Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological SciencesHost
2025 Vol. 45, No. 2
Article Contents

ZENG Fuhong, ZHOU Lanhua. Pre-reduction of Titanium Concentrate with Pulverized Coal and Iron Power Based on Response Surface Methodology Method[J]. Multipurpose Utilization of Mineral Resources, 2025, 46(2): 171-177. doi: 10.3969/j.issn.1000-6532.2025.02.024
Citation: ZENG Fuhong, ZHOU Lanhua. Pre-reduction of Titanium Concentrate with Pulverized Coal and Iron Power Based on Response Surface Methodology Method[J]. Multipurpose Utilization of Mineral Resources, 2025, 46(2): 171-177. doi: 10.3969/j.issn.1000-6532.2025.02.024

Pre-reduction of Titanium Concentrate with Pulverized Coal and Iron Power Based on Response Surface Methodology Method

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  • This is an article in the field of metallurgical engineering. The single factor and response surface experiments of heating reduction of titanium concentrate powder adding pulverized coal and iron powder were carried out, respectively so as to study the effects of temperature, heating time and iron powder addition on iron oxide reduction in titanium concentrate. The three regression model of iron metallization rate was constructed, and the influence law of various influencing factors on iron metallization rate was explored. The single factor test shows that the iron metallization rate can be significantly improved above 2.5% in the range of 1.5% ~ 4.0% of the addition amount of iron powder. The response surface method experiment shows that temperature is the most important factor, followed by time and then amount of iron powder, and the interaction between temperature and time is greater than that between heating time and the amount of iron powder added in the degree of influence on the reduction of iron. The iron metallization rate can reach 86.79%, and metallic iron obviously appears in the reduced product at the optimized conditions of 1 450 ℃, 33.5 min and 4% of iron power addition.

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  • [1] 刘立伟, 赵礼兵, 李国峰, 等. 某钒钛磁铁精矿深度还原-磁选试验研究[J]. 矿产综合利用, 2020(6): 56-63.LIU L W , ZHAO L B , LI G F, et al. Study on coal-based reduction followed by magnetic separation of a vanadium-titanium magnetite concentrate[J]. Multipurpose Utilization of Mineral, 2020(6): 56-63.

    Google Scholar

    LIU L W , ZHAO L B , LI G F, et al. Study on coal-based reduction followed by magnetic separation of a vanadium-titanium magnetite concentrate[J]. Multipurpose Utilization of Mineral, 2020(6): 56-63.

    Google Scholar

    [2] 范兴祥, 余宇楠, 袁威, 等. 利用云南钛铁精矿制备还原铁粉及富钛料的试验研究[J]. 矿产综合利用, 2018(2):52-56.FAN X X, YU Y N, YUAN W, et al. Experimental research on preparation of reduced iron powder and rich titanium materials from Yunnan titanium ore concentrate[J]. Multipurpose Utilization of Mineral, 2018(2):52-56.

    Google Scholar

    FAN X X, YU Y N, YUAN W, et al. Experimental research on preparation of reduced iron powder and rich titanium materials from Yunnan titanium ore concentrate[J]. Multipurpose Utilization of Mineral, 2018(2):52-56.

    Google Scholar

    [3] 付贵勤, 薛逊, 汪锋, 等. 钒钛酸性渣还原过程中钒钛赋存状态的研究[J]. 矿产资源综合利用, 2009(2):40-44.FU G Q, XUE X, WANG F, et al. Study on the occurrence of Ti during reduction process of the acidic vanadium -titanium[J]. Multipurpose Utilization of Mineral, 2009(2):40-44.

    Google Scholar

    FU G Q, XUE X, WANG F, et al. Study on the occurrence of Ti during reduction process of the acidic vanadium -titanium[J]. Multipurpose Utilization of Mineral, 2009(2):40-44.

    Google Scholar

    [4] 张世敏, 黄孟阳, 彭金辉, 等. 微波还原越南钛精矿制备初级富钛料新工艺研究[J]. 矿产资源综合利用, 2007(3):17-20.ZHANG S M, HUANG M Y, PENG J H, et al. Study on preparing primary titanium materials from self-reduced pellet 0f vietnam ilmenite concentrate by microwave reduction[J]. Multipurpose Utilization of Mineral, 2007(3):17-20.

    Google Scholar

    ZHANG S M, HUANG M Y, PENG J H, et al. Study on preparing primary titanium materials from self-reduced pellet 0f vietnam ilmenite concentrate by microwave reduction[J]. Multipurpose Utilization of Mineral, 2007(3):17-20.

    Google Scholar

    [5] 刘云龙, 郭培民, 庞建明, 等. 高杂质钛铁矿固态催化还原动力学研究[J]. 钢铁钒钛, 2013, 34(6):1-5.LIU Y L, GUO P M, PANG J M, et al. Kinetics study on solid-phase catalytic reduction of highly impure ilmenite by thermal analysis[J]. Iron Steel Vanadium Titanium, 2013, 34(6):1-5.

    Google Scholar

    LIU Y L, GUO P M, PANG J M, et al. Kinetics study on solid-phase catalytic reduction of highly impure ilmenite by thermal analysis[J]. Iron Steel Vanadium Titanium, 2013, 34(6):1-5.

    Google Scholar

    [6] Y. Zhao, F. Shadman. Kinetics and mechanism of ilmenite reduction with carbon monoxide[J]. AICHE Journal, 1990, 36(9):1433-1438. doi: 10.1002/aic.690360917

    CrossRef Google Scholar

    [7] J. Pesl, R. H. Eric. High temperature carbothermic reduction of Fe2O3-TiO2-MxOy oxide mixtures[J]. Minerals Engineering, 2002(15):971-984.

    Google Scholar

    [8] WANG Yu-ming, YUAN Zhang-fu, GUO Zhan-cheng, et al. Reduction mechanism of natural ilmenite with graphite[J]. Tansaction. Nonferrous Metals Society of China, 2008, 180:962-968.

    Google Scholar

    [9] C. S. Kucukkaragoz, R. H. Eric. Solid state reduction of a nature ilmenite[J]. Miners Engineering, 2006, 19:334-337. doi: 10.1016/j.mineng.2005.09.015

    CrossRef Google Scholar

    [10] Hai-peng GOU, Guo-hua ZHANG, Xiao-jun HU, et al. Kinetic study on carbothermicreduction of ilmenite with activated carbon[J]. Transactions of Nonferrous Metals Society of China, 2017, 27(8):1856-1861. doi: 10.1016/S1003-6326(17)60209-7

    CrossRef Google Scholar

    [11] 韩可喜. 钛精矿预还原球团冶炼钛渣的电耗水平分析[J]. 钢铁钒钛, 2014, 35(2):51-55.HAN K X. Analysis on electricity consumption for titanium slag smelting with pre-reduced concentrate pellets[J]. Iron Steel Vanadium Titanium, 2014, 35(2):51-55.

    Google Scholar

    HAN K X. Analysis on electricity consumption for titanium slag smelting with pre-reduced concentrate pellets[J]. Iron Steel Vanadium Titanium, 2014, 35(2):51-55.

    Google Scholar

    [12] 信晓飞, 张晋霞, 冯洪均. 响应曲面法优化含锌尘泥选择性浸出工艺[J]. 矿产综合利用, 2021(2):146-151.XIN X F, ZHANG J X, FENG H J. Optimization of selective leaching technology from zinc-bearing dust using response surface methodology[J]. Multipurpose Utilization of Mineral, 2021(2):146-151.

    Google Scholar

    XIN X F, ZHANG J X, FENG H J. Optimization of selective leaching technology from zinc-bearing dust using response surface methodology[J]. Multipurpose Utilization of Mineral, 2021(2):146-151.

    Google Scholar

    [13] 吕学伟, 张凯, 黄润, 等. 添加剂对钛精矿固相碳热还原强化作用的比较[J]. 东北大学学报(自然科学版), 2013, 34(11):1601-1605.LU X W, ZHANG K, HUANG R. Comparison of the effects of different additives on the solid phase carbon thermal reduction of ilmenite[J]. Journal of Northeastern University(Natural Science), 2013, 34(11):1601-1605.

    Google Scholar

    LU X W, ZHANG K, HUANG R. Comparison of the effects of different additives on the solid phase carbon thermal reduction of ilmenite[J]. Journal of Northeastern University(Natural Science), 2013, 34(11):1601-1605.

    Google Scholar

    [14] 郭兴敏, 唐洪福, 张圣弼. Li2CO3在含碳球团中催化机理的研究[J]. 金属学报, 2000, 36(6):638-641.GUO X M, TANG H F, ZHANG S B. Study on the catalysis mechanism of Li2CO3 for reduction of iron ore pellet with carbon[J]. Acta Metellurgical Sinica, 2000, 36(6):638-641.

    Google Scholar

    GUO X M, TANG H F, ZHANG S B. Study on the catalysis mechanism of Li2CO3 for reduction of iron ore pellet with carbon[J]. Acta Metellurgical Sinica, 2000, 36(6):638-641.

    Google Scholar

    [15] 刘牡丹, 姜涛, 李光辉. 硫酸钠和碳酸钠对高铝铁矿钠化还原动力学规律的影响[J]. 中国有色金属学报, 2015, 25(1):220-226.LIU M D, JIANG T, LI G H. Effects of Na2SO4 and Na2CO3 on sodium-reduction dynamics law of high aluminum iron ores[J]. The Chinese Journal of Nonferrous Metals, 2015, 25(1):220-226.

    Google Scholar

    LIU M D, JIANG T, LI G H. Effects of Na2SO4 and Na2CO3 on sodium-reduction dynamics law of high aluminum iron ores[J]. The Chinese Journal of Nonferrous Metals, 2015, 25(1):220-226.

    Google Scholar

    [16] 黄希祜. 钢铁冶金原理[M]. 北京: 冶金工业出版社, 2013.HUANG X G. Principles of iron and steel metallurgy [M]. Beijing: Metallurgical Industry Press, 2013.

    Google Scholar

    HUANG X G. Principles of iron and steel metallurgy [M]. Beijing: Metallurgical Industry Press, 2013.

    Google Scholar

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