Professional Committee of Rock and Mineral Testing Technology of the Geological Society of China, National Geological Experiment and Testing CenterHost
2013 Vol. 32, No. 1
Article Contents

Bin-bin XI, Wei-jun SHI, Fang BAO, Hong JIANG. Using Laser Raman Microprobe and Fused Silica Capillaries to Determine Salinity of Fluid Inclusions[J]. Rock and Mineral Analysis, 2013, 32(1): 34-39.
Citation: Bin-bin XI, Wei-jun SHI, Fang BAO, Hong JIANG. Using Laser Raman Microprobe and Fused Silica Capillaries to Determine Salinity of Fluid Inclusions[J]. Rock and Mineral Analysis, 2013, 32(1): 34-39.

Using Laser Raman Microprobe and Fused Silica Capillaries to Determine Salinity of Fluid Inclusions

  • Salinity is one of the most important parameters of fluid inclusions. The salinity of fluid inclusions can be measured quickly and accurately by using a Laser Raman Microprobe. The accuracy of the standard sample plays an important role in this method. The technique of synthesizing fluid inclusions in fused silica capillaries is a new method to prepare standard samples. In this study, this technique was applied to synthesize the fluid inclusions with different concentrations of salinity, which were used to establish the Raman standard curve. The results of microthermometry showed that the accuracy of salinity in synthesized fused silica capillaries was 0.5%. The concentrations of salinity of synthesized fluid inclusions in quartz and halite were determined to verify the standard curve with 1% error between measured value and theoretical value. Compared with the method of synthesizing fluid inclusions in minerals and the method of prepare samples in glass (quartz) tube, this technique can synthesize fluid inclusions quickly and prepare small size samples which are similar to the fluid inclusions in geology samples.
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  • [1] Mernagh T P, Wilde A R. The use of the laser Raman microprobe for the determination of salinity in fluid inclusions [J]. Geochimica et Cosmochimica Acta, 1989, 53(4): 765-771. doi: 10.1016/0016-7037(89)90022-7

    CrossRef Google Scholar

    [2] Dubessy J, Lhomme T, Boiron M C, Rull F. Determin-ation of chlorinity in aqueous fluids using Raman spectroscopy of the stretching band of water at room temperature: Application to fluid inclusions[J]. Applied Spectroscopy, 2002, 56(1): 99-106. doi: 10.1366/0003702021954278

    CrossRef Google Scholar

    [3] 吕新彪, 姚书振,何谋春.成矿流体包裹体盐度的拉曼光谱测定[J].地学前缘, 2001,8(4): 429-433.

    Google Scholar

    [4] 丁俊英,倪培,饶冰,周进,朱筱婷.显微激光拉曼光谱测定单个包裹体盐度的实验研究[J].地质论评, 2004, 50(2): 203-209.

    Google Scholar

    [5] 张鼐,张大江,张水昌,张蒂嘉,崔京钢.氯盐溶液的拉曼光谱特征及测试探讨[J].岩矿测试, 2005,24(1):40-42, 46.

    Google Scholar

    [6]

    [7] Zhang Y G, Frantz J D. Determination of the homogen-ization temperatures and densities of supercritical fluids in the system NaCl-KCl-CaCl2-H2O using synthetic fluid inclusions [J]. Chemical Geology, 1987,64(3-4): 335-350. doi: 10.1016/0009-2541(87)90012-X

    CrossRef Google Scholar

    [8] Teinturier S, Elie M, Pironon J. Oil-cracking processes evidence from synthetic petroleum inclusions[J]. Journal of Geochemical Exploration, 2003,78-79: 421-425. doi: 10.1016/S0375-6742(03)00135-3

    CrossRef Google Scholar

    [9] 倪培,饶冰,丁俊英,张林松.人工合成包裹体的实验研究及其在激光拉曼探针测定方面的应用[J].岩石学报, 2003, 19(2): 319-326.

    Google Scholar

    [10] Chou I M, Song Y, Burruss R C. A new method for synthesizing fluid inclusions in fused silica capillaries containing organic and inorganic material [J]. Geochimica et Cosmochimica Acta, 2008, 72(21): 5217-5231. doi: 10.1016/j.gca.2008.07.030

    CrossRef Google Scholar

    [11] Chou I M, Burruss R C, Lu W. Chapter 24—A New Optical Capillary Cell for Spectroscopic Studies of Geologic Fluids at Pressures up to 100 MPa [M]//Chen J H, Wang Y B, Duffy T S, Shen G Y, Dobrzhinetskaya L F. Advances in High-Pressure Technology for Geophysical Applications. Elsevier: Amsterdam, 2005: 475-485.

    Google Scholar

    [12] Bodnar R J. Revised equation and table for determining the freezing point depression of H2O-NaCl solutions[J]. Geochimica et Cosmochimica Acta, 1993, 57(3): 683-684. doi: 10.1016/0016-7037(93)90378-A

    CrossRef Google Scholar

    [13]

    [14] Lu W, Chou I M, Burruss R C, Song Y. A unified equation for calculating methane vapor pressures in the CH4-H2O system with measured Raman shifts [J]. Geochimica et Cosmochimica Acta, 2007, 71(16): 3969-3978. doi: 10.1016/j.gca.2007.06.004

    CrossRef Google Scholar

    [15] 吕万军, Chou I M, Burruss R C,金庆焕,傅家谟.拉曼光谱原位观测水合物形成后的饱和甲烷浓度[J].地球化学, 2005, 34(2): 187-192.

    Google Scholar

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