Citation: | MA Zhixin, LUO Maojin, SHI Hongliang, HUANG Teng, SUN Zhiming. Geological characteristics and genesis of crystalline graphite deposits in the North margin of Upper Yangtze Block[J]. Geological Bulletin of China, 2022, 41(5): 857-872. doi: 10.12097/j.issn.1671-2552.2022.05.011 |
Graphite ore is a kind of important national strategic protection resource.In order to deepen the understanding of the genesis of crystalline graphite ore in the northern margin of the Upper Yangtze Block, the ore-bearing strata, ore body characteristics, ore structure and ore geochemical characteristics of many graphite deposits in the area have been studied.It was found that graphite ore was mainly distributed in the Nanjiang-Wangcang area of Sichuan, forming a graphite mineralization zone extending about 60 km from the northeast-southwest direction, and graphite ore has a tendency to increase the thickness of the ore body and the degree of crystallinity in this direction.The main and trace element proxies (SiO2, Al2O3, V/Cr, Ni/Co, etc.) reflect the formation of the ore-bearing rock series in a relatively limited, oxygen-deficient shallow carbonate platform environment.This environment is conducive to the preservation of carbon, which provide material sources for graphite ore formation.The δ13C of graphite ore is between -24.9‰ and -14.2‰, which overlaps the distribution range of δ13C of organic matter, indicating that the carbon of graphite ore comes from biological organic matter.The surrounding rock of the graphite mine contains characteristic metamorphic minerals such as sericite, biotite, garnet, andalusite, indicating that it is a set of low-green schist facies shallow metamorphic rocks.The fixed carbon content in the contact part of the magmatic rock and the graphite ore increases significantly and is accompanied by the increase of the scale structure, indicating that the thermal contact metamorphism of the rock mass promotes the further enrichment of the graphite ore.A three-stage metallogenic model of graphite deposits in the study area is initially proposed, inclunding the Mesoproterozoic primary carbonaceous sedimentation enrichment stage, Mesoproterozoic to Neoproterozoic regional metamorphic graphite nucleation stage, and Neoproterozoic rock mass thermal metamorphic crystal growth and mineralization stage.This study will provide basic materials for in-depth understanding of the formation mechanism of graphite ore in the study area and the genesis of China's crystalline graphite ore.
[1] | 赵汀, 王安建, 刘超. 基于国情调查大数据的矿产资源保障程度动态分析系统设计与实现[J]. 地质通报, 2020, 39(2) : 400-405. |
[2] | 莫如爵, 刘绍斌, 黄翠蓉, 等. 中国石墨矿床地质[M]. 北京: 中国建筑工业出版社, 1989. |
[3] | 颜玲亚, 高树学, 陈正国, 等. 中国石墨矿成矿特征及成矿区带划分[J]. 中国地质, 2018, 45(3) : 421-440. |
[4] | 肖克炎, 邢树文, 丁建华, 等. 全国重要固体矿产重点成矿区带划分与资源潜力特征[J]. 地质学报, 2016, 90(7) : 1269-1280. doi: 10.3969/j.issn.0001-5717.2016.07.002 |
[5] | Duan L A, Wei Y F, Liu Q Y, et al. Discovery of the Dahongshan ultra- large crystalline graphite deposit, Urad Zhongqi of Inner Mongolia, China[J]. China Geology, 2020, 3(1) : 182-183. doi: 10.31035/cg2020019 |
[6] | 程林, 杨勇, 边敏, 等. 黄陵断穹核部鳞片石墨矿地球化学特征与成因研究[J]. 地质与勘探, 2020, 56(4) : 745-758. |
[7] | 王红军, 侯学文, 岑海涛, 等. 四川省南江县庙坪石墨矿成矿地质特征及成因探讨[J]. 科技创新导报, 2017, (6) : 45-46. |
[8] | 夏锦胜, 孙莉, 肖克炎. 四川南江尖山石墨矿床地质特征及成因[J]. 地质学刊, 2017, 41(2) : 212-217. doi: 10.3969/j.issn.1674-3636.2017.02.007 |
[9] | 夏锦胜, 孙莉, 肖克炎, 等. 四川省南江县坪河石墨矿床地质特征及成因分析[J]. 现代矿业, 2017, (2) : 57-61. doi: 10.3969/j.issn.1674-6082.2017.02.015 |
[10] | 段威, 唐文春, 熊观, 等. 川北旺苍—南江石墨矿带地质特征与找矿潜力[J]. 矿产勘查, 2021, 12(2) : 240-246. doi: 10.3969/j.issn.1674-7801.2021.02.007 |
[11] | 张国伟. 秦岭造山带的形成及其演化[M]. 西安: 西北大学出版社, 1988. |
[12] | 杜思清, 魏显贵, 刘援朝, 等. 汉南-米仓山区叠加东西向隆坳的北东向推覆构造[J]. 成都理工大学学报(自科版), 1998, 25(3) : 367-374. |
[13] | 肖安成, 魏国齐, 沈中延, 等. 扬子地块与南秦岭造山带的盆山系统与构造耦合[J]. 岩石学报, 2011, 27(3) : 601-611. |
[14] | 孙东. 米仓山构造带构造特征及中—新生代构造演化[D]. 成都理工大学博士学位论文, 2011. |
[15] | 魏显贵, 杜思清, 何政伟, 等. 米仓山地区构造演化[J]. 矿物岩石, 1997, 17(增刊) : 107-113. |
[16] | 魏显贵, 杜思清, 刘援朝, 等. 米仓山推覆构造的结构样式及演化特征[J]. 矿物岩石, 1997, 17(增刊) : 114-122. |
[17] | 肖渊甫, 马润则, 何政伟, 等. 米仓山碱性杂岩单元特征及构造环境分析[J]. 矿物岩石, 1997, 17(s1) : 62-69. |
[18] | 何利. 川北坪河碱性杂岩体特征及其构造背景[D]. 成都理工大学硕士学位论文, 2010. |
[19] | 甘保平, 赖绍聪, 秦江锋. 米仓山坪河新元古代二长花岗岩成因及其地质意义[J]. 地质论评, 2016, 62(4) : 929-935. |
[20] | 何政伟, 魏显贵, 刘援朝, 等. 米仓山西缘变质杂岩地质和岩石地球化学特征[J]. 矿物岩石, 1996, 16(4) : 23-31. |
[21] | 何政伟, 魏显贵, 吴德超, 等. 南米仓山火地垭群岩石地球化学特征及时代探讨[J]. 四川地质学报, 1996, 17(1) : 8-17. |
[22] | 徐学义, 李婷, 陈隽璐, 等. 扬子地台北缘檬子地区侵入岩年代格架和岩石成因研究[J]. 岩石学报, 2011, 27(3) : 699-720. |
[23] | 曹俊臣, 冉红彦. 中国非金属超大型矿床分布规律及成矿地质特征[J]. 地质与勘探, 1996, 32(4) : 1-8. |
[24] | Zong K, Klemd R, Yuan Y, et al. The assembly of Rodinia: The correlation of early Neoproterozoic (ca. 900Ma) high-grade metamorphism and continental arc formation in the southern Beishan Orogen, southern Central Asian Orogenic Belt (CAOB)[J]. Precambrian Research, 2017, 290: 32-48. doi: 10.1016/j.precamres.2016.12.010 |
[25] | Hu Z, Zhang W, Liu Y, et al. A novel "wave" signal smoothing and mercury removing device for laser ablation quadrupole and multiple collector ICP-MS analysis: application to lead isotope analysis[J]. Analytical Chemistry, 2015, 87(2) : 1152-1157. doi: 10.1021/ac503749k |
[26] | 刘汉彬, 金贵善, 李军杰, 等. 铀矿地质样品的稳定同位素组成测试方法[J]. 世界核地质科学, 2013, 30(3) : 174-179. doi: 10.3969/j.issn.1672-0636.2013.03.009 |
[27] | Jones B, Manning D A. Comparison of geochemical indices used for the interpretation of palaeoredox conditions in ancient mudstones[J]. Chemical Geology, 1994, 111(1/4) : 111-129. |
[28] | 马志鑫, 罗茂金, 刘喜停, 等. 四川南江坪河石墨矿炭质来源及成矿机制[J]. 地质科技情报, 2018, 37(3) : 134-139. |
[29] | Fuex A N, Baker D R. Stable carbon isotopes in selected granitic, mafic, and ultramafic igneous rocks[J]. Geochimica et Cosmochimica Acta, 1973, 37(11) : 2509-2521. doi: 10.1016/0016-7037(73)90295-0 |
[30] | Eckelmann W R, Wallace S. Implications of Carbon Isotopic Composition of Total Organic Carbon of Some Recent Sediments and Ancient Oils: Geological Notes[J]. American Association of Petroleum Geologists Bulletin, 1962, 46: 699-704. |
[31] | 何政伟, 魏显贵, 刘援朝, 等. 扬子克拉通北缘米仓山地区前震旦纪变质作用特征[J]. 地质通报, 1999, 18(1) : 34-38. doi: 10.3969/j.issn.1671-2552.1999.01.006 |
[32] | 刘登忠, 魏显贵, 杜思清, 等. 米仓山西段地质研究新进展[J]. 矿物岩石, 1997, 17(s1) : 4-11. |
[33] | 黄伯钧, Buseck P R. 变质岩中碳质物质的石墨化作用[J]. 矿物学报, 1986, 6(4) : 64-67, 102. |
[34] | 刘敬党, 肖荣阁, 张艳飞, 等. 华北显晶质石墨矿床[M]. 北京: 科学出版社, 2017. |
[35] | 姜高珍, 李以科, 王安建, 等. 内蒙古乌拉特中旗大乌淀石墨矿成因特征分析[J]. 地学前缘, 2017, 24(5) : 306-316. |
[36] | 裴利庭, 李立民, 王淑芬, 等. 中深层次韧性变形带中同构造脉及形成刍议——以马达加斯加国安巴希塔石墨矿区为例[J]. 河北地质, 2016, (4) : 6-10. |
[37] | 吴正伟, 姚立. 冀东龙关石墨矿区的韧性剪切带及其控矿机理[J]. 中国非金属矿工业导刊, 2008, (5) : 51-54. doi: 10.3969/j.issn.1007-9386.2008.05.017 |
[38] | 师洪亮. 四川省米仓山地区石墨矿矿床成因与成矿规律研究[D]. 成都理工大学硕士学位论文, 2018. |
[39] | 李婷. 扬子陆块北缘碑坝—西乡地区新元古代构造-岩浆作用研究[D]. 长安大学硕士学位论文, 2010. |
[40] | 段少帅, 焦建刚, 罗德智, 等. 南秦岭石泉北部将军河地区中酸性岩脉锆石U-Pb年代学及其构造意义[J]. 地质学报, 2017, 91(4) : 748-761. doi: 10.3969/j.issn.0001-5717.2017.04.004 |
[41] | 赵凤清, 赵文平, 左义成, 等. 陕南汉中地区新元古代岩浆岩U-Pb年代学[J]. 地质通报, 2006, 25(3) : 383-388. doi: 10.3969/j.issn.1671-2552.2006.03.007 |
[42] | 凌文黎, 高山, 程建萍, 等. 扬子陆核与陆缘新元古代岩浆事件对比及其构造意义——来自黄陵和汉南侵入杂岩LA-ICPMS锆石U-Pb同位素年代学的约束[J]. 岩石学报, 2006, 22(2) : 387-396. |
[43] | 张宏飞, 骆庭川, 张本仁, 等. 扬子克拉通北缘新元古代岛弧花岗岩类成分极性及成因的地球化学探讨[J]. 地球科学, 1994, 19(2) : 93-100. |
[44] | Dong Y P, Liu X M, Santosh M, et al. Neoproterozoic accretionary tectonics along the northwestern margin of the Yangtze Block, China: Constraints from zircon U-Pb geochronology and geochemistry[J]. Precambrian Research, 2012, 196/197(1) : 247-274. |
[45] | 凌文黎, 高山. 扬子克拉通北缘早前寒武纪地壳演化——后河杂岩元素和同位素地球化学限制[J]. 矿物岩石, 1997, 17(4) : 26-32. |
[46] | 赖绍聪, 李三忠, 张国伟. 陕西西乡群火山-沉积岩系形成构造环境: 火山岩地球化学约束[J]. 岩石学报, 2003, 19(1) : 141-152. |
[47] | Zhao J H, Li Q W, Liu H, et al. Neoproterozoic magmatism in the western and northern margins of the Yangtze Block (South China) controlled by slab subduction and subduction-transform-edge-propagator[J]. Earth-Science Reviews, 2018, 187: 1-18. doi: 10.1016/j.earscirev.2018.10.004 |
[48] | 刘伟, 杨晓勇, 马志鑫, 等. 扬子陆块北缘上两地区二长花岗岩成因: 锆石U-Pb年代学、Hf同位素及地球化学制约[J]. 地质学报, 2018, 92(1) : 65-76. |
[49] | 夏锦胜. 四川省南江县石墨矿床地质地球化学特征及成因[J]. 中国地质大学(北京) 硕士学位论文, 2018. |
[50] | 何政伟, 刘援朝, 魏显贵, 等. 扬子克拉通北缘米仓山地区基底变质岩系同位素地质年代学[J]. 矿物岩石, 1997, (s1) : 86-90. |
[51] | 高显忠. 南江县尖山石墨矿地质特征及成因浅析[J]. 四川地质学报, 2015, 35(增刊) : 19-22. |
[52] | 李焕同, 莫佳峰, 武玉良, 等. 湖南新化地区煤变形变质与构造环境特征[J]. 煤田地质与勘探, 2017, 45(4) : 7-12, 18. |
[53] | 董业绩, 曹代勇, 王路, 等. 地质勘查阶段煤系石墨与无烟煤的划分指标探究[J]. 煤田地质与勘探, 2018, 46(1) : 8-12. |
① | 国土资源部. 全国矿产资源储量通报(2015年). 2015. |
② | 自然资源部. 中国矿产资源报告(2019年). 2019. |
③ | 陕西省地质调查院. 1: 250000南江市幅(I48C004004) 区域地质调查报告. 2008. |
Regional geological and graphite ore distribution in North margin of Upper Yangtze Block
Schematic map of graphite ore body distribution in North margin of Upper Yangtze Block
Microscopic laser Raman spectrum characteristics of graphite ore
CL images of ziron from Neoproterozoic granodiorite samples in Liuwan area
Carbon isotope composition of graphite ore and surrounding rock and related materials
Characteristics of shear lens in graphite ore
Zircon U-Pb age chart of Neoproterozoic syenite samples in Liuwan area
Schematic plot of graphite mineralization model in the North margin of Upper Yangtze Block