SUN Qing-jin1, ZHANG Wei-hai1, ZHANG Wei-ping1, ZHAO Jian-she1, MIAO Jian-yu2, SUN Wei2, LIU Chi-yang2. Experimental simulation study of the role of organic matter in the formation of uranium deposits[J]. Geology in China, 2007, 34(3): 463-469.
Citation: |
SUN Qing-jin1, ZHANG Wei-hai1, ZHANG Wei-ping1, ZHAO Jian-she1, MIAO Jian-yu2, SUN Wei2, LIU Chi-yang2. Experimental simulation study of the role of organic matter in the formation of uranium deposits[J]. Geology in China, 2007, 34(3): 463-469.
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Experimental simulation study of the role of organic matter in the formation of uranium deposits
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1. Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Department of Chemistry, Northwest University, Xi'an 710069, Shaanxi, China;2. Department of Geology, Northwest University, Xi'an 710069, Shaanxi, China
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Abstract
Abstract:The formation of sedimentary uranium deposits has close relation to organic matter. Experimental simulation study indicates that: aromatic organic acid is very easy to coordinate with uranyl ions under the weakly acid to weakly alkaline conditions and the oxygen atoms of its carboxyl coordinate with uranium atoms in a variety of coordination forms to form coordinate bonds. The results of the experiment simulation validate some previous conclusions and intuitionally exhibit some migration forms of main organic matter functional groups and uranyl ions in solution. The results also show the reduction of hydrocarbon in the formation of uranium deposits under hydrothermal conditions. It can reduce U (Ⅵ) into U (Ⅳ) and deposit the latter.
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