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WANG Yunfeng, YANG Hongmei, LIU Chongpeng, CAI Yingxiong, TAN Juanjuan, QIU Xiaofei, ZHANG Liguo, ZHU Suizhou. 2018. Strontium and sulfur isotopic characteristics of the Tangjiazhai Pb-Zn deposit in western Hunan Province, China: Denotative significance for ore-forming materials Source[J]. Geology in China, 45(3): 564-572. doi: 10.12029/gc20180310
Citation: WANG Yunfeng, YANG Hongmei, LIU Chongpeng, CAI Yingxiong, TAN Juanjuan, QIU Xiaofei, ZHANG Liguo, ZHU Suizhou. 2018. Strontium and sulfur isotopic characteristics of the Tangjiazhai Pb-Zn deposit in western Hunan Province, China: Denotative significance for ore-forming materials Source[J]. Geology in China, 45(3): 564-572. doi: 10.12029/gc20180310
shu

Strontium and sulfur isotopic characteristics of the Tangjiazhai Pb-Zn deposit in western Hunan Province, China: Denotative significance for ore-forming materials Source

  • 1.

    Isotope Geochemistry Lab, Wuhan Center of Geological Survey, China Geological Survey, Wuhan 430205, Hubei, China

  • 2.

    University of Tuebingen, Tuebingen, 72074, Germany

  • 3.

    Geological Exploration Insitute of Shandong Zhengyuan, China Metallurgical Geology Burean, Jinan 250101, Shandong China

    • Fund Project: Supported by China Geological Survey Program (No. DD20160029 and 12120114005701)
More Information
  • Author Bio: WANG Yunfeng, male, born in 1990, doctor candidate, geochemistry; E-mail:wyf370826@126.com
  • Corresponding author: YANG Hongmei, female, born in 1976, Ph.D, professor, mainly engages in isotopic geochemistry; E-mail: ycyanghmei@163.com 
Received Date:  12 June 2016
Revised Date:  20 August 2017
Publish Date:  25 June 2018
    Abstract

  • The Tangjiazhai Pb-Zn deposit is located in the middle of the Longshan-Luota mining field in western Hunan Province, China, and is an important lead and zinc reserve base for Hunan Province. Sr isotope compositions measured for sphalerite were agecorrected by 372 Ma. As a result, the (87Sr/86Sr)i values range from 0.70904 to 0.71143 with an average value of 0.70998(n=10) which is higher than that of the seawaterin the mineralized age (372 Ma), and lower than that of Lower Cambrian Shipai Formation shale enriched in organic matter. Speculation can be made is that Sr in ore-forming fluids is sourced from seawater (372 Ma) with relatively lower Sr contaminated high Sr Lower Cambrian Shipai Formation shale. Sphalerite and galena are measured for sulfur isotope composition. The δ34SV-CDT values of them have a range from 14.78‰ to 7.21‰ with a mean of 15.84‰ (n=9) which is lower 13.66‰ than that of the Early Ordovician seawater sulfate. This variation conforms to sulfur isotope fractionation of 10‰-20‰ when the mineralized temperature is from 100℃ to 200℃.These evidences indicate that the reduced sulfur in the sulfides probably derive from the Thermochemical Sulfate Reduction (TSR) of seawater sulfate within the ore-bearing strata.

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    • References
  • Bao Juemin, Zhang Anyuan. 1989. Preliminary study on the sedimentary facies of the Longshan Pb-Zn mineralized zone in northwestern Hunan and its mineralization[J]. Journal of Guilin College of Geology, 9(4):309-410 (in Chinese with English abstract).

    Google Scholar

    Cai Chunfang, Li Hongtao. 2005. Thermochemical sulfate reduction in sedimentary basins:a review[J]. Advances in Earth Science, 20(10):1100-1105(in Chinese with English abstract).

    Google Scholar

    Cai Yingxiong, Yang Hongmei, Duan Ruichun, Lu Shansong Zhang Liguo, Liu Chongpeng, Qiu Xiaofei. 2014. Fluid inclusions and S, Pb, C isotope geochemistry of Pb-Zn deposits hosted by Lower Cambrian in western Hunan-eastern Guizhou area[J]. Geoscience, 28(1):29-41 (in Chinese with English abstract)

    Google Scholar

    Chen Fenning, Ji Wenhua, Zhang Haijun, Chen Shoujian, Gu Pingyang, Du Bingying. 2016. The discovery of conodonts fossils and the strontium isotope composition of Labuchari Formation in Tanggula Range and and their stratigraphic significance[J]. Geology in China, 43(4):1139-1148(in Chinese with English abstract).

    Google Scholar

    Claypool G E, Holser W T, Kaplan I R, Sakai H, Zak I. 1980. The age curves of sulfur and oxygen isotopes in marine sulfate and their mutual interpretation[J]. Chemical Geology, 28:199-260. doi: 10.1016/0009-2541(80)90047-9

    CrossRef Google Scholar

    Dixon G, Davidson G J. 1996. Stable isotope evidence for thermochemical sulfate reduction in the Dugald river (Australia) strata-bound shale-hosted zinc-lead deposit[J]. Chemical Geology, 129(3):227-246.

    Google Scholar

    Du Guomin, Cai Hong, Mei Yuping. 2012. Application of Rb-Sr isochron dating method in sphalerite of sulfide deposit-A case study from Dagoudong Pb-Zn deposit in Xinhuang Western Hunan Province[J]. Geology and Mineral Resources of South China, 28(2):175-180(in Chinese witn English abstract).

    Google Scholar

    Du Yudiao, Liu Jiajun, Yu Xinqi, Zhou Xiang, Yang Heming, Yang Longbo. 2013. The sources of metallogenic materials and mineralization of the Xiaoyao W-polymetallic deposit in Anhui Province:Evidence from carbon. Sulfur and lead isotopes[J]. Geology in China, 40(2):566-579 (in Chinese with English abstract).

    Google Scholar

    Duan Qifa, Cao Liang, Zeng Jiankang, Zhou Yun, Tang Chaoyang, Li Kun. 2014. Rb-Sr dating of sphalerites from Shizishan Pb-Zn deposit in Huayuan ore concentration area, western Hunan and its geological significance[J]. Erath Science——Journal of China University of Geosciences, 39(8):977-986+999 (in Chinese with English abstract). doi: 10.3799/dqkx.2014.089

    CrossRef Google Scholar

    Kuang Wenlong, Liu Xinhua, Chen Niansheng, Yu Peiran, Chen Xinyue. 2008. Main geochemical characteristics of lead-zinc deposits in Xiaguangrong ore district, northwestern Hunan[J]. Chinese Journal of Geology, 43(4):685-694(in Chinese with English abstract).

    Google Scholar

    Kuang Wenlong, Xiang Shichao, Xiao Wenzhou, Chen Wei, Yang Shaoxiang, Yu Peiran, Chen Niansheng. 2015. Metallogenic geological characteristics and genesis of lead-zinc deposit in northwestern Hunan[J]. Mineral Deposits, 34(5):1072-1082(in Chinese with English abstract).

    Google Scholar

    Li Kun, Wu Changxiong, Tang Chaoyang, Duan Qifa, Yu Yushuai. 2014. Carbon and oxygen isotopes of Pb-Zn ore deposits in western Hunan and eastern Guizhou Provinces and their implications for the ore-forming process[J]. Geology in China, 41(5):1608-1619(in Chinese with English abstract).

    Google Scholar

    Liang Xinquan, Guo Dingliang. 2002. Deep tectonic activation and its shallow response in Hunan Province[J]. Chinese Journal of Geology, 37(3):332-342(in Chinese with English abstract).

    Google Scholar

    Liu Jinsong, Zou Xianwu, Tang Chaoyang, Cui Sen, Xia Jie, Zhao Wuqiang. 2015. Geological characteristics of Pb-Zn deposit and prospecting directions in Songtao, Guizhou Province and Jiwei, Hunan Province[J]. Geology and Exploration, 51(4):634-645(in Chinese with English abstract).

    Google Scholar

    Liu Xuelong, Li Wenchang, Zhang Na, Yang Fucheng, Kang Jian, Zhang Biao. 2016. Characteristics of sulfur and lead Isotopes and tracing of mineral sources in the Tongchanggou porphyry Mo(Cu)deposit at the southern edge of Geza arc belt, Yunnan[J]. Geology in China, 43(1):209-220(in China with English abstract).

    Google Scholar

    Machel H G, Krouse H R, Sassen R. 1995. Products and distinguishing criteria of bacterial and thermochemical sulfate reduction[J]. Applied Geochemistry, 10(4):373-389. doi: 10.1016/0883-2927(95)00008-8

    CrossRef Google Scholar

    Machel H. 2001. Bacterial and thermochemical sulfate reduction in diagenetic settings-old and new insights[J]. Sedimentary Geology, 140(1):143-175.

    Google Scholar

    McArthur J M, Burnett J, Hancock J M. 1992. Strontium isotopes at K/T boundary:discussion[J]. Nature, 355(6355):28. doi: 10.1038/355028a0

    CrossRef Google Scholar

    McArthur J M, Howarth R J, Shields, G A. 2012. Strontium isotope stratigraphy[J].The Geological Time Scale, 127-144.

    Google Scholar

    Ohmoto H, Kaiser C J, Geer K A. 1990. Systematics of sulphur isotopes in recent marine sediments and ancient sediment-hosted basemetal deposits[C]//Herbert H R, Ho S E(eds. ). Stable Isotopes and fluid processes in Mineralization, 23: 70-120.

    Google Scholar

    Ohmoto H, Rye R. 1979. Isotopes of sulfur and carbon[C]//Geochemistry of Hydrothermal Ore Deposits, 509-567.

    Google Scholar

    Schneider J, Boni M, Lapponi F, Bechstädt, T. 2002. Carbonatehosted zinc-lead deposits in the Lower Cambrian of Hunan, South China:a radiogenic (Pb, Sr) isotope study[J]. Economic Geology, 97:1815-1827. doi: 10.2113/gsecongeo.97.8.1815

    CrossRef Google Scholar

    Team 405 of bureau of geology and mineral resources of Hunan province. 1988. Metallogenic Regularity and its Prediction of Yutang Orefield in Huayuan County Hunan Province[M]. Beijing:Geological Publishing House, 1-1100(in Chinese).

    Google Scholar

    Wang Xilong, Liu Jiajun, Zhai Degao, Wang Jianping, Zhang Qibin, Zhang Anli. 2014. A study of isotope geochemistry and sources of ore-forming materials of the Bianjiadayuan silver polymetallic deposit in Linxi, Inner Mongolia[J]. Geology in China, 41(4):1288-1303(in Chinese with English abstract).

    Google Scholar

    Wang Yunfeng, Yang Hongmei. 2016. Sulfur isotope tracing of oreforming hydrothermal fluid for metallic sulfide deposit[J]. Advances in Earth Science, 31(6):595-602 (in Chinese with English abstract).

    Google Scholar

    Wang Yunfeng, Yang Hongmei, Qiu Xiaofei, Lu Shansong, Cai Yingxiong. 2016. Ore-forming materials sources of the Shizishan Pb-Zn deposit in western Hunan Province, China[J]. Acta Geological Sinica (English Edition), 90(5):1929-1930. doi: 10.1111/acgs.2016.90.issue-5

    CrossRef Google Scholar

    Wen Kedong, Li Guozhen, Liu Haotian. 2011. Analysis on Shale Gasforming condition of Lower Cambrian in middle Yangtze Block[J]. Petroleum Technology of Jianghan, 21(3):1-5(in Chinese).

    Google Scholar

    Wu Genyao. 2002. The Yanshanian orogeny and late Mesozoic activation in China continent[J]. Chinese Journal of Geology, 37(4):453-461(in Chinese with English abstract).

    Google Scholar

    Yang Shaoxiang, Lao Ketong. 2007a. A tentative discussion on genesis of lead-zinc deposits in northwest Hunan[J]. Mineral Deposits, 26(3):330-340(in Chinese with English abstract).

    Google Scholar

    Yang Shaoxiang, Lao Ketong. 2007b. Geological characteristics and ore indicators of lead-zinc deposits in northwestern Hunan, China[J]. Geological Bulletin of China, 26(7):899-908(in Chinese with English abstract).

    Google Scholar

    Yang Shaoxiang, Yu Peiran, Lao Ketong. 2006. Pb-Zn deposits metallogenic regularity and prospecting direction in northwestern of Hunan, China[J]. Land and Resources Herald, 92-98(in Chinese).

    Google Scholar

    Zheng Yongfei, Chen Jiangfeng. 2000. Stable Isotope Geochemistry[M]. Beijing:Science Press, 1-468.

    Google Scholar

    Zhou Yun, Duan Qifa, Chen Yuchuan, Tang Juxing, Cao Liang, Gan Jinmu. 2015. Rb-Sr dating and tracer study of quartz from the Jiangjiaya lead-zinc deposit in western Hunan[J]. Geology in China, 42(2):597-606(in Chinese with English abstract).

    Google Scholar

    鲍珏敏, 张安源. 1989.湘西北龙山铅锌矿带沉积相及成矿作用[J].桂林冶金地质学院学报, 9(4):309-410.

    Google Scholar

    蔡春芳, 李宏涛. 2005.沉积盆地热化学硫酸盐还原作用评述[J].地球科学进展, 20(10):1100-1105. doi: 10.3321/j.issn:1001-8166.2005.10.009

    CrossRef Google Scholar

    蔡应雄, 杨红梅, 段瑞春, 卢山松, 张利国, 刘重芃, 邱啸飞. 2014.湘西-黔东下寒武统铅锌矿床流体包裹体和硫, 铅, 碳同位素地球化学特征[J].现代地质, 28(1):29-41.

    Google Scholar

    陈奋宁, 计文化, 张海军, 陈守建, 辜平阳, 杜兵盈. 2016.唐古拉地区拉卜查日组牙形石的发现、锶同位素组成及地层学意义[J].中国地质, 43(4):1139-1148.

    Google Scholar

    杜国民, 蔡红, 梅玉萍. 2012.硫化物矿床中闪锌矿Rb-Sr等时线定年方法研究[J].华南地质与矿产, 28(2):175-180.

    Google Scholar

    杜玉雕, 刘家军, 余心起, 周翔, 杨赫鸣, 杨隆勃. 2013.安徽逍遥钨多金属矿床成矿物质来源与找矿:碳、硫、铅同位素证据[J].中国地质, 40(2):566-579.

    Google Scholar

    段其发, 曹亮, 曾健康, 周云, 汤朝阳, 李堃. 2014.湘西花垣矿集区狮子山铅锌矿床闪锌矿Rb-Sr定年及地质意义[J].地球科学——中国地质大学学报, 39(8):977-986, 999.

    Google Scholar

    湖南省地质矿产局. 1988.湖南省区域地质志[M].北京:地质出版社, 1-1100.

    Google Scholar

    匡文龙, 刘新华, 陈年生, 余沛然, 陈新跃. 2008.湘西北下光荣矿区铅锌矿床主要地球化学特征[J].地质科学, 43(4):685-694.

    Google Scholar

    匡文龙, 向世超, 肖文舟, 陈伟, 杨绍祥, 余沛然, 陈年生. 2015.湘西北地区铅锌矿床成矿地质特征及矿床成因研究[J].矿床地质, 34(5):1072-1082.

    Google Scholar

    李堃, 吴昌雄, 汤朝阳, 段其发, 于玉帅. 2014.湘西黔东地区铅锌矿床C、O同位素地球化学特征及其对成矿过程的指示[J].中国地质, 41(5):1608-1619.

    Google Scholar

    梁新权, 郭定良. 2002.湖南深部构造活化及其浅部响应[J].地质科学, 37(3):332-342.

    Google Scholar

    刘劲松, 邹先武, 汤朝阳, 崔森, 夏杰, 赵武强. 2015.贵州松桃-湖南吉卫地区铅锌矿地质特征及找矿方向[J].地质与勘探, 51(4):634-645.

    Google Scholar

    刘学龙, 李文昌, 张娜, 杨富成, 康建, 张彪. 2016.云南格咱岛弧带南缘铜厂沟斑岩型铜钼矿床硫铅同位素特征与成矿物质来源示踪[J].中国地质, 43(1):209-220. doi: 10.12029/gc20160115

    CrossRef Google Scholar

    王喜龙, 刘家军, 翟德高, 王建平, 张琪彬, 张安立. 2014.内蒙古林西边家大院银多金属矿床同位素地球化学特征及成矿物质来源探讨[J].中国地质, 41(4):1288-1303.

    Google Scholar

    王云峰, 杨红梅. 2016.金属硫化物矿床的成矿热液硫同位素示踪[J].地球科学进展, 31(6):595-602

    Google Scholar

    文可东, 李国珍, 刘皓天. 2011.中扬子区下寒武统页岩气形成条件分析[J].江汉石油科技, 21(3):1-5.

    Google Scholar

    吴根耀. 2002.燕山运动和中国大陆晚中生代的活化[J].地质科学, 37(4):453-461.

    Google Scholar

    杨绍祥, 劳可通. 2007a.湘西北铅锌矿床碳氢氧同位素特征及成矿环境分析[J].矿床地质, 26(3):330-340.

    Google Scholar

    杨绍祥, 劳可通. 2007b.湘西北铅锌矿床的地质特征及找矿标志[J].地质通报, 26(7):899-908.

    Google Scholar

    杨绍祥, 余沛然, 劳可通. 2006.湘西北地区铅锌矿床成矿规律及找矿方向[J].国土资源导刊, 3, 92-98. doi: 10.3969/j.issn.1672-5603.2006.03.025

    CrossRef Google Scholar

    郑永飞, 陈江峰. 2000.稳定同位素地球化学[M].北京:科学出版社, 1-468.

    Google Scholar

    周云, 段其发, 陈毓川, 唐菊兴, 曹亮, 甘金木. 2015.湘西龙山江家垭铅锌矿床石英Rb-Sr同位素测年与示踪研究[J].中国地质, 42(2):597-605.

    Google Scholar

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