Citation: | HOU Kai, YANG Zefeng, YUAN Ji, CHEN Qiulin. Research Progress in the Application of Layered Double Hydroxides in Building Materials[J]. Conservation and Utilization of Mineral Resources, 2021, 41(1): 172-178. doi: 10.13779/j.cnki.issn1001-0076.2021.01.025 |
Layered double hydroxides (LDHs) are a kind of new nano clay with double-layer structure, which have excellent physical and chemical properties. This paper briefly describes the chemical composition, structure and properties of LDHs, summarizes and analyzes the main preparation methods of LDHs, as well as the advantages and disadvantages of each method, and focuses on the application research and application of LDHs in the field of building materials, including the application in cement and cement-based concrete, asphalt, building organic high molecular materials. In the end, the paper provides an outlook for the research development trend and direction of LDHs in the field of building materials.
[1] | WANG C, CHEN Y, SHANG X, et al. Facile synthesis of Ca/Mg/Al/Fe layered double hydroxides using steelmaking slag as raw material[J]. Materials Letters, 2016, 173: 115-118. doi: 10.1016/j.matlet.2016.03.022 |
[2] | 李茜. LDHs表面改性及其在聚丙烯中的应用研究[D]. 合肥: 合肥工业大学, 2014. |
[3] | BUKHTIYAROVA, M.V., A review on effect of synthesis conditions on the formation of layered double hydroxides[J]. Journal of Solid State Chemistry, 2019, 269, 494-506. doi: 10.1016/j.jssc.2018.10.018 |
[4] | DONG Z, LIM T T, GOH K H. Application of layered double hydroxides for removal of oxyanions: a review[J]. Water research, 2008, 42(6-7): 1343-1368. doi: 10.1016/j.watres.2007.10.043 |
[5] | 袁鹏. 制备不同形貌层状复合双金属氢氧化物研究进展[J]. 当代化工, 2015, 44(12): 2832-2834+2855. doi: 10.3969/j.issn.1671-0460.2015.12.030 |
[6] | 任锦, 梁良, 张亚平, 等. 层状双氢氧化物的可控合成及功能化研究进展[J]. 化工进展, 2018, 37(7): 2694-2703. |
[7] | 何璐红, 李娜. 层状双氢氧化物的制备及应用述评[J]. 盐业与化工, 2015, 44(11): 1-5. |
[8] | 王晨晔, 陈艳, 郭占成, 等. 以钢渣为原料合成Ca-Mg-Al-Fe层状双金属氢氧化物及其对甲基橙的吸附[J]. 过程工程学报, 2018, 18(3): 570-574. |
[9] | 徐岩, 秦华, 李海生. 粉煤灰制备镁铝层状双金属氢氧化物的研究[J]. 中国矿业大学学报, 2017, 46(3): 634-639. |
[10] | 秦华, 马晓燕, 徐岩, 等. 以煤矸石为铝源制备镁铝层状双金属氢氧化物[J]. 硅酸盐通报, 2017, 36(3): 833-838. |
[11] | 段平, 层状双氢氧化物改善混凝土耐久性能的机理及其应用研究[D]. 武汉: 武汉理工大学, 2014. |
[12] | 陈伟, 张世哲, 陈晓星, 等. 层状双氢氧化物改性混凝土的碳化行为与微观机理[J]. 武汉理工大学学报, 2013, 35(6): 1-6. doi: 10.3963/j.issn.1671-4431.2013.06.001 |
[13] | 陈宇轩. LDHs材料固化氯离子机理及其在水泥基材料中的应用[D]. 武汉: 武汉理工大学, 2015. |
[14] | DUAN P, Yan C, ZHOU W. Effects of calcined layered double hydroxides on carbonation of concrete containing fly ash[J]. Construction and Building Materials, 2018, 160: 725-732. doi: 10.1016/j.conbuildmat.2017.11.099 |
[15] | 张小娟, 王静静, 董士刚, 等. 锌铝层状双金属氢氧化物焙烧物对钢筋的缓蚀作用研究[J]. 电化学, 2013, 19(3): 256-261. |
[16] | 王爱国, 吕邦成, 段平, 等. 层状双氢氧化物改善地聚物抗氯离子渗透性能研究(英文)[J]. 材料导报, 2018, 32(10): 1707-1710+1720. doi: 10.11896/j.issn.1005-023X.2018.10.026 |
[17] | KE X, BERNAL S. A, PROVIS J. L. Uptake of chloride and carbonate by Mg-Al and Ca-Al layered double hydroxides in simulated pore solutions of alkali-activated slag cement[J]. Cement and Concrete Research, 2017, 100: 1-13. doi: 10.1016/j.cemconres.2017.05.015 |
[18] | CHEN Y, SHUI Z, CHEN W. et al. Effect of MgO content of synthetic slag on the formation of Mg-Al LDHs and sulfate resistance of slag-fly ash-clinker binder[J]. Construction and Building Materials, 2016, 125: 766-774. doi: 10.1016/j.conbuildmat.2016.08.086 |
[19] | GUAN X, LI H, LUO S. et al. Influence of LiAl-layered double hydroxides with 3D micro-nano structures on the properties of calcium sulphoaluminate cement clinker[J]. Cement and Concrete Composites, 2016, 70: 15-23. doi: 10.1016/j.cemconcomp.2016.03.009 |
[20] | QU Z Y, YU Q. L, BROUWERS, H. J. H. Relationship between the particle size and dosage of LDHs and concrete resistance against chloride ingress[J]. Cement and Concrete Research, 2018, 105: 81-90. doi: 10.1016/j.cemconres.2018.01.005 |
[21] | CHEN Y, YU R, WANG X. et al. Evaluation and optimization of Ultra-High Performance Concrete (UHPC) subjected to harsh ocean environment: Towards an application of Layered Double Hydroxides (LDHs)[J]. Construction and Building Materials, 2018, 177: 51-62. doi: 10.1016/j.conbuildmat.2018.03.210 |
[22] | XU S, CHEN Z, ZHANG B. et al. Facile preparation of pure CaAl-layered double hydroxides and their application as a hardening accelerator in concrete[J]. Chemical Engineering Journal, 2009, 155(3): 881-885. doi: 10.1016/j.cej.2009.08.003 |
[23] | 公晋芳, 贾鹏. 层状双氢氧化物改性沥青及其混合料的疲劳特性研究[J]. 中外公路, 2017, 37(3): 276-279. |
[24] | 朱凯, 唐大全, 王云鹤, 等. ZnMgAl-CO_3-LDHs的沥青阻燃抑烟性能与机理分析[J]. 建筑材料学报: 1-11. |
[25] | 孙思敖, 冯振刚, 栗培龙, 等. 沥青抗紫外光老化方法研究进展[J]. 石油沥青, 2018, 32(5): 1-7+12. doi: 10.3969/j.issn.1006-7450.2018.05.001 |
[26] | ZHAN C, YU J, XU S. et al. Influence of UV aging on the rheological properties of bitumen modified with surface organic layered double hydroxides[J]. Construction and Building Materials, 2016, 123: 574-580. doi: 10.1016/j.conbuildmat.2016.07.048 |
[27] | 杨钦麟, 李元元, 庞凌. 二苯酮-4改性LDHs对沥青混合料抗老化性能影响研究[J]. 武汉理工大学学报(交通科学与工程版), 2018, 42(1): 87-92. doi: 10.3963/j.issn.2095-3844.2018.01.019 |
[28] | 姚婷婷. 紫外吸收剂/LDHs改性沥青的制备与性能研究[D]. 武汉: 武汉理工大学, 2014. |
[29] | XU S, YU J, SUN Y. et al. Synthesis and characterization of organic intercalated layered double hydroxides and their application in bitumen modification[J]. Materials Chemistry and Physics, 2015, 152: 54-61. doi: 10.1016/j.matchemphys.2014.12.011 |
[30] | LI Y, WU S, DAI Y, et al. Investigation of sodium stearate organically modified LDHs effect on the anti aging properties of asphalt binder[J]. Construction and Building Materials, 2018, 172: 509-518. doi: 10.1016/j.conbuildmat.2018.03.181 |
[31] | CUI P. Q, ZHOU, H. G, LI C, et al. Characteristics of using layered double hydroxides to reduce the VOCs from bituminous materials[J]. Construction and Building Materials, 2016, 123: 69-77. doi: 10.1016/j.conbuildmat.2016.06.117 |
[32] | 李茜. LDHs表面改性及其在聚丙烯中的应用研究[D]. 合肥: 合肥工业大学, 2014. |
[33] | 赵世永. 聚丙烯/层状双氢氧化物纳米复合材料的制备及性能研究[D]. 南京: 南京理工大学, 2008. |
[34] | 郝建港, 吴涛, 王绪光, 等. 含铁层状复合氢氧化物对膨胀阻燃聚丙烯体系的抗滴落协效作用[J]. 功能材料, 2017, 48(8): 8085-8091. |
[35] | 王吉祥. LDHs阻燃剂的制备、改性及其在聚丙烯中的应用[D]. 合肥: 合肥工业大学, 2016. |
[36] | 汪标. 钼酸盐-双氢氧化物杂化材料的制备及其阻燃聚丙烯的研究[D]. 合肥: 中国科学技术大学, 2015. |
[37] | 王杰. MMT/LDH纳米复合材料的制备及其在PP阻燃中的应用研究[D]. 绵阳: 西南科技大学, 2015. |
[38] | 郑秀婷, 吴大鸣, 刘颖, 等. 水滑石部分替代三氧化二锑阻燃聚丙烯[J]. 塑料, 2011, 40(2): 16-18. |
[39] | 朱弘. 功能性层状双氢氧化物/聚合物纳米复合材料的制备及性能研究[D]. 上海: 复旦大学, 2011. |
[40] | 马佳骏. 一种层状双氢氧化物的制备及其与聚乙烯醇复合薄膜的阻燃性能研究[D]. 兰州: 兰州大学, 2018. |
[41] | DUTTA J, CHATTERJEE T, NASKAR K. LDH as a multifunctional additive in EVA/TPU blends: Influence on mechanical, thermal, rheological and flame retardancy properties[J]. Materials Science and Engineering: B, 2018, 236-237: 84-94. doi: 10.1016/j.mseb.2018.11.025 |
[42] | 单雪影. 聚乳酸/含镍化合物纳米复合材料的制备、热性能与阻燃性能研究[D]. 合肥: 中国科学技术大学, 2014. |
[43] | 李冲冲, 徐文总, 汪晓玲, 等. 偏硼酸根离子改性ZnMgAl层状双氢氧化物的制备及在聚氨酯弹性体中的应用[J]. 高分子材料科学与工程, 2017, 33(10): 94-100. |
[44] | 聂颖, 肖明. 水滑石类化合物及其在塑料中的应用研究进展[J]. 乙醛醋酸化工, 2018(6): 20-22. |
(a) Structure diagram of LDHs; (b) SEM images of the CaAl-NO3 LDHs