2018 Vol. 51, No. 4
Article Contents

WANG Xingjun, WANG Zitong, WANG Genhou, ZHOU Jie, CUI Yinliang, ZHANG Daohong, LI Weiqing, FAN Liangjun. 2018. Geochemical Characteristics of the Shazitang Bauxite Deposit in Guangnan County, Southeast Yunnan. Northwestern Geology, 51(4): 166-183.
Citation: WANG Xingjun, WANG Zitong, WANG Genhou, ZHOU Jie, CUI Yinliang, ZHANG Daohong, LI Weiqing, FAN Liangjun. 2018. Geochemical Characteristics of the Shazitang Bauxite Deposit in Guangnan County, Southeast Yunnan. Northwestern Geology, 51(4): 166-183.

Geochemical Characteristics of the Shazitang Bauxite Deposit in Guangnan County, Southeast Yunnan

  • Shazitang bauxite deposit is a rare high-quality bauxite deposit in Southeast Yunnan, which is characterized by high Al2O3 content and A/S ratio. In this paper, the sedimentary bauxite has been taken as the research object to study its geochemical characteristics, and then its ore-forming materials sources and metallogenetic environment have been discussed. Aluminum-containing rock series has higher REE contents, showing moderate negative Eu anomaly, positive Ce anomalies and negative Ce anomalies; REE distribution patterns are tilted to the right curve with weak "V"-shaped and various slope, reflecting the varying degree of REE fractionation. LILE (U), HFSE (Nb, Ta, Zr, Hf, Th) and siderophile element (Cr) are significantly enriched in aluminum-containing rock series, the other elements are significantly loss. Cluster analysis shows that Al2O3 is positively correlated with Nb, TiO2 and REE, but it has significantly negative correlation with Ga, Fe2O3 and Li. Aluminum-containing rock series is associated with black metal (Ti), rare earth elements, dispersed elements (Ga), rare metals (Nb and Li), and it can be comprehensively utilizated with Al2O3. REE distribution pattern for normalized aluminum-containing rock series are nearly horizontal "U"-shaped curve, the TiO2/Al2O3 ratio of aluminum-containing rock series (16.89) is close with the TiO2/Al2O3 ratio of limestone in Weining Formation (13.09), illustrating the close relationship between aluminiferous rock series and underlying limestone in Weining Formation. Among aluminum-containing rock series, Be content is low (3.60×10-6), Th/U ratio is high (6.07), and more samples have negative Ce anomalies. These geochemical characteristics indicate that the Shazitang bauxite deposit was sourced from weathering crust and experienced the sedimentation transformation. Ga content is high (25.25×10-6), Sr content is low (77.7×10-6), Ba content is low (34.4×10-6), and V/Zr ratio (0.22) is lower, Eu/Sm ratio is lower (0.21), which shows the continental sedimentary characteristics; Sr/Ba ratio is high (3.28), which indicates the sea facies characteristics; these characteristics indicate that the Shazitang bauxite deposit was derived from the weathering crust, without obvious sedimentation transformation.
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  • 陈德潜, 陈刚.实用稀土元素地球化学[M]. 北京:冶金工业出版社, 1990, 59-173.

    Google Scholar

    CHEN Deqian, CHEN Gang. Practical REE geochemistry[M]. Beijing:Metallurgical Industry Press, 1990, 59-173.

    Google Scholar

    陈平, 柴东浩.山西地块石炭纪铝土矿沉积地球化学研究[M]. 太原:山西科学出版社, 1997, 68-127.

    Google Scholar

    CHEN Ping, CHAI Donghao. Sedimentary geochemistry of Carboniferous bauxite deposits in Shanxi massif. Taiyuan:Shanxi Science and Technology Press, 1997, 68-127.

    Google Scholar

    成功,杨震,黄壁.板茂铝土矿地质特征及成因分析[J]. 轻金属, 2010, 10:8-12.

    Google Scholar

    CHEN Gong, YANG Zhen, HUANG Bi. Bauxite geological characteristics and genetic analysis of Banmao[J]. Light Metal, 2010, 10:8-12.

    Google Scholar

    戴塔根, 龙永珍, 张起钻, 等. 桂西某些铝土矿床稀土元素地球化学研究[J]. 地质与勘探, 2003, 39(4):1-5.

    Google Scholar

    DAI Tagen, LONG Yongzhen, ZHANG Qizuan, et al. REE geochemistry of some bauxite deposits in the western Guangxi district[J]. Geology and Exploration, 2003, 39(4):1-5.

    Google Scholar

    丰恺.河南铝土矿成因的一点认识[J]. 轻金属, 1992, 7:1-8.

    Google Scholar

    FENG Kai. A knowledge of the genesis of Henan bauxite deposit[J].Light Metal, 1992, 7:1-8.

    Google Scholar

    冯晓宏, 王臣兴, 崔子良, 等. 滇东南铝土矿成矿物质来源探讨[J]. 云南地质, 2009, 28(3):233-242.

    Google Scholar

    FENG Xiaohong, WANG Chenxing, CUI Ziliang, et al. The ore sources explore of bauxite in southeast Yunnan[J]. Yunnan Geology, 2009, 28(3):233-242.

    Google Scholar

    高泽培, 徐自斌, 任运华. 云南省丘北县大铁矿区铝土矿床特征分析与找矿标志[J]. 云南冶金, 2012, 41(4):1-6.

    Google Scholar

    GAO Zepei, XU Zibin, REN Yunhua. Features analysis and prospecting marks of bauxite deposit at Datie mining area in Qiubei county of Yunnan province[J]. Yunnan Metallurgy, 2012, 41(4):1-6.

    Google Scholar

    黄仁新. 滇东南地区铝土矿床类型[J]. 云南地质, 1992. 11(2):121-129.

    Google Scholar

    HUANG Renxin. Types of bauxite deposits in southeastern Yunnan[J]. Yunnan Geology, 1992. 11(2):121-129.

    Google Scholar

    黄镇国, 李平日, 张仲英, 等. 珠江三角洲形成发育演变[M]. 广州:科学普及出版社广州分社, 1982, 63-104.

    Google Scholar

    HUANG Zhenguo, LI Pingri, ZHANG Zhongying, et al. The formation, development and evolution of the Pearl River Delta[M]. Guangzhou:Guangzhou Branch, Popular Science Press, 1982, 63-104.

    Google Scholar

    蒋秀坤, 李亚辉. 云南文山红舍克铝土矿成因分析[J]. 云南地质, 2012, 31(3):316-319.

    Google Scholar

    JIANG Xiukun, LI Yahui. An analysis of the genesis of Hongshekebauxite deposit in Wenshan, Yunnan[J]. Yunhan Geology, 2012, 31(3):316-319.

    Google Scholar

    蓝先洪, 马道修, 徐明广, 等. 珠江三角洲若干地球化学标志及指相意义[J]. 海洋地质与第四纪地质, 1987, 7(1):39-49.

    Google Scholar

    LAN Xianhong, MA Daoxiu, XU Mingguang,et al. Some geochemical indicators of the Pearl River Delta and their facies significance[J]. Marine Geology & Quaternary Geology, 1987, 7(1):39-49.

    Google Scholar

    李昌年.火成岩微量元素岩石学[M]. 武汉:中国地质大学出版社, 1992, 74-125.

    Google Scholar

    LI Changnian.Trace elements in igneous petrology[M]. Wuhan:China University of Geosciences Press, 1992, 74-125.

    Google Scholar

    李传班, 刘幼平, 武国辉, 等. 贵州省凯里地区铝土矿床控矿因素研究[J]. 地质与勘探, 2012, 48(1):31-37.

    Google Scholar

    LI Chuanban, LIU Youping, WU Guohui,et al. Ore-controlling factors of the bauxite deposits in the Kaili area, Guizhou province[J]. Geology and Exploration, 2012, 48(1):31-37.

    Google Scholar

    李建强, 刘志乾.广西三水铝土矿矿床地质特征及成探讨[J]. 甘肃冶金, 2008, 30(6):56-64.

    Google Scholar

    LI Jianqiang, LIU Zhiqiang. Geological characteristics and genesis of Sanshui bauxite deposit, Guangxi[J]. Gansu Metallurgy, 2008, 30(6):56-64.

    Google Scholar

    李普涛, 张起钻.广西靖西县三合铝土矿稀土元素地球化学研究[J]. 矿产与地质, 2008, 22(6):536-545.

    Google Scholar

    LI Putao, ZHANG Qizuan. Research on geochemistry of REE in the Sanhe bauxite deposit in Jingxi county, Guangxi[J]. Mineral Resources and Geology, 2008, 22(6):536-545.

    Google Scholar

    李启津, 杨国高, 侯正洪.铝土矿成矿理论研究中的几个问题[J]. 矿产与地质, 1996, 10(1):22-26.

    Google Scholar

    LI Qijin, YANG Guogao, HOU Zhenghong. Several issues of bauxite ore theoretical studies[J].Mineral Resources and Geology, 1996, 10(1):22-26.

    Google Scholar

    刘英俊, 曹励明, 李兆麟, 等. 元素地球化学[M]. 北京:地质出版社, 1984, 50-215.

    Google Scholar

    LIU Yingjun, CAO Liming, LI Zhaolin,et al. Element geochemistry[M]. Beijing:Geological Press, 1984, 50-215.

    Google Scholar

    刘英俊, 曹励明.元素地球化学导论[M]. 北京:地质出版社, 1987, 57-80.

    Google Scholar

    LIU Yingjun, CAO Liming.Element geochemistry introduction[M]. Beijing:Geological Press, 1987,57-80.

    Google Scholar

    卢社香.河南省的铝土矿[J]. 地质与资源, 2009, 18(1):37-45.

    Google Scholar

    LU Shexiang. The bauxite deposits in Henan province, China[J]. Geology and Resources, 2009, 18(1):37-45.

    Google Scholar

    任运华, 徐自斌, 郑国龙, 等. 云南省文山地区铝土矿矿床类型、成因及找矿标志[J]. 矿物学报, 2013, 33(4):471-477.

    Google Scholar

    REN Yunhua, XU Zibin, ZHENG Guolong,et al. Ore type, genesis and prospecting indicator of bauxite deposits in Wenshan city, Yunnan province, China[J]. Acta Mineralogica Sinica, 2013, 33(4):471-477.

    Google Scholar

    邵厥年, 陶维屏.矿产资源工业要求手册[M]. 北京:地质出版社, 2010, 117-300.

    Google Scholar

    SHAO Juenian, TAO Weiping.Mineral resources industry requirements manual[M]. Beijing:Geological Publish Press, 2010, 117-300.

    Google Scholar

    汪云亮, 李臣初, 周蓉生, 等. 地球化学原理及其应用-兼论峨眉山玄武岩的成因[M]. 成都:成都科技大学出版社, 1993, 61-66.

    Google Scholar

    WANG Yunliang, LI Chenchu, ZHOU Rongsheng,et al. Principle on trace element geochemistry of igneous rocks and its applications-and demonstration of the petrogenesis of Emeishan basalts[M]. Chendu:Chendu University of Science and Technology Press, 1993, 61-66.

    Google Scholar

    王恩孚.论中国古生代铝土矿成因[J]. 轻金属, 1987, 1:1-5.

    Google Scholar

    WANG Enfu. A discussion on genesis of China Paleozoic bauxite deposits[J]. Light Metal, 1987, 1:1-5.

    Google Scholar

    王力, 龙永珍, 彭省临.桂西铝土矿成矿物质来源的地质地球化学分析[J].桂林工学院学报, 2004, 24(1):1-6.

    Google Scholar

    WANG Li, LONG Yongzhen, PENG Shenglin. Geologic and geochemical study on material derivation of bauxite deposits in western Guangxi[J]. Journal of Guilin Institute of Technology, 2004, 24(1):1-6.

    Google Scholar

    王行军, 王根厚, 周洁, 等. 滇东南丘北县大铁铝土矿稀土元素特征研究[J]. 地球学报, 2013a, 34(增刊1):127-134.

    Google Scholar

    WANG Xingjun, WANG Genhou, ZHOU Jie,et al. Ree Characteristics of the Datie bauxite deposit in Qiubei county, southeast Yunnan province[J]. Acta Geoscientica Sinica, 2013a, 34(Suppl. 1):127-134.

    Google Scholar

    王行军, 王根厚, 周洁, 等.滇东南文山市天生桥-者五舍铝土矿床地球化学特征研究[J]. 矿物学报, 2013b, 33(4):485-496.

    Google Scholar

    WANG Xingjun, WANG Genhou, ZHOU Jie, et al. Geochemical characters of the Tianshengqiao-zhewushe bauxite deposit, southeastern Yunman province[J]. Acta Mineralogica Sinica, 213b, 33(4):485-496.

    Google Scholar

    王行军, 王梓桐, 王根厚, 等.滇东南铝土矿床地球化学特征及成矿物质来源研究[J]. 中国地质, 2015a, 42(1):248-264.

    Google Scholar

    WANG Xingjun, WANG Zitong, WANG Genhou, et al. Research on geochemical characters and ore-formign materials of bauxite deposit in southeast Yunman Province[J]. Geology in China, 2015a, 42(1):248-264.

    Google Scholar

    王行军, 王根厚, 周洁, 等.滇东南铝土矿床共生矿产及伴生矿产研究[J]. 地质找矿论丛, 2015b, 20(2):167-173.

    Google Scholar

    WANG Xingjun, WANG Genhou, ZHOU Jie, et al. Research on the by-products of Bauxite deposit in southeast Yunman province[J]. Conributions to Geology and Mineral Resources Research, 2015b, 20(2):167-173.

    Google Scholar

    王行军, 王根厚, 周洁, 等.滇东南丘北县大铁铝土矿床微量元素特征与成矿环境[J]. 地质找矿论丛, 2015c, 20(3):313-320.

    Google Scholar

    WANG Xingjun, WANG Genhou, ZHOU Jie, et al. Research on trace element geochemical characteristics and ore-forming environment of the Datie bauxite deposit in Qiubei county, the southeast Yunnan province[J]. Conributions to Geology and Mineral Resources Research, 2015c, 20(3):313-320.

    Google Scholar

    王中刚, 于学元, 赵振华.稀土元素地球化学[M]. 北京:科学出版社, 1989, 76-93, 47-291.

    Google Scholar

    WANG Zhonggang, YU Xueyuan, ZHAO Zhenhua.REE geochemistry[M]. Beijing:Science Press, 1989, 76-93, 247-291.

    Google Scholar

    吴国炎.华北铝土矿的物质来源及成矿模式探讨[J]. 河南地质, 1997, 15(3):161-166.

    Google Scholar

    WU Guoyan. A discussion on material source and metallogenic model of bauxite deposits in north China[J]. Henan Geology, 1997, 161-166.

    Google Scholar

    严健, 豆松, 张道红.云南丘北大铁铝土矿地球化学特征及成矿物质来源[J]. 矿物学报, 2013, 33(4):462-470.

    Google Scholar

    YAN Jian, DOU Song, ZHANG Daohong. Geochemical characteristics and sources of ore-forming metals of Datie bauxite deposit, Qiubei county, Yunnan province, China[J]. Acta Mineralogica Sinica, 2013, 33(4):462-470.

    Google Scholar

    叶霖, 程曾涛, 潘自平.贵州修文小山坝铝土矿中稀土元素地球化学特征[J]. 矿物岩石地球化学通报, 2007, 26(3):228-233.

    Google Scholar

    YIE Lin, CHENG Zengtao, PAN Ziping. The REE geochemical characteristics of the Xiaoshanba bauxite deposit, Guizhou[J]. Bullet in Mineralogy, Petrology and Geochemistry, 2007, 26(3):228-233

    Google Scholar

    俞缙,李普涛,于航波. 靖西三合铝土矿微量元素地球化学特征与成矿环境研究[J]. 河南理工大学学报(自然科学版), 2009,28(3):289-292.

    Google Scholar

    YU Ji, LI Putao, YU Hangbo. Analysis on trace-element geochemical characteristics and ore-forming environment of bauxite mine in Sanhe town of Jingxi county[J]. Journal of Henan Polytechnic University (Natural Science), 2009, 28 (3):289-292.

    Google Scholar

    袁跃清.河南省铝土矿床成因探讨[J]. 矿产与地质, 2005, 19(1):52-56.

    Google Scholar

    YUAN Yueqing. Genesis of bauxite deposit in Henan[J]. Mineral Resources and Geology, 2005, 19(1):52-56.

    Google Scholar

    赵伦山, 张本仁.地球化学[M]. 北京:地质出版社, 1988, 31-39.

    Google Scholar

    ZHAO Lunshan, ZHANG Benren. Geochemistry[M]. Beijing:Geological Press, 1988, 31-39.

    Google Scholar

    西南有色昆明勘测设计(院)股份有限公司. 云南省广南县甲坝地区铝土矿普查报告[R], 2012.

    Google Scholar

    BOYNTON W V.Geochemistry of the rare earth element:meteorite studies[J]. Rare earth element geochemistry, Elservier, 1984,66-114.

    Google Scholar

    LAUKAST C. Origin of Bauxite at Eufaula Alabanma[J]. USA Clay Minerals, 1983,18:350-361.

    Google Scholar

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