Research Progress on the Effect of Metal Ions on the Floatability of Gangue Minerals in Magnesite Flotation System

ZHANG Zuojin; DAI Shujuan; HAN Jiahong; XI Yue; WANG Qianqian

doi:10.13779/j.cnki.issn1001-0076.2019.02.018

2019 Vol. 39, No. 2

Article Contents

Article navigation > Conservation and Utilization of Mineral Resources > 2019 > 39(2): 118-123

Next Article Previous Article

ZHANG Zuojin, DAI Shujuan, HAN Jiahong, XI Yue, WANG Qianqian. Research Progress on the Effect of Metal Ions on the Floatability of Gangue Minerals in Magnesite Flotation System[J]. Conservation and Utilization of Mineral Resources, 2019, 39(2): 118-123. doi: 10.13779/j.cnki.issn1001-0076.2019.02.018

Citation:

ZHANG Zuojin, DAI Shujuan, HAN Jiahong, XI Yue, WANG Qianqian. Research Progress on the Effect of Metal Ions on the Floatability of Gangue Minerals in Magnesite Flotation System[J]. Conservation and Utilization of Mineral Resources, 2019, 39(2): 118-123. doi: 10.13779/j.cnki.issn1001-0076.2019.02.018

Research Progress on the Effect of Metal Ions on the Floatability of Gangue Minerals in Magnesite Flotation System

1.
School of Mining Engineering, University of Science & Technology Liaoning, Anshan 114051, China
2.
Chaoyang Teachers College, Chaoyang 114200, China

More Information

Corresponding author: DAI Shujuan

Received Date: 29 September 2018

Publish Date: 25 April 2019

Abstract

Abstract

Flotation is an important method for the purification of magnesite and the separation of magnesite and gangue minerals is greatly affected by metal ions in flotation system. The effect of metal ions on the floatability of quartz, dolomite and talc in magnesite is reviewed, and the influence path and mechanism of metal ions on veinite minerals in magnesite has been analyzed. In the flotation process of magnesite, metal ions effect the action of flotation reagent and gangue mineral mainly by changing the surface wettability, Zeta potential of gangue mineral surface and forming metal complex adsorbed on mineral surface to change the floatability of gangue minerals. The effect of metal ions on the floatability of veinite minerals in magnesite can be eliminated by changing the type of flotation reagents and adding reagents to complex or precipitate with metal ions.
- metal ions /
- magnesite /
- dolomite /
- quartz /
- talc /
- flotation

FullText(HTML)

References

[1]	代淑娟, 于连涛, 张孟.辽宁吉美地区某低品位菱镁矿浮选提纯实验研究[J].矿冶工程, 2014, 34(4):52-54. doi: 10.3969/j.issn.0253-6099.2014.04.012 CrossRef Google Scholar
[2]	鲍荣华, 郭娟, 许容, 等.中国菱镁矿开发居世界重要地位[J].国土资源情报, 2012(12):25-30. doi: 10.3969/j.issn.1674-3709.2012.12.006 CrossRef Google Scholar
[3]	朱阳戈, 谭欣, 闫志刚, 等.低品位菱镁矿浮选试验研究[J].轻金属, 2014(2):1-4. Google Scholar
[4]	王星亮.低品位菱镁矿浮选提纯研究[D].沈阳: 东北大学, 2008.http://www.wanfangdata.com.cn/details/detail.do?_type=degree&id=Y1843333 Google Scholar
[5]	王淀佐, 胡岳华.浮选溶液化学[M].长沙:湖南科学技术出版社, 1988. Google Scholar
[6]	戴子林, 高丽霞, 李桂英, 等.滑石的矿物结构与浮选性能[J].金属矿山, 2018(2):1-6. Google Scholar
[7]	邹志雄, 罗惠华, 汤家焰.常见金属离子对白云母和石英浮选特性的影响[J].矿产保护与利用, 2018(1):66-71. Google Scholar
[8]	于洋, 宋磊, 周少珍, 等.多价金属阳离子对几种含钙盐类矿物可浮性的影响[J].化工矿物与加工, 2015, 44(9):9-13. Google Scholar
[9]	王纪镇, 印万忠, 李振, 等.铁离子和铅离子对白钨矿与石英浮选的影响及机理研究[J].矿产保护与利用, 2017(2):35-38, 46. Google Scholar
[10]	Zhang J, Wang W, Liu J, et al. Fe(Ⅲ) as an activator for the flotation of spodumene, albite and quartz minerals[J]. Minerals engineering, 2014, 61:16-22. doi: 10.1016/j.mineng.2014.03.004 CrossRef Google Scholar
[11]	Feng Q, Wen S, Zhao W, et al. Effect of calcium ions on adsorption of sodium oleate onto cassiterite and quartz surfaces and implications for their flotation separation[J]. Separation and purification technology, 2018, 200:300-306. doi: 10.1016/j.seppur.2018.02.048 CrossRef Google Scholar
[12]	周坤, 张覃, 唐云.Ca²⁺和Mg²⁺对石英浮选的影响研究[J].化工矿物与加工, 2014, 43(12):12-15. Google Scholar
[13]	张晋霞, 冯雅丽, 牛福生.矿浆中金属离子对蓝晶石矿物浮选行为的影响[J].东北大学学报(自然科学版), 2014, 35(12):1787-1791. Google Scholar
[14]	刘星, 张晋霞, 徐亮, 等.金属离子对赤铁矿、石英、绿泥石可浮性的影响[J].西部探矿工程, 2016, 28(7):93-95, 98. doi: 10.3969/j.issn.1004-5716.2016.07.030 CrossRef Google Scholar
[15]	时景阳, 叶军建, 王贤晨, 等.白云石表面溶出Ca²⁺、Mg²⁺对其可浮性的影响[J].矿产保护与利用, 2017(1):40-45. Google Scholar
[16]	张国范, 冯寅, 朱阳戈, 等.钙、镁离子对磷灰石与白云石浮选行为的影响[J].化工矿物与加工, 2011, 40(7):1-4, 10. doi: 10.3969/j.issn.1008-7524.2011.07.001 CrossRef Google Scholar
[17]	张孟, 代淑娟, 马芳源, 等.钙、镁离子对菱镁矿与白云石浮选行为的影响[J].非金属矿, 2015, 38(5):50-53. Google Scholar
[18]	祁宗, 孙传尧.两种pH调整剂、不同矿浆pH值测试点对白云石浮选规律的影响[J].有色金属(选矿部分), 2012(5):74-78. doi: 10.3969/j.issn.1671-9492.2012.05.018 CrossRef Google Scholar
[19]	李冬莲, 张亚东.钙镁离子对胶磷矿、白云石及石英的浮选影响试验[J].现代矿业, 2013, 29(7):111-113. doi: 10.3969/j.issn.1674-6082.2013.07.038 CrossRef Google Scholar
[20]	王雪, 黎艳, 王晓军, 等.Fe³⁺、Fe²⁺对白云石、高岭土、石英浮选行为的影响研究[J].冶金分析, 2017, 37(2):59-64. Google Scholar
[21]	潘高产.硫化矿浮选体系中滑石的可浮性研究[J].湖南有色金属, 2012, 28(1):9-12. doi: 10.3969/j.issn.1003-5540.2012.01.003 CrossRef Google Scholar
[22]	张其东, 袁致涛, 刘炯天, 等.葡聚糖对辉钼矿与滑石浮选分离的影响[J].中国有色金属学报, 2016, 26(4):884-890. Google Scholar
[23]	Ma X D, Marek P. The effect of lignosulfonates on the floatability of talc[J]. International journal of mineral processing, 2007, 83:19-27. doi: 10.1016/j.minpro.2007.03.007 CrossRef Google Scholar
[24]	刘谷山, 冯其明, 欧乐明, 等.铜离子和镍离子对滑石浮选的影响及作用机理[J].硅酸盐学报, 2005, 33(8):1018-1022. doi: 10.3321/j.issn:0454-5648.2005.08.021 CrossRef Google Scholar
[25]	冯其明, 刘谷山, 喻正军, 等.铁离子和亚铁离子对滑石浮选的影响及作用机理[J].中南大学学报:自然科学版, 2006, 37(3):476-480. Google Scholar
[26]	张其东, 袁致涛, 刘炯天, 等.金属离子对滑石浮选行为的影响及机理研究[J].金属矿山, 2016(4):67-71. doi: 10.3969/j.issn.1001-1250.2016.04.013 CrossRef Google Scholar
[27]	Kor M, Korezyk P M, Addai M J, et al. Carboxymethyl cellulose adsorption on molybdenite:the effect of electrolyte composition on adsorption, bubble-surface collisions, and flotation[J]. Langmuir, 2014, 40:11975-11984. Google Scholar
[28]	Charnay C, Lagerge S, Partyka S. Assessment of the surface heterogeneity of talc materials[J].Journal of colloid and interface science, 2001, 233(2):250-258. doi: 10.1006/jcis.2000.7259 CrossRef Google Scholar
[29]	YAO Xiumin, TAN Shouhong, HUANG Zhengren, et al. Dispersion of talc particles in a silica sol[J]. Materials letters, 2005, 59(1):100-104. doi: 10.1016/j.matlet.2004.09.025 CrossRef Google Scholar
[30]	王淀佐, 胡岳华.氢氧化物表面沉淀在石英浮选中的作用[J].中南矿冶学院学报, 1990(3):248-253. Google Scholar
[31]	D·福马西罗, 王兢, 张覃, 等.Cu(Ⅱ)和Ni(Ⅱ)在石英、蛇纹石和绿泥石浮选中的活化作用[J].国外金属矿选矿, 2006(10):16-20. Google Scholar
[32]	石云良, 邱冠周, 胡岳华, 等.石英浮选中的表面化学反应[J].矿冶工程, 2001(3):43-45, 48. doi: 10.3969/j.issn.0253-6099.2001.03.013 CrossRef Google Scholar
[33]	郭文达, 朱一民, 韩跃新, 等.钙离子对脂肪酸类捕收剂浮选石英的影响机理[J].东北大学学报(自然科学版), 2018, 39(3):409-415. Google Scholar
[34]	James R O, Healy T W J. Adsorption of hydrolyzable metal ions at the oxide-water interface.Ⅰ.Co(Ⅱ) adsorption on SiO₂ and TiO₂ as model systems[J]. Journal of colloid and interface science, 1972, 40(1):42-52. doi: 10.1016/0021-9797(72)90172-5 CrossRef Google Scholar
[35]	欧乐明, 叶家笋, 曾维伟, 等.铁离子和亚铁离子对菱锌矿和石英浮选的影响[J].有色金属(选矿部分), 2012(6):79-82, 88. doi: 10.3969/j.issn.1671-9492.2012.06.018 CrossRef Google Scholar
[36]	吴卫国, 孙传尧, 朱永楷.有机螯合剂对活化石英的抑制及其作用机理[J].金属矿山, 2007(2):33-37. doi: 10.3321/j.issn:1001-1250.2007.02.010 CrossRef Google Scholar
[37]	Jin S, Shi Q, Feng Q, et al. The role of calcium and carbonate ions in the separation of pyrite and talc[J]. Minerals engineering, 2018, 119:205-211. doi: 10.1016/j.mineng.2018.01.016 CrossRef Google Scholar
[38]	Jin S, Shi Q, Li Q, et al. Effect of calcium ionic concentrations on the adsorption of carboxymethyl cellulose onto talc surface:flotation, adsorption and AFM imaging study[J]. Powder technology, 2018, 331:155-161. doi: 10.1016/j.powtec.2018.03.014 CrossRef Google Scholar
[39]	梁冰, 陈楠, 姜利国.盐酸盐溶液中温度对方解石和白云石溶解度的影响[J].水资源与水程学报, 2011, 22(4):21-24. Google Scholar
[40]	李强, 印万忠, 马英强, 等.含镁碳酸盐矿物溶解度模拟计算及对浮选过程的影响[J].东北大学学报(自然科学版), 2011, 32(9):1348-135. Google Scholar
[41]	Luo N, Wei D Z, Shen Y B, et al. Elimination of the adverse effect of calcium ion on the flotation separation of magnesite from dolomite[J]. Minerals 2017, 7:150-156. doi: 10.3390/min7080150 CrossRef Google Scholar
[42]	丁浩.金红石浮选中消除Ca²⁺对石英活化作用的研究[J].矿产保护与利用, 1994(1):40-42. Google Scholar
[43]	谢兴中.褐铁矿与石英正浮选分离及其机理研究[J].矿产保护与利用, 2017(5):38-43. Google Scholar
[44]	孙大翔, 王毓华, 周瑜林.钙离子对铝土矿选择性絮凝的影响及消除的试验研究[J].矿冶工程, 2010(5):34-39. doi: 10.3969/j.issn.0253-6099.2010.05.009 CrossRef Google Scholar
[45]	崔萌萌.菱锌矿与石英浮选分离中难免离子的影响及消除[D].长沙: 中南大学, 2012.http://cdmd.cnki.com.cn/Article/CDMD-10533-1012474128.htm Google Scholar
[46]	伍喜庆, 刘长淼, 黄志华.石英浮选的新型捕收剂——N-十二烷基-β-氨基丙酰胺[J].中南大学学报(自然科学版), 2005(3):412-416. doi: 10.3969/j.issn.1672-7207.2005.03.013 CrossRef Google Scholar