Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological SciencesHost
2024 Vol. 45, No. 5
Article Contents

YANG Xiao, TAO Dongping, SHAO Huaizhi, SHEN Youyue. Research Progress of Nanobubble Flotation Technology[J]. Multipurpose Utilization of Mineral Resources, 2024, 45(5): 123-132. doi: 10.3969/j.issn.1000-6532.2024.05.018
Citation: YANG Xiao, TAO Dongping, SHAO Huaizhi, SHEN Youyue. Research Progress of Nanobubble Flotation Technology[J]. Multipurpose Utilization of Mineral Resources, 2024, 45(5): 123-132. doi: 10.3969/j.issn.1000-6532.2024.05.018

Research Progress of Nanobubble Flotation Technology

More Information
  • This is an article in the field of mineral processing engineering. Froth flotation is the main method for separating mineral particles. However, the conventional bubble size used in traditional flotation technology is relatively large, and the separation effect of fine particles is poor. As an important means to solve the problem of fine particle separation, nano bubbles have attracted extensive attention and in-depth research in the field of mineral flotation because of their unique physical and chemical properties. This article summarizes the research progress in the formation, preparation and stability of nano bubbles, introduces the application of nano bubble flotation in mineral processing and environmental treatment, and looks forward to the future research and development of nano bubble flotation.

  • 加载中
  • [1] 王澜, 艾光华, 杨冰, 等. 纳米技术浮选技术研究进展[J]. 矿产综合利用, 2020(1):29-32.WANG L, AI G H, YANG B, et al. Development of nano flotation technology[J]. Multipurpose Utilization of Mineral Resources, 2020(1):29-32.

    Google Scholar

    WANG L, AI G H, YANG B, et al. Development of nano flotation technology[J]. Multipurpose Utilization of Mineral Resources, 2020(1):29-32.

    Google Scholar

    [2] TAO D, SOBHY A. Nanobubble effects onhydrodynamic interactions between particles and bubbles[J]. Powder Technology, 2019, 346:385-395. doi: 10.1016/j.powtec.2019.02.024

    CrossRef Google Scholar

    [3] ZHANG F, XING Y, CHANG G, et al. Enhanced lignite flotation using interfacial nanobubbles based on temperature difference method[J]. Fuel, 2021, 293:120313. doi: 10.1016/j.fuel.2021.120313

    CrossRef Google Scholar

    [4] LEE J G, FLUMERFELT R W. A refined approach to bubble nucleation and polymer foaming process: dissolved gas and cluster size effects[J]. Journal of Colloid and Interface Science, 1996, 184(2):335-348. doi: 10.1006/jcis.1996.0628

    CrossRef Google Scholar

    [5] ERIKSSON J C, LJUNGGREN S. On the mechanically unstable free energy minimum of a gas bubble which is submerged in water and adheres to a hydrophobic wall[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 1999, 159(1):159-163. doi: 10.1016/S0927-7757(99)00171-5

    CrossRef Google Scholar

    [6] YOUNT D E, KUNKLE T D. Gas nucleation in the vicinity of solid hydrophobic spheres[J]. Journal of Applied Physics, 1975, 46(10):4484-4486. doi: 10.1063/1.321381

    CrossRef Google Scholar

    [7] ZHOU W, WU C, LV H, et al. Nanobubbles heterogeneous nucleation induced by temperature rise and its influence on minerals flotation[J]. Applied Surface Science, 2020, 508:145282. doi: 10.1016/j.apsusc.2020.145282

    CrossRef Google Scholar

    [8] LI D, QI L, LIU Y, et al. Study on the formation and properties of trapped nanobubbles and surface nanobubbles by spontaneous and temperature difference methods[J]. Langmuir, 2019, 35(37):12035-12041. doi: 10.1021/acs.langmuir.9b02058

    CrossRef Google Scholar

    [9] LUO L, WHITE H S. Electrogeneration of single nanobubbles at sub-50-nm-radius platinum nanodisk electrodes[J]. Langmuir, 2013, 29(35):11169-11175. doi: 10.1021/la402496z

    CrossRef Google Scholar

    [10] ETCHEPARE R, AZEVEDO A, CALGAROTO S, et al. Removal of ferric hydroxide by flotation with micro and nanobubbles[J]. Separation and Purification Technology, 2017, 184:347-353. doi: 10.1016/j.seppur.2017.05.014

    CrossRef Google Scholar

    [11] GAO Y, DASHLIBORUN A M, ZHOU J Z, et al. Formation and stability of cavitation microbubbles in process water from the oilsands industry[J]. Industrial & Engineering Chemistry Research, 2021, 60(7):3198-3209.

    Google Scholar

    [12] 黄艳. 浮选柱回收微细粒矿物的探索实验: 2013年全国选矿前沿技术与装备大会[C]. 昆明, 2013.HUANG Y. Exploration and experiment on recovery of fine minerals by flotation column: 2013 National Conference on Frontier Technology and equipment for Beneficiation[C]. Kunming, 2013.

    Google Scholar

    HUANG Y. Exploration and experiment on recovery of fine minerals by flotation column: 2013 National Conference on Frontier Technology and equipment for Beneficiation[C]. Kunming, 2013.

    Google Scholar

    [13] 赵敏捷, 方建军, 李国栋, 等. 旋流-静态微泡浮选柱的应用及研究进展[J]. 矿产综合利用, 2016(4): 6-10.ZHAO M J, FANG J J , LI G D, et al. State and application of cyclonic static microbubble flotationcolumn [J]. Multipurpose Utilization of Mineral Resources, 2016, No. 200(4): 6-10.

    Google Scholar

    ZHAO M J, FANG J J , LI G D, et al. State and application of cyclonic static microbubble flotationcolumn [J]. Multipurpose Utilization of Mineral Resources, 2016, No. 200(4): 6-10.

    Google Scholar

    [14] 阳华玲, 朱超英, 易峦, 等. 微细粒浮选柱的研究现状及其新进展[J]. 湖南有色金属, 2014, 30(5):11-16.YANG H L, ZHU C Y, YI L, et al. Research present situation and new progress of flotation column for finepaticles[J]. Hunan Nonferrous Metals, 2014, 30(5):11-16.

    Google Scholar

    YANG H L, ZHU C Y, YI L, et al. Research present situation and new progress of flotation column for finepaticles[J]. Hunan Nonferrous Metals, 2014, 30(5):11-16.

    Google Scholar

    [15] ZHANG X H, QUINN A, DUCKER W A. Nanobubbles at the interface between water and a hydrophobic solid[J]. Langmuir, 2008, 24(9):4756-4764. doi: 10.1021/la703475q

    CrossRef Google Scholar

    [16] ZHAO B, WANG X, WANG S, et al. In situ measurement of contact angles and surface tensions of interfacial nanobubbles in ethanol aqueous solutions[J]. Soft Matter, 2016, 12(14):3303-3309. doi: 10.1039/C5SM02871J

    CrossRef Google Scholar

    [17] FANG Z, WANG X, ZHOU L, et al. Formation and stability of bulk nanobubbles by vibration[J]. Langmuir, 2020, 36(9):2264-2270. doi: 10.1021/acs.langmuir.0c00036

    CrossRef Google Scholar

    [18] YANG J, DUAN J, FORNASIERO D, et al. Very small bubble formation at the solid− water interface[J]. The Journal of Physical Chemistry B, 2003, 107(25):6139-6147. doi: 10.1021/jp0224113

    CrossRef Google Scholar

    [19] ZHOU L, WANG X, SHIN H, et al. Ultrahigh density of gas molecules confined in surface nanobubbles in ambient water[J]. Journal of the American Chemical Society, 2020, 142(12):5583-5593. doi: 10.1021/jacs.9b11303

    CrossRef Google Scholar

    [20] 王硕. 纳米气泡的稳定性及其内部密度的测量[D]. 上海: 中国科学院大学(中国科学院上海应用物理研究所), 2018.WANG S. Stability of nano-bubbles and measurement of their internal density [D]. Shanghai: University of Chinese Academy of Sciences (Shanghai Institute of Applied Physics, Chinese Academy of Sciences), 2018.

    Google Scholar

    WANG S. Stability of nano-bubbles and measurement of their internal density [D]. Shanghai: University of Chinese Academy of Sciences (Shanghai Institute of Applied Physics, Chinese Academy of Sciences), 2018.

    Google Scholar

    [21] CHUN-LEI W, ZHAO-XIA L, JING-YUAN L, et al. High density gas state at water/graphite interface studied by molecular dynamics simulation[J]. Chinese Physics B, 2008, 17(7):2646. doi: 10.1088/1674-1056/17/7/049

    CrossRef Google Scholar

    [22] ZHANG X, CHAN D Y C, WANG D, et al. Stability of interfacial nanobubbles[J]. Langmuir, 2013, 29(4):1017-1023. doi: 10.1021/la303837c

    CrossRef Google Scholar

    [23] GUO Z, WANG X, ZHANG X. Stability of surface nanobubbles without contact line pinning[J]. Langmuir, 2019, 35(25):8482-8489.

    Google Scholar

    [24] MICHAILIDI E D, BOMIS G, VAROUTOGLOU A, et al. Bulk nanobubbles: Production and investigation of their formation/stability mechanism[J]. Journal of Colloid and Interface Science, 2020, 564:371-380. doi: 10.1016/j.jcis.2019.12.093

    CrossRef Google Scholar

    [25] NIRMALKAR N, PACEK A W, BARIGOU M. On the existence and stability of bulk nanobubbles[J]. Langmuir, 2018, 34(37):10964-10973. doi: 10.1021/acs.langmuir.8b01163

    CrossRef Google Scholar

    [26] ZHANG X, WANG Q, WU Z, et al. An experimental study on size distribution and zeta potential of bulk cavitation nanobubbles[J]. International Journal of Minerals, Metallurgy and Materials, 2020, 27(2):152-161. doi: 10.1007/s12613-019-1936-0

    CrossRef Google Scholar

    [27] TAO Y, LIU J, YU S, et al. Picobubble enhanced fine coal flotation[J]. Separation Science and Technology, 2006, 41(16):3597-3607. doi: 10.1080/01496390600957249

    CrossRef Google Scholar

    [28] FAN M, TAO D. A study on picobubble enhanced coarse phosphate froth flotation[J]. Separation Science and Technology, 2008, 43(1):1-10. doi: 10.1080/01496390701747853

    CrossRef Google Scholar

    [29] 李军,孙健翔,许泽胜,等. 微硅粉浮选中的纳米气泡稳定性及协同作用的讨论[J]. 矿业科学学报, 2022, 7(6):763-769.LI J, SUN J X, XU Z S, et al. On stability and synergistic effect of nano-bubbles in micro-silica flotation[J]. Journal of Mining Science and Technology, 2022, 7(6):763-769. doi: 10.19606/j.cnki.jmst.2022.06.013

    CrossRef Google Scholar

    LI J, SUN J X, XU Z S, et al. On stability and synergistic effect of nano-bubbles in micro-silica flotation[J]. Journal of Mining Science and Technology, 2022, 7(6):763-769. doi: 10.19606/j.cnki.jmst.2022.06.013

    CrossRef Google Scholar

    [30] 刘子帅, 李宁钧. 微细粒钨锡矿物选矿技术研究现状及进展[J]. 矿产综合利用, 2017(2):12-14+7.LIU Z S, LI N J. Research status and development of mineral processing technology of fine grain tungsten tin ore[J]. Multipurpose Utilization of Mineral Resources, 2017(2):12-14+7.

    Google Scholar

    LIU Z S, LI N J. Research status and development of mineral processing technology of fine grain tungsten tin ore[J]. Multipurpose Utilization of Mineral Resources, 2017(2):12-14+7.

    Google Scholar

    [31] TAO D, WU Z, SOBHY A. Investigation of nanobubble enhanced reverse anionic flotation of hematite and associated mechanisms[J]. Powder Technology, 2021, 379:12-25. doi: 10.1016/j.powtec.2020.10.040

    CrossRef Google Scholar

    [32] SOBHY A, TAO D. High-efficiency nanobubble coal flotation[J]. International Journal of Coal Preparation and Utilization, 2013, 33(5):242-256. doi: 10.1080/19392699.2013.810623

    CrossRef Google Scholar

    [33] MA F, TAO D, TAO Y. Effects of nanobubbles in column flotation of Chinese sub-bituminous coal[J]. International Journal of Coal Preparation and Utilization, 2019: 1-17.

    Google Scholar

    [34] TAO D, FAN M, WU Z, et al. Investigation of effects of nanobubbles on phosphate ore flotation[J]. International Journal of Georesources and Environment-IJGE (formerly Int'l J of Geohazards and Environment), 2018, 4(3):133-140.

    Google Scholar

    [35] 曾维能, 任浏祎, 魏鹏刚, 等. 微纳米气泡对典型细粒氧化矿物浮选的影响及机理[J]. 金属矿山, 2020(10): 156-160.ZENG W N, REN L Y, WEI P G, et al. Effects and mechanism of micro-nano bubbles on typical fine oxidized minerals flotation [J]. Metal Mine, 2020 (10): 156-160.

    Google Scholar

    ZENG W N, REN L Y, WEI P G, et al. Effects and mechanism of micro-nano bubbles on typical fine oxidized minerals flotation [J]. Metal Mine, 2020 (10): 156-160.

    Google Scholar

    [36] NAZARI S, SHAFAEI S Z, SHAHBAZI B, et al. Study relationships between flotation variables and recovery of coarse particles in the absence and presence of nanobubble[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2018, 559:284-288.

    Google Scholar

    [37] ZHANG Z, REN L, ZHANG Y. Role of nanobubbles in the flotation of fine rutile particles[J]. Minerals Engineering, 2021, 172.

    Google Scholar

    [38] MA F, TAO D, TAO Y, et al. An innovative flake graphite upgrading process based on HPGR, stirred grinding mill, and nanobubble column flotation[J]. International Journal of Mining Science and Technology, 2021.

    Google Scholar

    [39] 荆树励, 李梅, 冉宇, 等. 微纳米气泡对细粒稀土矿物聚团行为的影响[J]. 矿业研究与开发, 2019, 39(3):113-117.JING S L, LI M, RAN Y, et al. Effect of micro-nano bubbles on aggregation behavior of fine-grain rare earth minerals[J]. Mining Research and Development, 2019, 39(3):113-117.

    Google Scholar

    JING S L, LI M, RAN Y, et al. Effect of micro-nano bubbles on aggregation behavior of fine-grain rare earth minerals[J]. Mining Research and Development, 2019, 39(3):113-117.

    Google Scholar

    [40] 李军, 刘佳, 孙健翔, 等. 浮选法对非晶微硅粉提纯效果的研究[J]. 选煤技术, 2021(1): 136-141.LI J, LIU J, SUN J X, et al. Study on the effects of purification of noncrystallinemicro silica powder using flotation process [J]. Coal Preparation Technology, 2021 (1): 136-141.

    Google Scholar

    LI J, LIU J, SUN J X, et al. Study on the effects of purification of noncrystallinemicro silica powder using flotation process [J]. Coal Preparation Technology, 2021 (1): 136-141.

    Google Scholar

    [41] LIANG Y, ZHOU C, GUO Z, et al. Removal of cadmium, lead, and zinc from multi-metal–contaminated soil using chelate-assisted sedum alfredii hance[J]. Environmental Science and Pollution Research, 2019, 26(27):28319-28327. doi: 10.1007/s11356-019-06041-w

    CrossRef Google Scholar

    [42] 傅开彬, 秦天邦, 龙美樵, 等. 应用纳米气泡气浮应急修复重金属污染土壤[J]. 金属矿山, 2020(4):200-205.FU K B, QIN T B, LONG M Q, et al. Emergency remediation of heavy metal contaminated soil by nanobubbles flotation[J]. Metal Mine, 2020(4):200-205.

    Google Scholar

    FU K B, QIN T B, LONG M Q, et al. Emergency remediation of heavy metal contaminated soil by nanobubbles flotation[J]. Metal Mine, 2020(4):200-205.

    Google Scholar

    [43] KLANČNIK M. Coagulation and adsorption treatment of printing ink wastewater[J]. Acta Graphica: Znanstveni Časopis Za Tiskarstvo I Grafičke Komunikacije, 2014, 25(3-4):73-82.

    Google Scholar

    [44] LIU S, WANG Q, MA H, et al. Effect of micro-bubbles on coagulation flotation process of dyeing wastewater[J]. Separation and Purification Technology, 2010, 71(3):337-346. doi: 10.1016/j.seppur.2009.12.021

    CrossRef Google Scholar

    [45] 李臣威, 张海军. 纳米气泡对锂电池电极材料浮选行为的影响[J]. 煤炭学报, 2021(S1):1-9.LI C W, ZHANG H J. Influence of nanobubbles on flotation behavior of electrode materials from spent lithium ions batteries[J]. Journal of China Coal Society, 2021(S1):1-9.

    Google Scholar

    LI C W, ZHANG H J. Influence of nanobubbles on flotation behavior of electrode materials from spent lithium ions batteries[J]. Journal of China Coal Society, 2021(S1):1-9.

    Google Scholar

  • 加载中
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Figures(6)

Article Metrics

Article views(1339) PDF downloads(315) Cited by(0)

Access History

Other Articles By Authors

Catalog

    /

    DownLoad:  Full-Size Img  PowerPoint