Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological SciencesHost
2023 No. 4
Article Contents

Zhu Zhimin, Lin Jian, Zhang Guoli, Zeng Xiaojun, Chen Chao, Li Xiaoyu, Liu Yingdong. Comprehensive Utilizations of the Strategic Mineral Resources from Vanadium Titano-Magnetite Tailings in the Panxi Region, SW China[J]. Multipurpose Utilization of Mineral Resources, 2023, 44(4): 42-49. doi: 10.3969/j.issn.1000-6532.2023.04.006
Citation: Zhu Zhimin, Lin Jian, Zhang Guoli, Zeng Xiaojun, Chen Chao, Li Xiaoyu, Liu Yingdong. Comprehensive Utilizations of the Strategic Mineral Resources from Vanadium Titano-Magnetite Tailings in the Panxi Region, SW China[J]. Multipurpose Utilization of Mineral Resources, 2023, 44(4): 42-49. doi: 10.3969/j.issn.1000-6532.2023.04.006

Comprehensive Utilizations of the Strategic Mineral Resources from Vanadium Titano-Magnetite Tailings in the Panxi Region, SW China

  • This is an essay in the field of mineral processing engineering. Extraction of the vanadium titano-magnetite ore deposits in the Panxi Region, the biggest vanadium titano-magnetite mineral resource base, results in the production of a significant volume of tailings. The tailings have a high recovery potential of the strategic mineral resources (eg.,Vi, Ti, Fe, Co, Cu, Ni, P, and Sc). Based on the process mineralogy study, we determine the comprehensive utilization technology flowsheet and conduct a systematic recovery test of tailing samples from the Hongge mine in the Panxi Region. By the process of (1) flotation of sulfur, (2) low-intensity magnetic separation of iron, (3) high-intensity magnetic separation and flotation of titanium, (4) flotation of Phosphorous, we obtain the sulfur-cobalt concentrate (Co 0.175%), the iron concentrate (TFe 56.57%), the titanium concentrate (TiO2 45.97%) and phosphorous concentrate (P2O5 31.73%). These results show that the systematic recovery test of tailings can reduce the production of a volume of tailings with significant economic and social benefits.

  • 加载中
  • [1] Kossoff D, Dubbin W E, Alfredsson M, et al. Mine tailings dams: characteristics, failure, environmental impacts, and remediation[J]. Applied Geochemistry, 2014, 51:229-245. doi: 10.1016/j.apgeochem.2014.09.010

    CrossRef Google Scholar

    [2] Lottermoser B. Mine Wastes: Characterization, treatment and environmental impacts[M]. Springer, Berlin, Heidelberg, New York, 2007.

    Google Scholar

    [3] Mason L, Prior T D, Mudd G M, et al. Availability, addiction and alternatives: three criteria for assessing the impact of peak minerals on society[J]. Journal of Cleaner Production, 2010, 19:958-966.

    Google Scholar

    [4] 王海军, 王伊杰, 李文超, 等. 全国矿产资源节约与综合利用报告(2019) [M]. 北京: 地质出版社, 2020.

    Google Scholar

    WANG H J, WANG Y J, LI W C, et al. Report on national conservation and comprehensive utilization of mineral resources (2019)[M]. Beijing: Geological Publishing House, 2020.

    Google Scholar

    [5] 舒敏, 刘昆, 李德军, 等. 铁尾矿资源化利用标准化现状及对策研究[J]. 中国标准化, 2021(6):154-158. SHU M, LIU K, LI D J, et al. Study on standardization status and countermeasures of iron tailings resource utilization[J]. China Standardization, 2021(6):154-158.

    Google Scholar

    SHU M, LIU K, LI D J, et al. Study on standardization status and countermeasures of iron tailings resource utilization[J]. China Standardization, 2021(6): 154-158.

    Google Scholar

    [6] Provornaya I V, Yurkevich N V, Dzuba Y A. Mine Tailings: Environmental damage and resource potential[J]. IOP Conference Series:Earth and Environmental Science, 2020, 459:022084. doi: 10.1088/1755-1315/459/2/022084

    CrossRef Google Scholar

    [7] 路畅, 陈洪运, 傅梁杰, 等. 铁尾矿制备新型建筑材料的国内外进展[J]. 材料导报, 2021, 35(5):511-526. LU C, CHEN H Y, FU L J, et al. Research progress on the preparation of new building materials using iron tailings[J]. Materials Review, 2021, 35(5):511-526.

    Google Scholar

    LU C, CHEN H Y, FU L J, et al. Research progress on the preparation of new building materials using iron tailings[J]. Materials Review, 2021, 35(5): 511-526.

    Google Scholar

    [8] 李德先, 王锦, 张长青, 等. 冀东司家营铁矿尾矿特征及综合利用建议[J]. 地质学报, 2022, 96(4):1460-1468. LI D X, WANG J, ZHANG C Q, et al. Tailing characteristics and comprehensive utilization suggestions of the Sijiaying iron ore deposit in eastern Hebei Province[J]. Acta Geologica Sinica, 2022, 96(4):1460-1468.

    Google Scholar

    LI D X, WANG J, ZHANG C Q, et al. Tailing characteristics and comprehensive utilization suggestions of the Sijiaying iron ore deposit in eastern Hebei Province[J]. Acta Geologica Sinica, 2022, 96(4): 1460-1468.

    Google Scholar

    [9] Hudson-Edwards K A, Macklin M G, Jamieson H E, et al. The impact of tailings dam spills and clean-up operations on sediment and water quality in river systems: the Rios Agrio-Guadiamar, Aznalcollar, Spain[J]. Applied Geochemistry, 2003, 18:221-239. doi: 10.1016/S0883-2927(02)00122-1

    CrossRef Google Scholar

    [10] 王茜, 廖阮颖子, 田小林, 等. 四川省攀西地区钒钛磁铁矿[M]. 北京: 科学出版社, 2015.

    Google Scholar

    WANG Q, LIAO R Y Z, TIAN X L, et al. Vanadium Titano-Magnetite deposits in the Panxi region, Sichuan province[M]. Beijing: Science Press, 2015.

    Google Scholar

    [11] 周家云, 毛益林, 邓杰, 等. 攀西地区金属矿山尾矿资源化综合利用[M]. 武汉: 中国地质大学出版社, 2021.

    Google Scholar

    ZHOU J Y, MAO Y L, DENG J, et al. Comprehensive utilization of tailings in the Panxi Region[M]. Wuhan: China University of Geosciences Press, 2021.

    Google Scholar

    [12] 朱志敏, 刘应冬, 陈超, 等. 攀枝花矿业城市矿山地质环境调查成果报告[R]. 成都: 中国地质科学院矿产综合利用研究所, 2021.

    Google Scholar

    ZHU Z M, LIU Y D, CHEN C, et al. Report of mining geo-environment survey of the Panzhihua mining city[R]. Chengdu: Institute of Multipurpose Utilization of Mineral Resources, CAGS, 2021.

    Google Scholar

    [13] 黄霞光, 罗国清, 李亚平. 攀西钒钛磁铁矿中钪的赋存状态研究[J]. 有色金属(选矿部分), 2016(6):1-4. HUANG X G, LUO G Q, LI Y P. Study on the occurrence state of scandium in Panxi vanadium-titanium magnetite[J]. Nonferrous Metals(Mineral Processing Section), 2016(6):1-4.

    Google Scholar

    HUANG X G, LUO G Q, LI Y P. Study on the occurrence state of scandium in Panxi vanadium-titanium magnetite[J]. Nonferrous Metals(Mineral Processing Section), 2016(6): 1-4.

    Google Scholar

    [14] 李潇雨, 朱志敏, 周家云, 等. 钒钛磁铁矿尾矿资源调查取样方法比较——以红格尾矿库为例[J]. 矿产综合利用, 2020(6):96-99. LI X Y, ZHU Z M, ZHOU J Y, et al. Comparison of sampling methods for investigation of vanadium-titanium magnetite tailings resources - taking Hongge tailings pond as an example[J]. Multipurpose Utilization of Mineral Resources, 2020(6):96-99.

    Google Scholar

    LI X Y, ZHU Z M, ZHOU J Y, et al. Comparison of sampling methods for investigation of vanadium-titanium magnetite tailings resources -- taking Hongge tailings pond as an example[J]. Multipurpose Utilization of Mineral Resources, 2020(6): 96-99.

    Google Scholar

    [15] Xiao J H, Chen C, Ding W, et al. Extraction of phosphorous from a phosphorous-containing vanadium titano-magnetite tailings by direct flotation[J]. Processes, 2020, 8:874. doi: 10.3390/pr8070874

    CrossRef Google Scholar

    [16] 吕子虎, 赵登魁, 程宏伟, 等. 某钒钛磁铁矿尾矿资源化利用[J]. 有色金属(选矿部分), 2020(1):55-58. LV Z H, ZHAO D K, CHENG H W, et al. Resource utilization of titanomagnetite tailings[J]. Nonferrous Metals (Mineral Processing Section), 2020(1):55-58.

    Google Scholar

    LV Z H, ZHAO D K, CHENG H W, et al. Resource utilization of titanomagnetite tailings[J]. Nonferrous Metals (Mineral Processing Section), 2020(1): 55-58.

    Google Scholar

    [17] 印万忠, 徐东, 杨耀辉, 等. 承德某钒钛磁铁矿尾矿资源化利用技术研究[J]. 矿产综合利用, 2020(6):37-42. YIN W Z, XU D, YANG Y H, et al. Research on the recycling technology for a vanadium-titanium magnetite tailings in Chengde[J]. Multipurpose Utilization of Mineral Resources, 2020(6):37-42.

    Google Scholar

    YIN W Z, XU D, YANG Y H, et al. Research on the recycling technology for a vanadium-titanium magnetite tailings in Chengde[J]. Multipurpose Utilization of Mineral Resources, 2020(6): 37-42.

    Google Scholar

    [18] 刘能云, 陈超, 张裕书, 等. 从尾矿中回收钛铁矿的实验研究[J]. 矿冶工程, 2020, 40(1):65-68. LIU N Y, CHEN C, ZHANG Y S, et al. Experimental study on recovery of ilmenite from tailings[J]. Mining and Metallurgical Engineering, 2020, 40(1):65-68.

    Google Scholar

    LIU N Y, CHEN C, ZHANG Y S, et al. Experimental study on recovery of ilmenite from tailings[J]. Mining and Metallurgical Engineering, 2020, 40(1): 65-68.

    Google Scholar

    [19] 邹锋, 殷志刚, 陈思竹. 攀枝花白马选铁尾矿综合回收利用研究[J]. 矿产综合利用, 2020(6):19-25. ZOU F, YIN Z G, CHEN S Z. Research on cmprehensiveutilization of iron tailings from Baima Panzhihua[J]. Multipurpose Utilization of Mineral Resources, 2020(6):19-25. doi: 10.3969/j.issn.1000-6532.2020.06.004

    CrossRef Google Scholar

    ZOU F, YIN Z G, CHEN S Z. Research on cmprehensiveutilization of iron tailings from Baima Panzhihua[J]. Multipurpose Utilization of Mineral Resources, 2020(6): 19-25. doi: 10.3969/j.issn.1000-6532.2020.06.004

    CrossRef Google Scholar

    [20] 黄雯孝, 卢可可. 攀西钒钛磁铁矿尾矿中钪的提取工艺研究[J]. 矿产综合利用, 2020(2):135-139. HUANG W X, LU K K. Study on scandium extraction technology for Panxi vanadium titanium magnetite tailings[J]. Multipurpose Utilization of Mineral Resources, 2020(2):135-139.

    Google Scholar

    HUANG W X, LU K K. Study on scandium extraction technology for Panxi vanadium titanium magnetite tailings[J]. Multipurpose Utilization of Mineral Resources, 2020(2): 135-139.

    Google Scholar

    [21] 王浚杰, 肖军辉, 张烨毓, 等. 从攀西地区含钪钒钛磁铁矿尾矿中回收钪研究[J]. 矿冶工程, 2021, 41(6):61-64. WANG J J, XIAO J H, ZHANG Y Y, et al. Recovery of scandium resource from Sc-bearing vanadium-titanium magnetite tailings in Panxi Region[J]. Mining and Metallurgical Engineering, 2021, 41(6):61-64. doi: 10.3969/j.issn.0253-6099.2021.06.015

    CrossRef Google Scholar

    WANG J J, XIAO J H, ZHANG Y Y, et al. Recovery of scandium resource from Sc-bearing vanadium-titanium magnetite tailings in Pan-Xi Region[J]. Mining and Metallurgical Engineering, 2021, 41(6) : 61-64. doi: 10.3969/j.issn.0253-6099.2021.06.015

    CrossRef Google Scholar

    [22] 邓杰, 张渊, 刘飞燕, 等. 钒钛磁铁矿选铁尾矿中硫钴资源综合回收研究[J]. 有色金属(选矿部分), 2015(2):30-33+48. DENG J, ZHANG Y, LIU F Y, et al. Recovery of cobalt and sulfur from the iron ore tailing of vanadium-titanium magnetite[J]. Nonferrous Metals(Mineral Processing Section), 2015(2):30-33+48.

    Google Scholar

    DENG J, ZHANG Y, LIU F Y, et al. Recovery of cobalt and sulfur from the iron ore tailing of vanadium-titanium magnetite[J]. Nonferrous Metals(Mineral Processing Section), 2015(2): 30-33+48.

    Google Scholar

    [23] 陈超, 张裕书, 李潇雨, 等. 攀西某钒钛磁铁矿尾矿中磷的回收实验研究. 矿产综合利用, 2021(4): 165-169.

    Google Scholar

    CHEN C, ZHANG Y S, LI X Y, et al. Recovery of phosphorus from a vanadium titanium magnetite tailing in Panxi [J]. Multipurpose Utilization of Mineral Resources, 2021(4): 165-169.

    Google Scholar

    [24] 陈超, 张裕书, 李潇雨, 等. 钛磁铁矿选矿技术研究进展[J]. 矿产综合利用, 2021(3):99-105. CHEN C, ZHANG YS, LI X Y, et al. Research progress in titanium-magnetite beneficiation technology[J]. Multipurpose Utilization of Mineral Resources, 2021(3):99-105.

    Google Scholar

    CHEN C, ZHANG YS, LI X Y, et al. Research progress in titanium-magnetite beneficiation technology [J]. Multipurpose Utilization of Mineral Resources, 2021(3): 99-105.

    Google Scholar

    [25] 肖仪武. 钒钛磁铁矿矿石基因特性及其对选铁的影响[J]. 矿产综合利用, 2021(5):198-201. XIAO Y W. Ore genetic characteristics of vanadium-titanium magnetite and its influence for mineral processing[J]. Multipurpose Utilization of Mineral Resources, 2021(5):198-201. doi: 10.3969/j.issn.1000-6532.2021.05.033

    CrossRef Google Scholar

    XIAO Y W. Ore genetic characteristics of vanadium-titanium magnetite and its influence for mineral processing[J]. Multipurpose Utilization of Mineral Resources, 2021(5): 198-201. doi: 10.3969/j.issn.1000-6532.2021.05.033

    CrossRef Google Scholar

  • 加载中
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Figures(6)

Tables(10)

Article Metrics

Article views(1310) PDF downloads(385) Cited by(0)

Access History

Catalog

    /

    DownLoad:  Full-Size Img  PowerPoint