 转炉溅渣护炉技术的发展及现状[J]. 铸造技术, 2007, 28(8): 1140−1143. doi: 10.3969/j.issn.1000-8365.2007.08.039

    CrossRef Google Scholar

    LI X M, WANG G F, YANG J. Progress and status of BOF protection technology by slag splashing[J]. Foundry Technology, 2007, 28(8): 1140−1143. doi: 10.3969/j.issn.1000-8365.2007.08.039

    CrossRef Google Scholar

    [44] 齐晓峰, 李静, 闰欣, 等. 利用菱镁石尾矿优化溅渣护炉改质剂[J]. 中国稀土学报, 2012(30): 756−760.

    Google Scholar

    QI X F, LI J, RUN X, et al. Experimental study on optimization of slag splashing modifiers with magnesite tailings[J]. Journal of the Chinese Society of Rare Earths, 2012(30): 756−760.

    Google Scholar

    [45] 黄文博. 菱镁矿在转炉炼钢的应用实践[J]. 中国金属通报, 2018(6): 280−281. doi: 10.3969/j.issn.1672-1667.2018.06.167

    CrossRef Google Scholar

    HUANG W B. Application practice of magnesite in converter steelmaking[J]. China Metal Bulletin, 2018(6): 280−281. doi: 10.3969/j.issn.1672-1667.2018.06.167

    CrossRef Google Scholar

    [46] 王亚芳, 仲剑初, 刘霁斌, 等. 由菱镁矿制备高纯氧化镁的工艺研究[J]. 矿产保护与利用, 2005(6): 17−20. doi: 10.3969/j.issn.1001-0076.2005.06.006

    CrossRef Google Scholar

    WANG Y F, ZHONG J C, LIU J B, et al. Preparation of high-purity magnesia from magnesite[J]. Conservation and Utilization of Mineral Resources, 2005(6): 17−20. doi: 10.3969/j.issn.1001-0076.2005.06.006

    CrossRef Google Scholar

    [47] 栾澈, 朱世玲, 杨合, 等. 由低品位菱镁矿提取氧化镁[J]. 材料与冶金学报, 2013, 12(2): 89−102. doi: 10.14186/j.cnki.1671-6620.2013.02.005

    CrossRef Google Scholar

    LUAN C, ZHU S L, YANG H, et al. Extraction of magnesia from a low-grade magnesite[J]. Journal of Materials and Metallurgy, 2013, 12(2): 89−102. doi: 10.14186/j.cnki.1671-6620.2013.02.005

    CrossRef Google Scholar

    [48] 陈可可. 低品位菱镁矿制备纳米氧化镁的工艺优化研究[J]. 新乡学院学报(自然科学版), 2013, 30(5): 342−345.

    Google Scholar

    CHEN K K. Preparation nanometer magnesia from low-grade magnesite[J]. Journal of Xinxiang University (Natural Science Edition), 2013, 30(5): 342−345.

    Google Scholar

    [49] WANG N, CHEN M, LI Y Y, et al. Preparation of MgO whisker from magnesite tailings and its application[J]. Transactions of Nonferrous Metals Society of China, 2011, 21(9): 2061−2065. doi: 10.1016/S1003-6326(11)60973-4

    CrossRef Google Scholar

    [50] 臧月龙. 氧化镁晶须的研究进展[J]. 广东微量元素科学, 2009, 16(10): 24−28. doi: 10.3969/j.issn.1006-446X.2009.10.003

    CrossRef Google Scholar

    ZANG Y L. Research progress of magnesium oxide whiske[J]. Guangdong Trace Elements Science, 2009, 16(10): 24−28. doi: 10.3969/j.issn.1006-446X.2009.10.003

    CrossRef Google Scholar

    [51] WANG N, LI Y Y, NI H W. Preparation of magnesium carbonate whisker by using magnesite tailings[J]. Materials Science Forum, 2010, 654/655/656: 2022−2024. doi: 10.4028/www.scientific.net/MSF.654-656.2022

    CrossRef Google Scholar

    [52] ZHAO Y, ZHU G. A technology of preparing honeycomb-like structure MgO from low grade magnesite[J]. International Journal of Mineral Processing, 2014, 126: 35−40. doi: 10.1016/j.minpro.2013.11.006

    CrossRef Google Scholar

    [53] QIAN H, DENG M, ZHANG S, et al. Synthesis of superfine Mg(OH)2 particles by magnesite[J]. Materials Science and Engineering:A, 2007, 445/446: 600−603. doi: 10.1016/j.msea.2006.09.079

    CrossRef Google Scholar

    [54] 姜玉芝, 韩跃新, 印万忠, 等. 利用菱镁矿制备氢氧化镁[J]. 东北大学学报(自然科学版), 2006, 27(6): 694−697. doi: 10.3321/j.issn:1005-3026.2006.06.027

    CrossRef Google Scholar

    JIANG Y Z, HAN Y X, YIN W Z, et al. Preparation of magnesium hydroxide from magnesite[J]. Journal of Northeastern University (Natural Science), 2006, 27(6): 694−697. doi: 10.3321/j.issn:1005-3026.2006.06.027

    CrossRef Google Scholar

    [55] 杜高翔, 王柏昆. 利用菱镁矿尾矿制备纳米级片状氢氧化镁[J]. 地学前缘, 2008, 15(4): 142−145. doi: 10.3321/j.issn:1005-2321.2008.04.016

    CrossRef Google Scholar

    DU G X, WANG B K. The preparation of plate-shape nano-Mg(OH)2 powder from magnesite tailing[J]. Earth Science Frontiers, 2008, 15(4): 142−145. doi: 10.3321/j.issn:1005-2321.2008.04.016

    CrossRef Google Scholar

    [56] DU G, WANG B. Preparation of plate-shape nano-Mg(OH)2 powder from magnesite tailing[J]. Earth Science Frontiers, 2008, 15(4): 142−145. doi: 10.1016/S1872-5791(08)60047-0

    CrossRef Google Scholar

    [57] ÖZDEMIR M, ÇAKIR D, KIPÇAK İ. Magnesium recovery from magnesite tailings by acid leaching and production of magnesium chloride hexahydrate from leaching solution by evaporation[J]. International Journal of Mineral Processing, 2009, 93(2): 209−212. doi: 10.1016/j.minpro.2009.08.001

    CrossRef Google Scholar

    [58] 滕青, 冯雅丽, 马英. 菱镁矿尾矿酸浸动力学研究[J]. 金属矿山, 2017(11): 189−193. doi: 10.3969/j.issn.1001-1250.2017.11.037

    CrossRef Google Scholar

    TENG Q, FENG Y L, MA Y. Acid leaching kinetics of magnesite tailings[J]. Metal Mine, 2017(11): 189−193. doi: 10.3969/j.issn.1001-1250.2017.11.037

    CrossRef Google Scholar

    [59] LAÇIN O, DÖNMEZ B, DEMIR F. Dissolution kinetics of natural magnesite in acetic acid solutions[J]. International Journal of Mineral Processing, 2005, 75(1/2): 91−99. doi: 10.1016/j.minpro.2004.05.002

    CrossRef Google Scholar

    [60] DÖNMEZ B, DEMIR F, LAÇIN O. Leaching kinetics of calcined magnesite in acetic acid solutions[J]. Journal of Industrial and Engineering Chemistry, 2009, 15(6): 865−869. doi: 10.1016/j.jiec.2009.09.014

    CrossRef Google Scholar

    [61] BAKAN F, LAÇIN O, BAYRAK B, et al. Dissolution kinetics of natural magnesite in lactic acid solutions[J]. International Journal of Mineral Processing, 2006, 80(1): 27−34. doi: 10.1016/j.minpro.2006.01.005

    CrossRef Google Scholar

    [62] BAYRAK B, LACIN O, BAKAN F, et al. Investigation of dissolution kinetics of natural magnesite in gluconic acid solutions[J]. Chemical Engineering Journal, 2006, 117(2): 109−115. doi: 10.1016/j.cej.2005.12.020

    CrossRef Google Scholar

    [63] DEMIR F, DÖNMEZ B. Optimization of the dissolution of magnesite in citric acid solutions[J]. International Journal of Mineral Processing, 2008, 87(1/2): 60−64. doi: 10.1016/j.minpro.2008.01.006

    CrossRef Google Scholar

    [64] RAZA N, ZAFAR Z I, NAJAM-UL-HAQ M. Utilization of formic acid solutions in leaching reaction kinetics of natural magnesite ores[J]. Hydrometallurgy, 2014, 149: 183−188. doi: 10.1016/j.hydromet.2014.08.008

    CrossRef Google Scholar

    [65] RAZA N, ZAFAR Z I, NAJAM-UL-HAQ, et al. Leaching of natural magnesite ore in succinic acid solutions[J]. International Journal of Mineral Processing, 2015, 139: 25−30. doi: 10.1016/j.minpro.2015.04.008

    CrossRef Google Scholar

    [66] 田玉海, 李延波. 谈谈如何开发利用菱镁尾矿[C]//2006年中国镁盐行业年会暨新技术、新产品、新设备推介会论文集, 沈阳, 77-82.

    Google Scholar

    TIAN Y H, LI Y B. Discussion on how to develop and utilize magnesite tailings[C]//Proceedings of the 2006 China Magnesium Salt Industry Annual Conference and New Technology, New Products and New Equipment Promotion Conference, Shenyang, 77-82.

    Google Scholar

    [67] 张作诗, 田玉海, 于清泉, 等. 一种利用菱镁尾矿生产轻质碳酸镁的方法: CN1789133A[P]. 2006-06-21.

    Google Scholar

    ZHANG Z S, TIAN Y H, YU Q Q, et al. A method for producing light magnesium carbonate from magnesite tailings: CN1789133A[P]. 2006-06-21.

    Google Scholar

    [68] MASINDI V. A novel technology for neutralizing acidity and attenuating toxic chemical species from acid mine drainage using cryptocrystalline magnesite tailings[J]. Journal of Water Process Engineering, 2016, 10: 67−77. doi: 10.1016/j.jwpe.2016.02.002

    CrossRef Google Scholar

    [69] EROL S, ÖZDEMIR M. Kinetics, equilibrium and thermodynamics studies on Cd(Ⅱ) removal from aqueous solution by magnesite tailing[J]. Indian Journal of Chemical Technology, 2018, 25: 246−254.

    Google Scholar

    [70] KIPÇAK İ, ÖZDEMIR M. Removal of boron from aqueous solution using calcined magnesite tailing[J]. Chemical Engineering Journal, 2012, 189/190: 68−74. doi: 10.1016/j.cej.2012.02.025

    CrossRef Google Scholar

    [71] KIPÇAK İ, ISIYEL T G. Magnesite tailing as low-cost adsorbent for the removal of copper (Ⅱ) ions from aqueous solution[J]. Korean Journal of Chemical Engineering, 2015, 32(8): 1634−1641. doi: 10.1007/s11814-014-0377-8

    CrossRef Google Scholar

    [72] KIPÇAK İ. Removal of zinc ions from aqueous solution by sorption onto magnesite tailing[J]. Fresenius Environmental Bulletin, 2012, 21(8c): 2459−2465.

    Google Scholar

    [73] 董广前, 王洁. 镁法烟气脱硫技术与应用前景展望[J]. 无机盐工业, 2005, 37(1): 11−12. doi: 10.3969/j.issn.1006-4990.2005.01.004

    CrossRef Google Scholar

    DONG G Q, WANG J. The prospect on technology and application of FGD by magnesium oxide scrubbing[J]. Inorganic Chemicals Industry, 2005, 37(1): 11−12. doi: 10.3969/j.issn.1006-4990.2005.01.004

    CrossRef Google Scholar

    [74] 连娜, 陈树江, 田琳, 等. 菱镁矿浮选尾矿浆液的烟气脱硫性能[J]. 化工环保, 2014, 34(1): 81−83. doi: 10.3969/j.issn.1006-1878.2014.01.019

    CrossRef Google Scholar

    LIAN N, CHEN S J, TIAN L, et al. Flue gas desulfurization capability of magnesite flotation tailings slurry[J]. Environmental Protection of Chemical Industry, 2014, 34(1): 81−83. doi: 10.3969/j.issn.1006-1878.2014.01.019

    CrossRef Google Scholar

    [75] YANG N, NING P, LI K, et al. MgO-based adsorbent achieved from magnesite for CO2 capture in simulate wet flue gas[J]. Journal of the Taiwan Institute of Chemical Engineers, 2018, 86: 73−80. doi: 10.1016/j.jtice.2018.02.006

    CrossRef Google Scholar

    [76] 姜勇, 张玉革, 陈欣. 一种利用菱镁尾矿的设施菜田土壤改良剂及其制备方法: CN101781564A[P]. 2010-07-21.

    Google Scholar

    JIANG Y, ZHANG Y G, CHEN X. A soil conditioner for facility vegetable field using magnesite tailing and its preparation method: CN101781564A[P]. 2010-07-21.

    Google Scholar

    [77] HUANG Y, KANG R, MA X, et al. Effects of calcite and magnesite application to a declining Masson pine forest on strongly acidified soil in Southwestern China[J]. The Science of the Total Environment, 2014, 481: 469−478. doi: 10.1016/j.scitotenv.2014.02.090

    CrossRef Google Scholar

    [78] GAWEL J, MALISZEWSKA I, SADOWSKI Z. The effect of biopretreatment on the flotation recovery of magnesite tailings[J]. Minerals Engineering, 1997, 10(8): 813−824. doi: 10.1016/S0892-6875(97)00059-9

    CrossRef Google Scholar

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