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2023 Vol. 50, No. 5
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Article navigation > Geology in China > 2023 > 50(5): 1446-1459
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LI Hui, QIAN Yong, HAN Zhantao, KONG Xiangke, ZHANG Wei, MA Lisha, ZHANG Xianfu, TIAN Xia. 2023. Natural attenuation monitoring of 1,2,3-trichloropropane and benzene in the groundwater of organic pollution sites, Tianjin chemical plant and its environmental restoration suggestions[J]. Geology in China, 50(5): 1446-1459. doi: 10.12029/gc20220302001
Citation: LI Hui, QIAN Yong, HAN Zhantao, KONG Xiangke, ZHANG Wei, MA Lisha, ZHANG Xianfu, TIAN Xia. 2023. Natural attenuation monitoring of 1,2,3-trichloropropane and benzene in the groundwater of organic pollution sites, Tianjin chemical plant and its environmental restoration suggestions[J]. Geology in China, 50(5): 1446-1459. doi: 10.12029/gc20220302001
shu

Natural attenuation monitoring of 1,2,3-trichloropropane and benzene in the groundwater of organic pollution sites, Tianjin chemical plant and its environmental restoration suggestions

  • 1.

    Institute of Hydrogeology and Environmental Geology, Chinese Academy of Geological Sciences, Shijiazhuang 050061, Hebei, China

  • 2.

    Key Laboratory of Groundwater Contamination and Remediation of Hebei Province and China Geological Survey, Shijiazhuang 050061, Hebei, China

  • 3.

    Technical Centre for Soil, Agriculture and Rural Ecology and Environment, Ministry of Ecology and Environment, Beijing 100012, China

  • 4.

    Hebei Geology University, Shijiazhuang 050061, Hebei, China

    • Fund Project: Supported by the Open Project of Hebei Province Collaborative innovation center for sustainable utilization of water resources and optimization of industrial structure (No.XTZX202108) and the project of China Geological Survey (No. 12120113102700)
More Information
  • Author Bio: LI Hui, female, bore in 1986, associate researcher, engaged in the control and remediation of contaminated site; E-mail: lihui.107@163.com
  • Corresponding author: QIAN Yong, male, born in 1980, senior engineer, engaged in water resources and water environment; E-mail: desertqy@163.com 
Received Date:  02 March 2022
Revised Date:  23 May 2022
Publish Date:  25 October 2023
    Abstract

  • This paper is the result of environmental geological survey engineering.

     Objective

    Organic pollutants, such as chlorinated hydrocarbons and BTEX, have an important threat to groundwater environment in China. Natural attenuation monitoring plays an important role in contaminated sites remediation. Researches on natural attenuation monitoring will be conductive to promoting the development of groundwater organic pollution control and environmental remediation technologies.

     Methods

    In order to study the natural attenuation of 1,2,3-trichloropropane (TCP) and benzene in different aquifers groundwater, the 3-year monitoring data of TCP, benzene, oxidation reduction potential (ORP), nitrate (NO3-) and biodiversity in an organic contaminated site has been collected and analyzed. Natural attenuation capacity of the pollution source area of the site was calculated using first order attenuation kinetic equation.

     Results

    The results show that the natural attenuation of TCP and benzene occurred in the aquifer for different degrees, and ORP values of the groundwater in phreatic and confined aquifer were -225~-57 mV and -182~-3 mV, respectively, which were medium-high reducing environment with basic environmental conditions for anaerobic biodegradation of organic pollutants. Moreover, the effect of microbial degradation was stronger in the pollution source area and phreatic aquifer than that in non-pollution source area and confined aquifer, and the degradation rates of TCP and benzene in the phreatic aquifer of MMW02 monitoring well were 80.00% and 77.88%, respectively. The attenuation rate of TCP and benzene were 0.0018 d-1 and 0.0016 d-1 in phreatic aquifer, and 0.001 d-1 and 0.0015 d-1 in confined aquifer.

     Conclusions

    According to the different degree of groundwater pollution, the natural attenuation monitoring technology can be used alone or combined with other remediation methods and technologies, which is a low cost and high efficiency method to reduce groundwater organic pollution for this kind of industrial contaminated sites.
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