Citation: | CHEN Wanqing, WANG Xiaotong, LI Mingyu, JIANG Lijun. Preparation of Iron Oxide Pigment by Super Iron Concentrate[J]. Multipurpose Utilization of Mineral Resources, 2025, 46(2): 201-210. doi: 10.3969/j.issn.1000-6532.2025.02.029 |
In recent years, there are some problems in domestic iron powder price fluctuation and low economic benefits. By using super iron concentrate as raw materials to prepare high quality iron oxide pigment, the added value of iron essence powder can be increased.The effect of various conditions in the preparation process on the pigment purity was investigated, and the results showed that iron oxide black with iron content of 98.20% was obtained using super iron concentrate(TFe:71.81%) from a concentrator in Fushun, which was 3.20% higher than that of HG/ T 2250—1991 medium grade. The iron oxide red with iron content of 97.60% was obtained, which was 2.40% higher than that of class A iron in GB/T 1863—2008. The iron oxide yellow with an iron content of 83.20% was obtained, which was 0.20% higher than the iron content of class A in GB/ T 1863—2008. The other indexes of the three pigments also exceeded their respective optimal standards, which provides basic research for finding another way to improve the economic benefits of enterprises.
[1] | 韩俊红, 李纪磊, 吴金甜, 等. 安徽金安矿业铁精粉提纯实验研究[J]. 有色金属(选矿部分), 2020(5):31-37.HAN J H, LI J L, WU J T, et al. Experimental study on purification of iron concentrate powder in Jin 'an Mining Company, Anhui Province[J]. Non-ferrous Metals (Mineral Processing Section), 2020(5):31-37. HAN J H, LI J L, WU J T, et al. Experimental study on purification of iron concentrate powder in Jin 'an Mining Company, Anhui Province[J]. Non-ferrous Metals (Mineral Processing Section), 2020(5):31-37. |
[2] | 史政良, 严海军, 周玉娟. 甘肃某石煤钒矿焙烧灰渣综合利用工艺研究[J]. 矿产综合利用, 2020(3):158-163.SHI Z L, YAN H J, ZHOU Y J. Research on comprehensive utilization of roasting ash and slag from a stone coal vanadium mine in Gansu Province[J]. Multipurpose Utilization of Mineral Resources, 2020(3):158-163. doi: 10.3969/j.issn.1000-6532.2020.03.027 SHI Z L, YAN H J, ZHOU Y J. Research on comprehensive utilization of roasting ash and slag from a stone coal vanadium mine in Gansu Province[J]. Multipurpose Utilization of Mineral Resources, 2020(3):158-163. doi: 10.3969/j.issn.1000-6532.2020.03.027 |
[3] | 钱有军, 裴晓东, 骆艳华, 等. 钛白副产物硫酸亚铁净化液制备高品质氧化铁红实验[J]. 金属矿山, 2021(541):211-215.QIAN Y J, PEI X D, LUO Y H, et al. Preparation of high quality iron oxide red from ferrous sulfate purification solution of titanium white byproduct[J]. Metal Mine, 2021(541):211-215. QIAN Y J, PEI X D, LUO Y H, et al. Preparation of high quality iron oxide red from ferrous sulfate purification solution of titanium white byproduct[J]. Metal Mine, 2021(541):211-215. |
[4] | 刘吉军, 李明玉, 卢峰, 等. 共沉淀法制备氧化铁黑的影响因素研究[J]. 现代化工, 2018, 38(2):139-143.LIU J J, LI M Y, LU F, et al. Study on the influencing factors of coprecipitation for the preparation of iron oxide black[J]. Modern Chemical Industry, 2018, 38(2):139-143. LIU J J, LI M Y, LU F, et al. Study on the influencing factors of coprecipitation for the preparation of iron oxide black[J]. Modern Chemical Industry, 2018, 38(2):139-143. |
[5] | 许小荣, 李建芬, 肖波, 等. 均匀沉淀法制备纳米氧化铁及工艺优化[J]. 无机盐工业, 2009, 41(6):14-16.XU X R, LI J F, XIAO B, et al. Preparation of nano ferric oxide by homogeneous precipitation method and process optimization[J]. Inorganic Salt Industry, 2009, 41(6):14-16. doi: 10.3969/j.issn.1006-4990.2009.06.005 XU X R, LI J F, XIAO B, et al. Preparation of nano ferric oxide by homogeneous precipitation method and process optimization[J]. Inorganic Salt Industry, 2009, 41(6):14-16. doi: 10.3969/j.issn.1006-4990.2009.06.005 |
[6] | 孙智辉. 硫铁矿烧渣制备纳米氧化铁黑研究[D]. 武汉: 武汉理工大学, 2006.SUN Z H. Preparation of nano-sized iron oxide black from pyrite cinder [D]. Wuhan: Wuhan University of Technology, 2006. SUN Z H. Preparation of nano-sized iron oxide black from pyrite cinder [D]. Wuhan: Wuhan University of Technology, 2006. |
[7] | 姚佐胜. 尿素水解法合成氧化铁黄技术研究[J]. 辽宁化工, 2016, 45(10):1267-1270.YAO Z S. Study on synthesis of iron oxide yellow by urea hydrolysis[J]. Liaoning Chemical Industry, 2016, 45(10):1267-1270. YAO Z S. Study on synthesis of iron oxide yellow by urea hydrolysis[J]. Liaoning Chemical Industry, 2016, 45(10):1267-1270. |
[8] | 郑为国, 于鹏浩, 施险峰, 等. 氧化铁黄晶种工艺优化[J]. 上海化工, 2019, 44(10):8-12.ZHENG W G, YU P H, SHI X F, et al. Optimization of ferric oxide topaz seed technology[J]. Shanghai Chemical Industry, 2019, 44(10):8-12. doi: 10.3969/j.issn.1004-017X.2019.10.007 ZHENG W G, YU P H, SHI X F, et al. Optimization of ferric oxide topaz seed technology[J]. Shanghai Chemical Industry, 2019, 44(10):8-12. doi: 10.3969/j.issn.1004-017X.2019.10.007 |
[9] | 汤瑞湖. 氨法制备铁黄颜料工艺研究[D]. 长沙: 中南大学, 2004.TANG R H. Study on preparation of iron yellow pigment by ammonia method [D]. Changsha: Central South University, 2004. TANG R H. Study on preparation of iron yellow pigment by ammonia method [D]. Changsha: Central South University, 2004. |
[10] | 张文学. 酸洗废液资源化: 纳米四氧化三铁的制备及性能研究[D]. 哈尔滨: 哈尔滨师范大学, 2015.ZHANG W X. Recycling of pickling waste liquid: Preparation and performance of nano trioxide [D]. Harbin: Harbin Normal University, 2015. ZHANG W X. Recycling of pickling waste liquid: Preparation and performance of nano trioxide [D]. Harbin: Harbin Normal University, 2015. |
[11] | 孙晓庆, 杜松松. 功能型新材料氧化铁黑工业废副清洁法生产技术研究[J]. 辽宁化工, 2019, 48(1):70-73.SUN X Q, DU S S. Research on the production technology of iron oxide of functional new material[J]. Liaoning Chemical Industry, 2019, 48(1):70-73. doi: 10.3969/j.issn.1004-0935.2019.01.024 SUN X Q, DU S S. Research on the production technology of iron oxide of functional new material[J]. Liaoning Chemical Industry, 2019, 48(1):70-73. doi: 10.3969/j.issn.1004-0935.2019.01.024 |
[12] | 王家伟, 李安静, 王海峰. 硫酸渣加碱焙烧过程中富铁效果研究[J]. 矿产综合利用, 2016(5):88-91.WANG J W, LI J J, WANG H F. Study on the effect of iron-rich iron in sulfate slag and alkali roasting[J]. Multipurse Utilization of Minerals, 2016(5):88-91. doi: 10.3969/j.issn.1000-6532.2016.05.021 WANG J W, LI J J, WANG H F. Study on the effect of iron-rich iron in sulfate slag and alkali roasting[J]. Multipurse Utilization of Minerals, 2016(5):88-91. doi: 10.3969/j.issn.1000-6532.2016.05.021 |
[13] | 王春雨. 阴离子型表面活性剂对ZnO微/纳结构的形貌调控[D]. 石家庄: 河北师范大学, 2015.WANG C Y. Morphology regulation of ZnO micro/nano structure by anionic surfactants [D]. Shijiazhuang: Hebei Normal University, 2015. WANG C Y. Morphology regulation of ZnO micro/nano structure by anionic surfactants [D]. Shijiazhuang: Hebei Normal University, 2015. |
[14] | 中华人民共和国化工行业标准. HG/T 2250—1991氧化铁黑颜料[S]. 北京: 化学工业出版社, 2000.Chemical industry Standard of the People's Republic of China. Iron oxide black pigment HG/T 2250—1991[S]. Beijing: Chemical Industry Press, 2000. Chemical industry Standard of the People's Republic of China. Iron oxide black pigment HG/T 2250—1991[S]. Beijing: Chemical Industry Press, 2000. |
[15] | 郝晓斌. 硫铁矿烧渣制备软磁铁氧体原料的研究[D]. 武汉: 武汉理工大学, 2007.HAO X B. Preparation of soft ferrite from pyrite cinder [D]. Wuhan: Wuhan University of Technology, 2007. HAO X B. Preparation of soft ferrite from pyrite cinder [D]. Wuhan: Wuhan University of Technology, 2007. |
[16] | 中华人民共和国国家标准. GB/T 1863—2008氧化铁颜料[S]. 北京: 中国标准出版社, 2008.National standards of the People's Republic of China. GB/T 1863—2008 Iron oxide pigment [S]. Beijing: Standards Press of China, 2008. National standards of the People's Republic of China. GB/T 1863—2008 Iron oxide pigment [S]. Beijing: Standards Press of China, 2008. |
Comparison before and after adding dispersants
XRD patterns of iron oxide black samples
SEM analysis of iron oxide black samples
XRD patterns of iron oxide red samples
SEM analysis of iron oxide red samples
XRD patterns of iron oxide yellow samples
SEM analysis of iron oxide yellow samples