Determination of 33 pesticides residues in soil by QuEChERS-GC-MS/MS

MA Jian-sheng; ZHANG Ze-yu; LI Li-jun; ZHAO Xue-juan

doi:10.13686/j.cnki.dzyzy.2025.01.014

2025 Vol. 34, No. 1

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Article navigation > Geology and Resources > 2025 > 34(1): 128-136

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MA Jian-sheng, ZHANG Ze-yu, LI Li-jun, ZHAO Xue-juan. Determination of 33 pesticides residues in soil by QuEChERS-GC-MS/MS[J]. Geology and Resources, 2025, 34(1): 128-136. doi: 10.13686/j.cnki.dzyzy.2025.01.014

Citation:

MA Jian-sheng, ZHANG Ze-yu, LI Li-jun, ZHAO Xue-juan. Determination of 33 pesticides residues in soil by QuEChERS-GC-MS/MS[J]. Geology and Resources, 2025, 34(1): 128-136. doi: 10.13686/j.cnki.dzyzy.2025.01.014

Determination of 33 pesticides residues in soil by QuEChERS-GC-MS/MS

1.
Shenyang Center of China Geological Survey, Shenyang 110034, China
2.
Key Laboratory of Black Soil Evolution and Ecological Effect, Ministry of Natural Resources, Shenyang 110034, China

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Corresponding author: ZHAO Xue-juan, wkykjyhl@163.com

Received Date: 03 July 2023

Revised Date: 07 September 2023

Publish Date: 25 February 2025

Abstract

Abstract

The QuEChERS method is optimized to extract pesticide residues from frozen-drying soil samples, including 24 organochlorine pesticides (OCPs) and 8 organophosphorus pesticides (OPPs) as well as atrazine. An approach to simultaneous determination of 33 pesticide residues in soil is established by combining with gas chromatography-tandem mass spectrometry (GC-MS/MS). The results show that the concentration of 33 pesticide residues is 5.0-100 μg/L, in good linearity, with method limit of detection (LOD) 0.09×10^-9-0.52×10^-9, limit of quantitation (LOQ) 0.30×10^-9-1.71×10^-9, relative standard deviation (RSD) of precision 3.7%-17.2%, and recovery 51.6%-118.8%. The method is simple and rapid, characterized by high recovery and sensitivity, and strong resistance to matrix interference, which is suitable for trace analysis and detection of OCPs and OPPs in soil.
- soil /
- pesticide residue /
- tandem mass spectrometry /
- QuEChERS /
- chemical analysis

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References

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