Development Status and Comprehensive Utilization of Kaolin

Feng Xueru; Deng Jian; Yan Weiping; Li Weisi

doi:10.3969/j.issn.1000-6532.2022.06.001

2022 No. 6

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Article navigation > Multipurpose Utilization of Mineral Resources > 2022 > 43(6): 1-10

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Feng Xueru, Deng Jian, Yan Weiping, Li Weisi. Development Status and Comprehensive Utilization of Kaolin[J]. Multipurpose Utilization of Mineral Resources, 2022, 43(6): 1-10. doi: 10.3969/j.issn.1000-6532.2022.06.001

Citation:

Feng Xueru, Deng Jian, Yan Weiping, Li Weisi. Development Status and Comprehensive Utilization of Kaolin[J]. Multipurpose Utilization of Mineral Resources, 2022, 43(6): 1-10. doi: 10.3969/j.issn.1000-6532.2022.06.001

Development Status and Comprehensive Utilization of Kaolin

Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological Sciences, Chengdu, Sichuan, China

Received Date: 18 September 2022

Publish Date: 25 December 2022

Abstract

Abstract

Kaolin is a kind of widely used metalloid mineral resources, China is the first country to discover and make use of kaolin, and kaolin reserves rank front in the world. Although kaolin reserves are large in China, with the expansion of its application field, resources are seriously in short supply, and the price rises accordingly. Especially, high quality high-end kaolin processing products are far from meeting the demand of market consumption. The main development of kaolin in China was reviewed in this paper the present situation, the comprehensive utilization of field development progress, and summarized the development and use of kaolin, booster formation kaolin mineral resources development and utilization of innovative concept, way of exploring the development and application of kaolin resources, promote efficiency of utilization of kaolin to promote China's economic sustainable development of high quality.
- Kaolin /
- Development present situation /
- Comprehensive utilization progress

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References

[1]	郭春雷, 马莹, 赵拓, 等. 南方某高岭土除铁增白实验[J]. 矿产综合利用, 2022, 43(4):183-187. doi: 10.3969/j.issn.1000-6532.2022.04.031 CrossRef Google Scholar GUO C L, MA Y, ZHAO T, et al. Experimental study on iron removal and whitening of a kaolin in South China[J]. Multipurpose Utilization of Mineral Resources, 2022, 43(4):183-187. doi: 10.3969/j.issn.1000-6532.2022.04.031 CrossRef Google Scholar
[2]	汪先三. 我国高岭土开发利用现状及应用前景[J]. 中国非金属矿工业导刊, 2016(2):8-9,19. doi: 10.3969/j.issn.1007-9386.2016.02.003 CrossRef Google Scholar WANG X S. Exploitation and application prospects of kaolin in China[J]. China Non-metallic Minerals Industry, 2016(2):8-9,19. doi: 10.3969/j.issn.1007-9386.2016.02.003 CrossRef Google Scholar
[3]	任伟. 浅谈高岭土的成因类型及开发应用[J]. 西部探矿工程, 2015, 27(5):105-107. doi: 10.3969/j.issn.1004-5716.2015.05.036 CrossRef Google Scholar REN W. Discussion on genetic types and development and application of kaolin[J]. West-China Exploration Engineering, 2015, 27(5):105-107. doi: 10.3969/j.issn.1004-5716.2015.05.036 CrossRef Google Scholar
[4]	刘玉海, 李海明. 四川某煤系高岭土工艺矿物学研究[J]. 矿产综合利用, 2019(4): 94-97. Google Scholar LIU Y H, LI H M. Study on process mineralogy of coal-series kaolin from Sichuan[J]. Multipurpose Utilization of Mineral Resources. 2019(4): 94-97. Google Scholar
[5]	申继学. 马鸿文. 高岭土资源及高岭石合成技术研究进展[J]. 硅酸盐通报. 2016. 35(4): 1150-1158. Google Scholar SHEN J X, MA H W. Research progress in kaolin resources and kaolinite synthesis technology[J]. Bulletin of the Chinese Ceramic Society. 2016. 5(4): 1150-1158. Google Scholar
[6]	王雪静, 周继红, 黄浪, 等. 不同产地高岭土的组成和结构研究[J]. 中国非金属矿工业导刊, 2006(1):27-29. doi: 10.3969/j.issn.1007-9386.2006.01.008 CrossRef Google Scholar WANG X J, ZHOU J H, HUANG L, et al. Study on the composition and structure of kaolin in different area[J]. China Non-metallic Minerals Industry, 2006(1):27-29. doi: 10.3969/j.issn.1007-9386.2006.01.008 CrossRef Google Scholar
[7]	任瑞晨, 宋金虎, 李彩霞, 等. 旋流器提纯煤泥伴生高岭土及底流浮选试验研究[J]. 非金属矿, 2015, 38(6):59-61. doi: 10.3969/j.issn.1000-8098.2015.06.018 CrossRef Google Scholar REN R C, SONG J H, LI C X, et al. Experimental study on purification of kaolin by hydrocyclone and underflow flotation test with slime[J]. Non-Metallic Mines, 2015, 38(6):59-61. doi: 10.3969/j.issn.1000-8098.2015.06.018 CrossRef Google Scholar
[8]	易龙生, 王三海, 冯泽平, 等. 离心氯化焙烧提纯澳大利亚某高岭土实验研究[J]. 非金属矿, 2014, 37(5):25-27. doi: 10.3969/j.issn.1000-8098.2014.05.008 CrossRef Google Scholar YI L S, WANG S H, FENG Z P, et al. Research on purification of an australian kaolin by centrifugation and chloridizing roasting[J]. Nonmetallic Minerals, 2014, 37(5):25-27. doi: 10.3969/j.issn.1000-8098.2014.05.008 CrossRef Google Scholar
[9]	陈剑, 李晨. 应用SLon立环脉动高梯度磁选机提纯非金属矿[J]. 中国非金属矿工业导刊, 2013(4):48-50. doi: 10.3969/j.issn.1007-9386.2013.04.015 CrossRef Google Scholar CHEN J, LI C. Application of SLon high-gradient vertical-ring magnetic separator in the field of non-metallic minerals purification the field of non-metallic minerals purification[J]. China Non-metallic Minerals Industry, 2013(4):48-50. doi: 10.3969/j.issn.1007-9386.2013.04.015 CrossRef Google Scholar
[10]	屈彬, 柯善军. 高岭土梯度磁分离除铁的研究[J]. 陶瓷, 2016(9):33-37. doi: 10.3969/j.issn.1002-2872.2016.09.007 CrossRef Google Scholar QU B, KE S J. Study on deferrization of kaoline using the gradient magnetic separation[J]. Ceramics, 2016(9):33-37. doi: 10.3969/j.issn.1002-2872.2016.09.007 CrossRef Google Scholar
[11]	洪微. 煤尾矿中硬质高岭土选矿提纯试验研究[D]. 武汉: 武汉理工大学, 2014. Google Scholar HONG W. Study of benefication and purification on hard kaolin from coal tailings [D]. Wuhan: Wuhan University of Technology, 2014. Google Scholar
[12]	曹学鹏. 富黄铁矿高岭土综合回收利用研究[D]. 长沙: 中南大学, 2014. Google Scholar CAO X P. Research on comprehensive recovery and utilization of pyrite-rich kaolin[D]. Changsha: Central South University, 2014. Google Scholar
[13]	余力, 刘全军, 高扬, 等. 四川叙永某高岭土增白实验研究[J]. 硅酸盐通报, 2016, 35(10):3157-3161+3166. doi: 10.16552/j.cnki.issn1001-1625.2016.10.012 CrossRef Google Scholar YU L, LIU Q J, GAO Y, et al. Bleaching test of kaolin from Xuyong in Sichuan[J]. Bulletin of the Chinese Ceramic Society, 2016, 35(10):3157-3161+3166. doi: 10.16552/j.cnki.issn1001-1625.2016.10.012 CrossRef Google Scholar
[14]	S·A·拉维山卡尔, 李长根, 肖力子. 在高岭土加工中应用螯合类型表面活性剂的优势[J]. 国外金属矿选矿, 2007(5):14-16+44. Google Scholar S. A. LAVISHANKAR, LI C G, XIAO L Z. Application of chelating surfactants in Kaolin processing[J]. Metal Ore Dressing Abroad, 2007(5):14-16+44. Google Scholar
[15]	陈武生, 聂光华, 申少贺. 贵州某高岭土除铁试验研究[J]. 广州化工, 2013, 41(22):97-99. doi: 10.3969/j.issn.1001-9677.2013.22.036 CrossRef Google Scholar CHEN W S, NIE G H, SHENG S H. Experimental research on certain kaolin deironing in Guizhou[J]. Guangzhou Chemical Industry, 2013, 41(22):97-99. doi: 10.3969/j.issn.1001-9677.2013.22.036 CrossRef Google Scholar
[16]	雷绍民, 龚文琪, 袁楚雄. 微生物浸出煤系高岭土中黄铁矿的初步研究[J]. 武汉工业大学学报, 2000(2):8-10,14. Google Scholar LEI S M, GONG W Q, YUAN C X. Study on compatibility of fiber optical sensor in construct of concrete[J]. Journal of Wuhan University of Technology, 2000(2):8-10,14. Google Scholar
[17]	孙宝岐. 高岭土的化学漂白提纯[J]. 江苏陶瓷, 1994(1):2-7. doi: 10.16860/j.cnki.32-1251/tq.1994.01.001 CrossRef Google Scholar SUN B Q. Purification of kaolin by chemical bleaching[J]. Jiangsu Ceramics, 1994(1):2-7. doi: 10.16860/j.cnki.32-1251/tq.1994.01.001 CrossRef Google Scholar
[18]	吕宪俊. 高岭土中染色物质的赋存形式及其漂白工艺的选择[J]. 中国非金属矿工业导刊, 2004(4):8-12. doi: 10.3969/j.issn.1007-9386.2004.04.002 CrossRef Google Scholar LV X J. Study on the occurrence form and bleaching process of kaolin[J]. China Non-Metallic Ore Industry, 2004(4):8-12. doi: 10.3969/j.issn.1007-9386.2004.04.002 CrossRef Google Scholar
[19]	付月华. 二氧化硫脲对高岭土增白试验研究[D]. 郑州: 郑州大学, 2016. Google Scholar FU Y H. Study on bleaching test of kaolin using thiourea dioxide[D]. Zhengzhou: Zhengzhou University, 2016. Google Scholar
[20]	姬梦姣, 雷绍民, 黄腾, 等. 低品位煤系高岭土焙烧脱除碳质物实验研究[J]. 无机盐工业, 2015, 47(11):53-56. Google Scholar JI M J, LEI S M, HUANG T, et al. Research on reduction carbonaceous material in low grade coal-series kaolin with roasting[J]. Inorganic Chemicals Industry, 2015, 47(11):53-56. Google Scholar
[21]	夏光华, 陈翌斌, 何婵, 等. 磁化焙烧法强化高岭土磁选除铁增白工艺研究[J]. 功能材料, 2015, 46(3):3144-3147. doi: 10.3969/j.issn.1001-9731.2015.03.031 CrossRef Google Scholar XIA G H, CHEN Y B, HE C, et al. Processes study on magnetization roasting method to strengthen whitening kaolin by magnetic separating removal iron method[J]. Journal of Functional Materials, 2015, 46(3):3144-3147. doi: 10.3969/j.issn.1001-9731.2015.03.031 CrossRef Google Scholar
[22]	任瑞晨, 陈康, 李成龙, 等. 煤泥伴生高岭土提纯与增白试验研究[J]. 非金属矿, 2017, 40(2):55-58. doi: 10.3969/j.issn.1000-8098.2017.02.015 CrossRef Google Scholar REN R C, CHEN K, LI C L, et al. Experimental study on purifying and whitening of coal slime associated kaolin[J]. Non-metallic ore, 2017, 40(2):55-58. doi: 10.3969/j.issn.1000-8098.2017.02.015 CrossRef Google Scholar
[23]	乔炜, 邹伟曦, 陈强. 剥片高岭土的开发与应用[J]. 非金属矿, 2007(S1):19-20. doi: 10.3969/j.issn.1000-8098.2007.z1.008 CrossRef Google Scholar QIAO W, ZOU W X, CHEN Q. Development and application of peeled kaolin[J]. Non-metallic Ore, 2007(S1):19-20. doi: 10.3969/j.issn.1000-8098.2007.z1.008 CrossRef Google Scholar
[24]	曹青, 李奥. 插层剂对高岭土插层改性的研究进展[J]. 中国陶瓷, 2016, 52(4):6-11. doi: 10.16521/j.cnki.issn.1001-9642.2016.04.002 CrossRef Google Scholar CAO Q, LI A. Research Progress on modification of kaolin intercalation[J]. China Ceramics, 2016, 52(4):6-11. doi: 10.16521/j.cnki.issn.1001-9642.2016.04.002 CrossRef Google Scholar
[25]	唐武飞, 谷晓昱, 张胜, 等. 磷酸二氢钾插层改性高岭土复合物的制备与表征[J]. 光谱学与光谱分析, 2015, 35(2):462-465. doi: 10.3964/j.issn.1000-0593(2015)02-0462-04 CrossRef Google Scholar TANG W F, GU X Y, ZHANG S, et al. Preparation and characterization of kaolinite-potassium dihydrogen phosphate intercalation composite[J]. Spectroscopy and Spectral Analysis, 2015, 35(2):462-465. doi: 10.3964/j.issn.1000-0593(2015)02-0462-04 CrossRef Google Scholar
[26]	张永利, 朱佳, 史册, 等. 高岭土的改性及其对Cr(Ⅵ)的吸附特性[J]. 环境科学研究, 2013, 26(5):561-568. doi: 10.13198/j.res.2013.05.100.zhangyl.012 CrossRef Google Scholar ZHANG Y L, ZHU J, SHI C, et al. Modification of kaolin and its adsorption properties on Cr(VI)[J]. Research of Environmental Science, 2013, 26(5):561-568. doi: 10.13198/j.res.2013.05.100.zhangyl.012 CrossRef Google Scholar
[27]	宋海兵. 煅烧高岭土的生产简述与全干法煅烧工艺制度[J]. 中国非金属矿工业导刊, 2004(1):19-23. doi: 10.3969/j.issn.1007-9386.2004.01.005 CrossRef Google Scholar SONG H B. Production brief of calcined kaolin and whole dry calcination process[J]. China Non-Metallic Minerals Industry, 2004(1):19-23. doi: 10.3969/j.issn.1007-9386.2004.01.005 CrossRef Google Scholar
[28]	欧延, 林敬东, 陈文瑞, 等. 酸改性高岭土的结构与性能的研究[J]. 厦门大学学报(自然科学版), 2004(2):272-274. Google Scholar OU Y, LIN J D, CHEN W R, et al. A study on structure and characteristic of acid- modified kaolin[J]. Journal of Xiamen University(Natural Science), 2004(2):272-274. Google Scholar
[29]	刘从华, 高雄厚, 张忠东, 等. 改性高岭土性能研究Ⅰ酸性和催化活性[J]. 石油炼制与化工, 1999(4):34-40. Google Scholar LIU C H, GAO X H, ZHANG Z D, et al. Study on the per formance of modified kaolin[J]. Petroleum Processing and Petrochemicals, 1999(4):34-40. Google Scholar
[30]	JOZEFACIUK G, BOWANKO G. Effect of acid and alkali treatments on surface areas and adsorption energies of selected minerals[J]. Clays and Clay Minerals, 2002, 50(6):771-783. doi: 10.1346/000986002762090308 CrossRef Google Scholar
[31]	郑云锋, 李荻, 陈淑琨, 等. 催化裂化催化剂专用高岭土改性研究进展[J]. 工业催化, 2012, 20(11):1-5. doi: 10.3969/j.issn.1008-1143.2012.11.001 CrossRef Google Scholar ZHENG Y F, LI D, CHEN S K, et al. Progress in modification research on kaolin used for catalytic cracking catalysts[J]. Industrial Catalysis, 2012, 20(11):1-5. doi: 10.3969/j.issn.1008-1143.2012.11.001 CrossRef Google Scholar
[32]	李新梅, 吴哈申, 张冬云, 等. 改性煤系高岭土在吸附方面的研究进展[J]. 内蒙古石油化工, 2013, 39(21):1-3. Google Scholar LI X M, WU H S, ZHANG D Y, et al. The research progress of activated coal-bearing kaolinite in adsorption respect[J]. Inner Mongolia Petrochemical Industry, 2013, 39(21):1-3. Google Scholar
[33]	刘建国. 高岭土在生产橡胶管填料中的应用[J]. 化工管理, 2018(2):154-156. doi: 10.3969/j.issn.1008-4800.2018.02.129 CrossRef Google Scholar LIU J G. Application of kaolin in rubber tube filler production[J]. Chemical Management, 2018(2):154-156. doi: 10.3969/j.issn.1008-4800.2018.02.129 CrossRef Google Scholar
[34]	周丽, 冯琦, 李远兵, 等. 煤系高岭土在耐火材料中的应用[J]. 耐火材料, 2021, 55(3):272-276. doi: 10.3969/j.issn.1001-1935.2021.03.019 CrossRef Google Scholar ZHOU L, FENG Q, LI Y B, et al. Application of coal series kaolin in refractories[J]. Refractories, 2021, 55(3):272-276. doi: 10.3969/j.issn.1001-1935.2021.03.019 CrossRef Google Scholar
[35]	蔡广超, 马驰, 黄科林, 等. 高岭土综合利用技术研究进展[J]. 大众科技, 2013, 15(166):111-114,25. Google Scholar CAI G C, MA C, HUANG K L, et al. The Research and progress on comprehensive utilization technology of kaolin[J]. Popular Science & Technology, 2013, 15(166):111-114,25. Google Scholar
[36]	亓春英, 刘星, 周跃飞. 高岭土的综合利用与发展前景[J]. 昆明理工大学学报(理工版), 2003, 28(2):4-7. Google Scholar QI C Y, LIU X, ZHOU Y F. Kaolin' s comprehensive utilization and developing prospect[J]. Journal of Kunming University of Science and Technology(Natural Science), 2003, 28(2):4-7. Google Scholar
[37]	凤孟龙, 田辉平, 张万弘, 等. 不同高岭土系黏土性质及在催化裂化催化剂中的应用[J]. 工业催化, 2018, 26(10):20-26. doi: 10.3969/j.issn.1008-1143.2018.10.003 CrossRef Google Scholar FENG M L, TIAN H P, ZHANG W H, et al. Properties of different kaolin clays and their application in FCC catalysts[J]. Industrial Catalysis, 2018, 26(10):20-26. doi: 10.3969/j.issn.1008-1143.2018.10.003 CrossRef Google Scholar
[38]	王文宗, 黄河. 改性煤系煅烧高岭土在电缆中的应用[J]. 非金属矿, 2009, 32(S1):24-25. doi: 10.3969/j.issn.1000-8098.2009.z1.013 CrossRef Google Scholar WANG W Z, HUANG H. Application of modified coal measure calcined kaolin in cable[J]. Non-metallic Ore, 2009, 32(S1):24-25. doi: 10.3969/j.issn.1000-8098.2009.z1.013 CrossRef Google Scholar
[39]	高传平, 王燕民, 潘志东. 纳米高岭土作为润滑添加剂的减摩行为[J]. 硅酸盐学报, 2014, 42(4):506-513. doi: 10.7521/j.issn.0454－5648.2014.04.14 CrossRef Google Scholar GAO C P, WANG Y M, PAN Z D. Friction reducing behavior of kaolin clay nanoparticles as lubricating additive[J]. Journal of the Chinese Ceramic Society, 2014, 42(4):506-513. doi: 10.7521/j.issn.0454－5648.2014.04.14 CrossRef Google Scholar
[40]	G MAINAK, TAO Y Y, LEE B, et al. Natural kaolin: sustainable technology for instantaneous and energy neutral recycling of anthropogenic mercury emissions[J]. Chem Sus Chem, 2019. Google Scholar
[41]	ZHANG Q, YAN Z, O Y J, et al. Chemically modified kaolinite nanolayers for the removal of organic pollutants[J]. Applied Clay Science, 2018, 157:283-290. doi: 10.1016/j.clay.2018.03.009 CrossRef Google Scholar
[42]	Boge Z, Yanping H, Zebin Y, et al. Three-dimensional electro-fenton degradation of rhodamine B with efficient Fe-Cu/kaolin particle electrodes: Electrodes optimization, kinetics, influencing factors and mechanism[J]. Separation and Purification Technology, 2018, 210:60-68. Google Scholar
[43]	李霞, 邓昭平, 李晶. 高岭土在盐湖卤水提锂中的应用[J]. 化工进展, 2017, 36(6):2057-2063. doi: 10.16085/j.issn.1000-6613.2017.06.013 CrossRef Google Scholar LI X, DENG Z P, LI J. Application of kaolin in the extraction of lithium from salt lake brine[J]. Chemical Industry Progress, 2017, 36(6):2057-2063. doi: 10.16085/j.issn.1000-6613.2017.06.013 CrossRef Google Scholar
[44]	汪红梅, 周婷婷, 孟维鑫, 等. 改性高岭土处理劣化汽轮机油的研究[J]. 石油化工, 2017, 46(12):1491-1495. doi: 10.3969/j.issn.1000-8144.2017.12.009 CrossRef Google Scholar WANG H M, ZHOU T T, MENG W X, et al. Modified kaolin used in the degradation of turbine oil adsorption process[J]. Petrochemical Industry, 2017, 46(12):1491-1495. doi: 10.3969/j.issn.1000-8144.2017.12.009 CrossRef Google Scholar
[45]	仇影, 吴其胜, 黎水平, 等. 二元有机/煤系高岭土复合相变储能材料的制备及其热性能[J]. 材料科学与工程学报, 2013, 31(2):268-272. doi: 10.14136/j.cnki.issn1673-2812.2013.02.022 CrossRef Google Scholar QIU Y, WU Q S, LI S P, et al. Preparation and thermal properties of binary preparation and thermal properties of binary organic/kaolin composites as shape stabilized phase change material for thermal energy storage[J]. Journal of Materials Science and Engineering, 2013, 31(2):268-272. doi: 10.14136/j.cnki.issn1673-2812.2013.02.022 CrossRef Google Scholar
[46]	S AHMET. Fabrication and thermal characterization of kaolin-based composite phase change materials for latent heat storage in buildings[J]. Energy and Buildings, 2015, 96:193-200. doi: 10.1016/j.enbuild.2015.03.022 CrossRef Google Scholar
[47]	陈祉如, 姚兴茂, 尹翔鹏. 应用于太阳能热发电站的高岭土基相变储热材料的制备[J]. 可再生能源, 2019, 37(3):37-41. doi: 10.3969/j.issn.1671-5292.2019.03.006 CrossRef Google Scholar CHEN Z R, YAO X M, YIN X P. Preparation of kaolin based phase change thermal storage materials for solar thermal power plant[J]. Renewable Energy Resources, 2019, 37(3):37-41. doi: 10.3969/j.issn.1671-5292.2019.03.006 CrossRef Google Scholar
[48]	沈耀生. 利用高岭土制备4A分子筛[J]. 云南化工, 2019, 46(10):8-11. Google Scholar SHEN Y S. Preparation of 4A zeolite from kaolin[J]. Yunnan Chemical Industry, 2019, 46(10):8-11. Google Scholar
[49]	蔡建. 我国高岭土加工技术现状与发展趋势[J]. 非金属矿, 2005, 28(S1):9-11. Google Scholar CAI J. Current status and development trend of kaolin processing technology in China[J]. Non-metallic Ore, 2005, 28(S1):9-11. Google Scholar
[50]	朱华. 高岭土应用的工业进展及现状[J]. 矿业工程, 2005, 3(6):25-26. doi: 10.3969/j.issn.1671-8550.2005.06.013 CrossRef Google Scholar ZHU H. Status & future of application of kaolin in industrial fields[J]. Mining Engineering, 2005, 3(6):25-26. doi: 10.3969/j.issn.1671-8550.2005.06.013 CrossRef Google Scholar
[51]	韩利雄, 姚远, 刘国斌. 国内外玻璃纤维用高岭土的质量差距及提高我国高岭土质量的对策[J]. 矿产综合利用, 2011(5):7-10. doi: 10.3969/j.issn.1000-6532.2011.05.002 CrossRef Google Scholar HAN L X, YAO Y, LIU G B. Differences of kaolin quality for glass fibers made in China and abroad and improving measures of kaolin quality made in China[J]. Multipurpose Utilization of Mineral Resources, 2011(5):7-10. doi: 10.3969/j.issn.1000-6532.2011.05.002 CrossRef Google Scholar
[52]	BECK J S, VARTULI J C, ROTH W J, et al. A new family of fesoporous molecular sieves prepared with liquid crystal templates[J]. J Am Chem Soc, 1992, 114(27):10834. doi: 10.1021/ja00053a020 CrossRef Google Scholar
[53]	ZHAO D Y, FENG J L, HUO Q S, et al. Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores[J]. Science, 1998, 279:548. doi: 10.1126/science.279.5350.548 CrossRef Google Scholar
[54]	龙梅. 高岭石基复合材料的性能调控及其生物医学应用探索[D]. 长沙: 中南大学, 2019. Google Scholar LONG M. Study on the properties of kaolinite matrix composites and its application in Biomedicine [D]. Changsha: Central South University, 2019. Google Scholar
[55]	吴瑾, 杨喆, 李翔, 等. 高岭土/壳聚糖载药微球的制备及性能研究[J]. 非金属矿, 2021, 44(5):1-5. doi: 10.3969/j.issn.1000-8098.2021.05.001 CrossRef Google Scholar WU J, YANG Z, LI X, et al. Preparation and properties of kaolin/chitosan microspheres[J]. Non-metallic Ore, 2021, 44(5):1-5. doi: 10.3969/j.issn.1000-8098.2021.05.001 CrossRef Google Scholar
[56]	TANG W, YUAN Y, LIN D, et al. Kaolin - reinforced 3D MBG scaffolds with hierarchical architecture and robust mechanical strength for bone tissue engineering[J]. Journal of Materials Chemistry B, 2014, 2(24):3782-3790. doi: 10.1039/C4TB00025K CrossRef Google Scholar