Citation: | FANG Jian, WU Dandan, WEN Shuming, ZHANG Song, LIN Qiqiang. Research Progress on Comprehensive Recovery and Utilization of Rhenium Resources[J]. Conservation and Utilization of Mineral Resources, 2020, 40(5): 62-69. doi: 10.13779/j.cnki.issn1001-0076.2020.05.008 |
Rhenium is a rare precious metal on the earth. It is often found in molybdenite, porphyry and other minerals. It plays a very important role in the fields of aerospace and petrochemical industry. At present, one of the most important methods to recover rhenium resources is to extract rhenium from molybdenum concentrates. In this paper, the process of rhenium extraction from molybdenum concentrate is summarized, which including the whole wet process and the combined process of calcination and wet leaching. Meanwhile, the separation and extraction method of rhenium in solution containing rhenium is introduced and summarized. Finally the development direction of the comprehensive recovery and utilization of rhenium resources is prospected.
[1] | 李平.人大代表何以心血"铼"潮[N].中国矿业报, 2020-05-25(002). |
[2] | USGS. Mineral commodity summaries 2020[R]. 2020. https://doi.org/10.3133/mcs2020. |
[3] | 杨尚磊, 陈艳, 薛小怀, 等.铼(Re)的性质及应用研究现状[J].上海金属, 2005(1):45-49, 4. |
[4] | UCHENNA KESIEME, ANDREAS CHRYSANTHOU, MAURIZIO CATULLI. Assessment of supply interrup-tion of rhenium, recycling, processing sources and technologies[R]. 2019, 82: 150-158. |
[5] | HISAO HORI, YUTA YOSHIMURA, TAKAFUMI OTSU, et al. Efficient photochemical recovery of rhenium from aqueous solutions[J]. Separation and Purification Technology, 2015, 156:242-248. |
[6] | ANDERSON C D, TAYLOR P R, ANDERSON C G. Extractive metallurgy of rhenium:a review[J]. Mining, Metallurgy & Exploration, 2013, 30(1):59-73. |
[7] | 陈喜峰, 陈秀法, 李娜, 等.全球铼矿资源分布特征与开发利用形势及启示[J].中国矿业, 2019, 28(5):7-12, 23. |
[8] | 党晓娥, 孟裕松, 王璐, 宋永辉.铜钼矿冶炼过程铼的行为研究与工业应用实践[J].有色金属(冶炼部分), 2017(6):45-52. |
[9] | CAO Z F, ZHONG H, LIU G Y, et al. Electric-oxidation extraction of molybdenite concentrate in alkaline NaCl electrolyte[J]. Journal of Central South University of Technology, 2010, 17(3):480-484. |
[10] | LINDSTROM R E, SCHEINER B J.用电氧化法从精矿中提取钼和铼[J].稀有金属与硬质合金, 1980(1):1-15. |
[11] | 曹占芳, 钟宏, 姜涛, 等.德兴铜矿钼精矿精矿的选择性电氧化浸出与分离过程研究[J].中国有色金属学报, 2013(8):2290-2295. |
[12] | 贾丽娟.钼精矿超声电氧化分解新工艺的研究[D].长沙: 中南大学, 2008: 10-11. |
[13] | FU J G, ZHONG H, BU X M, et al. Electro-oxidation process for molybdenum concentrates[J]. Journal of Central South University of Technology(English Edition), 2005(2):134-139. |
[14] | 董海刚, 刘杨, 范兴祥, 等.铼的回收技术研究进展[J].有色金属(冶炼部分), 2013(6):30-33. |
[15] | 李天锁.氧压煮钼精矿工艺的应用研究[J].中国钼业, 2018, 42(3):38-43. |
[16] | 郭株辉.钼精矿氨加压浸出钼铼分离试验研究[J].中国钼业, 2019, 43(1):9-13. |
[17] | ZAMANI M A A, HIROYOSHI N, TSUNEKAWA M, et al. Bioleaching of Sarcheshmeh molybdenite concentrate for extraction of rhenium[J]. Hydrometallurgy, 2005, 80(1-2):23-31. |
[18] | 曹占芳, 钟宏, 姜涛, 等.辉钼矿中钼和铼分离过程研究[J].现代化工, 2012, 32(12):49-52. doi: 10.3969/j.issn.0253-4320.2012.12.012 |
[19] | 符剑刚, 钟宏, 吴江丽, 等.常温常压条件下钼精矿的湿法浸出[J].金属矿山, 2004(12):35-38. doi: 10.3321/j.issn:1001-1250.2004.12.011 |
[20] | 徐彪, 王鹏程, 谢建宏.从钼精矿中综合回收铼的新工艺研究[J].矿冶工程, 2012, 32(1):92-94. doi: 10.3969/j.issn.0253-6099.2012.01.025 |
[21] | FAN X H, DENG Q, GAN M, et al. Roasting oxidation behaviors of ReS2 and MoS2 in powdery rhenium-bearing, low-grade molybdenum concentrate[J].中国有色金属学报(英文版), 2019, 29(4):840-848. |
[22] | 马高峰, 郭金亮, 白宏斌, 等.复合型钼矿中铼的回收及环保治理[J].材料导报, 2012, 26(S1):328-333. |
[23] | 刘红召, 刘玲, 张博, 等.自热式回转窑钼精矿焙烧系统中铼走向研究[J].有色金属(冶炼部分), 2019(11):42-45. |
[24] | 刘红召, 王寒飞, 张博, 等.钼精矿多膛炉焙烧系统中铼走向分布的研究[J].有色金属(冶炼部分), 2020(6):48-52. |
[25] | 范晓慧, 汪国靖, 甘敏, 等.钙化焙烧-酸浸工艺提取钼精矿中铼的研究[J].矿冶工程, 2017, 37(6):71-75. |
[26] | SHARIAT M H, HASSANI M. Rhenium recovery from Sarcheshmeh molybdenite concentrate[J]. Journal of Materials Processing Technology, 1998, 74(1-3):243-250. |
[27] | 林泓富.钼精矿中铼回收工艺研究[J].有色冶金设计与研究, 2016, 37(4):10-13. |
[28] | 赵恒勤, 井小静, 刘红召, 等.钼精矿焙烧烟尘中回收铼和钼的研究[J].有色金属(冶炼部分), 2019(2):47-50. |
[29] | 刘伟, 丁留亮, 李继文, 等.碱熔-水浸法从钼精矿焙烧烟尘中回收铼和钼[J].稀有金属, 2018, 42(9):959-969. |
[30] | 沈强, 宣日荣, 李广安.碱浸置换法从烟道灰中提取铼的工艺研究[J].浙江冶金, 2002, 11(4):32-34. |
[31] | 陈昆昆, 操齐高, 张卜升, 等.高温合金酸浸液回收高纯铼酸铵试验研究[J].有色金属(冶炼部分), 2019(9):45-48. |
[32] | 李静.化学沉淀法分离铜冶炼废酸中的铜和铼[J].湿法冶金, 2016, 35(5):440-443. doi: 10.13355/j.cnki.sfyj.2016.05.017 |
[33] | JOO S H, KIM Y U, KANG J G, et al. Recovery of Molybdenum and Rhenium Using Selective Precipitation Method from Molybdenite Roasting Dust in Alkali Leaching Solution[J]. Materials Transactions, 2012, 53(11):2038-2042. |
[34] | 程光荣.铼的回收方法[J].中国钼业, 1993(4):34-40. |
[35] | 刘红召, 王力军, 张博, 等.一种弱碱性树脂对淋洗液中铼的静态吸附性能[J].稀有金属, 2017, 41(9):1028-1034. |
[36] | NEBEKER N, HISKEY J B. Recovery of rhenium from copper leach solution by ion exchange[J]. Hydrometallurgy, 2012, 125-126:64-68. |
[37] | TAO H, LIU M B, Ma J, et al. Selective recovery of Rhenium from industrial leach solutions by synergistic solvent extraction[J]. Separation and Purification Technology, 2020, 236. |
[38] | JINGU KANG, YUNGUK KIM, SUNGHO JOO, et al. Behavior of Extraction, Stripping and Separation Possibilities of Rhenium and Molybdenum from Molybdenite Roasting Dust Leaching Solution Using Amine Based Extractant Tri-Otyl-Amine(TOA)[J]. Materials Transactions, 2013, 54:1209-1212. |
[39] | 蒋克旭, 翟玉春, 熊英, 等.新型三烷基胺萃淋树脂合成及提取分离铼钼研究[J].有色金属(冶炼部分), 2010(2):35-37. |
[40] | 宿延涛, 任宇, 王凤菊, 等.磁性N235萃淋树脂的制备及其对铼的吸附性能研究[J].铀矿冶, 2019, 38(1):29-33. |
[41] | 李玉萍, 李莉芬, 王献科.液膜法提取高纯铼[J].中国钼业, 2001(6):24-27. |
[42] | SANG YUN SEO, WAN SEOP CHOI, TAE JIN YANG, et al. Recovery of rhenium and molybdenum from a roaster fume scrubbing liquor by adsorption using activated carbon[J]. Hydrometallurgy, 2012, 129-130:145-150. |
[43] | LOU Z N, XU R, ZHANG S Q, et al. Extraction of Re(VII) from hydrochloric acid medium by N263/TBP/n-heptane/NaCl microemulsion[J]. Hydrometallurgy, 2016, 165:329-335. |
Flow chart of oxidizing roasting process
Flow chart of lime roasting process
Flow chart of ion-exchange resin process
Process flow chart of solvent extraction method