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2024 Vol. 45, No. 4
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XUE Ge, WANG Xiaohu, DAO Yan, ZHOU Jiaxi, XING Cheng, XIAO Gaoqiang, SU Xiaoyu, CAO Xiaomin, DONG Tao, LI Rong, LUO Jianhong. 2024. Metallogenic Regularity of Germanium in Yunnnan Province. Acta Geoscientica Sinica, 45(4): 481-492. doi: 10.3975/cagsb.2024.052402
Citation: XUE Ge, WANG Xiaohu, DAO Yan, ZHOU Jiaxi, XING Cheng, XIAO Gaoqiang, SU Xiaoyu, CAO Xiaomin, DONG Tao, LI Rong, LUO Jianhong. 2024. Metallogenic Regularity of Germanium in Yunnnan Province. Acta Geoscientica Sinica, 45(4): 481-492. doi: 10.3975/cagsb.2024.052402
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Metallogenic Regularity of Germanium in Yunnnan Province

  • 1. Yunnan Institute of Geological Survey, Kunming, Yunnan 650051;

  • 2. Key Laboratory of Sanjiang Metallogeny and Resources Exploration and Utilization, Ministry of Natural Resources, Kunming, Yunnan 650051;

  • 3. Faculty of Land Resources Engineering, Kunming University of Science and Technology, Kunming, Yunnan 650093;

  • 4. Yunnan Key Laboratory of Sanjiang Metallogeny and Resources Exploration and Utilization, Kunming, Yunnan 650051;

  • 5. Key Laboratory of Critical Minerals Metallogeny in Universities of Yunnan Province, School of Earth Sciences, Yunnan University, Kunming, Yunnan 650500

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  • Corresponding author: DAO Yan  
    Abstract
  • Germanium (Ge) is a strategic mineral in China, and an advantageous mineral in Yunnan Province.There is a large reserve of Ge resources, a high degree of development and utilization, and a large space for prospecting in Yunnnan Province.The types of Ge ore deposits in Yunnan Province mainly include two types of coal-bearing type and carbonate hosting type germanium deposits.The coal-bearing germanium deposits are mainly distributed in Tengchong, Mangshi, Cangyuan, Lincang, Lancang and other regions in western Yunnan Province, and their formation ages are relatively concentrated in the Neogene time; the carbonate hosting germanium deposits are mainly distributed in Dongchuan, Huize, Yiliang, Ludian and other regions in northeastern Yunnan Province, and are symbiotic with lead-zinc deposit.The formation period of these deposits is generally recognized in the Triassic period.This paper comprehensively introduces the metallogenic geological conditions and spatial distribution characteristics of typical germanium deposits of above two types, summarizes the mineralization patterns of Ge resources, and proposes 23 prediction areas for Ge exploration in Yunnan Province.Meanwhile, it is necessary to strengthen the research on prospecting and comprehensive recycling of replacement resources in the deep and peripheral areas of existing Ge deposits, and to carry out prospecting exploration and target area optimization work for various prediction areas, in order to increase the storage of Ge resources in the old area and the prospecting breakthrough in the new area as soon as possible, so as to provide resources and technical support for a world-class Ge resource industrial base and national Ge resource strategic reserve demand.
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    • References
  • 陈进, 1993.麒麟厂铅锌硫化物矿床成因及成矿模式探讨[J].有色金属矿产与勘查, (2): 85-90.

    Google Scholar

    陈骏, 2019.关键金属超常富集成矿和高效利用[J].科技导报, 37(24): 1.

    Google Scholar

    陈世杰, 1984.黔西滇东北铅锌矿床的沉积成因探讨[J].贵州地质, 8(3): 56-62.

    Google Scholar

    陈星全, 屈金芝, 张艳松, 等, 2021.2021-2035 年世界锗矿产品供需形势分析[J].中国矿业, 30(3): 37-42.

    Google Scholar

    代世峰, 魏强, 王西勃, 等, 2021.煤型锗矿床[M].北京: 科学出版社.

    Google Scholar

    邓明国, 秦德先, 雷振, 等, 2003.滇西褐煤中锗富集规律及远景评价[J].昆明理工大学学报(理工版), 28(1): 1-7.

    Google Scholar

    翟明国, 吴福元, 胡瑞忠, 等, 2019.战略性关键金属矿产资源:现状与问题[J].中国科学基金, 33(2): 106-111.

    Google Scholar

    高德荣, 2000.会泽铅锌矿床成矿地质条件及找矿方向[J].昆明理工大学学报, 25(4): 19-24.

    Google Scholar

    韩润生, 陈进, 黄智龙, 等, 2006.构造成矿动力学及隐伏矿定位预测--以云南会泽超大型铅锌银、锗矿床为例[M].北京: 科学出版社.

    Google Scholar

    韩润生, 胡煜昭, 王学琨, 等, 2012.滇东北富锗银铅锌多金属矿集区矿床模型[J].地质学报, 86(2): 280-294.

    Google Scholar

    韩润生, 王峰, 胡煜昭, 等, 2014.会泽型(HZT)富锗银铅锌矿床成矿构造动力学研究及年代学约束[J].大地构造与成矿学, 38(4): 758-771.

    Google Scholar

    韩润生, 吴鹏, 张艳, 等, 2022.西南特提斯川滇黔成矿区富锗铅锌矿床成矿理论研究新进展[J].地质学报, 96(2):554-573.

    Google Scholar

    侯增谦, 陈骏, 翟明国, 2020.战略性关键矿产研究现状与科学前沿[J].科学通报, 65(33): 3651-3652.

    Google Scholar

    胡瑞忠, 毕献武, 苏文超, 等, 1997.对煤中锗矿化若干问题的思考-以临沧锗矿为例[J].矿物学报, 17(4): 364-368.

    Google Scholar

    胡瑞忠, 毕献武, 叶造军, 等, 1996.临沧锗矿床成因初探[J].矿物学报, 16(2): 97-102.

    Google Scholar

    胡瑞忠, 苏文超, 戚华文, 等, 2000.锗的地球化学、赋存状态和成矿作用[J].矿物岩石地球化学通报, 19(4): 215-217.

    Google Scholar

    黄智龙, 陈进, 韩润生, 等, 2004.云南会泽超大型铅锌矿床地球化学及成因-兼论峨眉山玄武岩与铅锌成矿的关系[M].北京: 地质出版社.

    Google Scholar

    李余华, 2000.临沧锗矿床地质特征[J].云南地质, 19(3):263-269.

    Google Scholar

    刘锋, 2005.云南会泽大型铅锌矿床成矿机制及锗的赋存状态[D].北京: 中国地质科学院.

    Google Scholar

    刘欢, 张长青, 吉晓佳, 等, 2022.云南会泽铅锌矿床闪锌矿中稀散元素锗的差异性富集规律研究[J].矿床地质, 41(5):1057-1072.

    Google Scholar

    刘建楠, 丁建华, 陈炳翰, 等, 2023.中国锗矿成矿规律概要[J].矿床地质, 42(2): 267-86.

    Google Scholar

    刘正义, 张玉燕, 尹金双, 等, 2014.临沧盆地超大型锗(铀)矿床成矿机理及其模拟实验[J].东华理工大学学报(自然科学版), 37(1): 1-7.

    Google Scholar

    柳贺昌, 林文达, 1999.滇东北铅锌银矿床规律研究[M].昆明:云南大学出版社.

    Google Scholar

    马奎, 洛桑才仁, 陈超, 等, 2019.全球锗资源分布、供需及消费趋势研究[J].矿产保护与利用, 5: 16-25.

    Google Scholar

    毛景文, 杨宗喜, 谢桂青, 等, 2019.关键矿产-国际动向与思考[J].矿床地质, 38(4): 689-698.

    Google Scholar

    戚华文, 胡瑞忠, 2002.临沧锗矿床的微量元素地球化学[J].煤田地质与勘探, 30(2): 1-3.

    Google Scholar

    戚华文, 胡瑞忠, 苏文超, 等, 2001.临沧锗矿床的稀土元素地球化学研究[J].矿物学报, 21(4): 689-694.

    Google Scholar

    任辉, 林中湘, 白维灿, 等, 2023.我国锗矿资源供应现状及可持续发展对策建议[J].中国煤炭地质, 35(5): 1-5.

    Google Scholar

    山成栋, 2020.会泽铅锌矿富锗闪锌矿的沉淀机制研究[D].北京: 中国地质大学(北京).

    Google Scholar

    陶琰, 胡瑞忠, 唐永永, 等, 2019.西南地区稀散元素伴生成矿的主要类型及伴生富集规律[J].地质学报, 93(6):1210-1230.

    Google Scholar

    涂光炽, 高振敏, 胡瑞忠, 2004.分散元素地球化学及成矿机制[M].北京: 地质出版社.

    Google Scholar

    汪毓煌, 1992.滇西褐煤伴生元素锗的富集与评价[J].煤田地质与勘探, 20(3): 24-30.

    Google Scholar

    王登红, 2019.关键矿产的研究意义、矿种厘定、资源属性、找矿进展、存在问题及主攻方向[J].地质学报, 93(6):1189-1209.

    Google Scholar

    温汉捷, 朱传威, 杜胜江, 等, 2020.中国镓锗铊镉资源[J].科学通报, 65(33): 3688-3699.

    Google Scholar

    叶霖, 韦晨, 胡宇思, 等, 2019.锗的地球化学及资源储备展望[J].矿床地质, 38(4): 711-728.

    Google Scholar

    云南省地质调查局, 2022.云南省锗矿潜力预测成果图说明书[R].昆明: 云南省地质调查局.

    Google Scholar

    张淑苓, 王淑英, 尹金双, 1987.云南临沧地区帮卖盆地含铀煤中锗矿的研究[J].铀矿质, 3(5): 267-275, 266.

    Google Scholar

    张淑苓, 尹双金, 王淑英, 1988.云南帮卖盆地煤中锗存在形式的研究[J].沉积学报, (3): 29-40.

    Google Scholar

    张位及, 1984.试论滇东北铅锌矿床的沉积成因和成矿规律[J].地质与勘探, (7): 11-16.

    Google Scholar

    张艳, 韩润生, 魏平堂, 等, 2017.云南会泽矿山厂铅锌矿床流体包裹体特征及成矿物理化学条件[J].吉林大学学报(地球科学版), 47(3): 719-733.

    Google Scholar

    赵汀, 王登红, 刘超, 等, 2019.中国锗矿成矿规律与开发利用现状[J].地质学报, 93(6): 1245-1251.

    Google Scholar

    周朝宪, 1998.滇东北麟麒厂锌铅矿床成矿金属来源, 成矿流体特征和成矿机理研究[J].矿物岩石地球化学通报, 17(1):34-36.

    Google Scholar

    BERNSEIN L R, 1985.Germanium geochemistry and mineralogy[J].Geochimica et Cosmochimica Acta, 49(11): 2409-2422.

    Google Scholar

    CHEN Jin, 1993.A Discussion on the Genesis and Metallogenic Model of the Qilinchang Pb-Zn Sulfide Deposit[J].Non-Ferrous Mineral Resources and Exploration, (2):85-90(in Chinese with English abstract).

    Google Scholar

    CHEN Jun, 2019.Supernormal enrichment and high efficient utilization of key metals[J].Science and technology Guide, Science & Technology Review, 37(24): 1.

    Google Scholar

    CHEN Shijie, 1984.A Discussion on the Sedimentary Origin of Pb-Zn Deposits in Western Guizhou and Northeastern Yunnan[J].Guizhou Geology, 8(3): 56-62(in Chinese with English abstract).

    Google Scholar

    CHEN Xingquan, QU Jinzhi, ZHANG Yansong, et al., 2021.Analysis of the global germanium resource supply and demand situation from 2021 to 2035[J].China Mining Magazine, 30(3): 37-42(in Chinese with English abstract).

    Google Scholar

    CONG Feng, WU Fuyuan, LI Wenchang, et al., 2020.Origin of the Triassic Lincang granites in the southeastern Xizang Plateau:Crystallization from crystal mush[J].Lithos, (360/361):105452.

    Google Scholar

    COOK N J, CIOBANU C L, PRING A, et al., 2009.Trace and minorelements in sphalerite: A LA-ICP-MS study[J].Geochimica et Cosmochimica Acta, 73(16): 4761-4791.

    Google Scholar

    DAI Shifeng, WEI Qiang, WANG Xibo, et al., 2021.Coal-bearing geimanium deposits[M].Beijing: Science Press(in Chinese).

    Google Scholar

    DENG Mingguo, QIN Dexian, LEI Zhen, et al., 2003.Germanium resources evaluation in hydrogenous coal in the West of Yunnan and formation ore geologic condition[J].Journal of Kunming University of Science and Technology(Science and Technology), 28(1): 1-7(in Chinese with English abstract).

    Google Scholar

    FRENZEL M, KETRIS M P, GUTZMER J, 2014.On the geological availability of germanium[J].Mineralium Deposita, 49(4):471-486.

    Google Scholar

    FROELICH P N, HAMBRICK G A, KAUL L W, et al., 1985.Geochemical behavior of inorganic germanium in an unperturbed estuary[J].Geochimica et Cosmochimica Acta, 49(2): 519-524.

    Google Scholar

    GAO Derong, 2000.The ore-forming geological condition and the ore prospecting direction of Huize lead zinc deposit[J].Journal of Kunming University of Science and Technology, 24(4):19-24(in Chinese with English abstract).

    Google Scholar

    HAN Runsheng, CHEN Jin, HUANG Zhilong, et al., 2006.Dynamic dynamics of formation and prediction of hidden ore localization-Take Yunnan Huize super large lead-zinc-silver, germa-nium deposit as an example[M].Beijing: Science Press(in Chinese).

    Google Scholar

    HAN Runsheng, HU Yuzhao, WANG Xuekun, et al., 2012.Mineralization model of rich Ge-Ag-bearing Zn-Pb polymetallic deposit concentrated district in Northeastern Yunnan, China[J].Acta Geologica Sinica, 86(2): 280-294(in Chinese with English abstract).

    Google Scholar

    HAN Runsheng, WANG Feng, HU Yuzhao, et al., 2014.Metallogenic Tectonic Dynamics andChronology Constrains on the Huize-Type (HZT) Germanium-Rich Silver-Zinc-Lead Deposits[J].Geotectonic et Metallogenia, 38(4): 758-771(in Chinese with English abstract).

    Google Scholar

    HAN Runsheng, WU Peng, ZHANG Yan, et al., 2022.New research progress in metallogenic theory for rich Zn-Pb-(Ag-Ge)deposits in the Sichuan-Yunnan-Guizhou Triangle(SYGT) area, southwestern Tethys[J].Acta Geologica Sinica, 96(2):554-573(in Chinese with English abstract).

    Google Scholar

    HÖLL R, KLING M, SCHROLL E, 2007.Metallogenesis of germanium-A review[J].Ore Geology Reviews, 30(3/4): 145-180.

    Google Scholar

    HOU Zengqian, CHEN Jun, ZHAI Mingguo, 2020.Current status and frontiers of research on critical mineral resources[J].Chinese Science Bulletin, 65(33): 3651-3652(in Chinese with English abstract).

    Google Scholar

    HU Ruizhong, BI Xianwu, SU Wenchao, et al., 1997.Some considerations on germanium mineralization in coal-asexemplified by Lincang germanium deposit[J].Acta Mineralogica Sinica, 17(4):364-368(in Chinese with English abstract).

    Google Scholar

    HU Ruizhong, BI Xianwu, YE Zaojun, et al., 1996.The genesis of Lincang germanium deposit-Apreliminary investigation[J].Acta Mineralogica Sinica, 16(2): 97-1021(in Chinese with English abstract).

    Google Scholar

    HU Ruizhong, SU Wenchao, QI Huawen, et al., 2000.The geochemistry, occurrence and metallogeny of germanium[J].Bulletin of Mineralogy, Petrology and Geochemistry, 19(4):215-217(in Chinese with English abstract).

    Google Scholar

    HUANG Zhilong, CHEN Jin, HAN Runsheng, et al., 2004.Geochemistry and causes of super large lead-zinc deposits in Huize, Yunnan Province-On the relationship between Emei Mountain basalt and lead-zinc mineralization[M].Beijing:Geological Publishing House(in Chinese).

    Google Scholar

    HUANG Zhi-long, LI Wenbo, CHEN Jin, et al., 2003.Carbon and oxygen lsotope constraints on mantle fluid involvement in the mineralization of the Huize super-Large Pb-Zn deposits, Yunnan Province, China[J].Journal of Geochemical Exploration, 78-79: 637-642.

    Google Scholar

    LI Yu-hua, 2000.The geological characteristic of Lincang Ge deposit[J].Yunnan Geology, 19(3): 263-269(in Chinese with English abstract).

    Google Scholar

    LIU Feng, 2005.The metallogenetic mechanism of the Huize lead-zinc ore deposit and the occurrence of gemanium, Yunnan Province, China (dissertation for Master degree)[D].Beijing: Chinese Academy of Geological Sciences(in Chinese with English abstract).

    Google Scholar

    LIU Hechang, LIN Wenda, 1999.Metallogenic Rules of Zn Pb-(Ag) Deposits in Northeastern Yunnan[M].Kunming: Yunnan University Publishing House(in Chinese).

    Google Scholar

    LIU Huan, ZHANG Changqing, JI Xiaojia, et al., 2022.Differential enrichment of germanium in sphalerite from Huize lead-zinc deposit, Yunnan Province[J].Mineral Deposits, 41(5): 1057-1072(in Chinese with English abstract).

    Google Scholar

    LIU Jiannan, DING Jianhua, CHEN Binghan, et al., 2023.Metallogenic regularity of germanium in China[J].Mineral Deposits, 42(2): 267-28(in Chinese with English abstract).

    Google Scholar

    LIU Zhengyi, ZHANG Yuyan, YIN Jinshuang, et al., 2014.Metallogenic mechanism and simulating experiment of super large germanium-uranium deposit in Lincang basin[J].Journal of East China Institute of Technology, 37(1): 1-7(in Chinese with English abstract).

    Google Scholar

    MA Kui, LUO SANG Cairen, CHEN Chao, et al., 2019.Global germanium resource distribution, supply and demand and consumption trends[J].Conservation and Utilization of Mineral Resources, 5: 16-25(in Chinese with English abstract).

    Google Scholar

    MAO Jingwen, YANG Zongxi, XIE Guiqing, et al., 2019.Critical minerals: International trends and thinking[J].Mineral Deposits, 38(4): 689-698(in Chinese with English abstract).

    Google Scholar

    QI Huawen, HU Ruizhong, 2002.Trace element geochemistry of Lincang germanium deposit[J].Coal Geology & Exploration, 30(2): 1-3(in Chinese with English abstract).

    Google Scholar

    QI Huawen, HU Ruizhong, SU Wenchao, et al., 2001.REE ge-chemistry of Lincang super large germanium deposit[J].Acta Mineralogica Sinica, 21(4): 689-694(in Chinese with English abstract).

    Google Scholar

    REN Hui, LIN Zhongxiang, BAI Weican, et al., 2023.Current situation of germanium mineral resource supply and suggestions for sustainable development in China[J].Coal Geology of China, 35(5): 1-5(in Chinese with English abstract).

    Google Scholar

    SHAN Chendong, 2020.Study on the precipitation mechanism of germanium rich sphalerite in Huize lead-zinc mine[D].Beijing: China University of Geosciences (Beijing)(in Chinese with English abstract).

    Google Scholar

    TAO Yan, HU Ruizhong, TANG Yongyong, et al., 2019.Types of dispersed elements bearing ore-deposits and their enrichment re gularity in Southwest China[J].Acta Geologica Sinica, 93(6): 1210-1230(in Chinese with English abstract).

    Google Scholar

    TU Guangzhi, GAO Zhenmin, HU Ruizhong, 2004.Geochemistry and mineralization mechanism of dispersed elements[M].Beijing: Geological Publishing House(in Chinese).

    Google Scholar

    WANG Denghong, 2019.Study on critical resources: significance of research, determination of type, attributes of resources, progress of prospecting, problems of utilization, and direction of exploitation[J].Acta Geologica Sinica, 93(6): 1189-1209.

    Google Scholar

    WANG Yuhuang, 1992.Concentratiion law of the accompany element - germanium in the brown coal of western Yunnan province and its comprehensive evaluation[J].Coal Geology & Exploration, 20(3): 24-30(in Chinese with English abstract).

    Google Scholar

    WEN Hanjie, ZHU Chuanwei, DU Shenjiang, et al., 2020.Gallium(Ga), germanium(Ge), thallium (Tl) and cadmium(Cd)resources in China[J].Chinese Science Bulletin, 65(33): 3688-3699(in Chinese with English abstract).

    Google Scholar

    WOOD S A, SAMSON I M, 2006.The aqueous geochemistry of gall ium, germanium, indium and scandium[J].Ore Geology Reviews, 28(1): 57-102.

    Google Scholar

    YE Lin, WEI Chen, HU Yusi, et al., 2019.Geochemistry of germanium and its resources reserves[J].Mineral Deposits, 38(4):711-728(in Chinese with English abstract).

    Google Scholar

    YUDOVICH Y E, 2003.Notes on the marginal enrichment of germanium in coal beds[J].International Journal of Coal Geology, 56: 223-232.

    Google Scholar

    Yunnan Geological Survey, 2022.Manual for map of germanium ore potential prediction results of Yunnan[R].Kunming: Yunnan Geological Survey(in Chinese).

    Google Scholar

    ZHAI Mingguo, WU Fuyuan, HU Ruizhong, et al., 2019.Strategic critical metal mineral resources: status and problems[J].Bulletin of National Natural Science Foundation of China, 33(2):106-111(in Chinese with English abstract).

    Google Scholar

    ZHANG Shuling, WANG Shuying, YIN Shuangjin, 1987.The study of germanium ore in uranium-bearing coal of the Bangmai basin, Lincang region, Yunnan province[J].Uranium Geology, 3(5): 267-275, 266(in Chinese with English abstract).

    Google Scholar

    ZHANG Shuling, YIN Shuangjin, WANG Shuying, 1988.Study on existment forms of germanium in coal Bangmai Basin, Yunnan[J].Acta Sedimentologica Sinica, 6(3): 29-40(in Chinese with English abstract).

    Google Scholar

    ZHANG Weiji, 1984.A Preliminary Discussion on the Sedimentary Origin and Metallogenic Rule of Pb-Zn Deposits in NortheasternYunnan[J].Geology and Exploration, (7): 11-16(in Chinese with English abstract).

    Google Scholar

    ZHANG Yan, HAN Ruisheng, WEI Pingtang, et al., 2017.Fluid inclusion features and physicochemical conditions of the Kuangshanchang Pb-Zn deposit, Huize, Yunnan Province[J].Journal of Jilin University (Earth Science Edition), 47(3):719-733(in Chinese with English abstract).

    Google Scholar

    ZHAO Ting, WANG Denghong, LIU Chao, et al., 2019.Metallogenic and utilization status of Ge deposit in China[J].Acta Geologica Sinica, 93(6): 1245-1251(in Chinese with English abstract).

    Google Scholar

    ZHOU Chaoxian, 1998.The Source of Mineralizing Metals, Geochemical Characterization of Ore-FormingSolution, and Metallogenetic Mechanism of Qilingchang Pb-Zn Deposit, Northeastern Yunnan ProvinceChina[J].Bulletin of Mineralogy, Petrology and Geochemistry, 17(1): 34-36(in Chinese with English abstract).

    Google Scholar

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