Citation: | ZHOU Yinzhu, MA Tao, YUAN Lei, LI Fucheng, HAN Shuangbao, ZHOU Jinlong, LI Yong. 2024. Hydrochemistry−isotope characteristics and quality assessment of groundwater in the Beiluo River Basin, Shaanxi Province[J]. Geology in China, 51(2): 663-675. doi: 10.12029/gc20220401003 |
This paper is the result of hydrogeological survey engineering.
The Beiluo River Basin is an important secondary tributary of the Yellow River. Research on groundwater quality in typical tributary basin of theYellow River is of significant for ecological protection and high−quality development. To ensure local drinking water safety, we systematically identified status of groundwater quality and delineated inferior groundwater region in the Beiluo River Basin.
Besides, based on analysis of D−18O isotope in groundwater, characteristics and evolution mechanism of groundwater hydrochemistry were studied and effects of hydrogeological condition and anthropogenic activities on groundwater hydrochemistry were revealed.
Groundwater hydrochemical composition was jointly affected by rock weathering and evaporation concentration, part of which was influenced by anthropogenic activities. D−18O isotope composition suggested that evaporation concentration is the major influence factor of groundwater hydrogeochemistry.
Leaching of soluble minerals such as gypsum halite in clasolite and evaporation concentration of pore water in Cenozoic faulted basin in the downstream caused salt accumulation and high TDS in groundwater in the upstream and downstream, respectively. Hydrochemical composition of groundwater in Ordovician karst aquifer and Cenozoic faulted basin aquifer was mainly controlled by evaporites and anthropogenic activities. While hydrochemical composition in Cretaceous aquifer and Carboniferous−Jurassic aquifer was mainly controlled by rock weathering (especially silicate rocks and evaporite) and less affected by anthropogenic activities. Moreover, groundwater in the upstream and downstream was significantly affected by industrial and mining activities. While groundwater in the midstream is of good quality due to less influence of industrial/mining activities, agricultural activities and domestic wastewater.
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Location of the study area and distribution of sampling points
Hydrogeological profile of the study area
Piper trilinear diagram of groundwater in different aquifer groups
Piper trilinear diagram of typical ground water samples along the hydrogeological profile
Box plot of TDS(a), pH (b), Fe (c), γNa/γCl(d), 100×γSO4/γCl(e) and γ(Cl−Na)/γMg(f) of typical groundwater samples along the hydrogeological profile
Isotope composition of D and18O of surface water, spring water and groundwater in different aquifer groups
Quality evaluation of shallow (a) and deep (b) groundwater in the Beiluo River Basin
Gibbs diagram of groundwater in different aquifer groups
Correlation between γCa2+/γNa+,γMg2+/γNa+ and γHCO3−/γNa+of groundwater in different aquifer groups
Correlation between γSO42−/γCa2+ and γNO3−/γCa2+of groundwater in different aquifer groups