2020 Vol. 47, No. 2
Article Contents

PAN Chunrong, MOU Ping, ZHONG Fujun, HUANG Guangwen, LI Haidong, PAN Jiayong. 2020. Genesis of chlorite in the Huangsha uranium deposit, middle part of Nanling Mountains and its relationship with uranium mineralization[J]. Geology in China, 47(2): 348-361. doi: 10.12029/gc20200206
Citation: PAN Chunrong, MOU Ping, ZHONG Fujun, HUANG Guangwen, LI Haidong, PAN Jiayong. 2020. Genesis of chlorite in the Huangsha uranium deposit, middle part of Nanling Mountains and its relationship with uranium mineralization[J]. Geology in China, 47(2): 348-361. doi: 10.12029/gc20200206

Genesis of chlorite in the Huangsha uranium deposit, middle part of Nanling Mountains and its relationship with uranium mineralization

    Fund Project: Supported by China Geological Survey Program (No. 1212011085395), National Nature Science Fund of China(No. U1403292) and the Innovation Project for Graduate Students of Jiangxi Province (No. YC2016-B074)
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  • Author Bio: PAN Chunrong, female, born in 1992, master candidate, mainly engages in the study of uranium geology; E-mail: 184799613@qq.com
  • Corresponding author: PAN Jiayong, male, born in 1967, professor, mainly engages in the teaching and study of uranium geology; E-mail: jypan@ecit.cn
  • Chloritization is a type of hydrothermal alteration widely developed in the Huangsha uranium deposit in the middle part of the Nanling Mountains. Based on petrographic studies, the authors investigated the types and morphological characteristics of chlorite minerals in No. 221 and No. 223 uranium deposits by using electron microprobe analysis, and classified chemical types of chlorite. Four kinds of chlorite production status were recognized, and the temperature and environment of the formation of chlorite as well as the relationship between chlorite formation and uranium mineralization was discussed. The results are as follows:(1) The early chlorite was mainly of biotite pseudomorph or starlike shape characterized by mass output, and the metallogenic chlorite was mainly produced in the vein. (2) There are four types of genesis i.e., chlorite biotite alteration, feldspar alteration, fracture filling type and uranium deposit association. (3) The chlorite-forming temperature was 200-310℃, and the average formation temperature of chlorite coexisting with uranium minerals was 215℃, suggesting a middle-low temperature hydrothermal deposit. (4) Chlorite was mainly formed in a reductive environment, and the formation mechanism was dissolution-precipitation and dissolutionmigration-precipitation.

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  • Ai Yongfu, Liu Guoping. 1998. The study chlorite at Dajing deposit in Inner-Mogolia of China[J]. Acta Scientiarum Naturalium Universititas Pekinensis(Natural Sinence Edition), 34(1):97-105(in Chinese with English abstract).

    Google Scholar

    Battaglia.1999. Applying X-ray diffraction geothermometer to chlorite[J].Clays and Clay Minerals, 47(1):54-63.

    Google Scholar

    Bevins R E, Robinson D, Rowbotham G. 1991. Compositional variations in mafic phyllosilicates from regional low-grade metabasites and application of the chlorite geothermometer[J]. Journal Metamorphic Geology, 9:711-721.

    Google Scholar

    Bryndzia L T, Steven D S. 1987. The composition of chlorite as a function of sulfur and oxygen fugacity:An experimental study[J]. American Journal of Science, 287:50-76.

    Google Scholar

    Cathelineau M.1988. Catio site occupancy in chlorites and illite as a function of temperature[J]. Clay Minerals, 23:471-485. doi: 10.1180/claymin.1988.023.4.13

    CrossRef Google Scholar

    Cathelineau M, Nieva D. 1985. A chlorite solid solution geothermometer:The LosAzufres(Mexico) geothermal system[J]. Contribution to Mineralogy and Petrology, 91:235-244. doi: 10.1007/BF00413350

    CrossRef Google Scholar

    Chen Qiping. 2010. Discussion on the relationship between uranium mineralization belt sodium metasomatism and uranium mineralization in the north margin of North Qilian, Gansu[J]. Gansu Science and Technology, 26(17):33-36(in Chinese with English abstract).

    Google Scholar

    Cheng Huahan, Ma Hanfeng, Xiang Weidong. 2000. Study on changes of existing state of uranium during alkalic metasomatism using Fission-Track method[J]. Uranium Geology, 16(5):291-296(in Chinese with English abstract).

    Google Scholar

    Decaritat P, Hutchion I, Walshe J L. 1993. Chlorite geothememetry:A review[J]. Clays and Clay Minerals, 40:470-479.

    Google Scholar

    Deer W A, Howie R A, Iussman J. 1962. Rock-Forming Minerals:Sheet Silicates[M]. London:Longman, 270.

    Google Scholar

    Du L T. 1982. Granite Type Uranium Deposit Collection[M]. Beijing:Atomic Energy Press.

    Google Scholar

    Fang Qinghao, Feng Junchu, He Lingyi. 1987. The s-type granite suite in Darongahan Guangxi provinde[J]. Acta Petrologica Sinica, (3):23-34, 100 (in Chinese with English abstract).

    Google Scholar

    Foster M D. 1962. Interpretation of the composition and classification for the chlorite[J]. US Geology Survey Prof Paper, 414A:33.

    Google Scholar

    Fu Jianming, Ma Changqian, Xie Caifu, Zhang Yeming, Peng Sunbo. 2004. Zircon SHRIMP dating of the Cailing granite on the eastern margin of the Qitianling granite, Hunan South China, and its significance[J].Geology in China, 31(1):96-100(in Chinese with English abstract).

    Google Scholar

    Guo Guolin, Liu Chengdong, Pan Jiayong, Zhang Zhanshi, Li Xingbin. 2012. Character of chlorite and its relationship to uranium mineralization in uranium deposit No.302[J]. Uranium Geology, 28(1):35-41(in Chinese with English abstract).

    Google Scholar

    Hiller S, Velde B.1991.Octahedral occupancy and the chemical composition of diagenetic (low-temperature) chlorite[J]. Clay Minerals, 26:149-168.

    Google Scholar

    Hu Shouxi, Zhou Shunxi, Ren Qijiang, Sun Mingzhi. 1982. Theoretical basis of alkali metasomatic metallogenic model and its metallogenic mechanism[J]. Geology and Exploration, (1):1-6(in Chinese with English abstract).

    Google Scholar

    Hua Rengming, Li Xiaofeng, Zhang Kaiping, Ji Junfeng, Zhang Wenlan. 2003. Characteristics of clay Minerals derived from hydrothermal alteration in Jinshan gold deposit:Implication for the environment of water-rock interaction[J]. Acta Mineralogica Sinica.23(1):23-30(in Chinese with English abstract).

    Google Scholar

    Huang Guolong, Wu Lieqing, Deng Ping, Zhu Ba, Zhang Yanchun. 2006. Analysis of geological setting of uranium mineralization in Jiuquling area, Hunan[J].Uranium Geology, 22(5):267-275 + 280(in Chinese with English abstract).

    Google Scholar

    Inoue A. 1995. Formation of clay minerals in hydrothermal environments[C]//Veide Origin and Mineralogy of Clays. Berlin: Springer, 268-30.

    Google Scholar

    Laird J.1998. Chlorites: Metamorphic petrology[C]//Bailey S W.Hydrous Phyllosilicattes. Reviews in Mineralogy, 9: 405-453.

    Google Scholar

    Li Jinyi.2009. Cycles and Stages of Geological History of China Mainland[J]. Geology in China, 36(3):504-527(in Chinese with English abstract).

    Google Scholar

    Li Renze, Liu Chengdong, Liangliang, Kong Ming, Wan Bing, Wan Jianjun. 2016. Characteristics and geological significance of chlorite from the Dafushang eranium deposit in Taoshan area, Jiangxi Province[J]. Acta Petrologica et Mineralogica, 27(2):297-305(in Chinese with English abstract).

    Google Scholar

    Li Xiaofeng, Hua Renming, Ji Junfeng, Lu Jianjun, Liu Shengxiangxian, Liu Lianwen. 2002. Origin of illite and its relation with ore-forming fluids in yinshan polymetallic deposit, Dexing, Jiangxi Province[J]. Chinese Journal of Geology, 37(1):86-95(in Chinese with English abstract).

    Google Scholar

    Liu Yingjun, Cao Liming. 1987. Introduction to Elemental Geochemistry[M]. Beijing:Geological Publishing House, 124-128(in Chinese with English abstract).

    Google Scholar

    MacDowell S D, Elders W A. 1980. Authigenic layer silicate minerals in borehole Elmore ISalton Sea geothermal field, California, USA[J]. Contribution to Mineralogy and Petrology, 74:293-310. doi: 10.1007/BF00371699

    CrossRef Google Scholar

    Martinez-Serrano R G, Dubois M.1998. Chemical variations in chlorite at the Los Humeros geothermal system, Mexico[J]. Clays and Clay Minerals, 46(6):615-628.

    Google Scholar

    Niteo F. 1997. Chemical composition of matapelitic chlorites:X-ray diffraction and optical property approach[J]. Eur.J.Mineral, 829-841.

    Google Scholar

    Raused-Colom J A, Wiewiora A, Matesanz E.1991.Relation between composition and d001 for chlorite[J].Am. Mineral., 76:1373-1379.

    Google Scholar

    Shang Pengqiang, Hu Ruizhong, Bi Xianwu, Zhang Guoquan, Tian Jianji. 2012. Sr, Nd and Pb isopotic geochemistry of gangue minerals in the Xiazhuang uranium orefield, northern Guangdong Province[J]. Geology in China, 39(6):1847-1856(in Chinese with English abstract).

    Google Scholar

    Walshe J L.1986. A six-component chlorite solid solution model and the conditions of chlorite formation in hydrothermal and geothermal systems[J]. Econ. Geol., 81:681-703.

    Google Scholar

    Wang Xiaoyu, Mao Jingwen, Chen Yanbo, Zhang Xinkang, Liu Peng, Liu Shihua, Fang Si. 2014. Characteristics of chlorite from the Xinliaodong Cu polymetallic deposit in eastern Guangdong province and their geological significance[J]. Acta Petrologica et Mineralogica, 33(5):885-905(in Chinese with English abstract)

    Google Scholar

    Wei Jinting, Chen Qiping, An Guobao. 2009. Discussion about the relationship between sodium metasomatism and uranium mineraliza tion in uranium metallogenic belt on north edge of middle section of Northern Qilianshan[J]. Mineral Resources and Geology, 23(1):36-41(in Chinese with English abstract).

    Google Scholar

    Wei Zhengyu, Zhang Shuming, Liu Jinzhi, Chen Yunjie, Fu Chengming, Zhang Liang. 2014. Characteristics and significance of chlorite in the Longshoushan alkalimetasomatic type uranium depost[J]. Acta Petrologica et Mineralogica, 33(3):517-526(in Chinese with English abstract).

    Google Scholar

    Xie X G, Gary R. Byerly Ray E. Ferrell Jr. 1997. Ⅱ b trioctahedral chlorite from the Barberton greenstone belt:Crystal structure and rock composition constraints with implications to geothermometry[J]. Contrib. Mineral. Petrol., 126:275-291.

    Google Scholar

    Zang W, Fyfe W S. 1995. Chloritization of the hydrothermally altered bedrock at the Igarape Bahia gold deposite, Carajas, Brazi[J]. Mineral Deposita, 30:30-38(in Chinese with English abstract). doi: 10.1007/BF00208874

    CrossRef Google Scholar

    Zhang Bangtong. 1994. Geochemical evidence for uranium mobilization and migration in granites form South China[J]. Geochimica, 23(2):161-167(in Chinese with English abstract).

    Google Scholar

    Zhang Chengjiang.1996.The genesis of uranium and non-uranium bearing granites from several complexes in South China and their relationship to uranium mineralization[J].Journal of Chengdu Institute of Technology, 23(4):33-40(in Chinese with English abstract).

    Google Scholar

    Zhang Wanliang, Gao Mengqi, Lü Chuan, Huang Chao, Huang Di, Xie Zhicong.2018. Zircon LA-ICP-MS U-Pb dating and its geological significance in Lujing area of Hunan and Jiangxi border[J]. Geological Survey and Research, 41(3):161-166, 175.

    Google Scholar

    Zhao Xiling, Liu Kai, Mao Jianren, Ye Haimin.2012. Metallogenesis of two types of late early Yanshanian granitoids in South China:Case studies of south Jiangxi and southwest Fujian[J]. Geology in China, 39(4):871-886(in Chinese with English abstract).

    Google Scholar

    Zhang Yuyan, Li Yuying, Cao Shousun. 2011. Alteration zone and its geochemical characteristics of Julongan uranium deposit[J]. Uranium Geology, 27(2):95-102(in Chinese with English abstract).

    Google Scholar

    Zhang Zhanshi, Hua Renming, Ji Junfeng, Zhang Yanchun, Guo Guolin, Yin Zhenping. 2007. Characteristics and formation conditions of chlorite in No.201 and No.306 uranium deposit[J]. Acta Mineralogica Sinica, 27(2):161-172(in Chinese with English abstract).

    Google Scholar

    艾永福, 刘国平.1998.内蒙古大井矿床的绿泥石研究[J].北京大学学报(自然科学版), 34(1):97-105

    Google Scholar

    陈其平.2010.甘肃北祁连中段北缘铀成矿带钠交代与铀成矿关系探讨[J].甘肃科技, 26(17):33-36.

    Google Scholar

    程华汉, 马汉峰, 向伟东. 2000.利用裂变径迹方法研究碱交代作用中铀赋存状态的变化[J].铀矿地质, 16(5):291-296.

    Google Scholar

    杜乐天.1982.花岗岩型铀矿床文集[M].北京:原子能出版社.

    Google Scholar

    方清浩, 冯君储, 何令仪.1987.广西大容山S-型花岗岩套[J].岩石学报, (3):23-34, 100.

    Google Scholar

    付建明, 马昌前, 谢才富, 张业明, 彭松柏. 2004.湖南骑田岭岩体东缘菜岭岩体的锆石SHRIMP定年及其意义[J].中国地质, 31(1):96-100.

    Google Scholar

    郭国林, 刘晓东, 潘家永, 张展适, 李兴斌. 2012. 302铀矿床绿泥石特征及其与铀成矿的关系[J].铀矿地质, 28(1):35-41.

    Google Scholar

    胡受溪, 周顺元, 任启江, 孙明志.1982.碱交代成矿模式及其成矿机制的理论基础[J].地质与勘探, (1):1-6.

    Google Scholar

    华仁民, 李晓峰, 张开平, 季峻峰, 张文兰. 2003.金山金矿热液蚀变黏土矿物特征及水——岩反应环境研究[J].矿物学报, 23(1):23-30.

    Google Scholar

    黄国龙, 吴烈勤, 邓平, 朱捌, 张彦春. 2006.粤北花岗岩型铀矿找矿潜力及找矿方向[J].铀矿地质, 22(5):267-275, 280.

    Google Scholar

    李锦轶. 2009.中国大陆地质历史的旋回与阶段[J].中国地质, 36(3):504-527.

    Google Scholar

    李仁泽, 刘成东, 梁良, 孔明, 王冰, 万建军. 2016.江西省桃山铀矿田大府上矿床绿泥石特征及其地质意义[J].矿物岩石学杂志, 27(2):297-305.

    Google Scholar

    李晓峰, 华仁民, 季俊峰, 陆建军, 刘盛祥, 刘连文. 2002.江西银山多金属矿床伊利石的形成与流体成矿作用的初步研究[J].地质科学, 37(1):86-95.

    Google Scholar

    刘英俊, 曹励明.1987.元素地球化学导论[M].北京:地质出版社, 124-128.

    Google Scholar

    商朋强, 胡瑞忠, 毕献武, 张国全, 田建吉. 2012.粤北下庄铀矿田脉石矿物Sr、Nd、Pb同位素地球化学研究[J].中国地质, 39(6):1847-1856.

    Google Scholar

    王小雨, 毛景文, 程彦博, 张兴康, 刘鹏, 刘石华, 方思.2014.粤东新寮岽铜多金属矿床绿泥石特征及其地质意义[J].岩石矿物学杂志, 33(5):885-905

    Google Scholar

    魏晋庭, 陈其平, 安国堡. 2009.北祁连中段北缘铀成矿带钠交代与铀成矿关系探讨[J].矿产与地质, 23(1):36-41.

    Google Scholar

    魏正宇, 张树明, 刘金枝, 陈云杰, 傅成铭, 张良. 2014.甘肃龙首山碱交代型铀矿床绿泥石特征及意义[J].岩石矿物学杂志, 33(3):517-526.

    Google Scholar

    章邦桐. 1994.华南花岗岩中铀活化转移的地球化学证据[J].地球化学, 23(2):161-167.

    Google Scholar

    张成江.1996.华南几个杂岩体中产铀与非产铀花岗岩的成因及其与铀成矿关系[J].成都理工学院学报, 23(4):33-40.

    Google Scholar

    张万良, 高梦奇, 吕川, 黄超, 黄迪, 谢智聪.2018.湘赣边境鹿井地区花岗斑岩LA-ICP-MS锆石U-Pb年龄及意义[J].地质调查与研究, 41(3):161-166, 175.

    Google Scholar

    赵希林, 刘凯, 毛建仁, 叶海敏. 2012.华南燕山早期晚阶段两类花岗质岩体与成矿作用:以赣南-闽西南地区为例[J].中国地质, 39(4):871-886.

    Google Scholar

    张玉燕, 李子颖, 曹寿孙. 2011.居隆庵铀矿床蚀变分带及其地球化学特征[J].铀矿地质, 27(2):95-102.

    Google Scholar

    张展适, 华仁民, 季峻峰, 张彦春, 郭国林, 尹征平. 2007. 201和306铀矿床中绿泥石的特征及其形成环境研究[J].矿物学报, 27(2):161-172.

    Google Scholar

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