Zhengzhou Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological SciencesHost
2017 Vol. 37, No. 5
Article Contents

ZHENG Kai, XIA Yong, WEN Xiaoying, LIU Qingyou. Development of Concentration and Extraction of Rare Earth from Rare Earth-containing Phosphorite[J]. Conservation and Utilization of Mineral Resources, 2017, (5): 93-98. doi: 10.13779/j.cnki.issn1001-0076.2017.05.019
Citation: ZHENG Kai, XIA Yong, WEN Xiaoying, LIU Qingyou. Development of Concentration and Extraction of Rare Earth from Rare Earth-containing Phosphorite[J]. Conservation and Utilization of Mineral Resources, 2017, (5): 93-98. doi: 10.13779/j.cnki.issn1001-0076.2017.05.019

Development of Concentration and Extraction of Rare Earth from Rare Earth-containing Phosphorite

  • The grade of rare earth in rare earth-containing phosphorite is low in nature, but its reserves are abundant, which offer a high potential for exploitation. Limited to occurrence state of rare earth, crystal structure, and the current scientific and technological level, the industrial recovery of rare earth from phosphorite has not been realized till now. This paper systematically summarized the different methods of concentration and separation of rare earth from phosphorite, and pointed out the bottlenecks that limiting the utilization of rare earth-containing phosphorite resource. Furthermore, the possible technologies for recovery were introduced. The solutions to key issues of concentration and separation will provide more new approaches for the development and utilization of rare earth resource.

  • 加载中
  • [1] 李梅, 柳召刚, 吴锦绣, 等.稀土元素及其分析化学[M].北京:化学工业出版社, 2009.

    Google Scholar

    [2] C. K. Gupta, N. Krishnamurthy. Extractive metallurgy of rare earths[M]. 1st ed. Florida:CRC Press, 2005.

    Google Scholar

    [3] 谢锋斌, 李颖, 陆挺, 等.未来全球稀土供需格局分析[J].中国矿业, 2014(10):5-8. doi: 10.3969/j.issn.1004-4051.2014.10.002

    CrossRef Google Scholar

    [4] 吴素彬, 聂登攀, 王振杰, 等.织金磷矿在盐酸中的酸解工艺研究[J].化工矿物与加工, 2012, 41(7):5-8.

    Google Scholar

    [5] 张培善.中国稀土矿物学[M].北京:科学出版社, 1998.

    Google Scholar

    [6] A. V. Ⅱyin. Phosphorites of the Russian Craton[J]. Earth-Science Reviews, 1998, 45(1-2):89-101.

    Google Scholar

    [7] J. Zhang, C. Edwards. A review of rare earth mineral processing technology[C]//44th Annual Canadian Mineral Processors Operators Conference. Ottawa, 2012:79-102.

    Google Scholar

    [8] 刘家仁.试谈织金磷矿的综合利用问题[J].贵州地质, 1999, 16(3):253-258.

    Google Scholar

    [9] 张新海, 周卫宁.含稀土磷矿石捕收剂研究进展[J].矿产与地质, 2012, 26(2):168-171.

    Google Scholar

    [10] A. V. Slack. Phosphoric acid. Vol I, Part Ⅱ[M]. New York:Marcel Dekker Inc, 1968.

    Google Scholar

    [11] 王华, 洪业汤, 朱咏煊, 等.黄磷生产中的稀土元素分布[J].稀土, 2002, 23(4):25-28.

    Google Scholar

    [12] 李成秀, 文书明.我国磷矿选矿现状及其进展[J].矿产综合利用, 2010(2):22-25.

    Google Scholar

    [13] 王聘仪, 许长连.重介质分选技术在磷矿选矿中的应用前景[J].精细化工中间体, 1990(4):27-29.

    Google Scholar

    [14] 王树林, 黄志良, 刘苗, 等.宜昌磷矿重介质选矿工艺矿物学[J].武汉工程大学学报, 2013, 35(11):27-31. doi: 10.3969/j.issn.1674-2869.2013.11.007

    CrossRef Google Scholar

    [15] 符瑞良, 樊旭东.宜昌磷矿重介质选矿的生产实践[J].化工矿山技术, 1993, 23(2):29-30.

    Google Scholar

    [16] 王聘仪, 许长连.洗溪磷矿重介质选矿研究[J].精细化工中间体, 1990, 19(6):19-21.

    Google Scholar

    [17] 刘盛庚.湖南洗溪磷矿重介质选精矿利用途径的探讨[J].湖南化工, 1994(1):8-12.

    Google Scholar

    [18] 张冬冬, 魏爱斌, 瞿广飞, 等.磷矿脱镁研究进展[J].矿产综合利用, 2015(5):1-7.

    Google Scholar

    [19] 戴惠新, 王春秀, 段希祥.电选在我国磷矿选矿中应用的可能性探讨[J].化工矿物与加工, 2003(2):5-7.

    Google Scholar

    [20] 戴惠新, 段希祥, 王春秀, 等.磷矿的电选试验研究[J].中国矿业, 2003, 12(9):52-54.

    Google Scholar

    [21] 选矿手册编辑委员会. 选矿手册第八卷第五分册[M]. 北京: 冶金工业出版社, 1985.

    Google Scholar

    [22] 张惠琼.金沙厂胶磷矿焙烧-消化-脱泥试验[J].云南冶金, 1990(2):30-33.

    Google Scholar

    [23] 郑其, 张文彬.用焙烧消化工艺处理碳酸盐磷矿[J].矿产综合利用, 1998(3):5-8.

    Google Scholar

    [24] Koopal L K, 顾惕人, 卢寿慈.浮选物理化学原理的某些进展[J].化学通报, 1995(10):19-24.

    Google Scholar

    [25] S. M. Bulatovic. Handbook of flotation reagents:Chemistry, theory and practice[M]. Amsterdam:Elsevier Science, 2015:1-19.

    Google Scholar

    [26] 杨隽峰, 高丽红.磷矿浮选工艺技术特点探讨[J].化学工程与装备, 2015(4):50-51.

    Google Scholar

    [27] 张覃, 张杰, 陈肖虎, 等.贵州织金含稀土磷矿石选别工艺的选择[J].金属矿山, 2003(3):23-25.

    Google Scholar

    [28] 张小敏, 沈静, 辜国杰, 等.含稀土磷块岩选矿工艺研究[J].化工矿物与加工, 2004(11):12-13. doi: 10.3969/j.issn.1008-7524.2004.11.004

    CrossRef Google Scholar

    [29] 李军旗, 路坊海, 毛小浩, 等.织金中低品位磷矿石反浮选工艺的探索[J].贵州工业大学学报, 2006, 35(1):1-3.

    Google Scholar

    [30] 金会心, 王华, 李军旗, 等.新华含稀土磷矿浮选实验研究[J].过程工程学报, 2008, 8(3):453-459.

    Google Scholar

    [31] 李军旗, 李轶轁, 曾从江, 等.贵州织金中低品位磷矿浮选试验研究[J].矿业研究与开发, 2010, 30(5):45-49.

    Google Scholar

    [32] 刘安荣, 聂登攀, 赵伟毅, 等.织金含稀土磷矿石反浮选试验研究[J].金属矿山, 2012(4):83-85.

    Google Scholar

    [33] G. Kongshaug, B. A. Brentnall, K. Chaney, et al. Ullamann's encyclopedia of industrial chemistry:Phosphate fertilizers[M]. Verlagsgesellschaft, Weinheim, Germany, 1991:425-427.

    Google Scholar

    [34] A. V. Slack. Phosphoric Acid. Vol I, Part Ⅱ[M]. New York:Marcel Dekker Inc, 1968.

    Google Scholar

    [35] P. Becker. Phosphates and phosphoric acid:raw materials, technology, and economics of the wet process[M]. New York:Marcel Dekker, 1983.

    Google Scholar

    [36] 李秀芹, 袁凤英, 杨位红, 等.从磷石膏中提取稀土的研究现状[J].磷肥与复肥, 2014(1):63-65.

    Google Scholar

    [37] 鲁毅强, 杨启山, 杨武成, 等. 一种以磷块岩矿为原料湿法制取磷酸及从中提取稀土的工艺方法: 200710179749. 7[P]. 2008-05-28.

    Google Scholar

    [38] A. Jarosinski, J. Kowalczyk, C. Mazanek. Development of the polish wasteless technology of apatite phosphogypsum utilization with recovery of rare earth[J]. Journal of Alloys and Compounds, 1993, 200(1-2):147-150.

    Google Scholar

    [39] 殷宪国. 从磷石膏中提取稀土的方法: 200710053196. 0[P]. 2009-03-18.

    Google Scholar

    [40] I. Kulawik, J. Kulawik, C. Mazanek. Extraction method of lanthanides recovery from solution after phosphogypsum lixiviation with sulphuric and nitric acid[M]. Monografia, 1988:44-74.

    Google Scholar

    [41] J. S. Preston, P. M. Cole, W. M. Craig, et al. The recovery of rare earth oxides from a phosphoric acid byproduct[J]. Hydrometallurgy, 1996, 41(1):1-19.

    Google Scholar

    [42] 杨启山, 殷宪国. 从磷石膏浸取液结晶出的硫酸稀土转化为氯化稀土的方法: 200810068761. 5[P]. 2009-12-09.

    Google Scholar

    [43] E. P. Lokshin, J. A. Vershkova, V. T. Kalinnikov, et al. Method of recovering rare earth minerals from phoshogypsum:RU2225892[P]. 2004-05-18.

    Google Scholar

    [44] 袁凤英, 李秀芹, 杨位红, 等.磷矿湿法生产中伴生稀土回收研究进展[J].山东化工, 2013, 42(10):62-63.

    Google Scholar

    [45] M. Krea, H. Khalaf. Liquid-liquid extraction of uranium and lanthanides from phosphoric acid using a synergistic DOPPA-TOPO mixture[J]. Hydrometallurgy, 2000(58):215-225.

    Google Scholar

    [46] 王良士, 彭新林, 李明来, 等.磷酸体系中微量稀土元素萃取动力学研究[J].中国稀土学报, 2009, 27(6):812-815.

    Google Scholar

    [47] 龙志奇, 王良士, 黄小卫, 等. 一种从硫酸处理磷矿过程中提取稀土的工艺: 200910078794. 2[P]. 2010-09-08.

    Google Scholar

    [48] 范文娟, 党亚固, 刘勇.乳化液膜法萃取湿法磷酸中的稀土镧[J].四川化工, 2011, 14(2):7-10.

    Google Scholar

    [49] S. Radhika, K. B. Nagaphani, M. L. Kantam. Slovent extraction and separation of rare-earths from phosphoricacid solutions with TOPS 99[J]. Hydrometallurgy, 2011, 110(1):50-55.

    Google Scholar

    [50] C. Koopman, G. J. Witkamp. Extraction of lanthanides from the phosphoric acid production process to gain purified gypsum and a valuable lanthanide by-product[J]. Hydrometallurgy, 2000, 58(1):51-60.

    Google Scholar

    [51] B. N. Kumar, S. Ramachandra, B. R. Reddy. Solid-liquid extraction of heavy rare-earths from phosphoric acid solutions using Tulsion CH-96 and T-PAR resins[J]. Chemical Engineering Journal, 2010, 160(1):138-144.

    Google Scholar

  • 加载中
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Tables(4)

Article Metrics

Article views(1153) PDF downloads(57) Cited by(0)

Access History

Other Articles By Authors

Catalog

    /

    DownLoad:  Full-Size Img  PowerPoint